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151.
Due to large deserts on Earth surface a thorough understanding of climate change, landscape evolution and geomorphological processes having occurred in deserts is crucial for Earth System Science. The landscapes in deserts are, however, diverse and different over the globe with regard to their geomorphological nature, human activities and geological histories. In the last decades a great number of efforts have been put to the investigation of the initial timing of the occurrence of arid climate, e. g. in northwestern China. Silty sediments in the downwind directions have been used to deduce the histories of deserts. In general, there is a lack of knowledge about processes and landscapes in Chinese drylands between the initial Miocene silt sedimentation at desert margins and the late Quaternary multiple occurrences of wetter climate with assumed large lakes in many of the deserts in northern China. The geomorphological concept of three primary triggering factors, i.e., the sediment supply, sediment availability and transport capacity of wind, and additionally the underground geology need to be fully considered for a better understanding of the environmental histories of sand seas which should not be viewed as equivalent for deserts because sand seas cover between < 1% and ca. 45% of the desert areas in various continents dependent on a complex interaction between various processes of both exogenous and endogenous origins.  相似文献   
152.
Knowledge on the stresses in shotcrete tunnel shells is of great importance, as to assess their safety against severe cracking or failure. Estimation of these stresses from 3D optical displacement measurements requires shotcrete material models, which may preferentially consider variations in the water–cement and aggregate–cement ratios. Therefore, we employ two representative volume elements within a continuum micromechanics framework: the first one relates to cement paste (with a spherical material phase representing cement clinker grains, needle-shaped hydrate phases with isotropically distributed spatial orientations, a spherical water phase, and a spherical air phase; all being in mutual contact), and the second one relates to shotcrete (with phases representing cement paste and aggregates, whereby aggregate inclusions are embedded into a matrix made up by cement paste). Elasticity homogenization follows self-consistent schemes (at the cement paste level) and Mori–Tanaka estimates (at the shotcrete level), and stress peaks in the hydrates related to quasi-brittle material failure are estimated by second-order phase averages derived from the RVE-related elastic energy. The latter permits upscaling from the hydrate strength to the shotcrete strength. Experimental data from resonant frequency tests, ultrasonics tests, adiabatic tests, uniaxial compression tests, and nanoindentation tests suggest that shotcrete elasticity and strength can be reasonably predicted from mixture- and hydration-independent elastic properties of aggregates, clinker, hydrates, water, and air, and from strength properties of hydrates. At the structural level, the micromechanics model, when combined with 3D displacement measurements, predicts that a decrease of the water–cement ratio increases the safety of the shotcrete tunnel shell.  相似文献   
153.
Strongly influenced by seasonal and interannual (i.e. El Niño‐Southern Oscillation) upwelling, the equatorial setting of the Galápagos Archipelago is divided into well‐defined temperature, nutrient and calcium carbonate saturation (Ωaragonite) regions. To understand the relationship between oceanographic properties and sediment grain associations, grain size, carbonate content and components from sea floor surface samples were analysed, representing the main geographical regions of the Galápagos Archipelago. The shallow‐water rocky reefs of the Galápagos Archipelago are characterized by mixed carbonate–siliciclastic slightly gravelly sands. Despite minor differences in carbonate content, major differences exist in the distribution and composition of key carbonate producing biota. Halimeda is absent and benthic foraminifera occur in extremely low abundance. The western side of the Galápagos Archipelago is strongly influenced by nutrient‐rich, low‐Ωaragonite, subtropical water, which generates a heterozoan carbonate biofacies in a tropical realm resembling cold‐water counterparts (i.e. serpulid, echinoderm, gastropod, barnacle and bryozoan‐rich facies). The Central East region is composed of a transitional‐heterozoan biofacies. Biofacies observed in the northern region have an increased occurrence of tropical corals, albeit with a minor overall contribution to the carbonate components. Although the temperature gradient would allow for a broader distribution of photozoan biofacies, the increased nutrient concentration and related reduced light penetration from the upwelled waters favour heterozoan carbonate factories, mimicking cool‐water, deeper or higher latitude environments. The recent sedimentary record of the Galápagos Archipelago presents a range of tropical heterozoan carbonate communities, responding to more than simply latitude or temperature but a much more complex mixture of physical, evolutionary and geological processes.  相似文献   
154.
155.
Three monazite generations were observed in garnet-bearing micaschists from the Schobergruppe in the basement to the south of the Tauern Window, Eastern Alps. Low-Y monazite of Variscan age (321?±?14?Ma) and high-Y monazite of Permian age (261?±?18?Ma) are abundant in the mica-rich rock matrix and in the outer domains of large garnet crystals. Pre-Alpine monazite commonly occurs as polyphase grains with low-Y Variscan cores and high-Y Permian rims. Monazite of Eo-Alpine age (112?±?22?Ma) is rarer and was observed as small, partly Y-enriched grains (3?wt. %?Y2O3) in the rock matrix and within garnet. Based on monazite-xenotime thermometry, Y?+?HREE values in monazite indicate minimum crystallization conditions of 500?°C during the Variscan and 650?°C for the Permian and Alpine events, respectively. Garnet zoning and thermobarometric calculations with THERMOCALC 3.21 record an amphibolite facies, high-pressure stage of ~600?°C/13?C16?kbar, followed by a thermal maximum at 650?C700?°C and 6?C9?kbar. The Eo-Alpine age for these two events is supported by inclusions of Cretaceous monazite in the garnet domains used for thermobarometric constraints and through the high growth temperatures of Eo-Alpine monazite, which is consistent with that of the thermal maximum (~700?°C). The age and growth conditions of a few Mn-rich garnet cores, sporadically present within Eo-Alpine garnet, are unclear because inclusions of monazite, plagioclase and biotite necessary for thermobarometric- and age constraints are absent. However, based on monazite thermometry, Permian and Variscan metamorphic conditions were high enough for the growth of pre-Alpine garnet. The formation of Variscan garnet and its later resorption, plus Y-release, would also explain the high Y in Permian monazite, which cannot originate from preexisting Variscan monazite only. Monazite of Variscan, Permian and/or Eo-Alpine ages were also observed in other garnet-bearing micaschists from the Schobergruppe. This suggests that the basement of the Schobergruppe was overprinted by three discrete metamorphic events at conditions of at least lower amphibolite facies. While the Variscan event affected all parts of this basement, the younger events are more pronounced in its structurally lower units.  相似文献   
156.
The macroscopically-zoned grandite from the garnetite skarn of Meka Presedla (Kopaonik Mountain, Serbia) was studied with optical microscopy, electron microprobe analysis (EMPA), Fourier transform infra-red (FT–IR), and Raman methods. The EMPA results indicate that the main core–rim compositional variations (Ca2.93–2.97Mn0.05–0.06Mg0.00–0.01Al1.14–1.26Fe3+0.72–0.83Ti0.00–0.02Si2.97–3.02O12) slightly differ along the zones, showing evidence for a quasi-cyclic alternation of the oscillatory zoning nature. Among this, considerable variation is observed only by the Al–Fe3+ substitutions in the octahedral site. The EMPA also indicate that the grandite zones compositionally vary, mostly within ±1 and ±2 mol% of the homogeneity level range, that is, Grs64±1Adr36±1Sps2 (A), Grs62±1Adr38±1Sps2 (B), Grs59±2Adr40±2Sps2 (C), Grs58±2Adr41±2Sps2 (D), and Grs58±1Adr41±1Sps2 (E). Therefore, the investigated garnet can be considered as relatively highly homogeneous. The majority of compositions lie within the narrow miscibility region of 0.58±2相似文献   
157.
Elements involved in biogeochemical cycles undergo rapid turnover at the oxic–anoxic interface of stratified lakes. Here, the presence or absence of oxygen governs abiotic and biotic processes and rates. However, achieving a detailed sampling resolution to precisely locate the oxic–anoxic interface is difficult due to a lack of fast, drift-free sensors in the working range of 10 to a few 1,000 nmol O2 L?1. Here, we demonstrate that conventional amperometric and optical microsensors can be used to resolve submicromolar oxygen concentrations in a continuous profiling mode. The amperometric drift was drastically reduced by anoxic preconditioning. In situ offset correction in the anoxic layer and a high amplification scheme allowed for an excellent detection limit of < 10 nmol L?1. The optical microsensors also showed a similar performance with a detection limit of < 20 nmol L?1. Their drift stability allowed for a laboratory calibration in combination with a minor in situ anoxic offset correction. The two different sensor systems showed virtually identical profiles during parallel use in stratified lakes. Both sensors were able to resolve the fine-scale structure at the oxic–anoxic interface and revealed hitherto unnoticed extended zones of submicromolar oxygen concentrations even below a steep oxycline. The zones extended up to several meters and showed substantial vertical variability. These results underline the need of a precise localization of the oxic–anoxic interface on a submicromolar scale in order to constrain the relevant aerobic and anaerobic redox processes.  相似文献   
158.
New data suggest syn-convergent extrusion and polyphase tectonics followed by late Variscan extension in the Strudengau area of the southern Moldanubian zone in Austria. The tectonic history can be summarized as follows: (1) The oldest ductile event is observed in HT/LP metamorphic pelitic gneisses, which preserve E-dipping foliation planes (D1-fabric) with NW–SE-trending lineations. (2) The overlying gneisses record HT/HP conditions with decompression-induced anatexis in the central part of the domain. These gneisses exhibit N–S trending, horizontal lineations along steep-dipping foliation planes (D2-fabric) crosscutting the D1-fabric of the pelitic gneisses. Along the margin, these rocks have been strongly mylonitized under amphibolite facies conditions (D2). D2 is interpreted as a significant vertical shear zone, which juxtaposes the HT/LP rocks against the orogenic lower crust. (3) Lastly, the whole area is overprinted by localized shear zones (D3-fabric) with top-to-the-NW kinematics. This newly discovered Strudengau shearing event is associated with isoclinal folding that possesses axial planes parallel to the mylonitic foliation and fold axes parallel to the stretching lineations. Initial mylonitization occurred under greenschist facies, representing the latest ductile event of the Strudengau area. The new geochronological data presented here indicate a narrow time frame (c. 323–318 Ma) for the D3 deformation. Therefore, this event is contemporaneous with the intrusion of the granites of the South Bohemian Batholith (330–310 Ma). The nearby South Bohemian Batholith and generally steep dyke swarms in the Strudengau area and to the north trend in a NE–SW preferred orientation, interpreted to be D3-synkinematic magmatism. In a regional context, the NW–SE stretching during D3 together with the synkinematic intrusion of dykes is associated with late orogenic extension in the Austrian Moldanubian Zone. Kinematic data of brittle normal faults and tension gashes are consistent with NW–SE-oriented extension under cooler conditions.  相似文献   
159.
Acid mine drainage (AMD) from the Zn–Pb(–Ag–Bi–Cu) deposit of Cerro de Pasco (Central Peru) and waste water from a Cu-extraction plant has been discharged since 1981 into Lake Yanamate, a natural lake with carbonate bedrock. The lake has developed a highly acidic pH of ∼1. Mean lake water chemistry was characterized by 16,775 mg/L acidity as CaCO3, 4330 mg/L Fe and 29,250 mg/L SO4. Mean trace element concentrations were 86.8 mg/L Cu, 493 mg/L Zn, 2.9 mg/L Pb and 48 mg/L As, which did not differ greatly from the discharged AMD. Most elements showed increasing concentrations from the surface to the lake bottom at a maximal depth of 41 m (e.g. from 3581 to 5433 mg/L Fe and 25,609 to 35,959 mg/L SO4). The variations in the H and O isotope compositions and the element concentrations within the upper 10 m of the water column suggest mixing with recently discharged AMD, shallow groundwater and precipitation waters. Below 15 m a stagnant zone had developed. Gypsum (saturation index, SI ∼ 0.25) and anglesite (SI ∼ 0.1) were in equilibrium with lake water. Jarosite was oversaturated (SI ∼ 1.7) in the upper part of the water column, resulting in downward settling and re-dissolution in the lower part of the water column (SI ∼ −0.7). Accordingly, jarosite was only found in sediments from less than 7 m water depth. At the lake bottom, a layer of gel-like material (∼90 wt.% water) of pH ∼1 with a total organic C content of up to 4.40 wet wt.% originated from the kerosene discharge of the Cu-extraction plant and had contaminant element concentrations similar to the lake water. Below the organic layer followed a layer of gypsum with pH 1.5, which overlaid the dissolving carbonate sediments of pH 5.3–7. In these two layers the contaminant elements were enriched compared to lake water in the sequence As < Pb ≈ Cu < Cd < Zn = Mn with increasing depth. This sequence of enrichment was explained by the following processes: (i) adsorption of As on Fe-hydroxides coating plant roots at low pH (up to 3326 mg/kg As), (ii) adsorption at increasing pH near the gypsum/calcite boundary (up to 1812 mg/kg Pb, 2531 mg/kg Cu, and 36 mg/kg Cd), and (iii) precipitation of carbonates (up to 5177 mg/kg Zn and 810 mg/kg Mn; all data corrected to a wet base). The infiltration rate was approximately equal to the discharge rate, thus gypsum and hydroxide precipitation had not resulted in complete clogging of the lake bedrocks.  相似文献   
160.
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