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101.
A key question in volcanology is the driving mechanisms of resurgence at active, recently active, and ancient calderas. Valles caldera in New Mexico and Lake City caldera in Colorado are well-studied resurgent structures which provide three crucial clues for understanding the resurgence process. (1) Within the limits of 40Ar/39Ar dating techniques, resurgence and hydrothermal alteration at both calderas occurred very quickly after the caldera-forming eruptions (tens of thousands of years or less). (2) Immediately before and during resurgence, dacite magma was intruded and/or erupted into each system; this magma is chemically distinct from rhyolite magma which was resident in each system. (3) At least 1?km of structural uplift occurred along regional and subsidence faults which were closely associated with shallow intrusions or lava domes of dacite magma. These observations demonstrate that resurgence at these two volcanoes is temporally linked to caldera subsidence, with the upward migration of dacite magma as the driver of resurgence. Recharge of dacite magma occurs as a response to loss of lithostatic load during the caldera-forming eruption. Flow of dacite into the shallow magmatic system is facilitated by regional fault systems which provide pathways for magma ascent. Once the dacite enters the system, it is able to heat, remobilize, and mingle with residual crystal-rich rhyolite remaining in the shallow magma chamber. Dacite and remobilized rhyolite rise buoyantly to form laccoliths by lifting the chamber roof and producing surface resurgent uplift. The resurgent deformation caused by magma ascent fractures the chamber roof, increasing its structural permeability and allowing both rhyolite and dacite magmas to intrude and/or erupt together. This sequence of events also promotes the development of magmatic–hydrothermal systems and ore deposits. Injection of dacite magma into the shallow rhyolite magma chamber provides a source of heat and magmatic volatiles, while resurgent deformation and fracturing increase the permeability of the system. These changes allow magmatic volatiles to rise and meteoric fluids to percolate downward, favouring the development of hydrothermal convection cells which are driven by hot magma. The end result is a vigorous hydrothermal system which is driven by magma recharge.  相似文献   
102.
The 2010-2011 wet season was one of extreme weather for the State of Queensland, Australia. Major rivers adjacent to the Great Barrier Reef (GBR) were discharging at rates 1.5 to >3 times higher than their long term median. Exposure to photosystem II herbicides has been routinely monitored over a period of up to 5 years at 12 inshore GBR sites. The influence of this wet season on exposure to photosystem II herbicides was examined in the context of this long-term monitoring record and during flood plume events in specific regions. Median exposures expressed as diuron equivalent concentration were an average factor of 2.3 times higher but mostly not significantly different (p<0.05) to the median for the long-term monitoring record. The herbicides metolachlor and tebuthiuron were frequently detected in flood plume waters at concentrations that reached or exceeded relevant water quality guidelines (by up to 4.5 times).  相似文献   
103.
104.
We examined the reduction of different size hematite (α-Fe2O3) nanoparticles (average diameter of 11, 12, 30, 43, and 99 nm) by the dissimilatory iron reducing bacteria (DIRB), Shewanella oneidensis MR-1, to determine how S. oneidensis MR-1 may utilize these environmentally relevant solid-phase electron acceptors. The surface-area-normalized-bacterial Fe(III) reduction rate for the larger nanoparticles (99 nm) was one order of magnitude higher than the rate observed for the smallest nanoparticles (11 nm). The Fe(III) reduction rates for the 12, 30, and 43 nm nanoparticles fell between these two extremes. Whole-cell TEM images showed that the mode of Fe2O3 nanoparticle attachment to bacterial cells was different for the aggregated, pseudo-hexagonal/irregular and platey 11, 12, and 99 nm nanoparticles compared to the non-aggregated 30 and 43 nm rhombohedral nanoparticles. Due to differences in aggregation, the 11, 12, and 99 nm nanoparticles exhibited less cell contact and less cell coverage than did the 30 and 43 nm nanoparticles. We hypothesize that S. oneidensis MR-1 employs both indirect and direct mechanisms of electron transfer to Fe(III)-oxide nanoparticles and that the bioreduction mechanisms employed and Fe(III) reduction rates depend on the nanoparticles’ aggregation state, size, shape and exposed crystal faces.  相似文献   
105.
The Kamoa sub‐basin, in the south‐eastern part of the Democratic Republic of Congo, is a rift basin that hosts a world‐class stratiform copper deposit at the base of a very thick (1·8 km) succession of matrix‐supported conglomerates (diamictite) (Grand Conglomérat Formation) that has been interpreted by some as the product of deposition in the aftermath of a planet‐wide glaciation. Newly available subsurface data consisting of more than 300 km of drill core throws new light on the origin of diamictite and associated facies types, and their tectonic, basinal and palaeoclimatic setting. Initiation of rifting is recorded by a lowermost subaqueous succession of fault‐related mass flow conglomerates and breccias (the ‘Poudingue’) with interdigitating coeval and succeeding sandstone turbidites (Mwashya Subgroup). Overlying diamictites of the Grand Conglomérat were deposited as subaqueous debrites produced by mixing and homogenization of antecedent breccias and gravel from the Poudingue and Mwashya sediments with basinal muds. Failure of over‐steepened basin margins and debris flow was likely to be triggered by faulting and seismic activity, and was accompanied by syn‐depositional subaqueous basaltic magmatism recorded by peperites and pillow lavas within diamictites. The thickness of diamictites reflects recurring phases of faulting, volcanism and rapid subsidence allowing continued accommodation of rapidly deposited resedimented facies well below wave base. A distal or indirect, glacial influence in the form of rare dropstones and striated clasts is evident, but tectonically‐driven mass flow destroyed any primary record of glacial climate originally present in basin margin sediments. Such basin margin settings were common during Rodinia rifting and their stratigraphy and facies record a dominant tectonic, rather than climatic, control on sedimentation. Deposition occurred on tectonic timescales inconsistent with a Snowball Earth model for Neoproterozoic diamictites involving a direct glacial contribution to deposition.  相似文献   
106.
Quantifying physical heterogeneity is essential for meaningful ecological research and effective resource management. Spatial patterns of multiple, co-occurring physical features are rarely quantified across a seascape because of methodological challenges. Here, we identified approaches that measured total site-specific heterogeneity, an often overlooked aspect of estuarine ecosystems. Specifically, we examined 23 metrics that quantified four types of common physical features: (1) river and creek confluences, (2) bathymetric variation including underwater drop-offs, (3) land features such as islands/sandbars, and (4) major underwater channel networks. Our research at 40 sites throughout Plum Island Estuary (PIE) provided solutions to two problems. The first problem was that individual metrics that measured heterogeneity of a single physical feature showed different regional patterns. We solved this first problem by combining multiple metrics for a single feature using a within-physical feature cluster analysis. With this approach, we identified sites with four different types of confluences and three different types of underwater drop-offs. The second problem was that when multiple physical features co-occurred, new patterns of total site-specific heterogeneity were created across the seascape. This pattern of total heterogeneity has potential ecological relevance to structure-oriented predators. To address this second problem, we identified sites with similar types of total physical heterogeneity using an across-physical feature cluster analysis. Then, we calculated an additive heterogeneity index, which integrated all physical features at a site. Finally, we tested if site-specific additive heterogeneity index values differed for across-physical feature clusters. In PIE, the sites with the highest additive heterogeneity index values were clustered together and corresponded to sites where a fish predator, adult striped bass (Morone saxatilis), aggregated in a related acoustic tracking study. In summary, we have shown general approaches to quantifying site-specific heterogeneity.  相似文献   
107.
Farewell Spit is a 25 km long barrier spit that marks the end of a littoral drift system, almost 1000 km in length that runs along South Island, New Zealand. The spit is composed of barchan dunes over 20 m high, sand sheets over 1 km wide and vegetated linear dunes. Analysis of aerial photography indicates a rapid colonization of the spit by vegetation which has expanded in area by 75% since 1950. Vegetation colonization preferentially occurs on the southern side of the spit, with its northern margin characterized by barchan dunes which migrate at rates of up to 64 m/yr. Sand sourced from longshore drift appears to be the primary source of beach sediment, which is then transported into the dune field by the persistent westerly winds of the Roaring 40s. While there has been significant dune roll‐over on the surface of the spit, its overall area has remained much the same for the past 54 years. Occasional cyclone events cause erosion, but this is balanced by aeolian sediment transport. It would appear that extension of the subaerial portion of the spit is related to the development of shells banks at its downdrift end which are periodically welded to the main spit by dune extension. Farewell Spit therefore provides an ideal example of a barrier environment where longshore sediment supply and aeolian transport dominates geomorphic evolution. This differentiates the study site from other barrier environments where overwash or tidal inlet development often characterizes recent landform evolution. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献   
108.
Technetium-99 (Tc) is an important fission product contaminant associated with sites of nuclear fuels reprocessing and geologic nuclear waste disposal. Tc is highly mobile in its most oxidized state and less mobile in the reduced form [Tc(IV)O2·nH2O]. Here we investigate the potential for oxidation of Tc(IV) that was heterogeneously reduced by reaction with biogenic Fe(II) in two sediments differing in mineralogy and aggregation state; unconsolidated Pliocene-age fluvial sediment from the upper Ringold (RG) Formation at the Hanford Site and a clay-rich saprolite from the Field Research Center (FRC) background site on the Oak Ridge Site. Both sediments contained Fe(III) and Mn(III/IV) as redox active phases, but FRC also contained mass-dominant Fe-phyllosilicates of different types. Shewanella putrefaciens CN32 reduced Mn(III/IV) oxides and generated Fe(II) that was reactive with Tc(VII) in heat-killed, bioreduced sediment. After bioreduction and heat-killing, biogenic Fe(II) in the FRC exceeded that in RG by a factor of two. More rapid reduction rates were observed in the RG that had lower biogenic Fe(II), and less particle aggregation. EXAFS measurements indicated that the primary reduction product was a TcO2-like phase in both sediments. The biogenic redox product Tc(IV) oxidized rapidly and completely in RG when contacted with air. Oxidation, in contrast, was slow and incomplete in the FRC, in spite of similar molecular scale speciation of Tc compared to RG. X-ray microprobe, electron microprobe, X-ray absorption spectroscopy, and micro X-ray diffraction were applied to the whole sediment and isolated Tc-containing particles. These analyses revealed that non-oxidizable Tc(IV) in the FRC existed as complexes with octahedral Fe(III) within intra-grain domains of 50-100 μm-sized, Fe-containing micas presumptively identified as celadonite. The markedly slower oxidation rates in FRC as compared to RG were attributed to mass-transfer-limited migration of O2 into intra-aggregate and intraparticle domains where Tc(IV) existed; and the formation of unique, oxidation-resistant, intragrain Tc(IV)-Fe(III) molecular species.  相似文献   
109.
The results of the initial deployment of a wideband (40-4000 Hz) vertical acoustic antenna system in the Tongue of the Ocean, the Bahamas are discussed. The instrumentation system consisted of seven octavely nested, four-wavelength linear apertures covering the above frequency range, and a VCR-based subsurface recording system that carried out a programmed sequence of recordings. The objective of the measurement system is the development of a database of directional spectra obtained in an acoustically isolated area where the ambient is principally controlled by the local (observable) sea-surface conditions. The purpose of the database is to identify a model of the space-time statistics of the acoustic ambient caused by sea-surface sound  相似文献   
110.
Review of biostratigraphical evidence from different regions shows that criteria used by workers on various marine fossil groups to define the Santonian-Campanian boundary differ considerably in relative age and position. Probably the most widely recognizable of these criteria is the extinction of the distinctive crinoid Marsupites testudinarius (North America, Europe, Asia, north Africa, Australia), which, coincides exactly with two separate definitions of the boundary - appearances of the ammonite Placenticeras bidorsatum and the belemnite Gonioteuthis granulataquadrata - and may also coincide with a third - entry of the planktic foraminiferan Globotruncana elevata. A comparison of evidence from upper Santonian and lower Campanian successions in widely separated regions allows us to place a series of important biostratigraphical markers in correct order. Defining the boundary at the extinction of M. testudinarius corresponds to a 87Sr/86Sr of 0.707479, and a small positive excursion in δ13C. The base of magnetochron 33R, generally considered to coincide with, or fall just above the base of the Campanian, is shown to lie within the upper Santonian Uintacrinus socialis Zone.  相似文献   
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