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11.
研究了一种基于雷达后向散射特性,从单张星载高分辨率SAR影像提取建筑物高度的方法。该方法通过检测建筑物二次散射强度,同时获取目标方位角、入射角等参数以及相关介质特性等信息,根据后向散射几何光学模型估算建筑物高度。实验验证了对于相当一部分典型建筑物都能够获得较为理想的高程估计值,进而证明了该方法提取建筑物高度的可行性和有效性。  相似文献   
12.
Olivine offers huge, largely untapped, potential for improving our understanding of magmatic and metasomatic processes. In particular, a wealth of information is contained in rare earth element (REE) mass fractions, which are well studied in other minerals. However, REE data for olivine are scarce, reflecting the difficulty associated with determining mass fractions in the low ng g?1 range and with controlling the effects of LREE contamination. We report an analytical procedure for measuring REEs in olivine using laser ablation quadrupole‐ICP‐MS that achieved limits of determination (LOD) at sub‐ng g?1 levels and biases of ~ 5–10%. Empirical partition coefficients (D values) calculated using the new olivine compositions agree with experimental values, indicating that the measured REEs are structurally bound in the olivine crystal lattice, rather than residing in micro‐inclusions. We conducted an initial survey of REE contents of olivine from mantle, metamorphic, magmatic and meteorite samples. REE mass fractions vary from 0.1 to double‐digit ng g?1 levels. Heavy REEs vary from low mass fractions in meteoritic samples, through variably enriched peridotitic olivine to high mass fractions in magmatic olivines, with fayalitic olivines showing the highest levels. The variable enrichment in HREEs demonstrates that olivine REE patterns have petrological utility.  相似文献   
13.
As a kind of generic sensor model, the rational function model (RFM) has been widely used in geometric processing of optical images, but has not yet been applied to SAR datasets. In this article the feasibility and methodology of rational function (RF) modeling for SAR datasets are investigated. After a review of the mathematic formulation of the RF model and the Range-Doppler model for SAR systems, the feasibility of applying RFM to SAR datasets is analyzed. Afterwards a two-stage approach is proposed as the key technique for SAR RF modeling to solve unknown parameters of RFM in a fast and unbiased way. The effectiveness and advantages of this approach are demonstrated by comparisons with traditional methods. Experimental results obtained for various spaceborne SAR datasets of different processing levels show that RFM is a suitable replacement of the rigorous Range-Doppler model for spaceborne SAR images. Furthermore, the impacts of several factors including the control point grid size, the number of elevation layers, and the orbit precision on SAR RFM solutions are evaluated quantitatively. The results show that the number of elevation layers is a key factor in SAR RF modeling, and its value should be set carefully according to terrain conditions of study areas. Finally, potential applications of SAR RFM are discussed in brief.  相似文献   
14.
Compared with solution ICP‐MS, LA‐ICP‐MS studies have thus far reported comparatively few external reference data for accuracy estimates of experiments. This is largely the result of a paucity of available reference materials of natural composition. Here, we report an evaluation of natural glass (obsidian) as an inexpensive and widely available external reference material. The homogeneity of over forty elements in six different obsidian samples was assessed by LA‐ICP‐MS. Accuracy was tested with two obsidian samples that were fully characterised by electron probe microanalysis and solution ICP‐MS. Laser ablation experiments were performed with a variety of ablation parameters (fluence, spot sizes, ablation repetition rates) and calibration approaches (natural vs. synthetic reference materials, and different internal standard elements) to determine the best practice for obsidian analysis. Furthermore, the samples were analysed using two different laser wavelengths (193 nm and 213 nm) to compare the effect of potential ablation‐related phenomena (e.g., fractionation). Our data indicate that ablation with fluences larger than 6 J cm?2 and repetition rates of 5 or 10 Hz resulted in the most accurate results. Furthermore, synthetic NIST SRM 611 and 612 glasses worked better as reference materials compared with lower SiO2 content reference materials (e.g., BHVO‐2G or GOR128‐G). The very similar SiO2 content of the NIST SRM glasses and obsidian (i.e., matrix and compositional match) seems to be the first‐order control on the ablation behaviour and, hence, the accuracy of the data. The use of different internal standard elements for the quantification of the obsidian data showed that Si and Na yielded accurate results for most elements. Nevertheless, for the analysis of samples with high SiO2 concentrations, it is recommended to use Si as the internal standard because it can be more precisely determined by electron probe microanalysis. At the scale of typical LA analyses, the six obsidian samples proved to be surprisingly homogenous. Analyses with a spot size of 80 μm resulted in relative standard deviations (% RSD) better than 8% for all but the most depleted elements (e.g., Sc, V, Ni, Cr, Cu, Cd) in these evolved glasses. The combined characteristics render obsidian a suitable, inexpensive and widely available, external quality‐control material in LA‐ICP‐MS analysis for many applications. Moreover, obsidian glass is suited for tuning purposes, and well‐characterised obsidian could even be used as a matrix‐matched reference material for a considerable number of elements in studies of samples with high SiO2 contents.  相似文献   
15.
A comparison between HBr-HCl and HBr-HNO3 based anion chemistry is presented to test the efficiency of Pb purification in the preparation of samples for isotope ratio measurement by ICP-MS. It was found that the small advantages in yield and blank offered by the HNO3-based method were more than compensated by the more effective matrix removal of the HCl-based method. Apart from very zinc rich matrices (e.g., sphalerite), a careful single pass purification using HBr and HCl removed more than 99.9% of the matrix. In preparation for the isotope ratio analysis, a small (2–5% m/v) liquid sample aliquot was analysed to determine U, Th and Pb concentrations by solution quadrupole ICP-MS. This allowed accurate prediction of the expected ion signal and permitted optimal spiking with Tl, if desired, for mass bias correction. Long-term results for international rock reference materials showed reproducibilities of better than 1% (Th/U) and 1.5% (U/Pb). For most geological applications, such analyses obviate the need for isotope dilution concentration measurements.  相似文献   
16.
LA-ICPMS原位微区面扫描技术的发展对解析具有包裹体、环带结构的矿物或受多期岩浆/热液活动影响形成的溶蚀再结晶的矿物具有重要的地质意义。黄铁矿作为最普遍的硫化物种类之一,可形成于各种类型矿床中,其微量元素组份记录了矿床形成过程的重要信息。通过LA-ICPMS原位微区面扫描技术获得的黄铁矿晶体内部结构组份信息可用来限定成矿流体的性质、厘定成矿流体的演化规律、示踪成矿物质来源、约束变形变质作用过程中元素的活化和迁移行为,以及约束矿床成因等。本次研究选取了内蒙古二连盆地中巴彦乌拉大型铀矿床、辽宁青城子地区榛子沟铅锌矿、加拿大Pardo砂金矿中的黄铁矿作为研究对象,运用原位微区LA-ICPMS元素面扫描技术揭示其内部组份及结构信息,探索该技术在不同类型矿床中的应用价值。巴彦乌拉大型砂岩型铀矿床中的黄铁矿的内部组构信息显示成矿体系的p H和Eh对硫酸盐还原细菌活动均有影响,并控制与之相关的铀矿化;且成矿体系的p H和Eh受到外界不断供给的地下水的影响,呈振荡性变化。辽宁榛子沟铅锌矿中的黄铁矿的内部组构信息显示矿化过程受到了至少两期流体活动的叠加影响,包括早期同沉积时期的流体以及晚期与燕山期岩浆活动有关的热液流体。加拿大Pardo金矿中黄铁矿的内部组构信息显示矿床中半自形-自形的黄铁矿实际包含碎屑成因的磨圆状核部及后期热液活动形成的增生边;金主要呈浸染状分布在碎屑成因的黄铁矿核部,后期热液活动对金矿化影响微弱。  相似文献   
17.
A method is developed which for a certain day permits the approximate calculation of closed small and large scale magnetic field lines. From the photospheric longitudinal components of the magnetic field measured at this day normal components are derived taking into account the curvature of the solar surface. The magnetic fields are assumed to be potential or force-free fields.The method is applied to observations of September 5 and September 7, 1973. The projected magnetic field lines are compared with the loop structures which are visible in XUV pictures taken on these days. In the cases where no good agreement could be obtained for potential fields, force-free fields are calculated and fitted to the observed structures.  相似文献   
18.
19.
We report high‐precision inductively coupled plasma mass spectrometric (ICP‐MS) compositional data for 39 trace elements in a variety of dust deposits, trapped sediments and surface samples from New Zealand and Australia. Dusts collected from the surface of alpine glaciers in the Southern Alps, New Zealand, believed to have undergone long‐distance atmospheric transport from Australia, are recognizable on account of their overabundances of Pb and Cu with respect to typical upper crustal values. Long‐travelled dust from Australia therefore scavenges these and other metals (e.g. Zn, Sb and Cd) from the atmosphere during transport and deposition. Hence, due to anthropogenic pollution, long‐travelled Australian dusts can be recognized by elevated metal contents. The relative abundance of 25 other elements that are not affected by atmospheric pollution, mineral sorting (Zr and Hf) and weathering[sol ]solubility (alkali and earth alkali elements) reflects the geochemistry of the dust source sediment. As a result, we are able to establish the provenance of dust using ultra‐trace‐element chemistry at regional scale. Comparison of long‐travelled dust chemistry with potential Australian sources shows that fits of variable quality are obtained. We propose that the best fitting potential source chemistry most likely represents the major dust source area. A binary mixing model is used to demonstrate that admixture of small quantities of local dust provides an even better fitting dust chemistry for the long‐travelled dusts. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   
20.
Peraluminous potassium-rich granitoids in the Semail Ophiolite   总被引:11,自引:0,他引:11  
Potassic granites are found as dikes and small stocks in the uppermost part of the mantle sequence of the Semail ophiolite, predominantly in the northern and less frequently in the central and southern part. New chemical analyses show that the biotite granites lie on the same evolutionary trend as the quartz diorites and tonalites, occurring as late intrusives in the gabboro and mantle sequence. Based on mineral chemistry, the P-T conditions of andalusite-cordierite bearing pegmatoidal granites were calculated, giving pressures of 1.8–2.2 kbar and a solidus within the stability field of andalusite. Hydrothermal experiments on five natural granite and tonalite compositions gave minimum melting between 650 and 675° C at 2 kbar. At 700° C, excess H2O, there is already 70–80% melt from the granitic starting compositions. Potassic granites in the ophiolite can be the result of extreme fractional crystallization in the late intrusive series. Granitic melts can also be produced by a two-stage process, in which fluids escaping from the underlying metamorphic sole trigger partial melting of the more felsic members in the ophiolite series. Two-mica granites and pegmatites in the underlying metamorphic sole, possibly melting products of amphibolites and biotite gneisses, are contemporaneous. These escaping fluids could also explain the Pb and Sr isotopic compositions of the leucocratic dikes, indicating variable crustal contamination.  相似文献   
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