Radioelements,radiogenic helium and age relationships for groundwaters from the granites at Stripa,Sweden   总被引：1，自引：0，他引：1  

J.N Andrews  I.S Giles  R.L.F Kay  D.J Lee  J.K Osmond  J.B Cowart  P Fritz  J.F Barker  J Gale 《Geochimica et cosmochimica acta》1982,46(9):1533-1543

The solution of radioelements and radiogenic ⁴He by groundwaters in fractured rocks is dependent upon the radioelement distribution in the rock matrix and the extent of the rock-water interface. The ${}^{234}\text{U}{}^{238}\text{U}$ activity ratio and the dissolved U, Rn and He contents of such groundwaters respond to changes in the flow regime with time. Although ${}^{234}\text{U}{}^{238}\text{U}$ activity ratios change with groundwater residence time as a consequence of ²³⁴Th-recoil induced solution of ²³⁴U, the activity ratio is strongly influenced by the U distribution within fractures, by the extent of the rock-water interface and by the amount of ²³⁸U in solution. A model for the quantitative evaluation of these effects is presented.Groundwaters from depths up to 880 m in the Stripa granite have variable dissolved uranium contents and ${}^{234}\text{U}{}^{238}\text{U}$ activity ratios. The uranium geochemistry is primarily determined by variations in flow path rather than by groundwater age.Dissolved radiogenic ⁴He in the groundwaters increases with their depth of origin, and is dependent upon the U content of the granite and upon its fracture porosity. It increases with groundwater residence time but movement of ⁴He by diffusion and transport processes make the actual groundwater age indeterminate.  相似文献   

Geochemical modelling of basalts from DSDP Leg 65, East Pacific Rise,Gulf of California     

A.M. Kudo  S.E. Barker  K. Keil  Marvin H. Beeson 《Geochimica et cosmochimica acta》1982,46(12):2427-2434

Major and rare earth element (REE) data for basalts from Holes 483, 483B, and 485A of DSDP Leg 65, East Pacific Rise, mouth of the Gulf of California, support a simple fractional crystallization model for the genesis of rocks from this suite. The petrography and mineral chemistry (presented in detail elsewhere) provide no evidence for magma mixing, but rather a simple multistage cooling process. Based on its lowest TiO₂ content (0.88%), $\text{FeO}{}^1\text{MgO}$ ratio (0.95 with total Fe as FeO), and Mg# (100 $\text{Mg}\text{Mg + Fe}\text{″ = 70}$), sample 483-17-2-(78–83) has been selected as the most primitive primary magma of the samples analyzed. This is supported by the REE data which show this sample has the lowest total REE content, a $\text{La}\text{Sm}{}_{\mathrm{cn}}$ (chondrite-normalized) = 0.36, and $\text{Eu}\text{Sm}{}_{\mathrm{cn}}$ = 1.05. Because other samples analyzed have higher SiO₂, lower Mg#, and a negative Eu anomaly ($\text{Eu}\text{Sm}{}_{\mathrm{cn}}$ as low as 0.89), they are most likely derivative magmas. Wright-Doherty and trace element modelling support fractional crystallization of 14.1% plagioclase (An₈₈), 6.7% olivine (Fo₈₆), and 4.7% clinopyroxene (Wo₄₁En₄₉Fs₁₀) from 483-17-2-(78–83) to form the least differentiated sample with Mg# = 63. The $\text{La}\text{Sm}{}_{\mathrm{cn}}$ of this derivative magma is almost identical to the parent magma (0.35 to 0.36), but the other samples have higher $\text{La}\text{Sm}{}_{\mathrm{cn}}$ (0.45 to 0.51), more total REE, and lower Mg# (60 to 56). Both Wright-Doherty and trace element modelling indicate that the primary magma chosen cannot produce these more evolved samples. For the major elements, the TiO₂ and P₂O₅ are too low in the calculated versus the observed (1.38 to 1.90; 0.11 to 0.17, respectively, for example). Rayleigh fractionation calculates a lower $\text{La}\text{Sm}{}_{\mathrm{cn}}$ and requires about 60% crystal removal versus 40% for the Wright-Doherty. These more evolved samples must be derived from a parent magma different from the one selected here and, unfortunately, not sampled in this study. A magma formed by a smaller degree of partial melting with slightly more residual clinopyroxene left in the mantle than for sample 483-17-2-(78–83) is required.  相似文献   

Leaching of quartz from precambrian hypabyssal rhyolite porphyry,Llano County,Texas     

Daniel S. Barker  Russell F. Burmester 《Contributions to Mineralogy and Petrology》1970,28(1):1-8

A Precambrian hypabyssal rhyolite porphyry in central Texas has retained its original texture, although alkali feldspar phenocrysts have inverted and unmixed from zoned, single-phase high-temperature feldspar to zoned microperthite with an intermediate microcline host.Blue quartz phenocrysts owe their color to dispersion by zircon inclusions. Neutron activation analysis reveals substitution of tetravalent cations for silicon in the quartz.In two outcrops, quartz and albite have been completely leached from the rock and K-feldspar added, leaving the texture intact. The leaching was most likely accomplished by residual brine from an overlying Lower Cretaceous evaporite deposit subsequently removed by erosion.  相似文献   

Nocturnal swimming ofScolecolepides viridis (Polychaeta: Spionidae)     

Daniel M. Dauer  R. Michael Ewing  Gary H. Tourtellotte  H. Russell Barker 《Estuaries and Coasts》1980,3(2):148-149

AdultScolecolepides viridis were collected by nocturnal plankton tows in the Lafayette River, Norfolk, Virginia. All adults (40–70 mm) were filled with ripe gametes. Swimming individuals were collected only at night on ebb tides. Large (36–60 setigers) post-metamorphic worms were also collected in the plankton. The occurrence of down estuary adult movement is used to explain paradoxical information concerning this species within estuary distribution and early development.  相似文献   

A theoretical model of the stable sulfur isotope distribution in marine sediments     

Bo Barker Jorgensen 《Geochimica et cosmochimica acta》1979,43(3):363-374

A diffusion-diagenesis model of the sulfur cycle is developed to calculate theoretical distributions of stable sulfur isotopes in marine sediments. The model describes the depth variation in δ³⁴S of dissolved sulfate and H₂S. and of pyrite. The effects of sulfate reduction, sulfate and H₂S diffusion. and of sedimentation are considered as well as the bacterial isotope fractionation and the degree of pyrite formation. Under open system conditions of sulfur diagenesis the isotopic difference, ΔSO^2?₄ — H₂S, tends to increase with depth being smaller than the bacterial fractionation factor near the sediment surface and larger in deeper layers. The two isotopes in SO^2?₄ or in H₂S do not diffuse in the same proportion as they occur in the porewater. This explains why sulfur, which is incorporated from seawater sulfate by diffusion and precipitation as pyrite, can be enriched in ³²S relative to the seawater sulfate. The model calculations demonstrate the importance of taking the whole dynamic sulfur cycle into account before drawing conclusions about sulfur diagenesis from the stable isotope distribution.  相似文献   

Biogeochemistry of pyrite and iron sulfide oxidation in marine sediments     

Axel Schippers  Bo Barker Jørgensen 《Geochimica et cosmochimica acta》2002,66(1):85-92

Pyrite (FeS₂) and iron monosulfide (FeS) play a central role in the sulfur and iron cycles of marine sediments. They may be buried in the sediment or oxidized by O₂ after transport by bioturbation to the sediment surface. FeS₂ and FeS may also be oxidized within the anoxic sediment in which NO₃⁻, Fe(III) oxides, or MnO₂ are available as potential electron acceptors. In chemical experiments, FeS₂ and FeS were oxidized by MnO₂ but not with NO₃⁻ or amorphous Fe(III) oxide (Schippers and Jørgensen, 2001). Here we also show that in experiments with anoxic sediment slurries, a dissolution of tracer-marked ⁵⁵FeS₂ occurred with MnO₂ but not with NO₃⁻ or amorphous Fe(III) oxide as electron acceptor. To study a thermodynamically possible anaerobic microbial FeS₂ and FeS oxidation with NO₃⁻ or amorphous Fe(III) oxide as electron acceptor, more than 300 assays were inoculated with material from several marine sediments and incubated at different temperatures for > 1 yr. Bacteria could not be enriched with FeS₂ as substrate or with FeS and amorphous Fe(III) oxide. With FeS and NO₃⁻, 14 enrichments were obtained. One of these enrichments was further cultivated anaerobically with Fe²⁺ and S⁰ as substrates and NO₃⁻ as electron acceptor, in the presence of ⁵⁵FeS₂, to test for co-oxidation of FeS₂, but an anaerobic microbial dissolution of ⁵⁵FeS₂ could not been detected. FeS₂ and FeS were not oxidized by amorphous Fe(III) oxide in the presence of Fe-complexing organic compounds in a carbonate-buffered solution at pH 8. Despite many different experiments, an anaerobic microbial dissolution of FeS₂ could not be detected; thus, we conclude that this process does not have a significant role in marine sediments. FeS can be oxidized microbially with NO₃⁻ as electron acceptor. O₂ and MnO₂, but not NO₃⁻ or amorphous Fe(III) oxide, are chemical oxidants for both FeS₂ and FeS.  相似文献   

Modeling the seismic source and tsunami generation of the December 12, 1992 Flores Island,Indonesia, earthquake   总被引：3，自引：0，他引：3  

Dannie Hidayat  Jeffrey S. Barker  Kenji Satake 《Pure and Applied Geophysics》1995,144(3-4):537-554

On December 12, 1992 a large earthquake (M _s 7.5) occurred just north of Flores Island, Indonesia which, along with the tsunami it generated, killed more than 2,000 people. In this study, teleseismicP andSH waves, as well asPP waves from distances up to 123°, are inverted for the orientations and time histories of multiple point sources. By repeating the inversion for reasonable values of depth, time separation and spatial separation, a 2-fault model is developed. Next, the vertical deformation of the seafloor is estimated from this fault model. Using a detailed bathymetric model, linear and nonlinear tsunami propagation models are tested. The data consist of a single tide gauge record at Palopo (650 km to the north), as well as tsunami runup height measurements from Flores Island and nearby islands. Assuming a tsunami runup amplification factor of two, the two-fault model explains the tide gauge record and the tsunami runup heights on most of Flores Island. It cannot, however, explain the large tsunami runup heights observed near Leworahang (on Hading Bay) and Riangkroko (on the northeast peninsula). Massive coastal slumping was observed at both of these locations. A final model, which in addition to the two faults, includes point sources of large vertical displacement at these two locations explains the observations quite well.  相似文献   

Two-dimensional resistivity imaging and modelling in areas of complex geology   总被引：2，自引：0，他引：2  

D.H Griffiths  R.D Barker 《Journal of Applied Geophysics》1993,29(3-4)

A system is described for the automatic measurement of electrical resistivity pseudo-sections. This comprises a linear array of up to 32 electrodes connected through a multicore cable to a computer controlled switching module and a resistivity meter. The processing of the measured sections to produce two-dimensional true resistivity images of the subsurface is briefly described. Some account is given of the capabilities and limitations of the technique. This is illustrated by a series of computed constant separation traverses for models of simple subsurface structures. Examples of processed images derived from sections measured in areas of relatively complex geology follow, a comparison being made of the interpretations obtained using an automatic imaging method and a manual iterative approach. It is concluded that with the equipment and software so far developed, in areas of modest subsurface geological complexity where some control is available and where the structures are essentially two-dimensional, then good approximations to the true geoelectric sections can be obtained down to depths of between 100 and 200 m.  相似文献   

Interpretation of Holocene lake-level change from diatom assemblages in Lake Sidi Ali,Middle Atlas,Morocco   总被引：1，自引：0，他引：1  

P. A. Barker  N. Roberts  H. F. Lamb  S. van der Kaars  A. Benkaddour 《Journal of Paleolimnology》1994,12(3):223-234

While palaeohydrological changes in non-outlet lakes provide a key proxy indicator of past climatic fluctuations, for lake systems which have been chemically insensitive, it is necessary to use indicators of water depth rather than salinity to reconstruct their hydro- climatic histories. A study of diatoms in the modern sediments of Sidi Ali, a non-outlet lake in the Middle Atlas of Morocco, has shown a statistically significant correlation between water depth and the ratio of planktonic to littoral diatoms. This relationship is used to calibrate fossil diatom assemblages from a lake sediment core from the same lake to provide a quantitative index of water levels over the pastc. 6500 years. Palaeoecological evidence suggests that climatically induced hydrological variations have dominated the bulk of the mid-late Holocene lake sediment record, with significant human-induced catchment disturbance only occurring during the twentieth century. The pattern of water depth fluctuations suggests that the response time of the regional groundwater system to climatic forcing is <100 years.This is the third in a series of papers published in this issue on the paleolimnology of arid regions. These papers were presented at the Sixth International Palaeolimnology Symposium held 19–21 April, 1993 at the Australian National University, Canberra, Australia. Dr A. R. Chivas served as guest editor for these papers.  相似文献   

Natural Attenuation of Aromatic Hydrocarbons in a Shallow Sand Aquifer   总被引：8，自引：0，他引：8  

J.P. Barker  G. C. Patrick  D. Major 《Ground Water Monitoring & Remediation》1987,7(1):64-71

Inadvertent release of petroleum products such as gasoline into the subsurface can initiate ground water contamination, particularly by the toxic, water-soluble and mobile gasoline components: benzene, toluene and xylenes (BTX). This study was undertaken to examine the processes controlling the rate of movement and the persistence of dissolved BTX in ground water in a shallow, unconfined sand aquifer.
Water containing about 7.6 mg/ L total BTX was introduced below the water table and the migration of contaminants through a sandy aquifer was monitored using a dense sampling network. BTX components migrated slightly slower than the ground water due to sorptive retardation. Essentially all the injected mass of BTX was lost within 434 days due to biodegradation. Rates of mass loss were similar for all monoaromatics; benzene was the only component to persist beyond 270 days. Laboratory biodegradation experiments produced similar rates, even when the initial BTX concentration varied.
A dominant control over BTX biodegradation was the availability of dissolved oxygen. BTX persisted at the field site in layers low in dissolved oxygen. Decreasing mass loss rates over time observed in the field experiment are not likely due to first-order deeradation rates, but rather to the persistence of small fractions of BTX mass in anoxic layers.  相似文献