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61.
62.
R.M. Brown H.R. Andrews G.C. Ball N. Burn Y. Imahori J.C.D. Milton E.L. Fireman 《Earth and Planetary Science Letters》1984,67(1):1-8
14C has been measured in three North American and seven Antarctic meteorites with the Chalk River MP tandem accelerator. In most cases cosmogenic14C, which is tightly bound, was separated from absorbed atmospheric radiocarbon by stepwise heating extractions. Terrestrial ages obtained by comparing cosmogenic14C in the meteorite to that in Bruderheim are (7.2 ± 0.6) × 103 years for Yamato 7304, (11.6 ± 0.4) × 103 years for Estacado, and range from (32.7 ± 0.5) × 103 to (41.0 ± 0.8) × 103 years for six meteorites recovered at Allan Hills and its vicinity. The present upper limit to age determination by the accelerator method varies from 50 × 103 to 70 × 103 years depending upon mass and carbon content of the sample. The natural limit caused by cosmic ray production of14C in silicate rocks at 2000 m elevation is estimated to be (55 ± 5) × 103 years. “Weathering ages” were estimated for the Antarctic meteorites from the specific activity of loosely-bound CO2 considered to be absorbed from the terrestrial atmosphere on weathering. The accelerator measurements are in accordance with previous low-level counting measurements but have higher precision and sensitivity. 相似文献
63.
A statistical examination of isotopic distributions for MORB from various ocean ridges leads to the “blob cluster model”, in which the oceanic crust accreting at ridges results from the mixing of two components within the ascending mantle. These are (1) upper mantle material and (2) discrete rising blobs of more radiogenic material. The blobs are fractionated to a variable degree and are distributed in the upper mantle circulation in a manner that is related to the spreading rate.(1) Themean values of the isotopic distributions allow us to calculate the probabilities of the two types of material within the mantle. The results show that theproportion of asthenospheric material in the mixtureincreases with the spreading rate, in agreement with the hypothesis of blob dilution within the upper mantle convection.Mass fluxes can be estimated for the rising blobs from these probabilities, which depend on the respective concentrations in the sources of the two types of material. If the blobs originate in the lower mantle, this flux estimation would suggest that a significant part of the lower mantle has been injected into the upper mantle during earth history.(2) Thestandard deviations of the distributions depend on the “efficiency” of the mixing process:the more imbricated are the asthenospheric and blob materials in the mixture,the smaller is theisotopic spread. This efficiency parameter is shown to increase with the spreading rate, as already suggested by previous comparisons between the East Pacific Rise and the Mid-Atlantic Ridge. Moreover, this feature may also be correlated with other data such as ridge bathymetric variations. 相似文献
64.
As a result of affiliation between the Hudson's Bay Company and the Royal Society a relatively large number of instrumental temperature records are available from York Factory and Churchill Factory on the southwest of Hudson Bay beginning in 1768. The nature of these records, details of the instruments and information about the observers are presented. The major difficulty with the records is that the number of observations and the time of observation varied considerably. Adjustment factors were calculated for all of the combinations using a modern record maintained at the Churchill airport. By combining the Hudson's Bay Company record with data recorded by members of the Royal Canadian Mounted Police after 1852, and up to 1910, a long and relatively continuous record of daily and monthly average temperatures has been created for Central Canada. 相似文献
65.
Measurements of low-level dissolved-sulfide concentrations in estuarine water from San Francisco Bay have been made using
the sulfide-specific electrode after preservation, separation, and preconcentration of the sulfide species. The separation
and preconcentration were acheived by coprecipitation of ZnS with Zn(OH)2 followed by collection and dissolution of the precipitate, giving concentration factors up to 160-fold Preconcentration provided
sulfide solutions that were adequately measurable within the practical working range of the specific-ion electrode The sulfide
detection limit with the preconcentration step is 0 02 μg/l Spike recoveries in the range of 81 to 10 1% have been achieved
for laboratory-prepared samples having S2− concentrations as low as 0 6 μg/l and 84 to 100% for an estuarine sample spiked in the field with 2 μg/l (S(−II) Positive
correlations have been found between dissolved S(−II) concentrations and concentrations of dissolved Cd, Cu, and Ni, negative
correlations have been found between bisulfide (HS−) activity and activities of Cd2+, Cu2+, and Ag+ species 相似文献
66.
J Jouzel R Vaikmae J R Petit M Martin Y Duclos M Stievenard C Lorius M Toots M A Mélières L H Burckle N I Barkov V M Kotlyakov 《Climate Dynamics》1995,11(3):151-161
The two-step character of the last deglaciation is well recognized in Western Europe, in Greenland and in the North Atlantic. For example, in Greenland, a gradual temperature decrease started at the Bölling (B) around 14.5 ky BP, spanned through the Alleröd (A) and was followed by the cold Younger Dryas (YD) event which terminated abruptly around 11.5 ky BP. Recent results suggest that this BA/YD sequence may have extended throughout all the Northern Hemisphere but the evidence of a late transition cooling is still poor for the Southern Hemisphere. Here we present a detailed isotopic record analyzed in a new ice core drilled at Dome B in East Antarctica that fully demonstrates the existence of an Antarctic cold reversal (ACR). These results suggest that the two-step shape of the last deglaciation has a worldwide character but they also point to noticeable interhemispheric differences. Thus, the coldest part of the ACR, which shows a temperature drop about three times weaker than that recorded during the YD in Greenland, may have preceded the YD. Antarctica did not experienced abrupt changes and the two warming periods started there before they started in Greenland. The links between Southern and Northern Hemisphere climates throughout this period are discussed in the light of additional information derived from the Antarctic dust record. 相似文献
67.
Hélène Dupuis Alain Weill Kristina Katsaros Peter K. Taylor 《Annales Geophysicae》1995,13(10):1065-1074
Heat flux estimates obtained using the inertial dissipation method, and the profile method applied to radiosonde soundings, are assessed with emphasis on the parameterization of the roughness lengths for temperature and specific humidity. Results from the inertial dissipation method show a decrease of the temperature and humidity roughness lengths for increasing neutral wind speed, in agreement with previous studies. The sensible heat flux estimates were obtained using the temperature estimated from the speed of sound determined by a sonic anemometer. This method seems very attractive for estimating heat fluxes over the ocean. However allowance must be made in the inertial dissipation method for non-neutral stratification. The SOFIA/ASTEX and SEMAPHORE results show that, in unstable stratification, a term due to the transport terms in the turbulent kinetic energy budget, has to be included in order to determine the friction velocity with better accuracy. Using the profile method with radiosonde data, the roughness length values showed large scatter. A reliable estimate of the temperature roughness length could not be obtained. The humidity roughness length values were compatible with those found using the inertial dissipation method. 相似文献
68.
69.
Since Nb and Zr are only little fractionated during magmatic processes, the 92Nb-92Zr relative chronometer has the potential of dating the formation of the planetary bodies through their differentiation. Thus, we have analyzed the isotopic composition of zirconium in lunar, meteoritic and old and recent terrestrial samples.No isotopic variation has been found. However, the ratio of 3.8 Ga. old zircons from the Isua acid conglomerate is on the lower limit of the range of the standard measurements. If considered an anomaly, it would correspond to a +1.5 × 10?492Zr relative deficiency or to a 3.0 × 10?494Zr relative excess.Our data constrain the isotopic ratio at the time of formation of the solar system to be less than 0.007, so that the maximum sensitivity of the 92Nb-92Zr relative chronometer for the formation of planetary bodies is around 107 a. A discussion of some possible nuclear reactions indicates that zirconium isotopic variations in zircons are not easily produced, and that the 92Nb and 94Nb natural activities (Apt et al., 1974) cannot be explained by any single one of the processes proposed so far. 相似文献
70.
While the chemical structure of the earth's mantle is probably rather complex, multi-box models have been used as a first approximation to evaluate this structure. Most commonly, a three-box model is used, involving the continental crust, the upper mantle and the lower mantle. The depleted upper mantle and the continental crust are assumed to represe1nt complementary reservoirs, related by crust formation processes occurring during geologic history.Here we investigate the Rb/Sr and Sm/Nd isotopic systematics of several three-box models, using mass balance equations and the definition of the mean age of the reservoirs. The geochemical uniqueness of the models, chosen from a large family of possible models, is evaluated from elementary graph theory, and these models are then solved using a total inversion approach. This paper (Part I) describes the methodology of the procedure; the companion paper (Part II) discusses the application of this approach to multi-box mantle models. 相似文献