Dissolution, solution transfer, diffusion versus fluid flow and volume loss during deformation/metamorphism   总被引：2，自引：0，他引：2  

T. H. BELL  C. CUFF 《Journal of Metamorphic Geology》1989,7(4):425-447

ABSTRACT Dissolution and solution transfer during deformation/metamorphism are controlled by the partitioning of deformation into progressive shearing and shortening components. Progressive shearing is readily accommodated by slip on the planar crystal structure of phyllosilicates and graphite without accumulating dislocation density gradients across grain boundaries. Progressive shortening is accommodated by the cores of most other minerals (including sulphides). These minerals develop strain, and hence dislocation density gradients, on their rims due to progressive shearing along grain boundaries. These gradients are particularly large when the mineral abuts phyllosilicate or graphite. The resulting chemical potential gradients between the core and rim drive dissolution, causing removal of the highly strained grain margins. Removal of dissolved material by solution transfer is aided by the geometry of shearing of phyllosilicates and graphite around other grains in an active anastomosing foliation. Interlayers and interfaces on boundaries lying at a low angle to the direction of shearing, and oriented relative to the sense of shear such that they can open, gape by small amounts. Water present in these interlayer spaces becomes destructured, considerably enhancing diffusion rates along the foliation. Penetrative volume loss, especially in deforming/metamorphosing pelitic rocks, is large at all metamorphic grades, increasing and becoming more penetrative with depth to at least the transition into granulite and eclogite facies. Transference of material by fluid flow from deep to high levels in the earth's crust is precluded because thousands to tens of thousands of rock volumes of fluid are required, necessitating continual recirculation of fluid from shallow to deep crustal levels in one large or several small sets of cells, unless some extremely large-scale form of fluid channelling is possible. Reassessment of diffusion mechanisms, and hence rates, during deformation and pervasive foliation generation in large volumes of rock where fluid channeling cannot provide enough fluid, indicates that diffusion can proceed with sufficient rapidity that massive recirculation of fluid is no longer required. The amount of fluid can be reduced sufficiently to allow large volume losses by a one-way flow of fluid to the earth's surface, in deforming/metamorphosing environments where the fluid pressure equals or exceeds the hydrostatic pressure. Deformation partitioning-controlled dissolution progressively changes the bulk chemistry of a rock containing phyllosilicates or graphite during deformation/metamorphism because matrix minerals, other than phyllosilicates and graphite, are preferentially removed. The large size of porphyroblasts, if present, tends to preserve them from dissolution. Hence, the bulk chemistry operative during subsequent porphyroblast growth can have changed considerably from that operative when the first porphyroblasts grew, in rocks in which bedding is still well preserved.  相似文献   

Strontium Isotopic Studies of Alkalic Rocks: The Potassium-rich Lavas of the Birunga and Toro--Ankole Regions, East and Central Equatorial Africa     

BELL  KEITH; POWELL  J. L. 《Journal of Petrology》1969,10(3):536-572

The present-day Sr⁸⁷/Sr⁸⁶ ratios of 117 representative samplesfrom the Birunga and Toro-Ankole regions vary significantlyand range between 0.7036 and 0.7111. The feldspar-bearing lavashave higher ratios (average = 0.707) than the melilite- andnepheline-bearing varieties (average = 0.705). Samples of carbonatedlavas have slightly lower Sr⁸⁷/Sr⁸⁶ ratios. The Sr⁸⁷/Sr⁸⁶ ratios show a highly significant, positive, linearcorrelation with Rb/Sr ratio, and a negative correlation withSr, Nb, and Zr abundances. Graphs of Sr⁸⁷/Sr⁸⁶ ratios againstelemental abundances in some cases give hyperbolic patterns.Such relationships are true, not only for the volcanic fieldas a whole, but also for lava flows from one extensively sampledvolcano. Hypotheses involving simple fractional crystallization or limestonesyntexis are inconsistent with the isotopic data. The elementaland isotopic abundance patterns are most easily explained bythe mixing of two end members of quite different Sr isotopicand chemical compositions. If mixing is assumed, approximatelimits can be set for the compositions of the two end members.These limits are consistent with the hypothesis of assimilationof sialic material by either a carbonatitic or nepheliniticparent magma.  相似文献   

Petrogenesis of Group I Kimberlites from Kimberley, South Africa: Evidence from Bulk-rock Geochemistry   总被引：8，自引：6，他引：8  

LE ROEX  ANTON P.; BELL  DAVID R.; DAVIS  PETER 《Journal of Petrology》2003,44(12):2261-2286

Fresh samples of hypabyssal kimberlite from the five major kimberlitepipes in the Kimberley area of South Africa have been analysedfor their bulk-rock major and trace element geochemistry. Thegeochemical data allow identification of the influence of crustalcontamination in certain samples, best illustrated in termsof elevated SiO₂, Al₂O₃, Pb and heavy rare earth element (HREE)contents. Samples devoid of such crustal contamination showcoherent major and fluid-immobile trace element variations,whereas fluid-mobile trace elements are scattered. Kimberlitesrich in macrocrysts are shown to reflect substantial (up to35%) entrainment of mantle peridotite, with Ni–SiO₂ andSc–SiO₂ variations defining mixing trajectories towardsgarnet lherzolite. The likely primary magma(s) parental to theKimberley kimberlites is suggested to have a composition of26–27 wt % MgO, 26–27 wt % SiO₂,  相似文献   

Isotopic and Geochemical Investigation of the Chilwa Island Carbonatite Complex, Malawi: Evidence for a Depleted Mantle Source Region, Liquid Immiscibility, and Open-System Behaviour   总被引：2，自引：0，他引：2  

SIMONETTI  A.; BELL  K. 《Journal of Petrology》1994,35(6):1597-1621

Initial Nd, Pb, and Sr isotopic data from carbonatites and associatedintrusive silica-undersaturated rocks from the early Jurassic,Chilwa Island complex, located in southern Malawi, central Africa,suggest melt derivation from a Rb/Sr- and Nd/Sm-depleted butTh/Pb- and U/Pb-enriched mantle source. Initial ¹⁴³Nd/¹⁴⁴Nd(0.51265–0.51270) isotope ratios from the Chilwa Islandcarbonatites are relatively constant, but their initial ⁸⁷Sr/⁸⁶Sr(0.70319–0.70361) ratios are variable. The ¹⁸O_smow (9.53–14.15%0)and ¹³C_PDB (–3.27 to –1.50%0) isotope ratios ofthe carbonates are enriched relative to the range of mantlevalues, and there is a negative correlation between ¹⁸O andSr isotope ratios. The variations in Sr, C, and O isotopic ratiosfrom the carbonatites suggest secondary processes, such as interactionwith meteoric groundwater during late-stage carbonatite activity.The initial ¹⁴³Nd/¹⁴⁴Nd (0.51246 0.51269) and initial ⁸⁷Sr/⁸⁶Sr(0.70344–0.70383) isotope ratios from the intrusive silicaterocks are more variable, and the Sr more radiogenic than thosefrom the carbonatites. Most of the Pb isotope data from Chilwa Island plot to the rightof the geochron and close to the oceanic regression line definedby MORBs and OIBs. Initial Pb isotopic ratios from both carbonatites(²⁰⁷Pb/²⁰⁴Pb 15.63–15.71; ²⁰⁶Pb/²⁰⁴Pb 19.13–19.78)and silicate rocks (²⁰⁷Pb/²⁰⁴Pb 15.61–15.72; ²⁰⁶Pb/²⁰⁴Pb18.18–20.12) show pronounced variations, and form twogroups in Pb-Pb plots. The isotopic variations shown by Nd, Pb, and Sr for the ChilwaIsland carbonatites and intrusive silicates suggest that thesemelts underwent different evolutionary histories. The chemicaldata, including isotopic ratios, from the carbonatites and olivinenephelinites are consistent with magmatic differentiation ofa carbonated-nephelinite magma. A model is proposed in whichdifferentiation of the carbonatite magma was accompanied byfenitization (metasomatic alteration) of the country rocks bycarbonatite-derived fluids, and subsequent alteration of thecarbonatite by hydrothermal activity. The chemical and isotopicdata from the non-nephelinitic intrusive silicate rocks reveala more complex evolutionary history, involving either selectivebinary mixing of lower-crustal granulites and a nephelinitemagma, or incremental batch melting of a depleted source andsubsequent crustal contamination.  相似文献   

PUNCTUATED DRAINAGE OF AN ICE-DAMMED QUATERNARY LAKE IN SOUTHERN SOUTH AMERICA     

C.M. BELL 《Geografiska Annaler: Series A, Physical Geography》2008,90(1):1-17

A chain of east‐west elongated lakes fringes the eastern flank of the Andes Mountains between 39 and 52°S in southern Chile and Argentina. These deep lakes fill valleys left by the retreat of outlet glaciers of the Patagonian Icefield about 16000 years ago. Two of the lakes, Lago General Carrera/Buenos Aires and Lago Cochrane, represent the shrunken remnants of a much larger lake (called here the predecessor lake) that developed in a moat alongside the icefield. A series of seven stepped lacustrine braid deltas on the southeastern shore of Lago General Carrera/Buenos Aires mark the progressive, punctuated drainage of the predecessor lake. The deltas were formed by the build‐out of fans of sand and gravel into the lake. They have the form of Gilbert deltas, with virtually flat subaerial topset beds and steeply inclined subaqueous foreset beds. The exposed delta fronts are marked by a series of small terraces produced by wave erosion during falling lake levels. On either side of the fans are embayments with beaches formed by deposition in the lee of the pro‐grading fans. These embayments are filled with ridges of well‐sorted gravel deposited by wave‐driven long‐shore drift. About 13 000 years ago the regional drainage underwent a remarkable change. Rivers flowing eastwards into the Atlantic reversed their direction to flow westwards through the Andes Mountains and into the Pacific Ocean. The watershed moved some 200 km to the east. The cause of this change, and the falling lake levels, was melting of the Patagonian Icefield. As the ice retreated the icefield split into north and south components. This broke the ice dam that impounded the western end of the predecessor lake. The stepped, progressive fall of the lake level suggests that as the ice melted a series of lower overflow sills of hard rock were exposed. Each of the major episodes of sudden drop in lake level was followed by a long period of up to thousands of years when lake level remained constant. Terraces on the delta fronts indicate that each major episode of fall in the lake level was punctuated by up to ten minor episodes possibly representing major storm events or annual cycles of freezing and melting, blocking the overflow sills.  相似文献   

The relationships between sedimentary structures, transport directions and dune types in Mesozoic aeolian sandstones, Atacama Region, Chile     

C. M. BELL 《Sedimentology》1991,38(2):289-300

Extensive occurrences of Upper Jurassic to Lower Cretaceous aeolian sandstones form part of a thick sequence of terrigenous red beds in northern Chile. These sediments accumulated in a N-S-elongated intermontane back-arc basin on the landward side of an active volcanic chain. This volcanic chain, which was produced by subduction beneath the continental margin, provided the source of almost all the clastic sediments. The aeolian sands formed isolated dune fields covering only part of the depositional basin at any one time. Cosets of cross-bedded sandstone up to 40 m thick represent the deposits of linear draas. Cross-bedded sets, which average between 0.5 and 1 m in thickness, were produced by the migration of small dunes down and along the gentle lee slopes of the draas. The majority of foreset laminations in the cross-bedded sets are thin, parallel and persistent. They are the product of the lateral migration of dunes which developed oblique to the prevailing winds. Foreset laminations dip at low angles (averaging 19°), well below the angle of repose of dry sand. Most of the laminations originated by tractional processes, rather than by grainflow (avalanching) or grainfall. This conclusion indicates that the dunes were gently undulating with no slip faces. The orientation of the direction of maximum dip of foreset laminations does not provide a reliable indicator of the palaeowind direction. Although individual sets or cosets commonly show a unidirectional pattern, significant variations have been recorded between sets of the same age at nearby locations and vertically between one coset and the next. Variations in vertical sections were produced by the superimposition of draas with different orientations.  相似文献   

Episodic metamorphic reactions during orogenesis: the control of deformation partitioning on reaction sites and reaction duration   总被引：1，自引：0，他引：1  

T. H. BELL  N. HAYWARD 《Journal of Metamorphic Geology》1991,9(5):619-640

Abstract Textural ‘unconformities’or truncations are common in porphyroblasts with complex inclusion trails. They reflect cycles of successive foliations that develop against competent porphyroblasts during orogenesis and are preserved by successive growth increments. Their truncational character results from shear and dissolution along a particular foliation generating a differentiated crenulation cleavage. The increment of porphyroblast growth that follows a textural ‘unconformity’may or may not mark a significant compositional change, depending on the amount of movement of the rock through P–T space between cleavage-forming events. Although historically interpreted to result from a significant metamorphic hiatus, most textural unconformities indicate that the reactions involved in the formation of these minerals are episodic during continuous prograde metamorphism, starting and stopping as a function of the stage of crenulation of the matrix foliation and the pattern of deformation partitioning. Such episodic reaction behaviour can only occur for multivariant reactions, or successive but different univariant reactions. The reason why garnet is the most common porphyroblast to exhibit evidence for episodic reactions is probably the fact that it grows by multivariant reactions over a much wider P–T range than most other common porphyroblast phases. Porphyroblast growth is micrometasomatic. It is episodic because a significant reduction of strain occurs within domains of progressive shortening each time continuous progressive shearing domains form on their margins. This stops microfracture development across the progressive shortening domains, thereby preventing rapid access and interaction of fluid, ions and complexes with porphyroblast boundaries. Shifting patterns of deformation partitioning and resulting small-scale juxtaposition of different compositional layers spreads the duration and location of multivariant reactions and causes differential timing of porphyroblast growth along a particular stratigraphic horizon. It may also locally preserve metastable metamorphic assemblages. In regionally metamorphosing/deforming pelites, near-simultaneous cessation of porphyroblast growth on all rims, once continuous differentiated progressive shearing domains have formed nearby, precludes fluid recirculation as a significant process for removal of material during cleavage development. Alternatively, diffusion of simple molecules and dissociated ions along actively shearing and micro-gaped phyllosilicates, with recomplexing in fluid-filled microfractures, readily explains the control of deformation partitioning on reaction site and reaction duration.  相似文献   

The inter‐relationships between long‐lived metamorphism,pluton emplacement and changes in the direction of bulk shortening during orogenesis     

I. V. SANISLAV  T. H. BELL 《Journal of Metamorphic Geology》2011,29(5):513-536

Foliation intersection/inflexion axes combined with pseudosections and garnet‐core isopleths reveal only 1.5 kbar variation in P–T conditions while plutons were emplaced regionally and deformation and metamorphism continued during orogenesis lasting 70 Myr. Tectonism ended with slight decompression into the cordierite stability field. Garnet growth was always overstepped by up to 100 °C occurring at conditions that staurolite growth was also possible. Episodic start, stop, start growth behaviour of both of these phases throughout this period did not result from the effects of bulk composition on their stability fields. Different porphyroblast growth patterns in same bulk composition and outcrop samples reveals reaction start/stop behaviour was controlled by the manner in which deformation partitioned through an outcrop. The regional isograds were established during the first period of bulk shortening near orthogonal to the orogen trend. They did not migrate across lower grade rocks during each of the subsequent periods of metamorphism in spite of dramatic changes in the direction of bulk shortening; rather they contracted slightly. During the youngest periods of orogenesis directed at a high angle to the current orogen trend the isograds were folded about axial planes parallel to the fold belt. The regional distribution of these isograds directly reflects the oldest period of pluton emplacement, with both controlled by orogen‐scale partitioning of bulk shortening at a high angle to the current orogen trend relative to intervening zones of transform‐like shear.  相似文献   

Abundance and Partitioning of OH in a High-pressure Magmatic System: Megacrysts from the Monastery Kimberlite, South Africa   总被引：9，自引：0，他引：9  

BELL  DAVID R.; ROSSMAN  GEORGE R.; MOORE  RORY O. 《Journal of Petrology》2004,45(8):1539-1564

Concentrations of OH, and major and trace elements were determinedin a suite of mantle-derived megacrysts that represent the crystallizationproducts of a kimberlite-like magma at  相似文献   

A COMPARATIVE STUDY OF GLAUCONITE AND THE ASSOCIATED CLAY FRACTION IN MODERN MARINE SEDIMENTS   总被引：1，自引：0，他引：1  

DAVID L. BELL  H. GRANT GOODELL 《Sedimentology》1967,9(3):169-202

The crystallinity and mineralogy of both the glauconite and the clay fraction of samples from six contemporary marine environments were investigated by X-ray diffraction. In those areas where glauconite is now forming, the mineralogy and the degree of crystallinity of both the glauconite pellets and the associated clay fraction are similar. In contrast, detrital and relic glauconites are observed to have mineralogies that are different from their clay fractions. No consistent relationship was observed between degree of crystallinity and color of the pellets. Further, only two classes of glauconite as defined by BURST (1958) were common: expandable, interlayered clays and two or more clay minerals in a mixed assemblage. Based on the clay fraction-glauconite similarities and other supporting evidence, glauconite on the Scotia Ridge is concluded to be authigenic. Glauconite from Santa Monica Bay, California and from the continental shelf off Morocco appear to be detrital. Glauconite pellets in the shelf sediments off Guinea and the southeastern Atlantic Shelf of the United States are both detrital and authigenic. The poor crystallinity exhibited by the Chatham Rise glauconite is in contrast to the well-crystallized associated clay fraction and indicates that they are not genetically related. However, the origin of this glauconite remains in doubt.  相似文献