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11.
Multiple Sources of Metals of Mineralization in Lower Cambrian Black Shales of South China: Evidence from Geochemical and Petrographic Study 总被引：6，自引：0，他引：6
Jan Pa&#;ava Bohdan K&#;íbek Anna Vymazalová Ivana Sýkorová Karel &#;ák Beate Orberger 《Resource Geology》2008,58(1):25-42
Black shales of the Lower Cambrian Niutitang Formation in southern China (Huangjiawan mine, Zunyi region, northern part of the Guizhou Province) host regionally distributed stratiform polymetallic Ni‐Mo‐platinum group elements (PGE)‐Au phosphate‐ and sulfide‐rich ores. These are confined to a ≥0.2‐m thick ore horizon composed of mineralized bodies of algal onkolites, phosphate nodules, and sulfide and shale clasts in a mineralized phosphate‐ and organic matter‐rich matrix. Compared to footwall and hanging wall shales, the ore bed is strongly enriched in Ni (up to 100‐fold), As (up to 97‐fold), Mo (up to 95‐fold), Sb (up to 67‐fold), Rh (up to 49‐fold), Cu (up to 37‐fold), Pd (up to 33‐fold), Ru (up to 24‐fold), Zn (up to 23‐fold), Pt (up to 21‐fold), Ir (up to 15‐fold), Co (up to 14‐fold), and Pb (up to 13‐fold). Even footwall and hanging wall black shales are significantly enriched by Mo (21‐fold) and Ni (12‐fold) but depleted in Cr in comparison to average Cambrian black shale. Organic matter is represented by separate accumulations dispersed in the rock matrix or as biotic bitumen droplets and veinlets in ore clasts. Similar organic carbon (Corg) values in an ore bed and enclosing footwall and hanging wall shales of little mineralization indicate that metal accumulation was not controlled only by biogenic productivity and organic matter accumulation rate. Evaporitic conditions during sedimentation of the basal part of the Niutitang Formation were documented by an occurrence of preserved Ni‐, V‐, Cr‐, and Cu‐enriched phosphate‐rich hardground with halite and anhydrite pseudomorphs on the paleosurface of the underlying Neoproterozoic carbonates. Neoproterozoic black shales of the Doushantuo Formation are characterized by increased metal concentrations. Comparison of metal abundances in both hardground and Doushantuo black shales indicate that black shales could have become a source of metal‐rich hardground during weathering. The polymetallic Ni‐Mo‐PGE sulfide‐rich ore bed is interpreted to represent a remnant of shallow‐water hardground horizon rich in metals, which originated in a sediment‐starved, semi‐restricted, seawater environment. During the Early Cambrian transgression an influx of fresh seawater and intensive evaporation, together with the hydrothermal enrichment of seawater in a semi‐restricted basin, resulted in the formation of dense metalliferous brines; co‐precipitation of metals together with phosphates and sulfides occurred at or above the oxic–anoxic sediment interface. Metal‐enriched hardground was disintegrated by the action of waves or bottom currents and deposited in a deeper part of the anoxic basin. Contemporaneously with the formation of a polymetallic Ni‐Mo‐PGE‐Au sulfide ore bed, economic sedimentary exhalative (SEDEX)‐type barite deposits were forming in a stratigraphically and geotectonically similar setting. The results of geochemical study at the Shang Gongtang SEDEX‐type Ba deposit indicate that concentrations of Ag, As, Cr, Cu, Fe, Mn, Ni, Pb, Sb, V, Zn and other metals decrease from top of the barite body toward the hanging wall black shale. Lower Cambrian black shales of the Niutitang Formation above the barite body also display similar element abundances as Neoproterozoic black shales of the Doushantuo Formation, developed in the footwall of the barite body. But the geochemical composition of the sulfide layer is different from the Ni‐Mo ore bed, showing only elevated Pb, Cu, Ni and Mo values. It is suggested that hydrothermal brines at Shang Gongtang might have leached metals from footwall Neoproterozoic sequences and became, after mixing with normal seawater, an additional source of Ag, Cr, Cu, Pb, Sb, Zn, Ni, PGE, V and other metals. 相似文献
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Arsenic speciation and turnover in intact organic soil mesocosms during experimental drought and rewetting 总被引：1，自引：0，他引：1
Christian Blodau Beate Fulda Markus Bauer Klaus-Holger Knorr 《Geochimica et cosmochimica acta》2008,72(16):3991-4007
Wetlands are significant sources and sinks for arsenic (As), yet the geochemical conditions and processes causing a release of dissolved arsenic and its association with the solid phase of wetland soils are poorly known. Here we present experiments in which arsenic speciation was determined in peatland mesocosms in high spatiotemporal resolution over 10 months. The experiment included a drought/rewetting treatment, a permanently wet, and a defoliated treatment. Soil water content was determined by the TDR technique, and arsenic, iron and sulfate turnover from mass balancing stocks and fluxes in the peat, and solid phase contents by sequential extractions. Arsenic content ranged from 5 to 25 mg kg−1 and dissolved concentrations from 10 to 300 μg L−1, mainly in form of As(III), and secondarily of As(V) and dimethylated arsenic (DMA). Total arsenic was mainly associated with amorphous iron hydroxides (R2 > 0.95, α < 0.01) and deeper into the peat with an unidentified residual fraction. Arsenic release was linked to ferrous iron release and primarily occurred in the intensely rooted uppermost soil. Volumetric air contents of 2-13 % during drought eliminated DMA from the porewater and suppressed its release after rewetting for >30 d. Dissolved As(III) was oxidized and immobilized as As(V) at rates of up to 0.015 mmol m−3 d−1. Rewetting mobilized As(III) at rates of up to 0.018 mmol m−3 d−1 within days. Concurrently, Fe(II) was released at depth integrated rates of up 20 mmol m−3 d−1. The redox half systems of arsenic, iron, and sulfur were in persistent disequilibrium, with H2S being a thermodynamically viable reductant for As(V) to As(III). The study suggests that rewetting can lead to a rapid release of arsenic in iron-rich peatlands and that methylation is of lesser importance than co-release with iron reduction, which was largely driven by root activity. 相似文献
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Numerous studies investigated the influence of abiotic (meteorological conditions) and biotic factors (tree characteristics) on stemflow generation. Although these studies identified the variables that influence stemflow volumes in simply structured forests, the combination of tree characteristics that allows a robust prediction of stemflow volumes in species‐rich forests is not well known. Many hydrological applications, however, require at least a rough estimate of stemflow volumes based on the characteristics of a forest stand. The need for robust predictions of stemflow motivated us to investigate the relationships between tree characteristics and stemflow volumes in a species‐rich tropical forest located in central Panama. Based on a sampling setup consisting of ten rainfall collectors, 300 throughfall samplers and 60 stemflow collectors and cumulated data comprising 26 rain events, we derive three main findings. Firstly, stemflow represents a minor hydrological component in the studied 1‐ha forest patch (1.0% of cumulated rainfall). Secondly, in the studied species‐rich forest, single tree characteristics are only weakly related to stemflow volumes. The influence of multiple tree parameters (e.g. crown diameter, presence of large epiphytes and inclination of branches) and the dependencies among these parameters require a multivariate approach to understand the generation of stemflow. Thirdly, predicting stemflow in species‐rich forests based on tree parameters is a difficult task. Although our best model can capture the variation in stemflow to some degree, a critical validation reveals that the model cannot provide robust predictions of stemflow. A reanalysis of data from previous studies in species‐rich forests corroborates this finding. Based on these results and considering that for most hydrological applications, stemflow is only one parameter among others to estimate, we advocate using the base model, i.e. the mean of the stemflow data, to quantify stemflow volumes for a given study area. Studies in species‐rich forests that wish to obtain predictions of stemflow based on tree parameters probably need to conduct a much more extensive sampling than currently implemented by most studies. Copyright © 2015 John Wiley & Sons, Ltd. 相似文献
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Beate Orberger Christiane Wagner Alina Tudryn Richard Wirth Rachael Morgan José D. Fabris Jean Marc Greneche Carlos Rosière 《Physics and Chemistry of Minerals》2014,41(9):651-667
The pseudomorphic transformation of magnetite into hematite (martitization) is widespread in geological environments, but the process and mechanism of this transformation is still not fully understood. Micro- and nano-scale techniques—scanning electron microscopy, focused ion bean transmission electron microscopy, and Raman spectroscopy—were used in combination with X-ray diffraction, Curie balance and magnetic hysteresis analyses, as well as Mössbauer spectroscopy on martite samples from a banded iron formation (2.9 Ga, Dharwar Craton, India), and from lateritic soils, which have developed on siliciclastic and volcanic rocks previously affected by metamorphic fluids (Minas Gerais, Brazil). Octahedral crystals from both samples are composed of hematite with minor patches of magnetite, but show different structures. The Indian crystals show trellis of subhedral magnetite hosting maghemite in sharp contact with interstitial hematite crystals, which suggests exsolution along parting planes. Grain boundary migrations within the hematite point to dynamic crystallization during deformation. Dislocations and fluid inclusions in hematite reflect its precipitation related to a hydrothermal event. In the Brazilian martite, dislocations are observed and maghemite occurs as Insel structures and nano-twin sets. The latter, typical for the hematite, are a transformation product from maghemite into hematite. For both samples, a deformation-induced hydrothermally driven transformation from magnetite via maghemite to hematite is proposed. The transformation from magnetite into maghemite comprises intermediate non-stoichiometric magnetite steps related to a redox process. This study shows that martite found in supergene environment may result from earlier hypogene processes. 相似文献
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On the ‘Divergence Problem’ in Northern Forests: A review of the tree-ring evidence and possible causes 总被引：1，自引：0，他引：1
Rosanne D'Arrigo Rob Wilson Beate Liepert Paolo Cherubini 《Global and Planetary Change》2008,60(3-4):289-305
An anomalous reduction in forest growth indices and temperature sensitivity has been detected in tree-ring width and density records from many circumpolar northern latitude sites since around the middle 20th century. This phenomenon, also known as the “divergence problem”, is expressed as an offset between warmer instrumental temperatures and their underestimation in reconstruction models based on tree rings. The divergence problem has potentially significant implications for large-scale patterns of forest growth, the development of paleoclimatic reconstructions based on tree-ring records from northern forests, and the global carbon cycle. Herein we review the current literature published on the divergence problem to date, and assess its possible causes and implications. The causes, however, are not well understood and are difficult to test due to the existence of a number of covarying environmental factors that may potentially impact recent tree growth. These possible causes include temperature-induced drought stress, nonlinear thresholds or time-dependent responses to recent warming, delayed snowmelt and related changes in seasonality, and differential growth/climate relationships inferred for maximum, minimum and mean temperatures. Another possible cause of the divergence described briefly herein is ‘global dimming’, a phenomenon that has appeared, in recent decades, to decrease the amount of solar radiation available for photosynthesis and plant growth on a large scale. It is theorized that the dimming phenomenon should have a relatively greater impact on tree growth at higher northern latitudes, consistent with what has been observed from the tree-ring record. Additional potential causes include “end effects” and other methodological issues that can emerge in standardization and chronology development, and biases in instrumental target data and its modeling. Although limited evidence suggests that the divergence may be anthropogenic in nature and restricted to the recent decades of the 20th century, more research is needed to confirm these observations. 相似文献
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Benjamin Bernard Silvana Hidalgo Claude Robin Bernardo Beate Jenny Quijozaca 《Bulletin of Volcanology》2014,76(9):1-20
Based on geochronological, petrological, stratigraphical, and sedimentological data, this paper describes the deposits left by the most powerful Holocene eruption of Chachimbiro compound volcano, in the northern part of Ecuador. The eruption, dated between 3640 and 3510 years BC, extruded a ～650-m-wide and ～225-m-high rhyodacite dome, located 6.3 km east of the central vent, that exploded and produced a large pyroclastic density current (PDC) directed to the southeast followed by a sub-Plinian eruptive column drifted by the wind to the west. The PDC deposit comprises two main layers. The lower layer (L1) is massive, typically coarse-grained and fines-depleted, with abundant dense juvenile fragments from the outgassed dome crust. The upper layer (L2) consists of stratified coarse ash and lapilli laminae, with juvenile clasts showing a wide density range (0.7–2.6 g cm?3). The thickness of the whole deposit ranges from few decimeters on the hills to several meters in the valleys. Deposits extending across six valleys perpendicular to the flow direction allowed us to determine a minimum velocity of 120 m s?1. These characteristics show striking similarities with deposits of high-energy turbulent stratified currents and in particular directed blasts. The explosion destroyed most of the dome built during the eruption. Subsequently, the sub-Plinian phase left a decimeter-thick accidental-fragment-rich pumice layer in the Chachimbiro highlands. Juvenile clasts, rhyodacitic in composition (SiO2?=?68.3 wt%), represent the most differentiated magma of Chachimbiro volcano. Magma processes occurred at two different depths (～14.4 and 8.0 km). The hot (～936 °C) deep reservoir fed the central vent while the shallow reservoir (～858 °C) had an independent evolution, probably controlled by El Angel regional fault system. Such destructive eruptions, related to peripheral domes, are of critical importance for hazard assessment in large silicic volcanic complexes such as those forming the Frontal Volcanic Arc of Ecuador and Colombia. 相似文献
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We have analysed ring-width records of two Miocene coniferous trees with an absolute age of 15–20 million years. Such data may reflect solar periodicities from the prehistoric past. Evidence for a main period of ～ 12.5 years has been found. This is near the present basic solar activity period of ～ 11 years. Other periodic components appear at 220, 150 and 53 years, respectively, which may also be related to solar variations. 相似文献
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Philip?SchütteEmail author Massimo?Chiaradia Fernando?Barra Diego?Villagómez Bernardo?Beate 《Mineralium Deposita》2012,47(4):383-410
Mineralization and alteration events at ten Miocene porphyry Cu and porphyry-related epithermal mineral deposits in southern,
central, and northern Ecuador were dated by means of molybdenite Re-Os, biotite and alunite 40Ar/39Ar, and titanite U-Pb geochronology. Most of these hydrothermal events show a spatio-temporal correlation with porphyry intrusion
emplacement as constrained by zircon U-Pb ages. The total age range for these events spans the 23.5–6.1 Ma period, without
displaying systematic along- or across-arc age distribution trends. While epithermal deposits tend to be spatially associated
with volcanic rocks of a similar age, porphyry Cu deposits in Ecuador are frequently spatially associated with deeper-seated
basement units and batholith-scale precursor intrusive systems assembled over ≥5 m.y. time periods. In most cases, formation
of the porphyry Cu deposits is related to the youngest magmatic (-hydrothermal) event in a given area, postdating batholith
construction at a regional scale. The majority of Miocene deposits occurs in southern Ecuador where areally extensive, post-mineralization
(late Miocene to recent) volcanic sequences with the potential to conceal mineralization at depth are lacking. Only few Miocene
deposits occur in northern-central Ecuador, where they mainly crop out in the Western Cordillera, west of the productive present-day
volcanic arc. The surface distribution of post-mineralization arc volcanism reflects along-arc variations in subducting slab
geometry. Porphyry Cu and epithermal deposits in Ecuador define a Miocene metallogenic belt broadly continuous with its coeval
counterpart in northern-central Peru. Although both belt segments were formed in an overall similar tectonomagmatic and metallogenic
setting, their respective metal endowments differ significantly. 相似文献