Magnetic properties of the profiles of polluted and non-polluted soils. A case study from Ukraine   总被引：7，自引：0，他引：7  

Maria Jele&#;ska  Agata Hasso-Agopsowicz  Barbara Kopcewicz  Anatoliy Sukhorada  Ksenija Tyamina  Magdalena K&#;dzia&#;ko-Hofmokl  Zhanna Matviishina 《Geophysical Journal International》2004,159(1):104-116

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Characterizing the properties of dissolved organic matter isolated by XAD and C-18 solid phase extraction and ultrafiltration   总被引：1，自引：0，他引：1  

Sara B. Schwede-Thomas  Yu-Ping Chin  Karl J. Dria  Patrick Hatcher  Edith Kaiser  Barbara Sulzberger 《Aquatic Sciences - Research Across Boundaries》2005,67(1):61-71

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Denitrification capacity in a subterranean estuary below a Rhode Island fringing salt marsh     

Kelly Addy  Arthur Gold  Barbara Nowicki  James McKenna  Mark Stolt  Peter Groffman 《Estuaries and Coasts》2005,28(6):896-908

Coastal waters are severely threatened by nitrogen (N) loading from direct groundwater discharge. The subterranean estuary, the mixing zone of fresh groundwater and sea water in a coastal aquifer, has a high potential to remove substantial N. A network of piezometers was used to characterize the denitrification capacity and groundwater flow paths in the subterranean estuary below a Rhode Island fringing salt marsh.¹⁵N-enriched nitrate was injected into the subterranean estuary (in situ push-pull method) to evaluate the denitrification capacity of the saturated zone at multiple depths (125–300 cm) below different zones (upland-marsh transition zone, high marsh, and low marsh). From the upland to low marsh, the water table became shallower, groundwater dissolved oxygen decreased, and groundwater pH, soil organic carbon, and total root biomass increased. As groundwater approached the high and low marsh, the hydraulic gradient increased and deep groundwater upwelled. In the warm season (groundwater temperature >12 °C), elevated groundwater denitrification capacity within each zone was observed. The warm season low marsh groundwater denitrification capacity was significantly higher than all other zones and depths. In the cool season (groundwater temperature <10.5 °C), elevated groundwater denitrification capacity was only found in the low marsh. Additions of dissolved organic carbon did not alter groundwater denitrification capacity suggesting that an alternative electron donor, possibly transported by tidal inundation from the root zone, may be limiting. Combining flow paths with denitrification capacity and saturated porewater residence time, we estimated that as much as 29–60 mg N could be removed from 11 of water flowing through the subterranean estuary below the low marsh, arguing for the significance of subterranean estuaries in annual watershed scale N budgets.  相似文献   

June 2005     

Barbara Sulzberger 《Environmental Geology》2005,48(1):125-126

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Thermal evolution of an extensional detachment as constrained by organic metamorphic data and thermal modeling: Graz Paleozoic Nappe Complex (Eastern Alps)   总被引：1，自引：0，他引：1  

Gerd Rantitsch  Reinhard F. Sachsenhofer  Christian Hasenhüttl  Barbara Russegger  Thomas Rainer 《Tectonophysics》2005,411(1-4):57-72

Following Early Cretaceous nappe stacking, the Eastern Alps were affected by late-orogenic extension during the Late Cretaceous. In the eastern segment of this range, a Late Cretaceous detachment separates a very low- to low-grade metamorphic cover (Graz Paleozoic Nappe Complex, GPNC) above a low- to high-grade metamorphic basement. Synchronously, the Kainach Gosau Basin (KGB) collapsed and subsided on top of the section.Metamorphism of organic material within this section has been investigated using vitrinite reflectance data and Raman spectra of extracted carbonaceous material. In the southern part of the GPNC, vitrinite reflectance indicates a decrease in organic maturity towards the stratigraphic youngest unit. The remaining part of the GPNC is characterized by an aureole of elevated vitrinite reflectance values and Raman R2 ratios that parallels the margins of the GPNC. Vitrinite reflectance in the KGB shows a steep coalification gradient and increases significantly towards the western basin margin. The observed stratigraphic trend in the southern GPNC is a result of deep Paleozoic to Early Cretaceous burial. This maturity pattern was overprinted along the margins by advective heat and convective fluids during Late Cretaceous to Paleogene exhumation of basement rocks.During shearing, the fault zone was heated up to ca. 500 °C. This overprint is explained by a two-dimensional thermal model with a ramp-flat fault geometry and a slip rate of 1 to 1.5 cm/year during 5 Ma fault movement. The collapse basin above the detachment subsided in a thermal regime which was characterized by relaxing isotherms.  相似文献   

Arsenic mobility in alteration products of sulfide-rich, arsenopyrite-bearing mine wastes, Snow Lake, Manitoba, Canada   总被引：2，自引：0，他引：2  

Kristin A. Salzsauler  Nikolay V. Sidenko  Barbara L. Sherriff 《Applied Geochemistry》2005,20(12):2303-2314

The Arsenopyrite Residue Stockpile (ARS) in Snow Lake, Manitoba contains approximately 250,000 tons of cyanide treated, refractory arsenopyrite ore concentrate. The residue was deposited between 1950 and 1959 in an open waste rock impoundment, and remained exposed until 2000, when the pile was capped with layers of waste rock and clay. During the time when the ARS was exposed to the atmosphere, arsenopyrite, pyrrhotite, pyrite and chalcopyrite were oxidized producing scorodite, jarosite and two generations of amorphous Fe sulfo-arsenates (AISA). These secondary phases attenuated some of the As released to pore water during oxidation in the upper layers of the ARS. The imposition of the cap prevented further oxidation. The secondary As minerals are not stable in the reduced environment that currently dominates the pile. Therefore, As currently is being released into the groundwater. Water in an adjacent monitoring well has concentrations of >20 mg/L total As with relative predominance of As(III).  相似文献   

Obsidian from the northern sector of the Main Ethiopian Rift: implications for archeology     

Agazi Negash  Mulugeta Alene  Asfawossen Asrat  Barbara Nash 《第四纪科学杂志》2021,36(4):664-671

Obsidian is abundant in the Main Ethiopian Rift (MER). Petrological and geochemical features of obsidian from four volcanic centers in the MER, namely Birenti, Dofen, Fentale and Kone, are presented. Compositional and petrological variability is noted among the Dofen and Fentale obsidian, but not in those from Kone and Birenti where each have separate but uniform elemental composition. The Fentale and Kone obsidian were source materials for the artifacts of a number of Middle Stone Age and Later Stone Age/Neolithic sites in the region. We have yet to determine whether Dofen and Birenti were sources for archeological artifacts. The study also shows that volcanic episodes from a single center do not necessarily result in compositional variability.  相似文献   

Impacts of a large Sahelian city on groundwater hydrodynamics and quality: example of Niamey (Niger)     

Aïssata B. Hassane  Christian Leduc  Guillaume Favreau  Barbara A. Bekins  Thomas Margueron 《Hydrogeology Journal》2016,24(2):407-423

The management of groundwater resources is very important in the semiarid Sahel region, which is experiencing rapid urban development. Impacts of urbanization on groundwater resources were investigated in the unconfined aquifer of the Continental Terminal beneath the city of Niamey, Niger, using water level and chemical data. Hydrodynamic and chemical changes are best described by a combination of factors including the historical development of the city, current land use, water-table depth and topography. Seasonal groundwater recharge occurs with high spatial variability, as indicated by water-level monitoring in all wells, but there was no interannual trend over the 5-year study period. Groundwater salinity shows high spatial variability and a minor rising trend. The highest salinity is in the old city centre, with Na–NO₃ dominant, and it increases seasonally with recharge. Salinity is much lower and more variable in the suburbs (Ca–HCO₃, Ca–NO₃, and Na–NO₃ dominant). Nitrate is the main ionic contaminant and is seasonally or permanently above the international guidelines for drinking water quality in 36 % of sampled wells, with a peak value of 112 mg L^?1 NO₃–N (8 meq L^?1). Comparison of urban and rural sites indicates a long-term increase in groundwater recharge and nitrate enrichment in the urban area with serious implications for groundwater management in the region.  相似文献   

Isotopic signatures for the assessment of snow water resources in the Moroccan high Atlas mountains: contribution to surface and groundwater recharge     

Angoran Baudelaire N’da  Lhoussaine Bouchaou  Barbara Reichert  Lahoucine Hanich  Yassine Ait Brahim  Abdelghani Chehbouni  El Hassane Beraaouz  Jean-Luc Michelot 《Environmental Earth Sciences》2016,75(9):755

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Changes in phosphorus content,phosphatase activity and some physicochemical and microbiological parameters of soil within the range of impact of illegal dumping sites in Bydgoszcz (Poland)     

Joanna Lemanowicz  Agata Bartkowiak  Barbara Breza-Boruta 《Environmental Earth Sciences》2016,75(6):510

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