Temperature dependence of the cation distribution in nickel aluminate (NiAl2O4) spinel: a powder XRD study     

H. St. C. O'Neill  W. A. Dollase  C. R. Ross II 《Physics and Chemistry of Minerals》1991,18(5):302-319

NiAl₂O₄ is a largely inverse spinel, which in detail shows increasing randomisation with temperature of Ni and Al between the octahedral and tetrahedral cation sites of the spinel structure. We have used powder XRD to determine this cation distribution in various samples of NiAl₂O₄ quenched after annealing between 700 and 1400° C. The inversion parameter (x) can be measured with a precision of ± 0.004 (one standard deviation), and a comparison of different methods of synthesis, X-ray diffraction and refinement techniques, suggests a probable accuracy of better than 0.01. The results are supported by some preliminary single crystal refinements on flux-grown samples.Below 800° C the rate of cation ordering becomes very slow, and, despite reaching an apparently steady state, it is doubtful if our samples attained complete internal equilibrium. Above 1250° C the cation redistribution becomes so fast that the quenching method becomes unreliable. Between 800 and 1250° C inclusive, the degree of inversion changes smoothly from 0.87 at 800° C to 0.79 at 1250° C, and is accompanied by linear changes in u, the oxygen parameter, from 0.2555 to 0.2563 (±0.0002), and a₀, the lattice parameter, from 8.0462 to 8.0522 Å (±0.0002 Å).  相似文献   

Biochemische Abbaubarkeit ausgewählter alicyclischer Verbindungen     

J. Wotzka  B. Giest  St. Pfitzner 《洁净——土壤、空气、水》1985,13(5):583-590

Thirteen alicyclic compounds (C₅… C₇) are examined for their biochemical degradability in a laboratory activating tank and in two respirometers (Warburg, Sapromat). The tests were performed with adapted and nonadapted activated sludge. In addition, the COD was determined by three different methods. With the exception of cycloheptane (BOD < 25% of the BOD_theor.), six compounds prove to be easily degradable (BOD > 45% of the BOD_theor.) and six compounds prove to be degradable (BOD 45… 25% of the BOD_theor.).  相似文献   

Thermodynamics of Co3O4: a possible electron spin unpairing transition in Co3+     

H.St. C. O'Neill 《Physics and Chemistry of Minerals》1985,12(3):149-154

The free energy of the reaction: $$Co_3 O_4 \rightleftarrows 3C_O O + \tfrac{1}{2}O_2$$ has been studied between 890 and 1,240 K using an e.m.f. technique. There is a phase transition in Co₃O₄ at 1,120±20 K which is accompanied by a large change in entropy (～47 JK^?1 mol^?1 of Co₃O₄), and a rapid increase in unit cell volume and in electical conductivity. This is interpreted to be due to a partial change in electronic spin states in Co^{3 +} from the spin-paired (low spin) configuration observed at room temperature to the spin-unpaired (high spin) state. The transition is probably not first order.  相似文献   

On some problems connected with the determination of recent vertical crustal movements from repeated levellings and gravity measurements     

Bernhard Heck  Hermann Mlzer 《Tectonophysics》1986,130(1-4):299-305

Besides systematic instrumental and environmental effects in high-precision levellings and gravimetry, some theoretical problems are decisive in the evaluation and interpretation of recent vertical crustal movements. In view of the increased accuracy of recently developed portable instruments for absolute gravity measurements, some global effects on gravity may no longer be neglected, necessitating additional time-dependent reductions for polar motion effects. Another problem concerns the evaluation of recent vertical crustal movements from repeated geodetic measurements: a rigorous treatment of the problem demands both repeated levellings and gravity measurements; only under additional hypotheses can these limitating prerequisites be eliminated.  相似文献   

Solar cosmic-ray-produced radionuclides in meteorites     

R. Michel  G. Brinkmann  R. Stück 《Earth and Planetary Science Letters》1982,59(1):33-48

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Structure of the upper mantle in the Northeastern Atlantic close to the azores-gibraltar ridge from surface-wave and body-wave observations     

F. Marillier  St. Mueller 《Tectonophysics》1982,90(1-2)

Phase velocities of teleseismic Rayleigh waves have been measured in the central North Atlantic on both sides of the Azores-Gibraltar Ridge (AGR) by means of a specially designed long-period station network. The dispersion data obtained were regionalized and then subjected to a “hedgehog” inversion, which gives a set of upper mantle models compatible with the observational data within specified error bounds.Reasonable model solutions were selected by using regional body-wave observations, such as P_n- and S_n-wave velocities determined from earthquakes along the AGR. The S_(itn) velocities measured indicate that the shear-wave velocity in the mantle part of the lithosphere is much higher on the northern side of the AGR. Strongly negative P-wave residuals in this area indicate faster seismic propagation than implied by the Jeffreys-Bullen travel-time tables, while propagation is much slower in the Gulf of Cadiz area. Furthermore the residuals show a clear difference for paths through oceanic and continental domains and suggest that the transition between these two domains extends much further into the ocean on the southern side of the AGR than on the northern side.The proposed model for the structure of the upper mantle in that region shows that there exists a pronounced velocity contrast across the AGR. Thickening of the lithospheric plate with increasing plate age is indicated to the south of the ridge. The greatest thickness is reached close to the continental margin within a zone about 500 km wide, whose velocity close to the Canary Islands and Madeira is significantly lower, probably due to the well-known volcanic activity there. These observations together with the travel time residuals reveal that this zone seems to be of a transitional nature somewhere between a continental and oceanic structure.  相似文献   

Lithification of gas-rich chondrite regolith breccias by grain boundary and localized shock melting     

A. Bischoff  A.E. Rubin  K. Keil  D. Stöffler 《Earth and Planetary Science Letters》1983

We studied the fine-grained matrices (< 150 μm) of 14 gas-rich ordinary chondrite regolith breccias in an attempt to decipher the nature of the lithification process that converted loose regolith material into consolidated breccias. We find that there is a continuous gradation in matrix textures from nearly completely clastic (class A) to highly cemented (class C) breccias in which the remaining clasts are completely surrounded by interstitial, shock-melted material. We conclude that this interstitial material formed by shock melting in the porous regolith. In general, the abundances of solar-wind-implanted ⁴He and ²⁰Ne are inversely correlated with the abundance of interstitial, shock-melted, feldspathic material. Chondrites with the highest abundance of interstitial, melted material (class C) experienced the highest shock pressures and temperatures and suffered the most extensive degassing. It is this interstitial, feldspathic melt that lithifies and cements the breccias together; those breccias with very little interstitial melt (class A) are the most porous and least consolidated.  相似文献   

Crustal structure beneath Spain from deep seismic sounding experiments     

E. Banda  A. Udias  St. Mueller  J. Mezcua  M. Boloix  J. Gallart  A. Aparicio 《Physics of the Earth and Planetary Interiors》1983,31(4):277-280

Major tectonic units of Spain have been investigated by deep seismic sounding experiments since 1974 to determine crustal structures and to delineate their differences. These areas are the central part of the Hercynian Meseta, and the Alpine chains: the Betic Cordillera in the south, including the Balearic promontory and the Alboran Sea, and the Pyrenees in the north.The main features of the crust and the upper mantle along a NNE-SSW cross-section from the Pyrenees to the Alboran Sea are described.The crust under the Meseta is typical of Hercynian areas found elsewhere in Europe, with an average thickness of 31 km, whereas the two Alpine regions are characterized by very large lateral inhomogeneities, such as rapid thickening of the crust to 50 and 40 km under the Pyrenees and the Betics, respectively. The deep-reaching E-W-trending North Pyrenean fault has a throw of 10–15 km at the base of the crust. A P_n velocity of 8.1 km s^?1 is found under the entire Iberian Peninsula.In the Alboran Sea, strongly varying thicknesses of sediments, shallow variable depths to the Moho (～ 13 km under the Alboran ridge), and strong variations of P_n velocity between 7.5 and 8.2 km s^?1 have been found.  相似文献   

The contact zone between the ALCAPA and Tisza-Dacia mega-tectonic units of Northern Romania in the light of new paleomagnetic data     

Emõ Márton  Matthias Tischler  László Csontos  Bernhard Fügenschuh  Stefan M. Schmid 《Swiss Journal of Geoscience》2007,100(1):109-124

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Progress in isotope paleohydrology using lake sediment cellulose     

Brent B. Wolfe  Matthew D. Falcone  Ken P. Clogg-Wright  Cherie L. Mongeon  Yi Yi  Bronwyn E. Brock  Natalie A. St. Amour  William A. Mark  Thomas W. D. Edwards 《Journal of Paleolimnology》2007,37(2):221-231

Recent advances in sample preparation techniques and mass spectrometry have fostered more routine oxygen isotope analysis of aquatic cellulose in lake sediment cores, a proxy for lake water oxygen isotope history. These methodological developments have significantly increased the feasibility of incorporating this approach into high-resolution, multi-site, and multi-proxy studies, which are frequently necessary to answer complex hydrological, hydroecological and hydroclimatic questions requiring a paleoenvironmental perspective. Direct translation of lake sediment aquatic cellulose oxygen isotope composition into lake water oxygen isotope composition offers appreciable opportunity for quantitative paleohydrological reconstructions, as evidenced by studies conducted over the past 15 years that span Holocene and pre-historical timescales.  相似文献