Zur Stabilität von Margarit im System CaO-Al2O3-SiO2-H2O     

Bernhard Storre  Karl-Heinz Nitsch 《Contributions to Mineralogy and Petrology》1974,43(1):1-24

An increasing number of occurrences of margarite have been reported in the last years. However, previous experimental investigations in the system CaO-Al₂O₃-SiO₂-H₂O are limited to the synthesis of margarite and to the upper stability limit according to the reaction (1) 1 margarite?1 anorthite +1 corundum +1 H₂O (Chatterjee, 1971; Velde, 1971). Since margarite often occurs together with quartz, the upper stability limit of margarite in the presence of quartz is of special interest. Therefore, the reactions (5) 1 margarite +1 quartz ?1anorthite +1 kyanite/andalusite +1 H₂O and (6) 4 margarite+3 quartz ? 2 zoisite+5 kyanite+3 H₂O were investigated experimentally using mixtures of natural margarite (from Chester, Mass., USA), quartz, kyanite, andalusite, zoisite, and synthetic anorthite. The indicated equilibrium temperatures at water pressures equal to total pressure are: 515± 25°C at 4 kb, 545 ±15°C at 5 kb, 590±10°C at 7 kb, and 650±10°C at 9 kb for reaction (5), and 651±11°C at 10 kb, 648 ± 8°C at 12.5kb, and 643±13°C at 15kb for reaction (6), respectively. Besides this, additional brackets for equilibrium temperatures were determined for the above cited reaction (1): 520±10°C at 3 kb, 580±10°C at 5 kb, and 640± 20°C at 7 kb. On the basis of these experimentally determined reactions (1), (5), and (6) and of the reactions (3) 2 zoisite +1 kyanite? 4 anorthite +1 corundum +1 H₂O (7) 2 zoisite +1 kyanite +1 quartz ? 4 anorthite +1 H₂O and (10) 1 pyrophyllite ? 1 andalusite/kyanite+3 quartz+1 H₂O for which experimental or, in the case of reaction (3), calculated data were already available, a pressure-temperature diagram with 3 invariant points and 11 univariant reactions was developed using the method of Schreinemakers. This diagram, summarizing both experimental and phase relation studies, allows conclusions about the conditions under which margarite has been formed in nature. Margarite is limited to low grade metamorphism at water pressures up to approximately 3.5 kb; in the presence of quartz, margarite is even limited to low grade metamorphism at water pressures up to 5.5 kb. Only at water pressures higher than the values stated before margarite, and margarite+quartz, respectively, can occur in medium grade metamorphism (as defined by Winkler, 1970 and 1973). For the combined occurrence of margarite+quartz and staurolite as reported by Harder (1956) and Frey (personal communication, 1973) it may be estimated that water pressure has been greater than approximately 5.5 kb, wheras temperature has been in the range from 550 to 650°C. Furthermore, the present study shows that the assemblage zoisite+kyanite (+ H₂O) is an indicator of both pressure [P _{H 2 O}> approximately 9kb]and temperature [T> approximately 640 to 650° Cat water Pressures up to 15 kb].  相似文献   

Nitrate pollution of groundwater in the alsatian plain (France)—A multidisciplinary study of an agricultural area: The Central Ried of the ill river     

C. Bernhard  R. Carbiener  A. R. Cloots  R. Froehlicher  Ch. Schenck  L. Zilliox 《Environmental Geology》1992,20(2):125-137

The area studied is part of the Ried Central of the Ill river (Middle Alsatian plain in northeastern France). This area is located mainly in the present floodplain of the Ill. The closeness of the water table to the surface results in quasi general soil hydromorphism.The economic constraints of the last two decades led to deep changes in agricultural activities in the study area. These have essentially involved a marked extension of intensive cultivation of grain corn at the expense of grasslands. The study of the influence of this change on the parallel increase in the concentration of nitrate in groundwater is only feasible when a multidisciplinary approach is adopted.The analyses carried out in the field and in the laboratory show that nitrate reduction occurs in gleyed or peaty horizons of hydromorphic soils. The aptitude and efficiency of the permanent ambient vegetation (alluvial forests and grasslands) in retaining nitrate must be emphasized. The amount of nitrate eliminated from the aquifer by rivers fed by this aquifer is considerable. This evacuation of nitrate into the Ill is a fine example of waste and illustrates the absurdity of the economic situation responsible for excessive nitrogen fertilization of farmlands.In determining hazard zones, this study also proposes practical solutions to the problem of nitrate pollution: diminution of land area under cultivation, reintroduction of grasslands, and a more judicious use of nitrogen manure.  相似文献   

Ecological impact of urban stormwater runoff studied in experimental flumes: Population loss by drift and availability of refugial space     

Dietrich Borchardt  Bernhard Statzner 《Aquatic Sciences - Research Across Boundaries》1990,52(4):299-314

Urban stormwater runoff discharged through sewer systems into streams causes flush spills of water and pollutants in the receiving water. To make the right decisions in future plannings of the very costly rehabilitation of sewer systems, a solid ecological data base on the critical parameters of sewer overflows is badly needed. Therefore, we designed a laboratory flume which was operated in circular flow mode (to ensure adaptation of the test organisms) and in flow-through mode during the simulation of sewer overflows (to allow a proper evaluation of population loss by drift). Examples on the behaviour during the adaptation phase and the population loss during the exposure to flush spills of water and/or a mixture of sewage and clean water of a benthic invertebrate (Gammarus pulex) demonstrate the potential of the flume to identify critical parameters of sewer overflows at quasireal-world-conditions. We found clear evidence for synergetic effects since the exposure to high flow and sewage caused higher population loss ofGammarus than the sum of population loss at exposure to only high flow or only sewage. Population loss considerably depended on the availability of refugial space: if the interstices of the gravel in the flume were silted, this loss was higher than at open interstices. Only ten minutes of movement of the material forming the flume bottom reduced the population ofGammarus to about 60 or 50% of its initial size. Hence, our data strongly suggest that the characteristics of the receiving stream (refugial space, bed stability) play an important role for the potential ecological impact of a sewer overflow. Changes of stream morphology and/or creation of refugial space plus an appropriate technical solution for overflow treatment may be less costly and more effective than a large-scale technical project. Thus, the stream itself should be a major element in future management decisions.  相似文献   

Characterizing solute transport with transient storage across a range of flow rates: The evidence of repeated tracer experiments in Austrian and Italian streams     

Bernhard H. Schmid  Ilaria Innocenti  Umberto Sanfilippo 《Advances in water resources》2010

Solute transport in rivers and streams with hyporheic zone exchange and/or in-stream storage is typically affected by the prevailing flow rate. The research reported here focuses on stream tracer experiments repeated many times along the same Austrian (Mödlingbach) and Italian (Torrente Lura) channel reaches to characterize parameter dependency on flow rate. Both groups of data sets showed an increase of storage zone area and main stream area with discharge. In either case, a strong negative correlation was obtained between storage zone residence time and flow rate. From the Mödlingbach data, no clear relationship with Q emerged for the dispersion coefficient and the dead zone ratio, whereas Torrente Lura showed a clear positive correlation of the dispersion coefficient with the flow rate and a slightly negative Q-dependency for the dead zone ratio. Mödlingbach and Torrente Lura results are presented against the background of other repeat experiments reported in literature.  相似文献   

An overview of solar and stellar flare research     

Bernhard M. Haisch 《Solar physics》1989,121(1-2):3-18

An overview of the many topics discussed at IAU Colloquium No. 104 is presented as an introduction to the Proceedings. Suggested areas for future research emerging from the conference are summarized.  相似文献   

Regulation and policies of American shipping: by Ernst G. Frankel Auburn House Publishing Company,Boston, MA, 1982, 347 pp     

Bernhard J. Abrahamsson 《Marine Policy》1983,7(1):60

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Structural and metamorphic evolution of the Camughera – Moncucco, Antrona and Monte Rosa units southwest of the Simplon line,Western Alps     

Lukas M. Keller  Maurus Hess  Bernhard Fügenschuh  Stefan M. Schmid 《Eclogae Geologicae Helvetiae》2005,98(1):19-49

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Reply to Comment by W. Kurz on “Tectonic map and overall architecture of the Alpine orogen”     

Stefan M. Schmid  Bernhard Fügenschuh  Eduard Kissling  Ralf Schuster 《Eclogae Geologicae Helvetiae》2005,98(1):99-101

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Transport and sediment–water partitioning of trace metals in acid mine drainage: an example from the abandoned Kwangyang Au–Ag mine area, South Korea     

Hun-Bok Jung  Seong-Taek Yun  Bernhard Mayer  Soon-Oh Kim  Seong-Sook Park  Pyeong-Koo Lee 《Environmental Geology》2005,48(4-5):437-449

Transport and sediment–water partitioning of trace metals (Cr, Co, Fe, Pb, Cu, Ni, Zn, Cd) in acid mine drainage were studied in two creeks in the Kwangyang Au–Ag mine area, southern part of Korea. Chemical analysis of stream waters and the weak acid (0.1 N HCl) extraction, strong acid (HF–HNO₃–HClO₄) extraction, and sequential extraction of stream sediments were performed. Heavy metal pollution of sediments was higher in Chonam-ri creek than in Sagok-ri creek, because there is a larger source of base metal sulfides in the ores and waste dump upstream of Chonam-ri creek. The sediment–water distribution coefficients (K _d) for metals in both creeks were dependent on the water pH and decreased in the order Pb ≈ Al > Cu > Mn > Zn > Co > Ni ≈ Cd. K _d values for Al, Cu and Zn were very sensitive to changes in pH. The results of sequential extraction indicated that among non-residual fractions, Fe–Mn oxides are most important for retaining trace metals in the sediments. Therefore, the precipitation of Fe(–Mn) oxides due to pH increase in downstream sites plays an important role in regulating the concentrations of dissolved trace metals in both creeks. For Al, Co, Cu, Mn, Pb and Zn, the metal concentrations determined by 0.1 N HCl extraction (Korean Standard Method for Soil Pollution) were almost identical to the cumulative concentrations determined for the first three weakly-bound fractions (exchangeable + bound to carbonates + bound to Fe–Mn oxides) in the sequential extraction procedure. This suggests that 0.1 N HCl extraction can be effectively used to assess the environmentally available and/or bioavailable forms of trace metals in natural stream sediments.  相似文献   

Correction of laser scanning intensity data: Data and model-driven approaches   总被引：7，自引：0，他引：7  

Bernhard Hfle  Norbert Pfeifer 《ISPRS Journal of Photogrammetry and Remote Sensing》2007,62(6):415-433

Most airborne and terrestrial laser scanning systems additionally record the received signal intensity for each measurement. Multiple studies show the potential of this intensity value for a great variety of applications (e.g. strip adjustment, forestry, glaciology), but also state problems if using the original recorded values. Three main factors, a) spherical loss, b) topographic and c) atmospheric effects, influence the backscatter of the emitted laser power, which leads to a noticeably heterogeneous representation of the received power. This paper describes two different methods for correcting the laser scanning intensity data for these known influences resulting in a value proportional to the reflectance of the scanned surface. The first approach – data-driven correction – uses predefined homogeneous areas to empirically estimate the best parameters (least-squares adjustment) for a given global correction function accounting for all range-dependent influences. The second approach – model-driven correction – corrects each intensity independently based on the physical principle of radar systems. The evaluation of both methods, based on homogeneous reflecting areas acquired at different heights in different missions, indicates a clear reduction of intensity variation, to 1/3.5 of the original variation, and offsets between flight strips to 1/10. The presented correction methods establish a great potential for laser scanning intensity to be used for surface classification and multi-temporal analyses.  相似文献