Experimental data on melting reactions of muscovite+quartz in the system K2O-Al2O3-SiO2-H2O to 20 Kb water pressure     

Dr. Bernhard Storre  Dr. Ekkehard Karotke 《Contributions to Mineralogy and Petrology》1972,36(4):343-345

New experiments on melting reactions of muscovite + quartz obtained for a mixture using a synthetic muscovite confirm he experimental data obtained for a mixture using a natural muscovite which have been reported recently. [  相似文献   

Environmental history of the south-eastern South Atlantic since the Middle Miocene: evidence from the sedimentological records of ODP Sites 1088 and 1092   总被引：1，自引：0，他引：1  

Bernhard Diekmann  Mareike Fälker†  Gerhard Kuhn† 《Sedimentology》2003,50(3):511-529

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Methane and CO₂ sorption and desorption measurements on dry Argonne premium coals: pure components and mixtures     

Andreas Busch  Yves Gensterblum  Bernhard M. Krooss 《International Journal of Coal Geology》2003,55(2-4):205-224

Sorption and desorption behaviour of methane, carbon dioxide, and mixtures of the two gases has been studied on a set of well-characterised coals from the Argonne Premium Coal Programme. The coal samples cover a maturity range from 0.25% to 1.68% vitrinite reflectance. The maceral compositions were dominated by vitrinite (85% to 91%). Inertinite contents ranged from 8% to 11% and liptinite contents around 1% with one exception (Illinois coal, 5%). All sorption experiments were performed on powdered (−100 mesh), dry coal samples.Single component sorption/desorption measurements were carried out at 22 °C up to final pressures around 51 bar (5.1 MPa) for CO₂ (subcritical state) and 110 bar (11 MPa) for methane.The ratios of the final sorption capacities for pure CO₂ and methane (in molar units) on the five coal samples vary between 1.15 and 3.16. The lowest ratio (1.15) was found for the North Dakota Beulah-Zap lignite (VR_r=0.25%) and the highest ratios (2.7 and 3.16) were encountered for the low-rank coals (VR_r 0.32% and 0.48%) while the ratio decreases to 1.6–1.7 for the highest rank coals in this series.Desorption isotherms for CH₄ and CO₂ were measured immediately after the corresponding sorption isotherms. They generally lie above the sorption isotherms. The degree of hysteresis, i.e. deviation of sorption and desorption isotherms, varies and shows no dependence on coal rank.Adsorption tests with CH₄/CO₂ mixtures were conducted to study the degree of preferential sorption of these two gases on coals of different rank. These experiments were performed on dry coals at 45 °C and pressures up to 180 bar (18 MPa). For the highest rank samples of this sequence preferential sorption behaviour was “as expected”, i.e. preferential adsorption of CO₂ and preferential desorption of CH₄ were observed. For the low rank samples, however, preferential adsorption of CH₄ was found in the low pressure range and preferential desorption of CO₂ over the entire pressure range.Follow-up tests for single gas CO₂ sorption measurements consistently showed a significant increase in sorption capacity for re-runs on the same sample. This phenomenon could be due to extraction of volatile coal components by CO₂ in the first experiment. Reproducibility tests with methane and CO₂ using fresh sample material in each experiment did not show this effect.  相似文献   

Thermobarometric data from a fossil zircon partial annealing zone in high pressure–low temperature rocks of eastern and central Crete, Greece     

Manfred R. Brix  Bernhard Stckhert  Eberhard Seidel  Thomas Theye  Stuart N. Thomson  Martina Küster 《Tectonophysics》2002,349(1-4)

A fossil partial annealing zone of fission tracks in zircon is described from high pressure–low temperature (HP–LT) rocks of the Phyllite–Quartzite Unit (PQ) on the island of Crete, Greece. Correlation of regional trends in fission track age populations with independent thermobarometric and microstructural data, and with new experimental annealing results, allows a calibration of this low temperature thermochronological method to a degree hitherto not available from other field examples.The zircon fission track (FT) ages of samples from the PQ across Crete range from original detrital signature through reduced to completely reset. The annealing is the result of a single heating period related to the HP–LT metamorphism with near-peak temperatures lasting for only a few million years some time between 24±1 and 20±1 Ma. In eastern Crete, where rocks have experienced temperatures of 300±50 °C and pressures of 0.8±0.3 GPa, zircon FT ages range from 414±24 to 145±10 Ma. Ages above 300 Ma occur mostly near the east coast of the island in rocks which have not been heated to above ca. 280 °C and probably represent a pre-Variscan source. Track lengths are already indicative of a substantial annealing at this temperature. Most of the zircon FT ages from eastern Crete scatter within error around the stratigraphic age. Samples with apparent zircon FT ages significantly younger than the depositional age are only observed in areas where temperatures exceeded ca. 320 °C. Towards the west, a sudden decrease to very young ages ranging from 17±2 to 18±1 Ma reflects a complete resetting at ca. 350 °C. Short tracks, however, are still observed. Throughout the central and western part of the island, ages are consistently below 22 Ma. Thermobarometric data for this area indicate maximum temperatures of 400±50 °C and pressures of 1±0.3 GPa. Only samples from western Crete, which have been exposed to 400±50 °C, show exclusively long tracks. Consequently, the high temperature limit of the zircon partial annealing zone (ZPAZ) appears to be between 350 and 400 °C.A significant influence of elevated confining pressure on the stability of fission tracks in zircon is ruled out by the results of annealing experiments at 0.5 GPa and at different temperatures, which fit the curves previously obtained by other authors at ambient pressure.  相似文献   

The influence of tortuosity on molecular diffusion in freshwater sediments of high porosity     

Martin Maerki  Bernhard Wehrli  Beat Müller 《Geochimica et cosmochimica acta》2004,68(7):1519-1528

In sediments, diffusive transport of ions and molecules is basically influenced by two sediment characteristics: tortuosity and porosity. For the first time, the formation factor F, which combines the effect of tortuosity and porosity on diffusion, was quantified in freshwater sediments at submillimeter resolution. Sediment cores were treated with KCl and F was determined using a resistivity sensor and K⁺ selective electrodes.F was determined in sediments from different water depths of the eutrophic Lake Zug (Switzerland): In sandy sediments from a shallow site (12 m depth), F increased by approximately 50% within a few millimeters below the sediment surface. In clayey and silty sediments from the oxic (<80 m depth) and seasonally anoxic (80-120 m depth) zones of the lake, the initial increase in F was only 20%. In the permanent anoxic zone (>160 m depth), F increased by only 10% just below the sediment surface. Values of F were correlated with the porosity at each depth. We found close correlations of F = 1.02 · φ^−1.81 for clay-silt sediments, and F = 1.04 · φ^−1.21 for sandy sediments. The exponents are considerably smaller in Lake Zug than found for marine sediments, thus, diffusive transport seems to be less affected by tortuosity in this freshwater system.  相似文献   

Investigation of the pyrolytic liberation of molecular nitrogen from Palaeozoic sedimentary rocks     

Bernhard M. Krooss  Lothar Friberg  Yves Gensterblum  Jan Hollenstein  Dirk Prinz  Ralf Littke 《International Journal of Earth Sciences》2005,94(5-6):1023-1038

Open-system non-isothermal pyrolysis up to 1,200°C in combination with elemental analysis was used to study the thermal liberation of molecular nitrogen (N₂) from sedimentary rocks and kerogen concentrates of Palaeozoic age from the Central European Basin system and an Eocene shale (Liaohe Basin, China) with a high content (36%) of ammonium feldspar (buddingtonite). The N/C_org (atomic) ratios of the kerogen concentrates ranged from 0.005 to 0.014, which represents the range commonly observed for coals. Bulk N/C_org ratios of the Palaeozoic shales extended from 0.035 to 0.108, indicating the presence of significant amounts of inorganic nitrogen. Namurian A and A-B (CnA; CnA-B) samples typically exhibited the earliest onset of N₂ generation with intense, characteristic peaks around 600°C. N₂ liberation from the buddingtonite-rich sample occurred at higher temperatures, with a broad peak around 700°C. Pyrograms of the kerogen concentrates showed no or strongly reduced N₂ generation in the 500–700°C range. On-line isotope-specific analysis of the pyrolytically liberated N₂ on one sample revealed a variability of ∼10‰ in the δ¹⁵N values and a steady increase in δ¹⁵N with temperature during the main phase of N₂ generation.  相似文献   

Tectonic map and overall architecture of the Alpine orogen   总被引：9，自引：0，他引：9  

Stefan M. Schmid  Bernhard Fügenschuh  Eduard Kissling  Ralf Schuster 《Eclogae Geologicae Helvetiae》2004,97(1):93-117

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Use of Plant Bioassays for the Detection of Genotoxins in the Aquatic Environment     

Bernhard J. Majer  Tamara Grummt  Maria Uhl  Siegfried Knasmüller 《洁净——土壤、空气、水》2005,33(1):45-55

The present article describes the use of plant bioassays for the detection of genotoxins in the aquatic environment and gives an overview of test methods, their detection spectrum for environmental mutagens and carcinogens and their limitations and pitfalls. The most widely used test systems are micronucleus assays with meiotic cells of Tradescantia and with meristematic root tip cells of Allium and Vicia. In the last years, protocols for single cell gel electrophoresis assays have been developed, which can be conducted with a variety of species. Also various gene mutation test procedures have been developed with plants but they have hardly ever been used in environmental studies. Plants detect a broad variety of environmentally relevant genotoxins, in particular directly acting compounds. Many pesticides and industrial chemicals caused positive results; plant assays are also a unique tool for the detection of DNA‐reactive carcinogenic heavy metals in the environment. In many studies with complex mixtures, positive results were obtained which indicates that plants are sufficiently sensitive to detect effects without concentration of water samples. One of the shortcomings of the use of plants as indicators is their lack of sensitivity towards certain classes of promutagens such as nitrosamines, heterocyclic amines, and polycyclic aromatic hydrocarbons (PAHs). However, the former compounds are hardly encountered in the environment and PAHs can easily be detected chemically and in other mutagenicity tests. Taken together, the currently available data show that plant bioassays are a useful component of test batteries for environmental monitoring.  相似文献   

Elliptical boundary of an intraplate volcanic field, Auckland, New Zealand     

K. Bernhard Sprli  Vera R. Eastwood 《Journal of Volcanology and Geothermal Research》1997,79(3-4)

The outer vents in the Auckland Volcanic Field lie within 19 to 559 m (mean 224.75 m) of a ‘best-fit' ellipse with a 28.9-km-long major axis trending almost north–south, and a minor axis 16.5 km long. The ellipse has formed the outer boundary of the field since the inception of volcanism 140,000 years ago. We present the following testable hypotheses as an explanation of this pattern: The boundary is the expression of a corresponding elliptical source area at depth in the lithospheric mantle (possibly asthenosphere material trapped at this level). The ellipse may represent a depth contour on a very small upper mantle dome or of a lens intruding into a neck of an extensional structure. Alternatively it could be the boundary of a flat elliptical area where tensional stresses allow decompressional melting. The elliptical tensional region may either have developed in a releasing bend during strike-slip faulting along a fundamental lithosphere structure inherited from Mesozoic tectonics, associated with the NNW-trending Dun Mountain ophiolite belt, or may represent the tip of a fracture along which the Auckland Volcanic Province is propagating northward.  相似文献   

Two-stage prograde and retrograde Variscan metamorphism of glaucophane-eclogites, blueschists and greenschists from Ile de Groix (Brittany, France)     

Bernhard Schulz  Claude Triboulet  Claude Audren  Hans-Rudolf Pfeifer  Albert Gilg 《International Journal of Earth Sciences》2001,90(4):871-889

On Ile de Groix, Variscan metamorphic former tholeiitic and alkaline basalts occur as glaucophane-eclogites, blueschists and greenschists in isolated lenses and layers within metapelites. Whole-rock '¹⁸O_SMOW values of the metabasites show limited variations (10.4-12.0‰) and no systematic differences among rock types and metamorphic grades. This provides no argument for large-scale blueschist-to-greenschist transformation driven by infiltration of externally derived fluids. Metamorphic mineralogical changes should have been triggered by internal fluids. Element variations in interlayered blue- and greenschists can be attributed to magmatic fractionation. Assemblages with garnet, clinopyroxene and glaucophane of a high-pressure/low-temperature (HP-LT) metamorphism M1, and NaCa-amphiboles (barroisite, magnesiohornblende, actinolite) of a medium-pressure/medium-temperature metamorphism M2 crystallized during deformation D1. Detailed core-rim zonation profiles display increasing and then decreasing Al^IV in glaucophane of M1. NaCa-amphiboles of M2, mantling glaucophane and crystallized in porphyroblasts, show first increasing, then decreasing, Al^IV and Al^VI. Empirically calibrated thermobarometers allowed P-T path reconstructions. In glaucophane-eclogites of a metamorphic zone I, a prograde evolution to M1 peak conditions at 400-500°C/10-12 kbar was followed by a retrograde P-T path within the glaucophane stability field. The subsequent M2 evolution was again prograde up to >600°C at 8 kbar and then retrograde. Similarly, in metamorphic zones II and III, prograde and retrograde paths of M1 and M2 at lower maximal temperatures and pressures exist. The almost complete metamorphic cycle during M2 signalizes that the HP-LT rocks escaped from an early erosion by a moderate second burial event and explains the long-lasting slow uplift with low average cooling rates.  相似文献