Are Natural Climate Forcings Able to Counteract the Projected Anthropogenic Global Warming?     

Cédric Bertrand  Jean-Pascal van Ypersele  André Berger 《Climatic change》2002,55(4):413-427

A two-dimensional global climate model is used to assessthe climatic changes associated with the new IPCC SRES emissions scenarios and to determine which kind of changes in total solar irradiance and volcanic perturbations could mask the projected anthropogenic global warming associated to the SRES scenarios. Our results suggest that only extremely unlikely changes in total solar irradiance and/or volcanic eruptions would be able to overcome the simulated anthropogenic global warming over the century. Nevertheless, in the critical interval of the next two decades the externally-driven natural climate variability might possibly confuse the debate about temperature trends and impede detection of the anthropogenic climate change signal.  相似文献   

Characterization and migration of atmospheric REE in soils and surface waters     

Dominique AubertPeter Stille  Anne ProbstFrançois Gauthier-lafaye  Laurent PourcelotMireille Del nero 《Geochimica et cosmochimica acta》2002,66(19):3339-3350

Rainwater and snow collected from three different sites in France (Vosges Mountains, French Alps and Strasbourg) show more or less similar shapes of their REE distribution patterns. Rainwater from Strasbourg is the most REE enriched sample, whereas precipitations from the two mountainous, less polluted catchments are less REE enriched and have concentrations close to seawater. They are all strongly LREE depleted.Different water samples from an Alpine watershed comprising snow, interstitial, puddle and streamwater show similar REE distributions with LREE enrichment (rainwater normalized) but MREE and HREE depletion. In this environment, where water transfer from the soil to the river is very quick due to the low thickness of the soils, it appears that REE in streamwater mainly originate from atmospheric inputs. Different is the behaviour of the REE in the spring- and streamwaters from the Vosges Mountains. These waters of long residence time in the deep soil horizons react with soil and bedrock REE carrying minerals and show especially significant negative Eu anomalies compared to atmospheric inputs. Their Sr and Nd isotopic data suggest that most of the Sr and Nd originate from apatite leaching or dissolution. Soil solutions and soil leachates from the upper soil horizons due to alteration processes strongly depleted in REE carrying minerals, have REE distribution patterns close to those of lichens and throughfall. Throughfall is slightly more enriched especially in light REE than filtered rainwater probably due to leaching of atmospheric particles deposited on the foliage and also to leaf excretion.Data suggest that Sr and Nd isotopes of the soil solutions in the upper soil horizons originate from two different sources: 1) An atmospheric source with fertilizer, dust and seawater components and 2) A source mainly determined by mineral dissolution in the soil. These two different sources are also recognizable in the Sr and Nd isotopic composition of the tree’s throughfall solution. The atmospheric contributions of Sr and Nd to throughfall and soil solution are of 20 to 70 and 20%, respectively. In springwater, however, the atmospheric Sr and REE contribution is not detectable.  相似文献   

An X-ray absorption fine structure and nuclear magnetic resonance spectroscopy study of gallium-silica complexes in aqueous solution     

Gleb S Pokrovski  Jacques SchottJean-Louis Hazemann  François Farges  Oleg S Pokrovsky 《Geochimica et cosmochimica acta》2002,66(24):4203-4222

The influence of aqueous silica on gallium(III) hydrolysis in dilute (2 × 10⁻⁴ ≤ m_Ga ≤ 5 × 10⁻³) and moderately concentrated (0.02 ≤ m_Ga ≤ 0.3) aqueous solutions was studied at ambient temperature, using high resolution X-ray absorption fine structure (XAFS) and nuclear magnetic resonance (NMR) spectroscopies, respectively. Results show that, in Si-free acidic solutions (pH < 3), Ga is hexa-coordinated with oxygens of H₂O molecules and/or OH groups in the first coordination sphere of the metal. With increasing pH, these hydroxyl groups are progressively replaced by bridging oxygens (-O-), and polymerized Ga-hydroxide complexes form via Ga-O-Ga chemical bonds. In the 2.5-3.5 pH range, both XAFS and NMR spectra are consistent with the dominant presence of the Ga₁₃ Keggin polycation, which has the same local structure as A1₁₃. Under basic pH (pH > 8), Ga exhibits a tetrahedral coordination, corresponding to Ga(OH)₄⁻ species, in agreement with previous NMR and potentiometric studies. Major changes in Ga hydrolysis have been detected in the presence of aqueous silica. Ga is tetra-coordinated, both in basic and acid (i.e., at pH > 2.7) Si-bearing solutions (0.01 ≤ m_Si ≤ 0.2), and forms stable gallium-silicate complexes. In these species, Ga binds via bridging oxygen to 2 ± 1 silicons, with an average Ga-Si distance of 3.16 ± 0.05 Å, and to 2 ± 1 silicons, with an average Ga-Si distance of 3.39 ± 0.03 Å. These two sets of Ga-Si distances imply the formation of two types of Ga-silicate aqueous complex, cyclic Ga-Si_2-3 species (formed by the substitution of Si in its tri-, tetra- or hexa-cyclic polymers by Ga atoms), and chainlike GaSi_2-4 species (similar to those found for A1), respectively. The increase in the number of Si neighbors (a measure of the complex concentration and stability), in alkaline media, with increasing SiO₂(aq) content and decreasing pH is similar to that for A1-Si complexes found in neutral to basic solutions. At very acid pH and moderate silica concentrations, the presence of another type of Ga-Si complex, in which Ga remains hexa-coordinated and binds to the silicon tetrahedra via the GaO₆ octahedron corners, has also been detected. These species are similar to those found for Al³⁺ in acid solutions. Thus, as for aluminum, silicic acid greatly hampers Ga hydrolysis and enhances Ga mobility in natural waters via the formation of gallium-silicate complexes.  相似文献   

Comparison between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr     

Jacques Bourgois  François Michaud 《Earth and Planetary Science Letters》2002,201(1):35-44

When combined with the Miocene-Recent volcanic record of Baja California, a parallel drawn between the Chile and Mexico triple junction areas substantiates slab window development beneath northwestern Mexico during the past 12-10 Myr. The slab-free zone manifestations challenge the notion that ridge subduction has not occurred beneath the southern Baja California peninsula. The geochemically distinctive rocks from the Santa Clara volcanic field of west-central Baja California, including coeval adakites and niobium-enriched basalt, are commonly inferred to signal partial melting of the subducting plate at shallow depths and relatively high temperatures, before slab dehydration occurs. Such PT conditions for slab melting have only been observed in association with spreading-ridge subduction. We propose that slab window development beneath southern Baja California and mainland Mexico (30° to 18°N) resulted from subduction of the East Pacific rise.  相似文献   

Uniform postglacial slip-rate along the central 600 km of the Kunlun Fault (Tibet), from ²⁶Al, ¹⁰Be, and ¹⁴C dating of riser offsets, and climatic origin of the regional morphology     

Jerome Van Der Woerd  Paul Tapponnier  Frederick J. Ryerson  Anne-Sophie Meriaux  Bertrand Meyer  Yves Gaudemer  Robert C. Finkel  Marc W. Caffee  Zhao Guoguang  Xu Zhiqin 《Geophysical Journal International》2002,148(3):356-388

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Paléoenvironnements et caractérisation des roches mères pétrolières des séries pré-salifères du bassin intérieur du Gabon     

Michel Mbina Mounguengui  François Baudin  Jacques Lang  Olivier Jocktane 《Comptes Rendus Geoscience》2003,335(3):327-334

The Interior Basin of Gabon, created during the break-up between South America and Africa, displays thick Neoproterozoic to Aptian p.p. fluvio-lacustrine deposits overlain by Aptian to Albian marine facies. Rock–Eval analyses from outcrop and drillhole samples show high content in organic matter (up to 25%) related to types I and II. These intervals are encountered within Permian, Neocomian–Barremian as well as Aptian siliciclastic succession. They constitute fairly good to excellent potential petroleum source rocks, which are most probably at the origin of oil indices recognized both in drillholes and in surface.  相似文献   

Simplified vibratory characterization of alluvial basins     

Jean-François Semblat  Roberto Paolucci  Anne-Marie Duval 《Comptes Rendus Geoscience》2003,335(4):365-370

For the analysis of seismic wave amplification, modal methods are interesting tools to study the modal properties of geological structures. Modal approaches mainly lead to information on such parameters as fundamental frequencies and eigenmodes of alluvial basins. For a specific alluvial deposit in Nice (France), a simplified modal approach involving the Rayleigh method is considered. This approach assumes a set of admissible shape functions for the eigenmodes and allows a fast estimation of the fundamental frequency of the basin. The agreement with other numerical results (Boundary Element Method) and experimental ones is fully satisfactory. The simplified modal method then appears as an efficient mean for the global vibratory characterization of geological structures towards resonance. To cite this article: J.-F. Semblat et al., C. R. Geoscience 335 (2003).  相似文献   

Wrench tectonics flip at oblique subduction. A model from New Zealand     

Jean Delteil  Jean-François Stéphan  Bernard Mercier de Lépinay  Étienne Ruellan 《Comptes Rendus Geoscience》2003,335(9):743-750

In eastern North Island New Zealand, oblique subduction of the Pacific Plate beneath the Australian Plate is associated with strain partitioning. Dextral along-strike component of displacement occurred first at Early Miocene major faults within the eastern fore-arc domain. These faults were active from Early Miocene to Pliocene times. Since Pliocene times, most of the movement occurs at western faults such as the Wellington Fault. The latter joins the back-arc domain to the north. The jump of wrench faulting is related to the oblique opening of the back-arc domain. Both phenomena are impeded southwards by the Hikurangi oceanic plateau entering the subduction zone. To cite this article: J. Delteil et al., C. R. Geoscience 335 (2003).  相似文献   

Diagenetic history and porosity evolution of Upper Carboniferous sandstones from the Spring Valley #1 well, Maritimes Basin, Canada–implications for reservoir development     

G. Chi  P. S. Giles  M. A. Williamson  D. Lavoie  R. Bertrand 《Journal of Geochemical Exploration》2003,80(2-3):171-191

Eighty-two core samples were collected from the Spring Valley #1 well which penetrates the Upper Carboniferous strata in the Late Devonian–Early Permian Maritimes Basin. The strata consist of alternating sandstones and mudstones deposited in a continental environment. The objective of this study is to characterize the relationship of sandstone porosity with depth, and to investigate the diagenetic processes related to the porosity evolution. Porosity values estimated from point counting range from 0% to 27.8%, but are mostly between 5% and 20%. Except samples that are significantly cemented by calcite, porosity values clearly decrease with depth. Two phases of calcite cement were distinguished based on Cathodoluminescence, with the early phase being largely dissolved and preserved as minor relicts in the later phase. Feldspar dissolution was extensive and contributed significantly to the development of secondary porosity. Quartz cementation was widespread and increased with depth. Fluid inclusions recorded in calcite and quartz cements indicate that interstitial fluids in the upper part of the stratigraphic column were dominated by waters with salinity lower than that of seawater, the middle part was first dominated by low-salinity waters, then invaded by brines, and the lower part was dominated by brines. Homogenization temperatures of fluid inclusions generally increase with depth and suggest a paleogeothermal gradient of 25 °C/km, which is broadly consistent with that indicated by vitrinite reflectance data. An erosion of 1.1–2.4 (mean 1.75) km of strata is inferred to have taken place above the stratigraphic column. δ¹⁸O values of calcite cements (mainly from the late phase) decrease with depth, implying increasing temperatures of formation, as also suggested by fluid-inclusion data. δ¹³C values of calcite cements range from −13.4‰ to −5.7‰, suggesting that organic matter was an important carbon source for calcite cements. A comparison of the porosity data with a theoretical compaction curve indicates that the upper and middle parts of the stratigraphic column show higher-than-normal porosity values, which are related to significant calcite and feldspar dissolution. Meteoric incursion and carboxylic acids generated from organic maturation were probably responsible for the abundant dissolution events.  相似文献   

Tectonics of the western margin of the Shan plateau (central Myanmar): implication for the India–Indochina oblique convergence since the Oligocene     

Guillaume Bertrand  Claude Rangin 《Journal of Asian Earth Sciences》2003,21(10):1139-1157

We present new data and interpretations on the Neogene tectonics of the Shan scarp area (central Myanmar) and its relationship with the India–Indochina oblique convergence. We describe ductile and brittle fabrics associated with the major features in this area, the Mogok Metamorphic Belt (MMB), the Shan scarp and the Sagaing fault. From these data we identify a succession of two tectonic regimes. First, a dominant NNW–SSE-trending extension, marked by ductile stretching that characterizes the MMB, and associated N70E brittle normal faults. Later, from Middle or Upper Miocene to the Present, these structures were cross-cut by brittle right-lateral faults, among which the most important are the N20W transpressive Shan scarp fault zone and the N–S Sagaing fault. To explain this transition from a dominant transtensive to a transpressive stress regime, that occurred during Miocene, we place our data within a larger geodynamic context. We suggest that, like the intraplate deformation in the Indian Ocean, the end of spreading in the South China sea, the opening of the Andaman basin or the end of subduction within the Indo-Burma range, the change in the tectonic regime in central Myanmar could be in response to a major Miocene regional plate kinematic reorganization.  相似文献