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61.
62.
The mechanism by which olivine grains became embedded within iron‐nickel alloy in pallasite meteorites continues to be a matter of scientific debate. Geochemical and textural observations have failed to fully elucidate the origin and history of the olivine crystals; however, little research attention has been devoted to their crystallographic orientations within the metal matrix. Using electron backscatter diffraction, we have collected crystallographic orientation data for 296 crystals within ~65 cm2 sample surface from Springwater. Though no global crystallographic preferred orientation exists, very low misorientations are observed among [100] axes of olivine crystals within specific texturally defined domains. Combined with a thorough characterization of large‐scale Springwater textures, the definitively nonrandom spatial distribution of olivine orientations provides clues regarding the nature of the olivine's initial formation environment as well as the sequence of events subsequent to metal incorporation.  相似文献   
63.
Identifying and dating large impact structures is challenging, as many of the traditional shock indicator phases can be modified by post-impact processes. Refractory accessory phases, such as zircon, while faithful recorders of shock wave passage, commonly respond with partial U–Pb age resetting during impact events. Titanite is an accessory phase with lower Pb closure temperature than many other robust chronometers, but its potential as indicator and chronometer of impact-related processes remains poorly constrained. In this study, we examined titanite grains from the Sudbury (Ontario, Canada) and Vredefort (South Africa) impact structures, combining quantitative microstructural and U–Pb dating techniques. Titanite grains from both craters host planar microstructures and microtwins that show a common twin–host disorientation relationship of 74° about <102>. In the Vredefort impact structure, the microtwins deformed internally and developed high- and low-angle grain boundaries that resulted in the growth of neoblastic crystallites. U–Pb isotopic dating of magmatic titanite grains with deformation microtwins from the Sudbury impact structure yielded a 207Pb/206Pb age of 1851?±?12 Ma that records either the shock heating or the crater modification stage of the impact event. The titanite grains from the Vredefort impact structure yielded primarily pre-impact ages recording the cooling of the ultra-high-temperature Ventersdorp event, but domains with microtwins or planar microstructures show evidence of U–Pb isotopic disturbance. Despite that the identified microtwins are not diagnostic of shock-metamorphic processes, our contribution demonstrates that titanite has great potential to inform studies of the terrestrial impact crater record.  相似文献   
64.
While extensive Pleistocene loess deposits have been identified across Eurasia, Holocene age loess (typically nonglaciogenic) is rarely recognized. We explore possible loess deposits in the Mureş River Valley of western Romania, providing a regional signal of increased aridity during the mid‐late Holocene. This proposed aridity may be responsible for the abandonment of Middle Bronze Age tell settlements along the major drainages of the eastern Carpathian Basin (Pannonian plain). This hypothesis centers on a proposed aeolian deposit (the “Pecica deposit”), a ca. 50–80 cm thick, relatively homogeneous, gray layer blanketing the top of the Bronze Age tell of Pecica—Şanţul Mare. Comparing the morphological, geochemical, and physical characteristics of this specific tell deposit with two representative profiles near the site containing glaciogenic calcareous loess and potential Holocene loess deposits developed in Chernozems, we find significant similarities to support this hypothesis. We then review various forms of proxy data published from elsewhere in Central and Eastern Europe suggesting a warming trend during this period. The temporal placement of the Pecica deposit is bracketed using diagnostic artifacts, radiocarbon dates, and the degree of soil development, suggesting a period of increased aridity likely occurring soon after the 17th century B.C.  相似文献   
65.
This study used realistic representations of cloudy atmospheres to assess errors in solar flux estimates associated with 1D radiative transfer models. A scene construction algorithm, developed for the EarthCARE mission, was applied to CloudSat, CALIPSO and MODIS satellite data thus producing 3D cloudy atmospheres measuring 61 km wide by 14,000 km long at 1 km grid-spacing. Broadband solar fluxes and radiances were then computed by a Monte Carlo photon transfer model run in both full 3D and 1D independent column approximation modes. Results were averaged into 1,303 (50 km)2 domains. For domains with total cloud fractions A c  < 0.7 top-of-atmosphere (TOA) albedos tend to be largest for 3D transfer with differences increasing with solar zenith angle. Differences are largest for A c  > 0.7 and characterized by small bias yet large random errors. Regardless of A c , differences between 3D and 1D transfer rarely exceed ±30 W m?2 for net TOA and surface fluxes and ±10 W m?2 for atmospheric absorption. Horizontal fluxes through domain sides depend on A c with ~20% of cases exceeding ±30 W m?2; the largest values occur for A c  > 0.7. Conversely, heating rate differences rarely exceed ±20%. As a cursory test of TOA radiative closure, fluxes produced by the 3D model were averaged up to (20 km)2 and compared to values measured by CERES. While relatively little attention was paid to optical properties of ice crystals and surfaces, and aerosols were neglected entirely, ~30% of the differences between 3D model estimates and measurements fall within ±10 W m?2; this is the target agreement set for EarthCARE. This, coupled with the aforementioned comparison between 3D and 1D transfer, leads to the recommendation that EarthCARE employ a 3D transport model when attempting TOA radiative closure.  相似文献   
66.
Granulitic lunar meteorites offer rare insights into the timing and nature of igneous,metamorphic and impact processes in the lunar crust.Accurately dating the different events recorded by these materials is very challenging,however,due to low trace element abundances(e.g.Sm,Nd,Lu,Hf),rare micrometerscale U-Th-bearing accessory minerals,and disturbed Ar-Ar systematics following a multi-stage history of shock and thermal metamorphism.Here we report on micro-baddeleyite grains in granulitic mafic breccia NWA 3163 for the first time and show that targeted microstructural analysis(electron backscatter diffraction)and nanoscale geochronology(atom probe tomography)can overcome these barriers to lunar chronology.A twinned(~90°/401)baddeleyite domain yields a ~(232)Th/~(208)Pb age of 4328 ± 309 Ma,which overlaps with a robust secondary ion mass spectrometry(SIMS)~(207)Pb/~(206)Pb age of 4308 ± 18.6 Ma and is interpreted here as the crystallization age for the igneous protolith of NWA 3163.A second microstructural domain,2μm in width,contains patchy overprinting baddeleyite and yields a Th-Pb age of 2175 ±143 Ma,interpreted as dating the last substantial impact event to affect the sample.This finding demonstrates the potential of combining microstructural characterization with nanoscale geochronology when resolving complex P-T-t histories in planetary materials,here yielding the oldest measured crystallization age for components of lunar granulite NWA 3163 and placing further constraints on the formation and evolution of lunar crust.  相似文献   
67.
IODP Expedition 350 was the first to be drilled in the rear part of the Izu-Bonin, although several sites had been drilled in the arc axis to fore-arc region; the scientific objective was to understand the evolution of the Izu rear arc, by drilling a deep-water volcaniclastic section with a long temporal record (Site U1437). The Izu rear arc is dominated by a series of basaltic to dacitic seamount chains up to ~100-km long roughly perpendicular to the arc front. Dredge samples from these are geochemically distinct from arc front rocks, and drilling was undertaken to understand this arc asymmetry. Site U1437 lies in an ~20-km-wide basin between two rear arc seamount chains, ~90-km west of the arc front, and was drilled to 1804 m below the sea floor (mbsf) with excellent recovery. We expected to drill a volcaniclastic apron, but the section is much more mud-rich than expected (~60%), and the remaining fraction of the section is much finer-grained than predicted from its position within the Izu arc, composed half of ashes/tuffs, and half of lapilli tuffs of fine grain size (clasts <3 cm). Volcanic blocks (>6.4 cm) are only sparsely scattered through the lowermost 25% of the section, and only one igneous unit was encountered, a rhyolite peperite intrusion at ~1390 mbsf. The lowest biostratigaphic datum is at 867 mbsf (~6.5 Ma), the lowest palaeomagnetic datum is at ~1300 mbsf (~9 Ma), and the rhyolite peperite at ~1390 mbsf has yielded a U–Pb zircon concordia intercept age of (13.6 + 1.6/?1.7) Ma. Both arc front and rear arc sources contributed to the fine-grained (distal) tephras of the upper 1320 m, but the coarse-grained (proximal) volcaniclastics in the lowest 25% of the section are geochemically similar to the arc front, suggesting arc asymmetry is not recorded in rocks older than ~13 Ma.  相似文献   
68.
Rethinking an old tracer experiment in fractured crystalline rock suggests a concept of groundwater flow in sparse networks of long channels that is supported by results from an innovative lattice network model. The model, HyperConv, can vary the mean length of ‘strings’ of connected bonds, and the gaps between them, using two independent probability functions. It is found that networks of long channels are able to percolate at lower values of (bond) density than networks of short channels. A general relationship between mean channel length, mean gap length and probability of percolation has been developed which incorporates the well-established result for ‘classical’ lattice network models as a special case. Using parameters appropriate to a 4-m diameter drift located 360 m below surface at Stripa Mine Underground Research Laboratory in Sweden, HyperConv is able to reproduce values of apparent positive skin, as observed in the so-called Macropermeability Experiment, but only when mean channel length exceeds 10 m. This implies that such channel systems must cross many fracture intersections without bifurcating. A general relationship in terms of flow dimension is suggested. Some initial investigations using HyperConv show that the commonly observed feature, ‘compartmentalization’, only occurs when channel density is just above the percolation threshold. Such compartments have been observed at Kamaishi Experimental Mine (Japan) implying a sparse flow network. It is suggested that compartments and skin are observable in the field, indicate sparse channel systems, and could form part of site characterization for deep nuclear waste repositories.  相似文献   
69.
The late glacial-Holocene transition from the Lago Chungará sedimentary record in northern Chilean Altiplano (18°S) is made up of laminated sediments composed of light-white and dark-green pluriannual couplets of diatomaceous ooze. Light-white sediment laminae accumulated during short-term extraordinary diatom blooms whereas dark-green sediment laminae represent the baseline limnological conditions during several years of deposition. Diatom oxygen isotope ratios (δ18Odiatom) from 40 consecutive dark-green laminae, ranging from 11,990 to 11,450 cal year BP, show that a series of decadal-to-centennial dry–wet oscillations occurred. Dry periods are marked by relatively high isotope values whereas wet episodes are indicated by lower values. This interpretation agrees with the reconstructions of terrigenous inputs and regional effective moisture availability carried out in the lake but there is a systematic temporal disagreement between them owing to the non-linear response of the lacustrine ecosystem to environmental forcings. Furthermore, the δ18Odiatom record tracks effective moisture changes at a centennial scale. Three major phases have been established (11,990–11,800, 11,800–11,550, and 11,550–11,450 cal year BP). Each phase is defined by an increasing isotope trend followed by a sudden depletion. In addition, several wet and dry events at a decadal scale are superimposed onto these major trends. Spectral analyses of the δ18Odiatom values suggest that cycles and events could have been triggered by both El Niño-Southern Oscillation (ENSO) and solar activity. Significant ENSO frequencies of 7–9 years and 15–17 years, and periodicities of the solar activity cycles such as 11 years (Schwabe), 23 years (Hale) and 35 years (Brückner) have been recognised in the oxygen isotope time series. Time–frequency analysis shows that although solar and ENSO forcing were present at the onset of the Holocene, they were more intense during the late glacial period. The early Holocene might have been mainly governed by La Niña-like conditions that correspond to wet conditions over the Andean Altiplano.  相似文献   
70.
In fractured-rock aquifers, the geometric and hydraulic properties of the fractures commonly have a dominant influence on transport. Tracer tests are often used to estimate directly the gross transport properties of a fractured rock mass. The prospects for understanding characteristics of the heterogeneities in a fractured porous medium were explored from evidence provided by tracer experiments. The approach was to simulate flow and transport on a large set of prescribed fracture networks in a two-dimensional homogeneous permeable medium, thus generating synthetic tracer test data. The fracture orientation, aperture, spacing and network geometry were systematically altered from one case to the next. A classification scheme was devised for the tracer breakthrough curves using principal component analysis and this classification was linked to the fracture pattern properties. Even under highly simplified and controlled conditions, quite different fracture patterns can produce very similar breakthrough curves. The classification scheme thus demonstrates that a single breakthrough curve cannot reveal the fracture geometry with any precision. However, the scheme provided a methodology for rejecting geometric properties that do not belong to the fracture pattern under investigation, thus reducing the uncertainty in fracture geometry.  相似文献   
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