Degradation of TCE with Iron: The Role of Competing Chromate and Nitrate Reduction   总被引：11，自引：0，他引：11  

Oliver Schlicker  Markus Ebert  Margit Fruth  Markus Weidner  Wolfgang Wüst  reas Dahmke 《Ground water》2000,38(3):403-409

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The IRAS PSCz dipole     

M. Rowan-Robinson  J. Sharpe  S. J. Oliver  O. Keeble  A. Canavezes  W. Saunders  A. N. Taylor  H. Valentine  C. S. Frenk  G. P. Efstathiou  R. G. McMahon  S. D. M. White  W. Sutherland  H. Tadros  S. Maddox 《Monthly notices of the Royal Astronomical Society》2000,314(2):375-397

We use the PSC z IRAS galaxy redshift survey to analyse the cosmological galaxy dipole out to a distance of 300  h ¹ Mpc. The masked area is filled in three different ways, first by sampling the whole sky at random, secondly by using neighbouring areas to fill a masked region, and thirdly using a spherical harmonic analysis. The method of treatment of the mask is found to have a significant effect on the final calculated dipole.
The conversion from redshift space to real space is accomplished by using an analytical model of the cluster and void distribution, based on 88 nearby groups, 854 clusters and 163 voids, with some of the clusters and all of the voids found from the PSC z data base.
The dipole for the whole PSC z sample appears to have converged within a distance of 200  h ¹ Mpc and yields a value for , consistent with earlier determinations from IRAS samples by a variety of methods. For b =1, the 2 range for ₀ is 0.431.02.
The direction of the dipole is within 13° of the cosmic microwave background (CMB) dipole, the main uncertainty in direction being associated with the masked area behind the Galactic plane. The improbability of further major contributions to the dipole amplitude coming from volumes larger than those surveyed here means that the question of the origin of the CMB dipole is essentially resolved.  相似文献   

Late Quaternary solifluction sheets in the British uplands     

Stephan Harrison  Leanne Hughes  Neil Glasser  Oliver Kuras 《第四纪科学杂志》2021,36(7):1162-1173

Solifluction sheets are large-scale and extensive valley-floor and valley-side landforms developed widely in the British Isles from mass-wasting of glacial and periglacial sediments during late-glacial times. We describe their geographical distribution and review the processes that have led to their development. We use data from the Cheviot Hills, the one site in the British Isles where sedimentology and optically stimulated luminescence dating have been combined, to assess their age and nature of deposition. We also present data from central Wales where a new mapping and resistivity survey has reconstructed the nature of valley-side solifluction sheets. We explore the relative lack of recent research on these landforms and argue that solifluction sheets represent a clear example of how upland geomorphological systems have responded to late-glacial climate change. We end by identifying a number of areas where research on these enigmatic features could be focussed, including better understanding of their distribution, sedimentology and age.  相似文献   

How can we model subsurface stormflow at the catchment scale if we cannot measure it?     

Peter Chifflard  Theresa Blume  Katja Maerker  Luisa Hopp  Ilja van Meerveld  Thomas Graef  Oliver Gronz  Andreas Hartmann  Bernhard Kohl  Edoardo Martini  Christian Reinhardt‐Imjela  Martin Reiss  Michael Rinderer  Stefan Achleitner 《水文研究》2019,33(9):1378-1385

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Cl/Br of scapolite as a fluid tracer in the earth's crust: insights into fluid sources in the Mary Kathleen Fold Belt,Mt. Isa Inlier,Australia     

J. Hammerli  C. Spandler  N. H. S. Oliver  B. Rusk 《Journal of Metamorphic Geology》2014,32(1):93-112

A combination of analytical methods, including trace element analysis of Br in scapolite by LA‐ICP‐MS, was employed to unravel the fluid–rock interaction history of the Mary Kathleen Fold Belt of northern Australia. Halogen ratios in the metamorphic and hydrothermally derived scapolite from a range of rock‐types record interaction between the host rocks and magmatic‐hydrothermal fluids derived from granite plutons and regional metamorphism. The results show that halite‐dissolution supplied at best only minor chlorine to fluids in the Fold Belt. Chlorine/bromine ratios in metamorphic scapolite indicate that fluids were dominantly derived from basinal brines formed from sub‐aerial evaporation of seawater beyond the point of halite saturation. This bittern fluid infiltrated the underlying sedimentary sequences prior to regional metamorphism. Zoned scapolite in a major late metamorphic mineralized shear‐zone records three discrete pulses of magmatic and metamorphic fluid, and it is suggested that fluid mixing may have assisted mineralization along and around this shear‐zone. As a crucial prerequisite for halogen fluid tracer studies using scapolite, we find in our samples that Cl and Br do not fractionate when incorporated in scapolite. Furthermore, unaltered rims of heavily retrogressed scapolite show indistinguishable Cl/Br signatures compared with fresh grains from the same sample indicating retrograde metamorphism did not significantly affect Cl and Br signatures in scapolite group minerals.  相似文献   

Short-term periodicities in sunspot areas during solar cycle 22     

R. Oliver  J. L. Ballester 《Solar physics》1995,156(1):145-155

We have analyzed the daily record of sunspot areas during the current cycle 22 looking for the short-term periodicity of around 155 days which was present during some previous solar cycles. Two different methods have been used to compute the power spectra and the results indicate that such periodicity has been absent during the current solar cycle, which confirms the results obtained by other authors who used flares or flare-related data.However, we have found that, during some intervals of time, a periodicity close to 86 days is statistically significant. A similar periodicity was found by Landscheit (1986) in energetic X-ray flares, between 1970 and 1982 (second and first half of solar cycles 20 and 21, respectively), and by Bai (1992b) for important solar flares during solar cycle 20.  相似文献   

A fresh look at discordant redshift galaxies in compact groups     

Jack W. Sulentic  J. Brett Smith 《Astrophysics and Space Science》1996,244(1-2):23-28

We reexamine the statistics of discordant redshift galaxies in compact groups. We find that 43 out of 100 groups in the Hickson catalog contain at least one discordant redshift galaxy. We show that, despite the prevailing impression, all previous attempts have failed to explain this large number of discordant redshift galaxies. The order of magnitude excess survives all of our attempts to refine the sample.  相似文献   

Assessment and Assimilation of FY-3 Humidity Sounders and Imager in the UK Met Office Global Model     

Fabien CARMINATI  Brett CANDY  William BELL  Nigel ATKINSON 《大气科学进展》2018,35(8):942-954

China's Feng Yun 3(FY-3) polar orbiting satellites are set to become an important source of observational data for numerical weather prediction(NWP),atmospheric reanalyses,and climate monitoring studies over the next two decades.As part of the Climate Science for Service Partnership China(CSSP China) program,FY-3 B Microwave Humidity Sounder 1(MWHS-1) and FY-3 C MWHS-2 observations have been thoroughly assessed and prepared for operational assimilation.This represents the first time observations from China's polar orbiting satellites have been used in the UK's global NWP model.Since 2016,continuous data quality monitoring has shown occasional bias changes found to be correlated to changes in the energy supply scheme regulating the platform heating system and other transient anomalies.Nonetheless,MWHS-1 and MWHS-2 significantly contribute to the 24-h forecast error reduction by 0.3% and 0.6%,respectively,and the combination of both instruments is shown to improve the fit to the model background of independent sounders by up to 1%.The observations from the Microwave Radiation Imager(MWRI) also are a potentially significant source of benefits for NWP models,but a solar-dependent bias observed in the instrument half-orbits has prevented their assimilation.This paper presents the bases of a correction scheme developed at the Met Office for the purpose of a future assimilation of MWRI data.  相似文献   

Application of the EnKF and Localization to Automatic History Matching of Facies Distribution and Production Data   总被引：3，自引：3，他引：0  

Chinedu C. Agbalaka  Dean S. Oliver 《Mathematical Geosciences》2008,40(4):353-374

The performance of the ensemble Kalman filter (EnKF) for continuous updating of facies location and boundaries in a reservoir model based on production and facies data for a 3D synthetic problem is presented. The occurrence of the different facies types is treated as a random process and the initial distribution was obtained by truncating a bi-Gaussian random field. Because facies data are highly non-Gaussian, re-parameterization was necessary in order to use the EnKF algorithm for data assimilation; two Gaussian random fields are updated in lieu of the static facies parameters. The problem of history matching applied to facies is difficult due to (1) constraints to facies observations at wells are occasionally violated when productions data are assimilated; (2) excessive reduction of variance seems to be a bigger problem with facies than with Gaussian random permeability and porosity fields; and (3) the relationship between facies variables and data is so highly non-linear that the final facies field does not always honor early production data well. Consequently three issues are investigated in this work. Is it possible to iteratively enforce facies constraints when updates due to production data have caused them to be violated? Can localization of adjustments be used for facies to prevent collapse of the variance during the data-assimilation period? Is a forecast from the final state better than a forecast from time zero using the final parameter fields?To investigate these issues, a 3D reservoir simulation model is coupled with the EnKF technique for data assimilation. One approach to enforcing the facies constraint is continuous iteration on all available data, which may lead to inconsistent model states, incorrect weighting of the production data and incorrect adjustment of the state vector. A sequential EnKF where the dynamic and static data are assimilated sequentially is presented and this approach seems to have solved the highlighted problems above. When the ensemble size is small compared to the number of independent data, the localized adjustment of the state vector is a very important technique that may be used to mitigate loss of rank in the ensemble. Implementing a distance-based localization of the facies adjustment appears to mitigate the problem of variance deficiency in the ensembles by ensuring that sufficient variability in the ensemble is maintained throughout the data assimilation period. Finally, when data are assimilated without localization, the prediction results appear to be independent of the starting point. When localization is applied, it is better to predict from the start using the final parameter field rather than continue from the final state.  相似文献   

Metal extractability in acidic and neutral mine tailings from the Cartagena-La Unión Mining District (SE Spain)     

Héctor M. Conesa  Brett H. Robinson  Rainer Schulin  Bernd Nowack 《Applied Geochemistry》2008

Mine tailings are ubiquitous in the landscapes of mined areas. Metal solubilities were compared in two chemically distinct mine tailings from the old Mining District of Cartagena-La Unión (SE Spain). One of the tailings was acidic (pH 3.0) with 5400 mg/kg Zn, 1900 mg/kg As and 7000 mg/kg Pb. The other was neutral (pH 7.4) with 9100 mg/kg Zn, 5200 mg/kg Pb and 350 mg/kg As. In samples from the acidic tailings, more than 15% of the Zn and 55% of the Cd were extractable with 0.1 M NaNO₃, and distilled water. In the neutral tailings, using the same reagents, less than 1% of the metals were extractable. A sequential extraction procedure revealed that the sum of the residual and the Fe oxide fractions of Cu, Zn and Pb comprised 80–95% in the acidic tailings and 70–90% in the neutral tailings. The acidic mine tailings had a higher metal solubility, resulting in more metal leaching in the short-term, but also a higher fraction of inert metal. In contrast, in the neutral tailings, the metals were evenly distributed between, oxides and the residual fraction. This implies lower metal mobility in the short-term, but that metal mobility may increase in the long-term. When applied to mine tailings, sequential extractions may provide misleading results because the strong cation exchange capacity of some extractants may induce pH changes and thereby significantly change metal solubility.  相似文献