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91.
92.
A high resolution (3–8 km grid), 3D numerical ocean model of the West Caribbean Sea (WCS) is used to investigate the variability and the forcing of flows near the Meso-American Barrier Reef System (MBRS) which runs along the coasts of Mexico, Belize, Guatemala and Honduras. Mesoscale variations in velocity and temperature along the reef were found in seasonal model simulations and in observations; these variations are associated with meandering of the Caribbean current (CC) and the propagation of Caribbean eddies. Diagnostic calculations and a simple assimilation technique are combined to infer the dynamically adjusted flow associated with particular eddies. The results demonstrate that when a cyclonic eddy (negative sea surface height anomaly (SSHA)) is found near the MBRS the CC shifts offshore, the cyclonic circulation in the Gulf of Honduras (GOH) intensifies, and a strong southward flow results along the reef. However, when an anticyclonic eddy (positive SSHA) is found near the reef, the CC moves onshore and the flow is predominantly westward across the reef. The model results help to explain how drifters are able to propagate in a direction opposite to the mean circulation when eddies cause a reversal of the coastal circulation. The effect of including the Meso-American Lagoon west of the Belize Reef in the model topography was also investigated, to show the importance of having accurate coastal topography in determining the variations of transports across the MBRS. The variations found in transports across the MBRS (on seasonal and mesoscale time scales) may have important consequences for biological activities along the reef such as spawning aggregations; better understanding the nature of these variations will help ongoing efforts in coral reef conservation and maintaining the health of the ecosystem in the region.  相似文献   
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When chromated copper arsenate (CCA)-treated wood is removed from service and turns into waste, the contents of Cu, Cr and As remain high due to the strong fixation of CCA in the wood. This high content of toxic compounds presents a disposal challenge. Incineration of CCA-treated waste wood is not allowed in Denmark; instead, the wood is to be land-filled until new methods for handling the wood are available. Since the amounts of CCA-treated wood being removed from service is expected to increase in the years to come, the need for finding alternative handling methods is very relevant. In this study, the usefulness of Electrodialytic Remediation was demonstrated for handling of CCA-treated waste wood in pilot scale. The electrodialytic remediation method, which uses a low-level direct current (DC) as the cleaning agent, combines electrokinetic movement of ions in the wood matrix with the principles of electrodialysis. It has previously been shown that it is possible to remove Cu, Cr and As from CCA-treated wood using electrodialytic remediation in laboratory scale, but until now, the method had not been studied in large scale. The pilot-scale plant used in this study was designed to contain up to 2 m3 wood chips. Six remediation experiments were carried out. In these experiments, the process was up-scaled stepwise by increasing the distance between the electrodes from initially 60 cm to finally 150 cm. The remediation time was varied between 11 and 21 days, and phosphoric acid and/or oxalic acid was used to facilitate the desorption of CCA from the wood. In the most successful of the experiments carried out, the concentration of CCA in the wood was reduced by up to 82% for Cr, 88% for Cu and at least 96% for As.  相似文献   
95.
Numerous studies have been conducted with electrochemical removal of heavy metals from spiked kaolinite. Meanwhile, when moving from kaolinite to real soils, new factors must be taken into account—factors influencing, e.g., the buffering capacity of the soil against acidification and the adsorption/desorption processes of the heavy metals. The present study gives some examples where it is necessary to use an enhancement solution to aid desorption of Cu, Zn and Pb during electrodialytic treatment. Dependent on the composition of the pollution, different choices can be made. In the case of a Cu-polluted calcareous soil, ammonia may be used as enhancement solution, due to the formation of charged complexes between ammonia and Cu. Thus, Cu is mobile at high pH when ammonia is added and Cu can be removed without dissolving the calcareous parts. Zn is also mobilized by ammonia, but to a lesser extent than Cu. In the case of Cu, Zn and Pb at the same time, alkaline ammonium citrate may be a solution. It was shown that this enhancement solution could mobilize these three pollutants, but optimization of concentration and pH of the ammonium citrate is still needed. When choosing a remediation scheme for electrochemical treatment of an actual industrially polluted soil, this scheme must be chosen on basis of characterization of soil and pollution combination.  相似文献   
96.
The phase relations of quaternary systems are generally represented by projections onto ternary compositional planes. Such projections often obscure relationships that would only be evident in a three-dimensional tetrahedral plot. The tetrahedral plot requires that compositions of the minerals and melts be transformed into Cartesian coordinates. It is shown here how this transformation is carried out. The application is demonstrated by tetrahedral plots of experimental melt compositions of partially molten lherzolite. Furthermore, the plot can be used to evaluate whether or not a particular basaltic composition represents a primary melt. The methods are applicable to any four-component system.  相似文献   
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This paper evaluates the impacts of climate change to European economies under an increase in global mean temperature at +2 °C and +4 °C. It is based on a summary of conclusions from available studies of how climate change may affect various sectors of the economies in different countries. We apply a macroeconomic general equilibrium model, which integrates impacts of climate change on different activities of the economies. Agents adapt by responding to the changes in market conditions following the climatic changes, thus bringing consistency between economic behaviour and adaptation to climate change. Europe is divided into 85 sub-regions in order to capture climate variability and variations in vulnerabilities within countries. We find that the impacts in the +2 °C are moderate throughout Europe, with positive impacts on GDP in some sub-regions and negative impacts down to 0.1 per cent per year in others. At +4 °C, GDP is negatively affected throughout Europe, and most substantially in the southern parts, where it falls by up to 0.7 per cent per year in some sub-regions. We also find that climate change causes differentiations in wages across Europe, which may cause migration from southern parts of Europe to northern parts, especially to the Nordic countries.  相似文献   
100.
We present new Fe and Si isotope ratio data for the Torres del Paine igneous complex in southern Chile. The multi-composition pluton consists of an approximately 1 km vertical exposure of homogenous granite overlying a contemporaneous 250-m-thick mafic gabbro suite. This first-of-its-kind spatially dependent Fe and Si isotope investigation of a convergent margin-related pluton aims to understand the nature of granite and silicic igneous rock formation. Results collected by MC-ICP-MS show a trend of increasing δ56Fe and δ30Si with increasing silica content as well as a systematic increase in δ56Fe away from the mafic base of the pluton. The marginal Torres del Paine granites have heavier Fe isotope signatures (δ56Fe = +0.25 ± 0.02 2se) compared to granites found in the interior pluton (δ56Fe = +0.17 ± 0.02 2se). Cerro Toro country rock values are isotopically light in both Fe and Si isotopic systems (δ56Fe = +0.05 ± 0.02 ‰; δ30Si = ?0.38 ± 0.07 ‰). The variations in the Fe and Si isotopic data cannot be accounted for by local assimilation of the wall rocks, in situ fractional crystallization, late-stage fluid exsolution or some combination of these processes. Instead, we conclude that thermal diffusion or source magma variation is the most likely process producing Fe isotope ratio variations in the Torres del Paine pluton.  相似文献   
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