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11.
Spatiotemporal variations of the quasi-biennial oscillation (QBO) in temperature and ozone over the tropical–subtropical belts (40°N–40°S) have been studied using Microwave Limb Sounder data for the period 1992–1999. Wavelet analysis has been performed to study inter-annual variations in amplitude and phases of the QBO. Latitude-height cross-sections of the amplitudes of temperature and ozone QBO exhibit a double-peak structure near the equator. Phase structure reveals that the temperature QBO descended faster than the ozone QBO. Cross-wavelet analysis shows an anti-phase relation between the amplitudes of the temperature and ozone QBO in the upper stratospheric region, whereas in-phase relation exists in the middle stratospheric region.  相似文献   
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Summary Latitude-altitude structure of ozone QBO over the tropical-subtropical stratosphere (40° S–40° N) has been explored by analyzing Microwave Limb Sounder (MLS) aboard Upper Atmospheric Research Satellite (UARS) data for the period 1992–1999 using the multifunctional regression model. The inferred ozone QBO shows two maxima located at 22 hPa and 10 hPa with coefficient of 2–3% per 10 m/s centered at the equator. The equatorial maxima are out of phase with each other. Subtropics exhibit two peak structure near 14 hPa but of opposite sign to that of equatorial maximum near 10 hPa. Over the equatorial region, positive (zonal winds westerly) coefficients overlay negative (zonal winds easterlies) coefficients which descend with time. A pattern of equatorial maximum and two subtropical minima appears in the months December to February near 10 hpa and it propagates upward with progression of seasons. Equatorial QBO is seasonally asynchronous while subtropical QBO is seasonally synchronous. Correspondence: Suvarna Fadnavis, Physical Meteorology and Aerology Division, Indian Institute of Tropical Meteorology, Dr. Homi Bhabha Road, Pashan, Pune 411008, India  相似文献   
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Temporal and spatial variability of indoor air volatile organic compound (VOC) concentrations can complicate vapor intrusion (VI) assessment and decision-making. Indicators and tracers (I&T) of VI, such as differential temperature, differential pressure, and indoor radon concentration, are low-cost lines of evidence to support sampling scheduling and interpretation of indoor air VOC sampling results. This study compares peak indoor air chlorinated VOC concentrations and I&T conditions before and during those peak events at five VI sites. The sites differ geographically and in their VI conceptual site models (CSM). Relative to site-specific baseline values, the results show that cold or falling outdoor temperatures, rising cross slab differential pressures, and increasing indoor radon concentrations can predict peak VOC concentrations. However, cold outdoor air temperature was not useful at one site where elevated shallow soil temperature was a better predictor. Correlations of peak VOC concentrations to elevated or rising barometric pressure and low wind speed were also observed with some exceptions. This study shows how the independent variables that control or predict peak indoor air VOC concentrations are specific to building types, climates, and VI CSMs. More I&T measurements at VI sites are needed to identify scenario-specific baseline and peak related I&T conditions to improve decision-making.  相似文献   
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Sampling of particulate matter with aerodynamic diameter cut off at 2.5 μm (PM2.5) has been carried out over a semi urban site of Pune and an urban site of Hyderabad. Analysis of elemental Carbon (EC) and Organic Carbon (OC) present in PM2.5 was carried out using advanced Desert Research Institute’s (DRI) Thermal/Optical Carbon Analyzer operated on IMPROVE_ A (Interagency Monitoring of Protected Visual Environments_ A) protocol. It is found that average concentration of EC and OC both at Pune and Hyderabad was highest during winter season and lowest during monsoon season. Winter high is mainly controlled by inversion, whereas monsoon low is due to rain-out and wash-out process. OC/EC ratio showed higher variation over Pune compared to that over Hyderabad in different seasons, indicating divergent sources of emission of OC and EC at Pune. Formation of Secondary Organic Carbon (SOC) has also been identified as one of the reasons for wide variation in OC/EC ratio value in different seasons over both the sites.  相似文献   
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There has been a considerable improvement in the knowledge of stratospheric positive ion chemistry during the last decade. Results of several in-situ measurements of ion composition have been reported. Total ion density has also been measured with greater accuracy. In this work, theoretical study has been made to reproduce the main features of the above observations. Difficulties encountered in such studies are discussed. Finally models of total ion density and ion composition are given.  相似文献   
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Seven year data of hourly surface ozone concentration is analyzed to study diurnal cycle, trends, excess of ozone levels above threshold value and cumulative ozone exposure indices at a tropical megacity, Delhi. The ozone levels clearly exhibit a diurnal cycle, similar to what has been found in other urban places. A sharp increase in the ozone levels during forenoon and a sharp decrease in the early afternoon can be observed. The average rate of increase in ozone concentration between 09 and 12 h has been observed to be 7.1 ppb h−1. We find that the daily maximum and daytime 8-h (10–17 h) ozone levels are increasing at a rate of about 1.7 (± 0.7) and 1.3 (± 0.56) ppb y−1, respectively. The directives on ozone pollution in ambient air provided by United Nations Economic Commission for Europe and World Health Organization for vegetation (AOT40) and human health protection were used to assess the air quality. The present surface ozone levels in the city are high enough to exceed “Critical Levels” which are considered to be safe for human health, vegetation and forest. The human health threshold was exceeded for up to ~45 days per year. The AOT40 (Accumulated exposure Over a Threshold of 40 ppb) threshold was exceeded significantly during winter (D-J-F) and pre-monsoon (M-A-M) (Rabi crop growing season) season in India. Translating AOT40 exceedances during pre-monsoon into relative yield loss we estimate yield loss of 22.7%, 22.5%, 16.3% and 5.5% for wheat, cotton, soybean and rice, respectively.  相似文献   
18.
Below-cloud aerosol scavenging is generally estimated from field measurements using advanced instruments that measure changes in aerosol distributions with respect to rainfall. In this study, we discuss various scavenging mechanisms and scavenging coefficients from past laboratory and field measurements. Scavenging coefficients derived from field measurements (representing natural aerosols scavenging) are two orders higher than that of theoretical ones for smaller particles (Dp < 2 μm). Measured size-resolved scavenging coefficients can be served as a better option to the default scavenging coefficient (e.g. a constant of 10?4 s?1 for all size of aerosols, as used in the CALPUFF model) for representing below-cloud aerosol scavenging. We propose scavenging correction parameter (CR) as an exponential function of size-resolved scavenging coefficients, winds and width in the downwind of the source–receptor system. For a wind speed of 3 m s?1, CR decrease with the width in the downwind for particles of diameters Dp < 0.1 μm but CR does not vary much for particles in the accumulation mode (0.1 < Dp < 2 μm). For a typical urban aerosol distribution, assuming 3 m s?1 air-flow in the source–receptor system, 10 km downwind width, 2.84 mm h?1 of rainfall and using aerosol size dependent scavenging coefficients in the CR, scavenging of aerosols is found to be 16% in number and 24% in volume of total aerosols. Using the default scavenging coefficient (10?4 s?1) in the CALPUFF model, it is found to be 64% in both number and volume of total aerosols.  相似文献   
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This paper presents three baseline scenarios of no policy action computed by the IMAGE 2 model. These scenarios cover a wide range of coupled global change Indicators, including: energy demand and consumption; food demand, consumption, and production; changes in land cover including changes in extent of agricultural land and forest; emissions of greenhouse gases and ozone precursors; and climate change and its impacts on sea level rise, crop productivity and natural vegetation. Scenario information is available for the entire world with regional and grid scale detail, and covers from 1970 to 2100. The scenarios indicate that the coming decades could be a period of relatively rapid global environmental change as compared to the period before and after. The natural vegetation in industrialized regions could be threatened by climate change, but abandonment of agricultural lands could also make new lands available for reforestation and revegetation. The opposite is true for most of Asia and Africa. Here the impacts of climate change on vegetation may not be as significant as in temperate climates, but the demand for food will lead to a significant expansion of agricultural lands at the expense of remaining forests and other natural areas.  相似文献   
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