Studies of the formation process of water-in-oil emulsions   总被引：2，自引：0，他引：2  

Fingas M  Fieldhouse B 《Marine pollution bulletin》2003,47(9-12):369-396

This paper summarizes studies to determine the formation process of water-in-oil emulsions and the stability of such emulsions formed in the laboratory and in a large test tank. These studies have confirmed that water-in-oil mixtures can be grouped into four states: stable emulsions, unstable water-in-oil mixtures, mesostable emulsions, and entrained water. These states are differentiated by rheological properties as well as by differences in visual appearance. The viscosity of a stable emulsion at a shear rate of one reciprocal second is about three orders of magnitude greater than that of the starting oil. An unstable emulsion usually has a viscosity no more than about 20 times greater than that of the starting oil. A stable emulsion has a significant elasticity, whereas an unstable emulsion does not. A mesostable emulsion has properties between stable and unstable, but breaks down within a few days of standing. The usual situation is that emulsions are either obviously stable, mesostable, or unstable. Entrained water, water suspended in oil by viscous forces alone, is also evident. Very few emulsions have questionable stability. Analytical techniques were developed to test these observations.

The type of emulsion produced is determined primarily by the properties of the starting oil. The most important of these properties are the asphaltene and resin content and the viscosity of the oil. The composition and property ranges of the starting oil that would be required to form each of the water-in-oil states are discussed in this paper.  相似文献   

Fishing for diplomacy in China's Seas     

Morton B 《Marine pollution bulletin》2003,46(7):795-796

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Hong Kong's gloom and doom     

Morton B 《Marine pollution bulletin》2003,46(11):1359-1360

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Spatial and temporal trend of sewage pollution indicated by coprostanol in Macao Estuary,southern China   总被引：1，自引：0，他引：1  

Peng X  Zhang G  Mai B  Min Y  Wang Z 《Marine pollution bulletin》2002,45(1-12):295-299

Bottom sediments and a ²¹⁰Pb dated sedimentary core in Macao Estuary were quantitatively analyzed with GC-MS for coprostanol and other sterols. Higher coprostanol concentrations were detected at Port Interior and Lower Qianshan River, indicative of serious sewage pollution from densely populated Macao Island and Zhuhai City. However, very low concentrations of coprostanol were detected around Coloane Island as well as Port Exterior and Maliuzhou River except sites adjacent sewage outlets. Coprostanol pollution in Macao Estuary originates mainly from locally direct discharge of untreated wastewater. The concentrations of coprostanol in ZJ-9 were mainly in range of 150–280 ng/g with an average of 210 ng/g for more than 20 years from early 1970s to early 1990s. However, it increased obviously since 1993, and reached the highest in 1995–1996. However, a sharp decrease of coprostanol concentration from 470 to 31 ng/g after 1996 was observed corresponding to the first wastewater treatment plant in Taipa Island going into action.  相似文献   

The influence of diet on comparative trace metal cadmium,copper and zinc accumulation in Thais clavigera (Gastropoda: Muricidae) preying on intertidal barnacles or mussels     

Blackmore G  Morton B 《Marine pollution bulletin》2002,44(9):870-876

The influence of diet on comparative metal accumulation was investigated using a predatory muricid gastropod Thais clavigera. Individuals were fed for up to 56 days on either barnacles, i.e., Tetraclita squamosa, or mussels, i.e., Perna viridis, collected from metal-contaminated and clean sites. Barnacles and mussels have contrasting metal handling strategies and, therefore, different body concentrations, intracellular distributions and detoxification systems. Field collection of prey items that accumulated body metal concentrations over a lifetime of exposure allowed bioavailability to the predator, T. clavigera, to be assessed naturally, which may not be the case for prey exposed to metals for a short time in the laboratory. T. clavigera that was fed cadmium- and copper-contaminated barnacles or mussels ingested significantly greater amounts compared to those fed conspecifics collected from clean locations. T. clavigera body cadmium and copper concentrations were not, however, significantly different between individuals fed either contaminated or clean prey. Amount of zinc ingested was similar in mussels collected from clean and contaminated environments but much less when compared to the barnacle prey. The body concentrations of zinc in T. clavigera fed mussels collected from both sites fell. In contrast, the amount of zinc ingested from barnacle prey was significantly greater from those collected from the metal-contaminated site as compared to the clean one. This was reflected as significantly greater body zinc concentrations in T. clavigera fed contaminated barnacles compared to those fed clean individuals. Copper and zinc accumulation from prey was, therefore, complex. It varied between metal and between prey type, but appeared to be related to the amount ingested and the metal handling strategy of the prey.  相似文献   

Analyses of organic and inorganic contaminants in Salton Sea fish   总被引：3，自引：0，他引：3  

Riedel R  Schlenk D  Frank D  Costa-Pierce B 《Marine pollution bulletin》2002,44(5):403-411

Chemical contamination of fish from the Salton Sea, a quasi-marine lake in Southern California, could adversely impact millions of birds using the Pacific Flyway and thousands of humans using the lake for recreation. Bairdiella icistia (bairdiella), Cynoscion xanthulus (orangemouth corvina), and Oreochromis spp. (tilapia) were sampled from two river mouths and two nearshore areas of the Salton Sea. Muscle tissues were analyzed for a complete suite of 14 trace metals and 53 pesticides. Fish muscle tissues had concentrations of selenium ranging between 1.89 and 2.73 microg/g wet weight. 4,4'-DDE accounted for 94% of the total DDT metabolites. Total DDTs ranged between 17.1 and 239.0 and total PCBs between 2.5 and 18.6 ng/g wet weight. PCB congeners 132, 138, 153, 168, and 180 comprised over 50% of the total PCBs. Given the potential implementation of a commercial fishing at the Salton Sea in the future, the presence of persistent organic pollutants and selenium warrants further research into the effects of these mixtures on fish populations, and on wildlife and humans consuming fish.  相似文献   

High Magnetic Field Pulsars and Magnetars: A Unified Picture     

Zhang B  Harding AK 《The Astrophysical journal》2000,535(1):L51-L54

We propose a unified picture of high magnetic field radio pulsars and magnetars by arguing that they are all rotating high-field neutron stars but that their magnetic axes have different orientations with respect to their rotation axes. In strong magnetic fields where photon splitting suppresses pair creation near the surface, the high-field pulsars can have active inner accelerators while the anomalous X-ray pulsars cannot. This can account for the very different observed emission characteristics of the anomalous X-ray pulsar 1E 2259+586 and the high-field radio pulsar PSR J1814-1744. A predicted consequence of this picture is that radio pulsars having surface magnetic fields greater than about 2x1014 G should not exist.  相似文献   

Detection of 33.8 Millisecond X-Ray Pulsations in SAX J0635+0533     

Cusumano G  Maccarone MC  Nicastro L  Sacco B  Kaaret P 《The Astrophysical journal》2000,535(1):L25-L28

Recently, detection of discrete features in the X-ray afterglow spectra of GRB 970508 and GRB 970828 was reported. The most natural interpretation of these features is that they are redshifted Fe K emission complexes. The identification of the line emission mechanism has drastic implications for the inferred mass of radiating material and hence the nature of the burst site. X-ray spectroscopy provides a direct observational constraint on these properties of gamma-ray bursters. We briefly discuss how these constraints arise in the context of an application to the spectrum of GRB 970508.  相似文献   

Large Magellanic Cloud Planetary Nebula Morphology: Probing Stellar Populations and Evolution     

Stanghellini L  Shaw RA  Balick B  Blades JC 《The Astrophysical journal》2000,534(2):L167-L171

Planetary nebulae (PNe) in the Large Magellanic Cloud (LMC) offer the unique opportunity to study both the population and evolution of low- and intermediate-mass stars, by means of the morphological type of the nebula. Using observations from our LMC PN morphological survey, and including images available in the Hubble Space Telescope Data Archive and published chemical abundances, we find that asymmetry in PNe is strongly correlated with a younger stellar population, as indicated by the abundance of elements that are unaltered by stellar evolution (Ne, Ar, and S). While similar results have been obtained for Galactic PNe, this is the first demonstration of the relationship for extragalactic PNe. We also examine the relation between morphology and abundance of the products of stellar evolution. We found that asymmetric PNe have higher nitrogen and lower carbon abundances than symmetric PNe. Our two main results are broadly consistent with the predictions of stellar evolution if the progenitors of asymmetric PNe have on average larger masses than the progenitors of symmetric PNe. The results bear on the question of formation mechanisms for asymmetric PNe-specifically, that the genesis of PNe structure should relate strongly to the population type, and by inference the mass, of the progenitor star and less strongly on whether the central star is a member of a close binary system.  相似文献   

SEDIMENT YIELD AND HYDROLOGY IN NORTHWESTERN RANGELANDS     

Charles W. Slaughter 《国际泥沙研究》2000,(2)

lINTRODUCTIONRangeandforestlandsofnorthwesternNorthAmericahavebeenutilizedforres0urceextracti0nandproductionsinceinitialhuman0ccupationofthecontinent.Intensive"managed"utilizati0nofec0systemsforspecificbenefitsincludingcattle,sheep,t1sh,w00dandagriculturalpr0ductshasbeenong0ingfornearly0ne-and-haIfcenturies.Intensiveresourceproducti0nhasto0oftenbeenacc0mpaniedbyunwanted"sideeffects"includingacceleratederosion,s0illossandsedimentdeliveredoffsitetod0wnstreamlocati0ns,estuariesandoceanicsin…  相似文献