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91.
This paper presents the extension of the self-calibrating method to the coupled inverse modelling of groundwater flow and mass transport. The method generates equally likely solutions to the inverse problem that display the variability as observed in the field and are not affected by a linearisation of the state equations. Conditioning to the state variables is measured by an objective function including, among others, the mismatch between the simulated and measured concentrations. Conditioning is achieved by minimising the objective function by gradient-based methods. The gradient contains the partial derivatives of the objective function with respect to: log conductivities, log storativities, prescribed heads at boundaries, retardation coefficients and mass sources. The derivatives of the objective function with respect to log conductivity are the most cumbersome and need the most CPU-time to be evaluated. For this reason, to compute this derivative only advective transport is considered. The gradient is calculated by the adjoint-state method. The method is demonstrated in a controlled, synthetic study, in which the worth of concentration data is analysed. It is shown that concentration data are essential to improve transport predictions and also help to improve aquifer characterisation and flow predictions, especially in the upstream part of the aquifer, even in the case that a considerable amount of other experimental data like conductivities and heads are available. Besides, conditioning to concentration data reduces the ensemble variances of estimated transmissivity, hydraulic head and concentration.  相似文献   
92.
Interpretation of the recent high-resolution survey, CANADOU 2000, in the Bay of Douarnenez (Finistère, France) allowed us to restore the morphology of the substratum and the sedimentary filling of the bay. The Brioverian and Palaeozoic substratum reveals a well-defined network of incised valleys as results of successive emergence stages of the Bay during the Quaternary. Valleys join in a westward-widened mean valley, called Ys Valley. The present-day sedimentary fill of the bay of Douarnenez appears mainly controlled by the Holocene rise and the consecutive highstand. It comprises fluvial and estuarine deposits filling up incised valleys and marine sedimentation extending out of the incised valleys. To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).To cite this article: G. Jouet et al., C. R. Geoscience 335 (2003).  相似文献   
93.
In eastern North Island New Zealand, oblique subduction of the Pacific Plate beneath the Australian Plate is associated with strain partitioning. Dextral along-strike component of displacement occurred first at Early Miocene major faults within the eastern fore-arc domain. These faults were active from Early Miocene to Pliocene times. Since Pliocene times, most of the movement occurs at western faults such as the Wellington Fault. The latter joins the back-arc domain to the north. The jump of wrench faulting is related to the oblique opening of the back-arc domain. Both phenomena are impeded southwards by the Hikurangi oceanic plateau entering the subduction zone. To cite this article: J. Delteil et al., C. R. Geoscience 335 (2003).  相似文献   
94.
Separate lead isotope analyses of leachate and residue fractions are applied to a broad spectrum of rocks commonly investigated in metallogenic studies. Resulting data highlight a systematic behavior of leachate and residue fractions with respect to lead isotope compositions, which essentially depends on the mineralogical composition of the rock. Granitoid and high-grade metamorphic rocks have residue compositions virtually identical to common lead. In contrast, low-grade metasedimentary rocks may have residue compositions swamped by radiogenic lead of leach-resistant zircons. Mafic magmatic rocks have residues that are often more radiogenic than leachates, depending on the ratio of leach-refractory zircons to common lead in the residual fraction of these rocks. Separate leachate and residue analyses of source rocks provide two lead isotope end members whose mixture may represent lead with the appropriate ore fluid composition. Our leaching experiments indicate that hot acid solutions (and by inference hydrothermal fluids) preferentially leach radiogenic lead from medium- to high-grade metamorphic and granitoid rocks, whereas they preferentially leach common lead from low-grade metasedimentary and mafic magmatic rocks. The method presented in this study provides a reliable alternative to other methods (i.e., age-correction of bulk-rock compositions) for the determination of the common lead signature of felsic to intermediate magmatic rocks. This may be preferable to age-corrected bulk-rock analyses, where ages to apply for corrections of bulk-rock data are not known or where moderately to highly altered rocks must be used. Case studies of orogenic gold and MVT districts of Peru (Pataz and San Vicente, respectively) show that separate leachate and residue lead isotope analyses carried out systematically on whole rocks allow a more thorough evaluation of metal source reservoirs than does the standard method of age-corrected or uncorrected bulk-rock analyses.  相似文献   
95.
Fluorine, chlorine, bromine, iodine and sulfur were determined in seventeen geological reference materials after extraction by pyrohydrolysis. Fluorine, Cl and S (as sulfate ions) were determined in the extraction solution by ion chromatography with detection limits of around 0.2 mg l−1. Bromine and I were measured by ICP-MS with detection limits of 1 μg l−1 for Br and 0.1 μg l−1 for I. For rock samples, using normal extraction conditions (500 mg of sample and 100 ml of final solution) detection limits were 40 mg kg−1 for F and Cl, 15 mg kg−1 for S, 0.2 mg kg−1 for Br and 0.02 mg kg−1 for I. These detection limits may be improved by increasing the amount of sample and hence the concentration of the final solution. Water was also determined using an extraction technique based on H2O degassing, reduction on zinc at 1000 °C and H2 manometry. Our results for fluorine, chlorine, sulfur and water are in good agreement with literature data. Very few reference materials have recommended values for bromine and especially for iodine. Among the analysed samples, three are new reference materials: BHVO-2, BCR-2 and AGV-2.  相似文献   
96.
Several Triassic and earliest Jurassic sedimentary units from the Colorado Plateau region have distributions of virtual geomagnetic poles (VGPs) that are highly elongate along the path of apparent polar wander (APW). This suggests that the remanent magnetizations measured in these units were acquired over an extended period of time, possibly approaching 35 m.y., and are not precisely coeval with the stratigraphic age of the rock. Comparison with other paleomagnetic studies shows that the observed elongation is not a general attribute of the age of the rock, nor is it related to paleolatitude. The rocks that yield elongate VGP distributions are dominantly red to brown mudstones, and it is possible that their remanence is dominated by a slowly acquired chemical remanent magnetization, as suggested by Larson et al. [J. Geophys. Res. 87 (1982) 1081] and other authors. However, several superficially similar units from the Colorado Plateau have nearly circular VGP distributions. The process by which remanence is acquired in clastic sedimentary rocks merits further study.  相似文献   
97.
Three large earthquakes (Mw>4.5) were triggered within 5 min, 85 km west of a Mw 6.5 earthquake in the South Iceland Seismic Zone (SISZ). We report on surface effects of these triggered earthquakes, which include fresh rupture, widespread rockfall, disrupted rockslides and block slides. Field data confirm that the earthquakes occurred along N-striking right-lateral strike-slip faults. Field data also support the conclusion from modeling of InSAR data that deformation from the second triggered event was more significant than for the other two. A major hydrological effect was the draining of water through an open fissure on a lake bed, lowering the lake level by greater than 4 m. Field relationships suggest that a component of aseismic slip could have been facilitated by water draining into the fault zone.  相似文献   
98.
Cleavage-fissility perpendicular to bedding is a common feature in the external part of fold-and-thrust belts. Three techniques were used to determine the internal distortion in the frontal Southern Pyrenees: the analysis of strain markers such as burrows and rain drops, the measurement of fissility, and the measurement of anisotropy of magnetic susceptibility (AMS). The comparison of the three techniques showed a good fit although they differ in sensitivity to penetrative strain variations in the range of deformation values explored in the study case. On the regional scale, the values of layer parallel shortening (LPS) derived from the markers analysis are very constant and account for 16–23% of shortening. These values are two to three times larger than the shortening values calculated from the restoration of the macroscopic scale structures and indicate a good decoupling above the Cardona salt Formation. This study permitted an accurate restoration of the low-amplitude el Guix detached anticline.  相似文献   
99.
We use paleomagnetic data to map Mesozoic absolute motion of North America, using paleomagnetic Euler poles (PEP). First, we address two important questions: (1) How much clockwise rotation has been experienced by crustal blocks within and adjacent to the Colorado Plateau? (2) Why is there disagreement between the apparent polar wander (APW) path constructed using poles from southwestern North America and the alternative path based on poles from eastern North America? Regarding (1), a 10.5° clockwise rotation of the Colorado Plateau about a pole located near 35°N, 102°W seems to fit the evidence best. Regarding (2), it appears that some rock units from the Appalachian region retain a hard overprint acquired during the mid-Cretaceous, when the geomagnetic field had constant normal polarity and APW was negligible.We found three well-defined small-circle APW tracks: 245–200 Ma (PEP at 39.2°N, 245.2°E, R=81.1°, root mean square error (RMS)=1.82°), 200–160 Ma (38.5°N, 270.1°E, R=80.4°, RMS=1.06°), 160 to 125 Ma (45.1°N, 48.5°E, R=60.7°, RMS=1.84°). Intersections of these tracks (the “cusps” of Gordon et al. [Tectonics 3 (1984) 499]) are located at 59.6°N, 69.5°E (the 200 Ma or “J1” cusp) and 48.9°N, 144.0°E (the 160 Ma or “J2” cusp). At these times, the absolute velocity of North America appears to have changed abruptly.North America absolute motion also changed abruptly at the beginning and end of the Cretaceous APW stillstand, currently dated at about 125 and 88 Ma (J. Geophys. Res. 97 (1992b) 19651). During this interval, the APW path degenerates into a single point, implying rotation about an Euler pole coincident with the spin axis.Using our PEP and cusp locations, we calculate the absolute motion of seven points on the North American continent. Our intention is to provide a chronological framework for the analysis of Mesozoic tectonics. Clearly, if APW is caused by plate motion, abrupt changes in absolute motion should correlate with major tectonic events. This follows because large accelerations reflect important changes in the balance of forces acting on the plate, the most important of which are edge effects (subduction, terrane accretion, etc.). Some tectonic interpretations: (1) The J1 cusp may be associated with the inception of rifting of North America away from land masses to the east; the J2 cusp seems to mark the beginning of rapid spreading in the North Atlantic. (2) The J2 cusp signals the beginning of a period of rapid northwestward absolute motion of western North America; motion of tectonostratigraphic terranes in the westernmost Cordillera seems likely to have been directed toward the south during this interval. (3) The interval 88 to 80 Ma saw a rapid decrease in the paleolatitude of North America; unless this represents a period of true polar wander, terrane motion during this time should have been relatively northward.  相似文献   
100.
Rivers, chemical weathering and Earth's climate   总被引:4,自引:0,他引:4  
We detail the results of recent studies describing and quantifying the large-scale chemical weathering of the main types of continental silicate rocks: granites and basalts. These studies aim at establishing chemical weathering laws for these two lithologies, describing the dependence of chemical weathering on environmental parameters, such as climate and mechanical erosion. As shown within this contribution, such mathematical laws are of primary importance for numerical models calculating the evolution of the partial pressure of atmospheric CO2 and the Earth climate at geological timescales. The major results can be summarized as follow: (1) weathering of continental basaltic lithologies accounts for about 30% of the total consumption of atmospheric CO2 through weathering of continental silicate rocks. This is related to their high weatherability (about eight times greater than the granite weatherability); (2) a simple weathering law has been established for basaltic lithologies, giving the consumption of atmospheric CO2 as a function of regional continental runoff, and mean annual regional temperature; (3) no such simple weathering law can be proposed for granitic lithologies, since the effect of temperature can only be identified for regions displaying high continental runoff; (4) a general law relating mechanical erosion and chemical weathering has been validated on small and large catchments. The consequences of these major advances on the climatic evolution of the Earth are discussed. Particularly, the impacts of the onset of the Deccan trapps and the Himalayan orogeny on the global carbon cycle are reinvestigated. To cite this article: B. Dupré et al., C. R. Geoscience 335 (2003).  相似文献   
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