ENSO and solar activity signals from oxygen isotopes in diatom silica during late glacial-Holocene transition in Central Andes (18°S)     

Armand Hernández  Santiago Giralt  Roberto Bao  Alberto Sáez  Melanie J. Leng  Philip A. Barker 《Journal of Paleolimnology》2010,44(2):413-429

The late glacial-Holocene transition from the Lago Chungará sedimentary record in northern Chilean Altiplano (18°S) is made up of laminated sediments composed of light-white and dark-green pluriannual couplets of diatomaceous ooze. Light-white sediment laminae accumulated during short-term extraordinary diatom blooms whereas dark-green sediment laminae represent the baseline limnological conditions during several years of deposition. Diatom oxygen isotope ratios (δ¹⁸O_diatom) from 40 consecutive dark-green laminae, ranging from 11,990 to 11,450 cal year BP, show that a series of decadal-to-centennial dry–wet oscillations occurred. Dry periods are marked by relatively high isotope values whereas wet episodes are indicated by lower values. This interpretation agrees with the reconstructions of terrigenous inputs and regional effective moisture availability carried out in the lake but there is a systematic temporal disagreement between them owing to the non-linear response of the lacustrine ecosystem to environmental forcings. Furthermore, the δ¹⁸O_diatom record tracks effective moisture changes at a centennial scale. Three major phases have been established (11,990–11,800, 11,800–11,550, and 11,550–11,450 cal year BP). Each phase is defined by an increasing isotope trend followed by a sudden depletion. In addition, several wet and dry events at a decadal scale are superimposed onto these major trends. Spectral analyses of the δ¹⁸O_diatom values suggest that cycles and events could have been triggered by both El Niño-Southern Oscillation (ENSO) and solar activity. Significant ENSO frequencies of 7–9 years and 15–17 years, and periodicities of the solar activity cycles such as 11 years (Schwabe), 23 years (Hale) and 35 years (Brückner) have been recognised in the oxygen isotope time series. Time–frequency analysis shows that although solar and ENSO forcing were present at the onset of the Holocene, they were more intense during the late glacial period. The early Holocene might have been mainly governed by La Niña-like conditions that correspond to wet conditions over the Andean Altiplano.  相似文献   

Constraining the uncertainty in fracture geometry using tracer tests     

Peter B. Johnston  Tim Atkinson  John Barker  Noelle Odling 《Hydrogeology Journal》2009,17(3):527-539

In fractured-rock aquifers, the geometric and hydraulic properties of the fractures commonly have a dominant influence on transport. Tracer tests are often used to estimate directly the gross transport properties of a fractured rock mass. The prospects for understanding characteristics of the heterogeneities in a fractured porous medium were explored from evidence provided by tracer experiments. The approach was to simulate flow and transport on a large set of prescribed fracture networks in a two-dimensional homogeneous permeable medium, thus generating synthetic tracer test data. The fracture orientation, aperture, spacing and network geometry were systematically altered from one case to the next. A classification scheme was devised for the tracer breakthrough curves using principal component analysis and this classification was linked to the fracture pattern properties. Even under highly simplified and controlled conditions, quite different fracture patterns can produce very similar breakthrough curves. The classification scheme thus demonstrates that a single breakthrough curve cannot reveal the fracture geometry with any precision. However, the scheme provided a methodology for rejecting geometric properties that do not belong to the fracture pattern under investigation, thus reducing the uncertainty in fracture geometry.  相似文献   

Lake evolution in a semi-arid montane environment: response to catchment change and hydroclimatic variation     

Henry Lamb  Neil Roberts  Melanie Leng  Philip Barker  Abdelfattah Benkaddour  Sander van der Kaars 《Journal of Paleolimnology》1999,21(3):325-343

Pollen, geochemical and sedimentological data from Sidi Ali, a montane Moroccan lake, provide a 7000 yr record of changes in climate, catchment vegetation and soil erosion intensity. Diatoms, non-silicious algae, macrophyte fossils and ostracods from the same core record the dynamics of the lake ecosystem. Oxygen isotope and trace-element ratios of benthic ostracods appear to be relatively insensitive to climatic variation in this open lake with low water-residence time, but diatom plankton / periphyton (P/L) ratios show lake-level variations that are probably climate controlled. At least two superimposed processes are recorded, but at different timescales: catchment vegetation and soils show long-term changes due to climate and human impact, whereas P/L ratios suggest century-scale oscillations in lake depth. The timing of changes in algal and macrophyte productivity and carbon cycling within the lake broadly corresponds to changes in terrestrial vegetation, suggesting either that lake nutrient status is linked to catchment vegetation and soils, or that both were influenced by climate. The lack of a sensitive and independent (non-biological) climate proxy makes it more difficult to assess the lake's ecological response to short-term climate variation. Overall, the lake's evolution has been influenced both by catchment-mediated nutrient flux and by changes in water balance, thus having characteristics in common with both temperate and arid zone lakes.  相似文献   

Trickle or treat: The dynamics of nutrient export from polar glaciers          下载免费PDF全文

Ashley Dubnick  Jemma Wadham  Martyn Tranter  Martin Sharp  Joel Barker  Elizabeth Bagshaw  Sean Fitzsimons 《水文研究》2017,31(9):1776-1789

Cold‐based polar glacier watersheds contain well‐defined supraglacial, ice‐marginal, and proglacial elements that differ in their degree of hydrologic connectivity, sources of water (e.g., snow, ice, and/or sediment pore water), meltwater residence times, allochthonous and autochthonous nutrient, and sediment loads. We investigated 11 distinct hydrological units along the supraglacial, ice marginal, and proglacial flow paths that drain Joyce Glacier in the McMurdo Dry Valleys of Antarctica. We found that these units play unique and important roles as sources and/or sinks for dissolved inorganic nitrogen and dissolved inorganic phosphorus and for specific fractions of dissolved organic matter (DOM) as waters are routed from the glacier into nutrient‐poor downstream ecosystems. Changes in nutrient export from the glacial system as a whole were observed as the routing and residence times of meltwater changed throughout the melt season. The concentrations of major ions in the proglacial stream were inversely proportional to discharge, such that there was a relatively constant “trickle” of these solutes into downstream ecosystems. In contrast, NO₃^? concentrations generally increased with discharge, resulting in delivery of episodic pulses of dissolved inorganic nitrogen‐rich water (“treats”) into those same ecosystems during high discharge events. DOM concentrations or fluorescence did not correlate with discharge rate, but high variability in DOM concentrations or fluorescence suggests that DOM may be exported downstream as episodic treats, but with spatial and/or temporal patterns that remain poorly understood. The strong, nutrient‐specific responses to changes in hydrology suggest that polar glacier drainage systems may export meltwater with nutrient compositions that vary within and between melt seasons and watersheds. Because nutrient dynamics identified in this study differ between glacier watersheds with broadly similar hydrology, climate, and geology, we emphasize the need to develop conceptual models of nutrient export that thoroughly integrate the biogeochemical and hydrological processes that control the sources, fate, and export of nutrients from each system.  相似文献   

The geochemical nature of the Archean Ancient Gneiss Complex and Granodiorite Suite,Swaziland: a preliminary study     

D.R. Hunter  F. Barker 《Precambrian Research》1978,7(2):105-127

The Ancient Gneiss Complex (AGC) of Swaziland, an Archean gray gneiss complex, lies southeast and south of the Barberton greenstone belt and includes the most structurally complex and highly metamorphosed portions of the eastern Kaapvaal craton. The AGC is not precisely dated but apparently is older than 3.4 Ga.The AGC consists of three major units: (a) a bimodal suite of closely interlayered siliceous, low-K gneisses and metabasalt; (b) homogeneous tonalite gneiss; and (c) interlayered siliceous microcline gneiss, metabasalt, and minor metasedimentary rocks — termed the metamorphite suite. A geologically younger gabbro-diorite-tonalite-trondhjemite suite, the Granodiorite Suite, is spatially associated with the AGC and intrusive into it.The bimodal suite consists largely of two types of low-K siliceous gneiss: one has SiO₂ < 75%, Al₂O₃ > 14%, low Rb/Sr ratios, and depleted heavy rare earth elements (REE's); the other has SiO₂ > 75%, Al₂O₃ < 13%, high Rb/Sr ratios, and relatively abundant REE's except for negative Eu anomalies. The interlayered metabasalt ranges from komatiitic to tholeiitic compositions. Lenses of quartz monzonitic gneiss of K₂O/Na₂O close to 1 form a minor part of the bimodal suite. Tonalitic to trondhjemitic migmatite locally is abundant and has major-element abundances similar to those of non-migmatitic varieties.The siliceous gneisses of the metamorphic suite show low Al₂O, K₂O/Na₂O ratios of about 1, high Rb/Sr ratios, moderate REE abundances and negative Eu anomalies.K/Rb ratios of siliceous gneisses of the bimodal suite are very low (～130); of the tonalitic gneiss, low (～225); of the siliceous gneiss of the metamorphite suite, moderate (～300); and of the Granodiorite Suite, high (～400).Rocks of the AGC differ geochemically in several ways from the siliceous volcanic and hypabyssal rocks of the Upper Onverwacht Group and from the diapirs of tonalite and trondhjemite that intrude the Swaziland Group.  相似文献   

Ultraviolet reflectivity and geometrical albedo of Titan     

Edwin S. Barker  Laurence M. Trafton 《Icarus》1973,20(4):444-454

Intermediate resolution (6Å) photoelectric spectral scans of Titan, Saturn, Saturn's Rings and the Moon appear in two forms: ratio spectra of Titan vs the Rings and of Saturn vs the Rings, and relative reflectivities, which are compared to previously published results. Titan's geometrical albedo of 0.094 ± 0.012 was measured at 4255Å with a 50Å bandpass. From this and the spectral measurements, we derived the geometrical albedo as a function of wavelength. We find that the wavelength dependences of Titan's uv spectrum and the spectrum of Saturn's Rings are remarkably similar. No trace of any absorption bands is apparent. These results imply that uv gaseous absorption and Rayleigh scattering play a strongly subdued role in Titan's atmosphere. Any homogeneous atmospheric model implies that the absorber responsible for Titan's uv spectral albedo varies strongly with wavelength. On the other hand, we find that the uv observations can be satisfied by an absorber having a relatively weak dependence upon wavelength if an inhomogeneous atmospheric model is employed. In particular, a fine dust, which absorbs as 1/λ, can explain the uv observations provided that it is preferentially distributed high up in Titan's atmosphere where the optical depth from Rayleigh scattering is low. The likely presence of such a dust in Jupiter's atmosphere and the difficulty in explaining the nature of a continuous uv absorber which varies rapidly with wavelength suggest that the gas and aerosol in Titan's atmosphere are inhomogeneously distributed.  相似文献   

Theoretical calculation of Martian airmass     

Jerry H. Woodman  Edwin S. Barker 《Icarus》1973,19(1):131-136

Analysis of spectroscopic observations of Mars requires values of the effective Martian airmass to obtain true abundances. Semi-arbitrary assumptions for the airmass correction have been used in most of the past publications on the subject. We have computed detailed values corresponding to specified slits superimposed on the disk of the planet, giving useful output in the form of curves presenting the average airmass for different regions of the planet and various conditions of planet diameter, seeing and phase angle.  相似文献   

Modeling fracture porosity development using simple growth laws   总被引：2，自引：0，他引：2  

Bloomfield JP  Barker JA  Robinson N 《Ground water》2005,43(3):314-326

A model of porosity development has been developed to investigate general relationships between simple fracture aperture growth laws and fracture porosity in evolved fracture arrays in aquifers. The growth of fracture apertures in two-dimensional orthogonal arrays with initially spatially uncorrelated lognormal aperture distributions has been studied, where aperture growth rate is proportional to an exponent of the flow rate through each fracture. The evolved arrays show geometrical phase changes as a function of the aperture growth rate exponent, e, and the standard deviation of the initial aperture distribution, sigma(z). Low values of e and sigma(z) lead to bimodal aperture distributions, where apertures parallel to flow are preferentially enlarged. At moderate values of e and sigma(z), there is a transition to a regime of more complex geometries consisting of networks of channel-like structures of preferentially enlarged apertures. At larger values of e, array-spanning channel-like paths of preferentially enlarged apertures develop, where the tortuosity of the channel-like paths is a linear function of sigma(z). Following an initial growth phase, during which dynamically stable aperture configurations develop, arrays undergo simple amplification. The geometry of the evolved aperture fields is diverse and they can be highly complex; consequently, parameterization and prediction of their evolution in terms of the initial aperture distributions and growth rate laws is not trivial.  相似文献   

Biogeochemistry of sulfur and iron in Thioploca-colonized surface sediments in the upwelling area off central chile     

Jakob Zopfi  Bo Barker Jørgensen 《Geochimica et cosmochimica acta》2008,72(3):827-843

The biogeochemistry of sedimentary sulfur was investigated on the continental shelf off central Chile at water depths between 24 and 88 m under partial influence of an oxygen minimum zone. Dissolved and solid iron and sulfur species, including the sulfur intermediates sulfite, thiosulfate, and elemental sulfur, were analyzed at high resolution in the top 20 cm. All stations were characterized by high rates of sulfate reduction, but only the sediments within the Bay of Concepción contained dissolved sulfide. Due to advection and/or in-situ reoxidation of sulfide, dissolved sulfate was close to bottom water values. Whereas the concentrations of sulfite and thiosulfate were mostly in the submicromolar range, elemental sulfur was by far the dominant sulfur intermediate. Although the large nitrate- and sulfur-storing bacteria Thioploca were abundant, the major part of S⁰ was located extracellularly. The distribution of sulfur species and dissolved iron suggests the reaction of sulfide with FeOOH as an important pathway for sulfide oxidation and sulfur intermediate formation. This is in agreement with the sulfur isotope composition of co-existing elemental sulfur and iron monosulfides. In the Bay of Concepción, sulfur isotope data suggest that pyrite formation proceeds via the reaction of FeS with polysulfides or H₂S. At the shelf stations, on the other hand, pyrite was significantly depleted in ³⁴S relative to its potential precursors FeS and S⁰. Isotope mass balance considerations suggest further that pyritization at depth includes light sulfide, potentially originating from bacterial sulfur disproportionation. The δ³⁴S-values of pyrite down to −38‰ vs. V-CDT are among the lightest found in organic-rich marine sediments. Seasonal variations in the sulfur isotope composition of dissolved sulfate indicated a dynamic non-steady-state sulfur cycle in the surface sediments. The ¹⁸O content of porewater sulfate increased with depth at all sites compared to the bottom water composition due to intracellular isotope exchange reactions during microbial sulfur transformations.  相似文献   

The bailer test: a simple effective pumping test for assessing borehole success     

A. M. MacDonald  J. A. Barker  J. Davies 《Hydrogeology Journal》2008,16(6):1065-1075

A new pumping test method has been designed around the practical requirements of those working in rural water-supply projects in developing countries. The bailer test needs only simple equipment and can be completed in under 1 h. The test involves removing 20–50 bails from a borehole over a 10-min period and then measuring the recovery. The test is analysed using large-diameter-well analysis (which accounts for well storage) and is appropriate for testing low productivity aquifers (transmissivity 0.1–10 m² d^–1), where water levels are shallow (<20 m depth). The bailer test was developed and trialled in a rural water supply project in Nigeria where it was found to predict similar transmissivity to 5-h constant rate tests (r²=0.9). Analysis of the test was further simplified to provide guidelines for field staff such as community health workers. The likelihood of a borehole sustaining a handpump for 250 people can be indicated by measuring the maximum drawdown and time for 50 and 75% recovery from a bailer test and comparing to a simple table. This simplified test is now being used in this and other rural water-supply projects, and has been modified to indicate whether a borehole can sustain higher yields for small-scale irrigation.  相似文献