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41.
A TEST OF SIGNIFICANCE FOR PARTIAL LEAST SQUARES REGRESSION   总被引:1,自引:0,他引:1  
Partial least squares (PLS) regression is a commonly used statistical technique for performingmultivariate calibration, especially in situations where there are more variables than samples. Choosingthe number of factors to include in a model is a decision that all users of PLS must make, but iscomplicated by the large number of empirical tests available. In most instances predictive ability is themost desired property of a PLS model and so interest has centred on making this choice based on aninternal validation process. A popular approach is the calculation of a cross-validated r~2 to gauge howmuch variance in the dependent variable can be explained from leave-one-out predictions. Using MonteCarlo simulations for different sizes of data set, the influence of chance effects on the cross-validationprocess is investigated. The results are presented as tables of critical values which are compared againstthe values of cross-validated r~2 obtained from the user's own data set. This gives a formal test forpredictive ability of a PLS model with a given number of dimensions.  相似文献   
42.
Luobusaite: A New Mineral   总被引:6,自引:0,他引:6  
A group of mantle minerals including about 70-80 subtypes of minerals are discovered from a podiform chromitite in Tibet, China. Recovered minerals include diamond, coesite, moissanite, wustite, Fe-silides and a new mineral, luobusaite. All of these minerals were hand-picked from heavymineral separates of the podiform chromitite in the mantle peridotite of an ophiolite. The grains of luobusaite are as host mineral with inclusions of native silicon or as an intergrowth with native silicon and Fe-Si phase. Luobusaite occurs as irregular grains, with 0.1-0.2 mm in size, consisting of very finegrained aggregates. The mineral is steel-grey in color, metallic luster, and opaque. The empirical formula (based on 2 for Si) is Fe0.83Si2, according to the chemical compositions of luobusaite. X-ray powder-diffraction data: orthorhombic system, space group Cmca, a = 9.874 (14) A, b = 7.784 (5) A, c= 7.829(7) A, Z=16.  相似文献   
43.
Junction and Evolution of the Qinling, Qilian and Kunlun Orogenic Belts   总被引:2,自引:0,他引:2  
As the main part of the "central mountain system" in the continent of China, the Qinling, Qilian and Kunlun orogenic belts have been comprehensively and deeply studied since the 1970s and rich fruits have been reaped. However, these achievements were mostly confined to an individual orogenic belt and the study of the mutual relationship among the three orogenic belts was obliged to depend on comparative studies. Different views were produced therefrom. The material composition and structural features of the junction region show that there are several epicontinental and intracontinental transform faults developed in different periods. Restricted by these transform faults, the large-scale lateral movements and, as a consequence, complicated magrnatism and tectonic deformation took place in the orogenic belts. According to these features, the authors put forward a three-stage junction and evolution model and point out that there is not a single junction zone traversing from west to east but that the three  相似文献   
44.
Because the cytoplasm of a plant normally degrades after the death of the plant, finding cytoplasm in a plant body after a prolonged period of time, especially in fossil plants, is unexpected. Recent work on several 100-Myr-old plant fossils from Kansas, USA indicates, however, that cells and their contents can be preserved. Most of the cells in these fossil plants appear to be in a state of plasmolysis, and these fossil cells bear a strong resemblance to laboratory-baked cells of extant plant tissues. Based on a comparison with extant material plus biophysical and biochemical analyses of the cytoplasm degrading process, a new hypothesis for cytoplasm preservation in nature is proposed: high temperature, a concomitant of commonly seen wildfires, may preserve cytoplasm in fossil plants. This hypothesis implies that fossilized cytoplasm should be rather common and an appropriate substance for research, unlike previously thought. Research on fossil cytoplasm closely integrates paleobotany with biochemistry, biophysics, as well as fire ecology, and invites inputs from these fields to paleobotany to interpret these provocative findings.  相似文献   
45.
46.
This work presents new experimental results on surface chemistry of reacting minerals and interface kinetics between mineral and aqueous solutions. These experiments were carried out using a flow reactor (packed bed reactor) of an open system as well as a continuous stirred tank reactor, CSTR. The authors measured reaction rates of such minerals as zeolite, albite and carbonate (rhodochrosite, dolomite) in various solutions, and tested corresponding mineral surface by using SEM, XPS, SIMS, etc. This paper mainly presents the experimental results of zeolite dissolution in water and in low pH solutions at room temperature, and dolomite dissolution at elevated temperatures. The results show that the release rates of Si, Al and Na of zeolite are different in most cases. The incongruent dissolution of zeolite is related to surface chemical modifications. The Na, Al and Si release rates for dissolution of albite and zeolite in water and various solutions were measured as a function of temperature, flow veloci  相似文献   
47.
Yunnan is famous for its attractive karst landscapes especially shilins, fengcong and fenglin. The development of caves beneath the shilins in the vicinity of Lunan is closely connected with the formation of shilins. Most of the waters percolating through shilins run through the caves beneath them and are responsible for their formation. The study of cave speleogenesis deepens knowledge about both the development of shilins and karst structure. In the vicinity of the Lunan Shilin, speleological, morphological and structural geological studies of four karst caves have been accomplished. At Puzhehei, Qiubei, which is characterised by numerous fenglin, fengcong and caves, speleological and morphological studies have been performed. Cave sediments for paleomagnetic analyses have been taken from all studied areas (samples CH 1-9). Karst caves in SE Yunnan are probably much older than the age of the cave sediments (<780,000 years B.P.). The studied areas are located in the vicinity of the Xiaojiang fault (N-S  相似文献   
48.
The objective of this project is to develop and construct an innovative imaging system for nuclear medicine and molecular imaging that uses photon diffraction and is capable of generating 1–2 mm spatial resolution images in two or three dimensions. The proposed imaging system would be capable of detecting radiopharmaceuticals that emit 100–200 keV gamma rays which are typically used in diagnostic nuclear medicine and in molecular imaging. The system is expected to be optimized for the 140.6 keV gamma ray from a Tc-99m source, which is frequently used in nuclear medicine. This new system will focus the incoming gamma rays in a manner analogous to a magnifying glass focusing sunlight into a small focal point on a detector's sensitive area. Focusing gamma rays through photon diffraction has already been demonstrated with the construction of a diffraction lens telescope for astrophysics and a scaled-down lens for medical imaging, both developed at Argonne National Laboratory (ANL). In addition, spatial resolutions of 3 mm have been achieved with a prototype medical lens. The proposed imaging system would be comprised of an array of photon diffraction lenses tuned to diffract a specific gamma ray energy (within 100–200 keV) emitted by a common source. The properties of photon diffraction make it possible to diffract only one specific gamma ray energy at a time, which significantly reduces scattering background. The system should be sufficiently sensitive to the detection of small concentrations of radioactivity that can reveal potential tumor sites at their initial stages of development. Moreover, the system's sensitivity would eliminate the need for re-injecting a patient with more radiopharmaceutical if this patient underwent a prior nuclear imaging scan. Detection of a tumor site at its inception could allow for an earlier initiation of treatment and wider treatment options, which can potentially improve the chances for cure.  相似文献   
49.
A major goal of the MAX program is to detect and measure gamma rays produced following the nuclear reactions that take place in a supernova explosion. To detect a reasonable number of supernovae, sensitivities of the order of a few times 10-7 γ cm-2sec-1 are needed – much better than possible with current instruments. The approach in the MAX program is to use a crystal diffraction lens to collect photons over a large area and concentrate them on a small well-shielded detector, greatly improving the signal to noise ratio. The crystals need to have both high diffraction efficiency and a relatively broad energy bandwidth. With mosaic crystals there is a trade-off between bandwidth and diffraction efficiency – one can have either high efficiency or large bandwidth, but not both without losing too much intensity through atomic absorption. A recent breakthrough in our understanding of crystal diffraction for high-energy gamma rays has made it possible to develop crystals that have both high diffraction efficiency and a relatively broad energy bandwidth. These crystals have near perfect crystal structure, but the crystalline planes are slightly curved. Such curved planes can be obtained in 3 different ways, by using mixed crystals with a composition gradient, by applying a thermal gradient, and by mechanically bending a near perfect crystal. A series of experiments have been performed on all three types of crystals using high-energy x-ray beams from the Advanced Photon Source at the Argonne National Laboratory. Experiments performed at 3 energies, 93 keV, 123 keV and 153 keV, with both the thermal gradient Si crystals and with the mechanically bent Si crystals, demonstrated that one can achieve diffraction efficiencies approaching 100% with moderate energy bandwidths (ΔE/E = 1.4%) and low atomic absorption (transmission = 0.65), in excellent agreement with theory. The use of this type of diffraction crystal is expected to increase the sensitivity of gamma ray telescopes by a factor of 5 over that possible with normal mosaic crystals.  相似文献   
50.
This work presents new experimental results on the kinetics of mineral dissolution in near-critical and supercritical water in a temperature range (T) from 25 to 400℃ and a constant pressure of 23 MPa. Kinetic experiments were carried out by using a flow reactor (packed bed reactor) of an open system. The dissolution rates of albite and magnetite were measured under these experimental conditions. Na, Al and Si release rates for albite dissolution in water were measured as a function of the temperature and flow velocity in the reaction system. The maximum release rates of Na, AI and Si of albite dissolution in the hydrothermal flow systems under different flow velocities were always obtained at 300℃, that is to say, the maximum albite dissolution rates in the flow systems, regardless of different flow rates, were repeatedly measured at 300℃. Results indicate a wide fluctuation in albite dissolution rates occurring close to the critical point of water. The dissolution rates increased when the temperatu  相似文献   
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