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31.
Lessons Learned from 25 Years of Research at the MADE Site   总被引:2,自引:0,他引:2  
Field studies at well‐instrumented research sites have provided extensive data sets and important insights essential for development and testing of transport theories and mathematical models. This paper provides an overview of over 25 years of research and lessons learned at one of such field research sites on the Columbus Air Force Base in Mississippi, commonly known as the Macrodispersion Experiment (MADE) site. Since the mid‐1980s, field data from the MADE site have been used extensively by researchers around the world to explore complex contaminant transport phenomena in highly heterogeneous porous media. Results from field investigations and modeling analyses suggested that connected networks of small‐scale preferential flow paths and relative flow barriers exert dominant control on solute transport processes. The classical advection‐dispersion model was shown to inadequately represent plume‐scale transport, while the dual‐domain mass transfer model was found to reproduce the primary observed plume characteristics. The MADE site has served as a valuable natural observatory for contaminant transport studies where new observations have led to better understanding and improved models have sprung out analysis of new data.  相似文献   
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The primary focus of this paper is to better understand carbon burial on the Louisiana continental margin using spatial scales that covered various shelf depositional areas far-field and near-field (sediment and organic carbon inputs relative to river mouth proximity) and covering a variety of sedimentation rates. Box-cores samples were collected in July 2003; cores were collected along two depositional transects extending westward and southward from the Southwest Pass (SW Pass). A key difference between the two transects sampled in this study was the greater occurrence of mobile muds derived from spillover from shallower regions along the westward 50 m isobaths. The dominant mechanism for mixing in the surface active zone (SAZ) on the inner Louisiana shelf was due to physical, not biological, forces. Burial efficiencies for organic carbon (57.2–91.5%) and total nitrogen (44.2–86.9%) ranged widely across all shelf stations. Lower burial efficiencies for bulk organic carbon, total nitrogen, and pigment biomarkers were associated with mobile muds west of Southwest Pass. Chlorophyll a concentrations were significantly higher than pheopigments at depth at the Mississippi River and Southwest Pass stations, making up 40.4 and 77.4% of total pigment concentrations in the (SAZ) and 46.2 and 63.2% in the accumulation zone (AZ), respectively. These results are in agreement with earlier plant pigment studies which showed that a large fraction of the phytodetritus delivered to the inner shelf was derived from coastal and river diatoms. The amount of lignin preserved with depth decreased with increasing residence time in the SAZ and diagenetic zone (DZ) along the canyon transect but not along the western transect. Trends for lignin concentration followed previously identified surface sediment trends indicating overall lower burial of refractory terrestrial material at depth with greater distance offshore.  相似文献   
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In June 2003, we conducted a two-part field exercise to examine biogeochemical characteristics of water in the lower Mississippi river during the 4 days prior to discharge and in the Mississippi river plume over 2 days after discharge. Here we describe the fates of materials immediately after their discharge through Southwest Pass of the Mississippi delta into the northern Gulf of Mexico. Changes in surface water properties immediately after discharge were much larger and more rapid than changes prior to discharge. Total suspended matter (TSM) declined, probably due to sinking, dissolved macronutrients were rapidly diminished by mixing and biological uptake, and phytoplankton populations increased dramatically, and then declined. This decline appeared to begin at salinities of approximately 10 and was nearly complete by 15. A large increase in dissolved organic carbon (DOC) occurred over approximately the same salinity range. Weak winds (<2 m s−1) during and preceding this cruise apparently led to the formation of an extensive but thin freshwater lens from the river. This lens spread widely without much mixing, and the bloom of phytoplankton that occurred between discharge and a salinity of 10 was probably a freshwater community seeded from the lower river. Phytoplankton bloomed for a period of about 1–2 days, then declined dramatically, apparently releasing large amounts of DOC. Macronutrients from the river were utilized by the river phytoplankton community in the extensive freshwater lens. This contrasted with the more typical situation in which river nutrients stimulate a marine phytoplankton bloom at salinities in the mid-20s. We concluded that the direct effects of dissolved and particulate bio-reactive materials discharged by the Mississippi river were spatially restricted at this time to low-salinity water, at least as surface phenomena. After being transported through the lower river essentially unaltered, these materials were biogeochemically processed within days and tens of km. More generally, the mixing rate of plume water with receiving oceanic water has profound effects on the food web structure and biogeochemical cycling in the plume.  相似文献   
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We present an assessment of the potential impacts of climate change on hydropower production within a paradigmatic, very highly exploited cryospheric area of upper Valtellina valley in the Italian Alps. Based on dependable and unique hydrological measures from our high‐altitude hydrometric network Idrostelvio during 2006–2015, we set up the Poly‐Hydro model to mimic the cryospheric processes driving hydrological flow formation in this high‐altitude area. We then set up an optimization tool, which we call Poly‐Power, to maximize the revenue of the plant manager under given hydrological regimes, namely, by proper operation of the hydroelectric production scheme (reservoirs, pipelines, and power plants) of the area. We then pursue hydrological projections until 2100, feeding Poly‐Hydro with the downscaled outputs of three general circulation models from the Intergovernmental Panel on Climate Change Fifth Assessment Report, under the scenarios Representative Concentration Pathway (RCP) 2.6, RCP 4.5, and RCP 8.5. We assess hydrological flows in two reference decades, that is, at half century (2040–2049), and end of century (2090–2099). We then feed the so obtained hydrological scenarios as inputs to Poly‐Power, and we project future production of hydroelectric power, with and without reoperation of the system. The average annual stream flows for hydropower production decreases along the century under our scenarios (?21 to +7%, on average ? 5% at half century; ?17 to ?2%, average ? 8%, end of century), with ice cover melting unable to offset such decrease. Reduction in snowfall and increase in liquid rainfall are the main factors affecting the modified hydrological regime. Energy production (and revenues) at half century may increase under our scenarios (?9 to +15%, +3% on average). At the end of century in spite of a projected increase on average (?7 to +6%, +1% on average), under the warmest scenario RCP 8.5 decrease of energy production is consistently projected (?4% on average). Our results provide an array of potential scenarios of modified hydropower production under future climate change and may be used for brain storming of adaptation strategies.  相似文献   
36.
A significant As anomaly has been reported in the literature for stream sediments and unlithified Quaternary deposits of the Pecora River valley in Southern Tuscany, extending from the “Colline Metallifere” pyrite-base metals district to the Tyrrhenian Sea. The As anomaly spreads over several square kilometers around a core that exceeds 500 ppm. Several source contributions (from natural to anthropogenic) have been invoked to explain the observed As distribution in the Pecora Valley, including the metal-working industry which was active in this area, particularly in Etrusco-Roman times and in the Middle Ages. In order to evaluate the contribution of ancient mining and metallurgical activities in the Pecora Valley to elevated As concentrations in the environment, a detailed mineralogical and geochemical survey of metallurgical slags and smelted ore minerals was undertaken from six different sites through the Pecora Valley: Poggio Butelli (Etrusco-Roman iron slags); Sata Creek, Arialla, Marsiliana, Forra and Cascata sites (all Medieval base metals slags). The As content of Etrusco-Roman slags is relatively low (few tens of ppm), whereas Medieval slags show variable, but higher amounts of base metals (±Ag) (ranging from tens to tens of thousands ppm) and As (up to 267 ppm, with average contents of about 40 ppm). Arsenic is mostly partitioned in sulfides disseminated through the glassy groundmass rather than in solid solution with the glassy matrix. Remnants of the ore used for base metal and Ag smelting during the Middle Ages had the highest As contents (up to about 1000 ppm).  相似文献   
37.
Climate data of mean monthly temperature and total monthly precipitation compiled from different sources in northern Patagonia were interpolated to 20-km resolution grids over the period 1997–2010. This northern Patagonian climate grid (NPCG) improves upon previous gridded products in terms of its spatial resolution and number of contributing stations, since it incorporates 218 and 114 precipitation and temperature records, respectively. A geostatistical method using surface elevation from a Digital Elevation Model (DEM) as the ancillary variable was used to interpolate station data into even spaced points. The maps provided by NPCG are consistent with the broad spatial and temporal patterns of the northern Patagonian climate, showing a comprehensive representation of the latitudinal and altitudinal gradients in temperature and precipitation, as well as their related patterns of seasonality and continentality. We compared the performance of NPCG and various other datasets available to the climate community for northern Patagonia. The grids used for the comparison included those of the Global Precipitation Climatology Project, ERAInterim, Climate Research Unit (University of East Anglia), and University of Delaware. Based on three statistics that quantitatively assess the spatial coherence of gridded data against available observations (bias, MAE, and RMSE), NPCG outperforms other global grids. NPCG represents a useful tool for understanding climate variability in northern Patagonia and a valuable input for regional models of hydrological and ecological processes. Its resolution is optimal for validating data from the general circulation models and working with raster data derived from remote sensing, such as vegetation indices.  相似文献   
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Abstract. The serpulid polychaete Ficopomatus enigmaticus (F auvel , 1923) builds huge aggregates in the "Sacca del Canarin", a brackish inlet of the Po River Delta (Italy). Distribution, structure and development of these 'reefs'. together with their associated biota, were studied by field observations and settlement panels from 1977 to 1979. Some aspects of the serpulid biology (settlement periods, tube growth, life strategy) were also taken into account. Ficopomatus reefs influence in many ways the brackish-water ecosystem: they form the main hard substrate; are major sediment source; help in regulating the trophic status of the lagoon; and act as refuge for many invertebrate species.  相似文献   
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