北爱尔兰Curraghinalt金矿床中低温卤水导致金再活化的证据     

J.J.Wilkinson  A.J.Boyce 《地质与资源》2000,9(3):184-187

许多研究资料都报道过造山晚期的横推断裂系统中以H2o－Co2－NaCl为主的流体与脉岩型金矿化的关系。其中一些系统中存在晚期的低温、高盐度卤水。这种卤水被认为是晚期分离作用的产物或作为叠加的流体导致同位素年龄再造并产生新的矿物组合。然而,目前还难以建立卤水与金矿化之间的成因联系．为此我们对北爱尔兰Curraghinalt石英－硫化物－金矿脉型矿床的结构、流体包裹体和同位素资料进行研究,这些资料不仅显示了是地表水渗入到原有的金矿中,而且也为低温、高盐度的CaCl2－NaCl流体促使金再活化提供了新证据。虽然还缺乏对金搬运机理的明确解释,但对认识与卤水有关的金矿化的形成有重要意义。 1 地质特征 位于北爱尔兰Curraghinalt 的石英脉型金矿床是英国最大金产地,是沿着主断裂系--高原边界断裂带(HBFZ)--分布的一系列矿床之一。  相似文献   

Particle-size distribution of inferred tsunami deposits in Sur Lagoon,Sultanate of Oman     

S.V. Donato  E.G. Reinhardt  J.I. Boyce  J.E. Pilarczyk  B.P. Jupp 《Marine Geology》2009,257(1-4):54-64

The sedimentary characteristics of shell beds within an interpreted tsunami deposit from Sur Lagoon, Oman were examined using shell taphonomy and high-resolution particle-size analysis. The tsunami bed was deposited by the 28 November, 1945 tsunami generated by the Makran subduction zone. Q-mode cluster analysis of particle-size data was evaluated as a means of discriminating individual tsunamite shell layers from lagoonal intertidal deposits. Results showed that the tsunami shell bed was more poorly sorted, and heterogeneous (in both the digested and undigested samples) than the background lagoonal sediments. The tsunami bed thickness correlated generally with the thickness of the shell-bed, however, cluster analysis extended the tsunami unit several centimeters above or below the shell bed in some cores. The particle-size analysis also showed subtle textural trends in the tsunami unit, suggesting that the tsunami bed was deposited in several distinctive phases during tsunami incursion into Sur Lagoon. The findings indicate that cluster analysis of particle-size data can be used to identify tsunami beds in intertidal environments and holds potential for identifying paleotsunami deposits in sediments from embayed intertidal–subtidal siliciclastic systems where obvious sedimentary structures may be absent.  相似文献   

O VI in the local interstellar medium     

M. A. Barstow  D. D. Boyce  J. K. Barstow  A. E. Forbes  B. Y. Welsh  R. Lallement 《Astrophysics and Space Science》2009,320(1-3):91-95

We report preliminary results of a search for O VI absorption in the spectra of ～100 hot DA white dwarfs observed by the FUSE satellite. We have carried out a detailed analysis of the radial velocities of interstellar and (where present) stellar absorption lines for the entire sample of stars. In many cases, the velocity differences between the interstellar and photospheric components are below the resolution of the FUSE spectrographs. However, in a significant number of cases the interstellar and photospheric contributions can be separated. In the majority of stars where we find O VI absorption lines, the material is clearly associated with the stellar photosphere and not the interstellar medium. There are a small number of lines-of-sight where the gas is interstellar in nature but the stars are located beyond the boundaries of the local cavity.  相似文献   

Genesis of sediment-hosted stratiform copper–cobalt mineralization at Luiswishi and Kamoto, Katanga Copperbelt (Democratic Republic of Congo)     

Hamdy A. El Desouky  Philippe Muchez  Adrian J. Boyce  Jens Schneider  Jacques L. H. Cailteux  Stijn Dewaele  Albrecht von Quadt 《Mineralium Deposita》2010,45(8):735-763

The sediment-hosted stratiform Cu–Co mineralization of the Luiswishi and Kamoto deposits in the Katangan Copperbelt is hosted by the Neoproterozoic Mines Subgroup. Two main hypogene Cu–Co sulfide mineralization stages and associated gangue minerals (dolomite and quartz) are distinguished. The first is an early diagenetic, typical stratiform mineralization with fine-grained minerals, whereas the second is a multistage syn-orogenic stratiform to stratabound mineralization with coarse-grained minerals. For both stages, the main hypogene Cu–Co sulfide minerals are chalcopyrite, bornite, carrollite, and chalcocite. These minerals are in many places replaced by supergene sulfides (e.g., digenite and covellite), especially near the surface, and are completely oxidized in the weathered superficial zone and in surface outcrops, with malachite, heterogenite, chrysocolla, and azurite as the main oxidation products. The hypogene sulfides of the first Cu–Co stage display δ³⁴S values (−10.3‰ to +3.1‰ Vienna Canyon Diablo Troilite (V-CDT)), which partly overlap with the δ³⁴S signature of framboidal pyrites (−28.7‰ to 4.2‰ V-CDT) and have ∆³⁴S_SO4-Sulfides in the range of 14.4‰ to 27.8‰. This fractionation is consistent with bacterial sulfate reduction (BSR). The hypogene sulfides of the second Cu–Co stage display δ³⁴S signatures that are either similar (−13.1‰ to +5.2‰ V-CDT) to the δ³⁴S values of the sulfides of the first Cu–Co stage or comparable (+18.6‰ to +21.0‰ V-CDT) to the δ³⁴S of Neoproterozoic seawater. This indicates that the sulfides of the second stage obtained their sulfur by both remobilization from early diagenetic sulfides and from thermochemical sulfate reduction (TSR). The carbon (−9.9‰ to −1.4‰ Vienna Pee Dee Belemnite (V-PDB)) and oxygen (−14.3‰ to −7.7‰ V-PDB) isotope signatures of dolomites associated with the first Cu–Co stage are in agreement with the interpretation that these dolomites are by-products of BSR. The carbon (−8.6‰ to +0.3‰ V-PDB) and oxygen (−24.0‰ to −10.3‰ V-PDB) isotope signatures of dolomites associated with the second Cu–Co stage are mostly similar to the δ¹³C (−7.1‰ to +1.3‰ V-PDB) and δ¹⁸O (−14.5‰ to −7.2‰ V-PDB) of the host rock and of the dolomites of the first Cu–Co stage. This indicates that the dolomites of the second Cu–Co stage precipitated from a high-temperature, host rock-buffered fluid, possibly under the influence of TSR. The dolomites associated with the first Cu–Co stage are characterized by significantly radiogenic Sr isotope signatures (0.70987 to 0.73576) that show a good correspondence with the Sr isotope signatures of the granitic basement rocks at an age of ca. 816 Ma. This indicates that the mineralizing fluid of the first Cu–Co stage has most likely leached radiogenic Sr and Cu–Co metals by interaction with the underlying basement rocks and/or with arenitic sedimentary rocks derived from such a basement. In contrast, the Sr isotope signatures (0.70883 to 0.71215) of the dolomites associated with the second stage show a good correspondence with the ⁸⁷Sr/⁸⁶Sr ratios (0.70723 to 0.70927) of poorly mineralized/barren host rocks at ca. 590 Ma. This indicates that the fluid of the second Cu–Co stage was likely a remobilizing fluid that significantly interacted with the country rocks and possibly did not mobilize additional metals from the basement rocks.  相似文献   

The nature of the dwarf population in Abell 868     

Peter J. Boyce  Steven Phillipps  J. Bryn Jones  Simon P. Driver  Rodney M. Smith  Warrick J. Couch 《Monthly notices of the Royal Astronomical Society》2001,328(1):277-282

We present the results of a study of the morphology of the dwarf galaxy population in Abell 868, a rich, intermediate-redshift     cluster which has a galaxy luminosity function (LF) with a steep faint-end slope     . A statistical background subtraction method is employed to study the     colour distribution of the cluster galaxies. This distribution suggests that the galaxies contributing to the faint-end of the measured cluster LF can be split into three populations: dwarf irregular galaxies (dIrrs) with     dwarf elliptical galaxies (dEs) with     and contaminating background giant ellipticals (gEs) with     . The removal of the contribution of the background gEs from the counts only marginally lessens the faint-end slope     . However, the removal of the contribution of the dIrrs from the counts produces a flat LF     . The dEs and the dIrrs have similar spatial distributions within the cluster, except that the dIrrs appear to be totally absent within a central projected radius of about 0.2 Mpc     . The number densities of both dEs and dIrrs appear to fall off beyond a projected radius of ≃ 0.35 Mpc. We suggest that the dE and dIrr populations of A868 have been associated with the cluster for similar time-scales, but evolutionary processes such as 'galaxy harassment' tend to fade the dIrr galaxies while having a much smaller effect on the dE galaxies. The harassment would be expected to have the greatest effect on dwarfs residing in the central parts of the cluster.  相似文献   

The oceanic anoxic event 2 at Es Souabaa (Tebessa,NE Algeria): bio-events and stable isotope study     

Sihem Salmi-Laouar  Bruno Ferré  Khoudair Chaabane  Rabah Laouar  Adrian J. Boyce  Anthony E. Fallick 《Arabian Journal of Geosciences》2018,11(8):182

At the southern margin of the Tethys, the Es Souabaa area recorded traces of Oceanic Anoxic Event 2 (OAE2) around the Cenomanian-Turonian boundary (C/Tb). The dark, laminated, filament- and pyrite-bearing limestones represent the typical facies of this event. In terms of sedimentary environment, these features reflect a transgressive drowning that had induced hypoxia in these sedimentary environments. Such conditions favored the deposition and preservation of organic matter of marine origin, the distribution of which was controlled by paleogeography and halokinetic tectonics at that period. The OAE2 reached a climax between the last upper Cenomanian occurrence of Rotalipora cushmani and the lower Turonian occurrence of Whiteinella praehelvetica. Positive shift of the δ¹³C excursion along with relatively high total organic carbon (TOC) contents during OAE2 both indicate palaeo-environmental modifications enhanced by a significant change in primary marine productivity. Meanwhile, negative δ¹⁸O peaks in carbonates reflect increasing temperatures. Comparison of the data from this study with those from the neighboring Kalaat Senan section (Tunisia) suggests close similarities of events, although OAE2 is much more enhanced in Algeria.  相似文献   

Copper–Gold Skarn Mineralization at the Karavansalija Ore Zone,Rogozna Mountain,Southwestern Serbia          下载免费PDF全文

Zhivko D. Budinov  Kotaro Yonezu  Thomas Tindell  Jillian Aira Gabo‐Ratio  Stanoje Milutinovic  Adrian J. Boyce  Koichiro Watanabe 《Resource Geology》2015,65(4):328-344

Karavansalija ore zone is situated in the Serbian part of the Serbo‐Macedonian magmatic and metallogenic belt. The Cu–Au mineralization is hosted mainly by garnet–pyroxene–epidote skarns and shifts to lesser presence towards the nearby quartz–epidotized rocks and the overlying volcanic tuffs. Within the epidosites the sulfide mineralogy is represented by disseminated cobalt‐nickel sulfides from the gersdorfite‐krutovite mineral series and cobaltite, and pyrite–marcasite–chalcopyrite–base metal aggregates. The skarn sulfide mineralization is characterized by chalcopyrite, pyrite, pyrrhotite, bismuth‐phases (bismuthinite and cosalite), arsenopyrite, gersdorffite, and sphalerite. The sulfides can be observed in several types of massive aggregates, depending on the predominant sulfide phases: pyrrhotite‐chalcopyrite aggregates with lesser amount of arsenopyrite and traces of sphalerite, arsenopyrite–bismuthinite–cosalite aggregates with subordinate sphalerite and sphalerite veins with bismuthinite, pyrite and arsenopyrite. In the overlying volcanoclastics, the studied sulfide mineralization is represented mainly by arsenopyrite aggregates with subordinate amounts of pyrite and chalcopyrite. Gold is present rarely as visible aggregate of native gold and also as invisible element included in arsenopyrite. The fluid inclusion microthermometry data suggest homogenization temperature in the range of roughly 150–400°C. Salinities vary in the ranges of 0.5–8.5 wt% NaCl eq for two‐phase low density fluid inclusions and 15–41 wt% NaCl eq for two‐phase high‐salinity and three‐phase high‐salinity fluid inclusions. The broad range of salinity values and the different types of fluid inclusions co‐existing in the same crystals suggest that at least two fluids with different salinities contributed to the formation of the Cu–Au mineralization. Geothermometry, based on EPMA data of arsenopyrite co‐existing with pyrite and pyrrhotite, suggests a temperature range of 240–360°C for the formation of the arsenopyrite, which overlaps well with the data for the formation temperature obtained through fluid inclusion microthermometry. The sulfur isotope data on arsenopyrite, chalcopyrite, pyrite and marcasite from the different sulfide assemblages (ranging from 0.4‰ to +3.9‰ δ³⁴S_CDT with average of 2.29 δ³⁴S_CDT and standard deviation of 1.34 δ³⁴S_CDT) indicates a magmatic source of sulfur for all of the investigated phases. The narrow range of the data points to a common source for all of the investigated sulfides, regardless of the host rock and the paragenesis. The sulfur isotope data shows good overlap with that from nearby base‐metal deposits; therefore the Cu–Au mineralization and the emblematic base‐metal sulfide mineralization from this metallogenic belt likely share same fluid source.  相似文献   

Seismic stratigraphy of Waterton Lake, a sediment-starved glaciated basin in the Rocky Mountains of Alberta, Canada and Montana, USA     

Nicholas Eyles  Joseph I. Boyce  John D. Halfman  Berkant Koseoglu 《Sedimentary Geology》2000,130(3-4):283-311

Upper and Middle Waterton lakes fill a glacially scoured bedrock basin in a large (614 km²) watershed in the eastern Front Ranges of the Rocky Mountains of southern Alberta, Canada and northern Montana, U.S.A. The stratigraphic infill of the lake has been imaged with 123 km of single-channel FM sonar (‘chirp') reflection profiles. Offshore sonar data are combined with more than 2.5 km of multi-channel, land-based seismic reflection profiles collected from a large fan-delta. Three seismic stratigraphic successions (SSS I to III) are identified in Waterton Lake resting on a prominent basal reflector (bedrock) that reaches a maximum depth of about 250 m below lake level. High-standing rock steps (reigels) divide the lake into sub-basins that can be mapped using lake floor reflection coefficients. A lowermost transparent to poorly stratified seismic succession (SSS I, up to 30 m thick) is present locally between bedrock highs and has high seismic velocities (1750–2100 m/s) typical of compact till or outwash. A second stratigraphic succession (SSS II, up to 50 m thick), occurs throughout the lake basin and is characterised by continuous, closely spaced reflectors typical of repetitively bedded and rhythmically laminated silts and clays most likely deposited by underflows from fan-deltas; paleo-depositional surfaces identify likely source areas during deglaciation. Intervals of acoustically transparent seismic facies, up to 5 m thick, are present within SSS II. At the northern end of Upper Waterton Lake, SSS II has a hummocky surface underlain by collapse structures and chaotic facies recording the melt of buried ice. Sediment collapse may have triggered downslope mass flows and may account for massive facies in SSS II. A thin Holocene succession (SSS III, <5 m) shows very closely spaced reflectors identified as rhythmically laminated fine pelagic sediment deposited from interflows and overflows. SSS III contains Mt. Mazama tephra dated at 6850 yr BP.  相似文献   

Orogenic gold mineralisation hosted by Archaean basement rocks at Sortekap, Kangerlussuaq area, East Greenland     

D. A. Holwell  G. R. T. Jenkin  K. G. Butterworth  T. Abraham-James  A. J. Boyce 《Mineralium Deposita》2013,48(4):453-466

A gold-bearing quartz vein system has been identified in Archaean basement rocks at Sortekap in the Kangerlussuaq region of east Greenland, 35 km north–northeast of the Skaergaard Intrusion. This constitutes the first recorded occurrence of Au mineralisation in the metamorphic basement rocks of east Greenland. The mineralisation can be classified as orogenic style, quartz vein-hosted Au mineralisation. Two vein types have been identified based on their alteration styles and the presence of Au mineralisation. Mineralised type 1 veins occur within sheared supracrustal units and are hosted by garnet-bearing amphibolites, with associated felsic and ultramafic intrusions. Gold is present as native Au and Au-rich electrum together with arsenopyrite and minor pyrite and chalcopyrite in thin alteration selvages in the immediate wall rocks. The alteration assemblage of actinolite-clinozoisite-muscovite-titanite-scheelite-arsenopyrite-pyrite is considered to be a greenschist facies assemblage. The timing of mineralisation is therefore interpreted as being later and separate event to the peak amphibolite facies metamorphism of the host rocks. Type 2 quartz veins are barren of mineralisation, lack significant alteration of the wall rocks and are considered to be later stage. Fluid inclusion microthermometry of the quartz reveals three separate fluids, including a high temperature (T _h ?=?300–350 °C), H₂O–CO₂–CH₄ fluid present only in type 1 veins that in interpreted to be responsible for the main stage of Au deposition and sulphidic wall rock alteration. It is likely that the carbonic fluids were actually trapped at temperatures closer to 400 °C. Two other fluids were identified within both vein types, which comprise low temperature (100–200 °C) brines, with salinities of 13–25 wt%?eq. NaCl and at least one generation of low salinity aqueous fluids. The sources and timings of the secondary fluids are currently equivocal but they may be related to the emplacement of Paleogene mafic intrusions. The identification of this occurrence of orogenic-style Au mineralisation has implications for exploration in the underexplored area of east Greenland between 62 and 69°?N, where other, similar supracrustal units are known to be present.  相似文献   

New mineralogical and isotopic constraints on Main Zone-hosted PGE mineralisation at Moorddrift, northern Bushveld Complex     

D. A. Holwell  A. Jones  J. W. Smith  A. J. Boyce 《Mineralium Deposita》2013,48(6):675-686

The northern limb of the Bushveld Complex, South Africa contains a number of occurrences of platinum-group element (PGE) mineralisation within Main Zone rocks, whereas the rest of the complex has PGE-depleted Main Zone units. On the farm Moorddrift, Cu–Ni–PGE sulphide mineralisation is hosted within the Upper Main Zone in a layered package of gabbronorites, mottled anorthosites and thin pyroxenites. Our observations indicate that a 10-m-thick, ‘reef-style’ package of mineralisation has been extensively ‘disturbed’, forming a mega breccia which in some localities may distribute mineralised rocks over intersections of over 300 m. The sulphides are made up of pyrrhotite, pentlandite and chalcopyrite, heavily altered around their margins and overprinted by secondary pyrite. Platinum-group mineral assemblages typical of primary magmatic deposits, with Pt and Pd tellurides and sperrylite, are present in the ‘reef-style’ package, whereas there is a decrease in tellurides and an increase in antimonides in the ‘disturbed’ package, interpreted to be related to hydrothermal recrystallization during veining and brecciation. Sulphur isotopes show that all sulphides within the mineralised package on Moorddrift have a crustal signature consistent with local country rock sediments of the Transvaal Supergroup. We interpret the mineralisation at Moorddrift as a primary sulphide reef, likely produced as a result of the mixing of crustally contaminated magmas in the Upper Main Zone, which has been locally disrupted post-crystallisation. At present, there are no firm links between Moorddrift and the other known PGE occurrences in the Main Zone at the Aurora and Waterberg projects, although the stratigraphic position of all may be similar and thus intriguing. Nonetheless, they do demonstrate that the Main Zone of the northern limb of the Bushveld Complex, unlike the eastern and western limbs, can be considered a fertile unit for potential PGE mineralisation.  相似文献