Mineral dissolution in the Cape Cod aquifer, Massachusetts, USA: I . Reaction stoichiometry and impact of accessory feldspar and glauconite on strontium isotopes, solute concentrations, and REY distribution     

Michael Bau  Brian Alexander  John T Chesley  Susan L Brantley 《Geochimica et cosmochimica acta》2004,68(6):1199-1216

To compare relative reaction rates of mineral dissolution in a mineralogically simple groundwater aquifer, we studied the controls on solute concentrations, Sr isotopes, and rare earth element and yttrium (REY) systematics in the Cape Cod aquifer. This aquifer comprises mostly carbonate-free Pleistocene sediments that are about 90% quartz with minor K-feldspar, plagioclase, glauconite, and Fe-oxides. Silica concentrations and pH in the groundwater increase systematically with increasing depth, while Sr isotopic ratios decrease. No clear relationship between ⁸⁷Sr/⁸⁶Sr and Sr concentration is observed. At all depths, the ⁸⁷Sr/⁸⁶Sr ratio of the groundwater is considerably lower than the Sr isotopic ratio of the bulk sediment or its K-feldspar component, but similar to that of a plagioclase-rich accessory separate obtained from the sediment. The Si-⁸⁷Sr/⁸⁶Sr-depth relationships are consistent with dissolution of accessory plagioclase. In addition, solutes such as Sr, Ca, and particularly K show concentration spikes superimposed on their respective general trends. The K-Sr-⁸⁷Sr/⁸⁶Sr systematics suggests that accessory glauconite is another major solute source to Cape Cod groundwater. Although the authigenic glauconite in the Cape Cod sediment is rich in Rb, it is low in in-grown radiogenic ⁸⁷Sr because of its young Pleistocene age. The low ⁸⁷Sr/⁸⁶Sr ratios are consistent with equilibration of glauconite with seawater. The impact of glauconite is inferred to vary due to its variable abundance in the sediments. In the Cape Cod groundwater, the variation of REY concentrations with sampling depth resembles that of K and Rb, but differs from that of Ca and Sr. Shale-normalized REY patterns are light REY depleted, show negative Ce anomalies and super-chondritic Y/Ho ratios, but no Eu anomalies. REY input from feldspar, therefore, is insignificant compared to input from a K-Rb-bearing phase, inferred to be glauconite. These results emphasize that interpretation of groundwater chemistry, even in relatively simple aquifers, may be complicated by solute contributions from “exotic” accessory minerals such as glauconite. To detect such peculiarities, groundwater studies should combine the study of elemental concentration and isotopic composition of several solutes that show different geochemical behavior.  相似文献   

Iron isotope fractionation by Fe(II)-oxidizing photoautotrophic bacteria     

Laura R. Croal  Brian L. Beard 《Geochimica et cosmochimica acta》2004,68(6):1227-1242

Photoautotrophic bacteria that oxidize ferrous iron (Fe[II]) under anaerobic conditions are thought to be ancient in origin, and the ferric (hydr)oxide mineral products of their metabolism are likely to be preserved in ancient rocks. Here, two enrichment cultures of Fe(II)-oxidizing photoautotrophs and a culture of the genus Thiodictyon were studied with respect to their ability to fractionate Fe isotopes. Fe isotope fractionations produced by both the enrichment cultures and the Thiodictyon culture were relatively constant at early stages of the reaction progress, where the ⁵⁶Fe/⁵⁴Fe ratios of poorly crystalline hydrous ferric oxide (HFO) metabolic products were enriched in the heavier isotope relative to aqueous ferrous iron (Fe[II]_aq) by ∼1.5 ± 0.2‰. This fractionation appears to be independent of the rate of photoautotrophic Fe(II)-oxidation, and is comparable to that observed for Fe isotope fractionation by dissimilatory Fe(III)-reducing bacteria. Although there remain a number of uncertainties regarding how the overall measured isotopic fractionation is produced, the most likely mechanisms include (1) an equilibrium effect produced by biological ligands, or (2) a kinetic effect produced by precipitation of HFO overlaid upon equilibrium exchange between Fe(II) and Fe(III) species. The fractionation we observe is similar in direction to that measured for abiotic oxidation of Fe(II)_aq by molecular oxygen. This suggests that the use of Fe isotopes to identify phototrophic Fe(II)-oxidation in the rock record may only be possible during time periods in Earth’s history when independent evidence exists for low ambient oxygen contents.  相似文献   

A method for calculating effective bulk composition modification due to crystal fractionation in garnet-bearing schist: implications for isopleth thermobarometry   总被引：11，自引：1，他引：11  

T. P. Evans 《Journal of Metamorphic Geology》2004,22(6):547-557

Quantitative P–T path determination in metamorphic rocks is commonly based on the variation in composition of growth‐zoned garnet. However, some component of growth zoning in garnet is necessarily the result of an effective bulk composition change within the rock that has been generated by crystal fractionation of components into the core of garnet. Therefore, any quantitative calculation of the P–T regime of garnet growth should be completed using an accurate assessment of the composition of the chemical system from which garnet is growing. Consequently, a method for calculating the extent of crystal fractionation that provides a means of estimating the composition of the unfractionated rock at any stage during garnet growth is developed. The method presented here applies a Rayleigh fractionation model based on measured Mn content of garnet to generate composition v. modal proportion curves for garnet, and uses those curves to estimate the vectors of crystal fractionation. The technique is tested by calculating the precision of the equilibrium between three garnet compositional variables within the chemical system determined to be appropriate for each of a series of microprobe analyses from garnet. Application of the fractionation calculations in conjunction with the P–T estimates based on intersecting compositional isopleths provides a means of calculating P–T conditions of garnet growth that is based on individual point‐analyses on a garnet grain. Such spatially precise and easily obtainable P–T data allow for detailed parallel studies of the microstructural, the P–T, and the chemical evolution of metamorphosed pelites. This method provides a means of studying the dynamics of orogenic systems at a resolution that was previously unattainable.  相似文献   

Genetic significance of fluid inclusions in the CSA Cu–Pb–Zn deposit, Cobar, Australia     

Alan D. Giles  Brian Marshall   《Ore Geology Reviews》2004,24(3-4):241

CSA mine exploits a ‘Cobar-type’ Cu–Pb–Zn±Au±Ag deposit within a cleaved and metamorphosed portion of the Cobar Supergroup, central New South Wales. The deposit comprises systems of ‘lenses’ that encompass veins, disseminations and semi-massive to massive Cu–Pb–Zn ores. The systems and contained lenses truncate bedding, are approximately coplanar with regional cleavage and similarly oriented shear zones and plunge parallel to the elongation lineation. Systems have extreme vertical continuity (>1000 m), short strike length (400 m) and narrow width (100 m), exhibit vertical and lateral ore-type variation and have alteration haloes. Models of ore formation include classical hydrothermalism, structurally controlled remobilisation and polymodal concepts; syntectonic emplacement now holds sway.Fluid inclusions were examined from quartz±sulphide veins adjacent to now-extracted ore, from coexisting quartz–sulphide within ore, and from vughs in barren quartz veins. Lack of early primary inclusions precluded direct determination of fluids associated with D₂–D₃ ore and vein emplacement. Similarly, decrepitation (by near-isobaric heating) of the two oldest secondary populations precluded direct determination of fluid phases immediately following D₂–D₃ ore and vein emplacement. Post-decrepitation outflow (late D₃ to early post-D₃) is recorded by monophase CH₄ inclusions. Entrained outflow of deeply circulated meteoric fluid modified the CH₄ system; modification is recorded by H₂O+CH₄ and H₂O+(trace CH₄) secondary populations and by an H₂O+(trace CH₄) primary population. The contractional tectonics (D₂–D₃) of ore emplacement was superseded by relaxational tectonics (D_4P) that facilitated meteoric water penetration and return flow.Under D₂ prograde metamorphism, entrapment temperatures (Tt) and pressures (Pt) for pre-decrepitation secondary inclusions are estimated as Tt300–330 °C and Pt1.5–2 kbar≈Plith (the lithostatic pressure). Decrepitation accompanied peak metamorphism (T350–380 °C) in mid- to late-D₃, while in late-D₃ to early post-D₃, essentially monophase CH₄ secondary inclusions were entrapped at Tt350 °C and Pt=1.5–2 kbar≈Plith. Subsequently, abundant CH₄ and entrained meteoric water were entrapped as H₂O+CH₄ secondaries under slowly decreasing temperature (Tt330–350 °C) and constant pressure (Pt1.5–2 kbar). Finally, with increasingly dominant meteoric outflow, H₂O+(trace CH₄) populations record decreasing temperatures (Tt>300 to <350 down to 275–300 °C) at pressures of Phydrostatic<Pt (1 kbar) <Plith (1.5 kbar).The populations of inclusions provide insight into fluid types, flow regimes and P–T conditions during parts of the deposit's evolution. They indirectly support the role of basin-derived CH₄ fluids in ore formation, but provide no insight into a basement-sourced ore-forming fluid. They fully support post-ore involvement of meteoric water. The poorly constrained entrapment history is believed to span 10 Ma from 395 to 385 Ma.  相似文献   

Barite deposition resulting from phototrophic sulfide-oxidizing bacterial activity     

John M. Senko  Brian S. Campbell  James R. Henriksen  Mostafa S. Elshahed  Lee R. Krumholz 《Geochimica et cosmochimica acta》2004,68(4):773-780

Barite (BaSO₄) deposits generally arise from mixing of soluble barium-containing fluids with sulfate-rich fluids. While the role of biological processes in modulating barium solubility has been shown, no studies have shown that the biological oxidation of sulfide to sulfate leads to barite deposition. Here we present an example of microbially mediated barite deposition in a continental setting. A spring in the Anadarko Basin of southwestern Oklahoma produces water containing abundant barium and sulfide. As emergent water travels down a stream to a nearby creek, sulfate concentration increases from 0.06 mM to 2.2 mM while Ba²⁺ concentration drops from 0.4 mM to less than 7 μM. Stable isotope analysis, microbial activity studies, and in situ experiments provide evidence that as sulfide-rich water flows down the stream, anaerobic, anoxygenic, phototrophic bacteria play a dominant role in oxidizing sulfide to sulfate. Sulfate then precipitates with Ba²⁺ producing barite as travertine, cements, crusts, and accumulations on microbial mats. Our studies suggest that phototrophic sulfide oxidation and concomitant sulfur cycling could prove to be important processes regulating the cycling of barium in continental sulfur-containing systems.  相似文献   

Marine and limnic radiocarbon reservoir corrections for studies of late- and postglacial environments in Georgia Basin and Puget Lowland, British Columbia, Canada and Washington, USA     

Ian Hutchinson  Thomas S. James  Brian D. Bornhold 《Quaternary Research》2004,61(2):193-203

Models of late-glacial environmental change in coastal areas are commonly based on radiocarbon ages on marine shell and basal lake sediments, both of which may be compromised by reservoir effects. The magnitude of the oceanic reservoir age in the inland waters of the Georgia Basin and Puget Lowland of northwestern North America is inferred from radiocarbon ages on shell-wood pairs in Saanich Inlet and previously published estimates. The weighted mean oceanic reservoir correction in the early and mid Holocene is −720±90 yr, slightly smaller than, but not significantly different from, the modern value. The correction in late-glacial time is −950±50 yr. Valley-head sites yield higher reservoir values (−1200±130 yr) immediately after deglaciation. The magnitude of the gyttja reservoir effect is inferred from pairs of bulk gyttja and plant macrofossil ages from four lakes in the region. Incorporation of old carbon into basal gyttja yields ages from bulk samples that are initially about 600 yr too old. The reservoir age declines to less than 100 yr after the first millennium of lake development. When these corrections are accounted for, dates of deglaciation and late-glacial sea-level change in the study area are pushed forward in time by more than 500 yr.  相似文献   

'Just sustainability': the emerging discourse of environmental justice in Britain?   总被引：1，自引：0，他引：1  

Julian Agyeman  Bob Evans 《The Geographical journal》2004,170(2):155-164

Environmental justice is both a vocabulary for political opportunity, mobilization and action, and a policy principle to guide public decision making. It emerged initially in the US, and more recently in the UK, as a new vocabulary underpinning action by community organizations campaigning against environmental injustices. However, as the environmental justice discourse has matured, it has become increasingly evident that it should play a role in the wider agendas for sustainable development and social inclusion. The links between sustainability and environmental justice are becoming clearer and more widely understood in the UK by NGOs and government alike, and it is the potential synergy between these two discourses which is the focus of this paper. This paper argues that the concept of 'just sustainability' provides a discourse for policymakers and activists, which brings together the key dimensions of both environmental justice and sustainable development.  相似文献   

Discrimination between climate and human-induced dryland degradation   总被引：21，自引：0，他引：21  

Jason Evans  Roland Geerken 《Journal of Arid Environments》2004,57(4):535

In this study we present a technique to discriminate between climate or human-induced dryland degradation, based on evaluations of AVHRR NDVI data and rainfall data. Since dryland areas typically have high inter-annual rainfall variations and rainfall has a dominant role in determining vegetation growth, minor biomass trends imposed by human influences are difficult to verify. By performing many linear regression calculations between different periods of accumulated precipitation and the annual NDVI_max, we identify the rainfall period that is best related to the NDVI_max and by this the proportion of biomass triggered by rainfall. Positive or negative deviations in biomass from this relationship, expressed in the residuals, are interpreted as human-induced. We discuss several approaches that use either a temporally fixed NDVI peaking time or an absolute one, a best mean rainfall period for the entire drylands or the best rainfall period for each individual pixel. Advantages and disadvantages of either approach or one of its combinations for discriminating between climate and human-induced degradation are discussed. Depending on the particular land-use either method has advantages. To locate areas with a high likelihood of human-induced degradation we therefore recommend combining results from each approach.  相似文献   

Geomorphic and sedimentological signature of a two‐phase outburst flood from moraine‐dammed Queen Bess Lake,British Columbia,Canada     

Jane A. Kershaw  John J. Clague  Stephen G. Evans 《地球表面变化过程与地形》2005,30(1):1-25

On 12 August 1997, the lower part of Diadem Glacier in the southern Coast Mountains of British Columbia fell into Queen Bess Lake and produced a train of large waves. The waves overtopped the broad end moraine at the east end of the lake and ?ooded the valley of the west fork of Nostetuko River. The displacement waves also incised the out?ow channel across the moraine. Stratigraphic and sedimentologic evidence supports the conclusion that the ?ood had two phases, one related to wave overtopping and a second to breach formation. Empirical equations were used to calculate the peak discharge of the ?ood at various points along the west fork of the Nostetuko valley and to describe the attenuation of the ?ood wave. The velocity of the ?ood was also calculated to determine the time it took for the ?ood to reach the main fork of Nostetuko River. The highest peak discharges were achieved in the upper reach of the valley during the displacement phase of the ?ood. Peak discharge declined rapidly just below the moraine dam, with little change thereafter for approximately 7 km. Empirical formulae and boulder measurements indicate a rise in peak discharge in the lower part of the west fork valley. We suggest that ?ow in the upper part of the valley records the passage of two separate ?ood peaks and that the rise in discharge in the lower part of the valley is due to amalgamation of the wave and breach peaks. Hydraulic ponding in con?ned reaches of the valley extended the duration of the ?ood. In addition, erosion of vegetation and sediment in the channel and valley sides may also have exerted an in?uence on the duration and nature of ?ooding. Sediments were deposited both upstream and downstream of channel constrictions and on a large fan extending out into the trunk Nostetuko River valley. This study extends our understanding of the variety and complexity of outburst ?oods from naturally dammed lakes. It also shows that simple empirical and other models for estimating peak discharges of outburst ?oods are likely to yield erroneous results. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献   

Testing a statistical curve‐fitting procedure for quantifying sediment populations within multi‐modal particle‐size distributions     

John Leys  Grant McTainsh  Terry Koen  Brian Mooney  Craig Strong 《地球表面变化过程与地形》2005,30(5):579-590

This paper describes a series of tests designed to evaluate the capacity of a personal computer (PC) based statistical curve‐fitting program called MIX to quantify composite populations within multi‐modal particle‐size distributions. Three natural soil samples were analysed by a Coulter Multisizer, and their particle‐size distributions analysed using MIX software to identify the modes, standard deviations and proportions of their composite populations. The particle‐size distributions of the three natural soil samples were then numerically combined in equal proportions using a spreadsheet program to create synthetic particle‐size distributions of known populations. MIX was then tested on the synthetic particle‐size distributions to see if the modes and proportions it identified were similar to those modes and proportions known to characterize the synthetic particle‐size distributions. The main outcome is that MIX can very accurately describe the modal particle size and proportions of the major composite populations within a particle‐size distribution. However MIX has difficulty in identifying small populations (those contributing <10 per cent of a total particle‐size distribution), particularly when they are located in the central sections of particle‐size distributions, overlain by larger populations, or when positioned in the fine tails of distributions. Despite these minor shortcomings, MIX is a valuable tool for the examination and interpretation of particle‐size data. Copyright © 2005 John Wiley & Sons, Ltd.  相似文献