Middle Pleistocene sedimentology and lithostratigraphy of Weybourne northeast Norfolk, England     

Steven M. Pawley  Brian S.P. Moorlock  Richard J.O. Hamblin 《Proceedings of the Geologists' Association. Geologists' Association》2004,115(1):25-42

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Experimental constraints on Fe isotope fractionation during magnetite and Fe carbonate formation coupled to dissimilatory hydrous ferric oxide reduction   总被引：3，自引：0，他引：3  

Clark M. Johnson  Eric E. Roden  Brian L. Beard 《Geochimica et cosmochimica acta》2005,69(4):963-993

Iron isotope fractionation between aqueous Fe(II) and biogenic magnetite and Fe carbonates produced during reduction of hydrous ferric oxide (HFO) by Shewanella putrefaciens, Shewanella algae, and Geobacter sulfurreducens in laboratory experiments is a function of Fe(III) reduction rates and pathways by which biogenic minerals are formed. High Fe(III) reduction rates produced ⁵⁶Fe/⁵⁴Fe ratios for Fe(II)_aq that are 2-3‰ lower than the HFO substrate, reflecting a kinetic isotope fractionation that was associated with rapid sorption of Fe(II) to HFO. In long-term experiments at low Fe(III) reduction rates, the Fe(II)_aq-magnetite fractionation is −1.3‰, and this is interpreted to be the equilibrium fractionation factor at 22°C in the biologic reduction systems studied here. In experiments where Fe carbonate was the major ferrous product of HFO reduction, the estimated equilibrium Fe(II)_aq-Fe carbonate fractionations were ca. 0.0‰ for siderite (FeCO₃) and ca. +0.9‰ for Ca-substituted siderite (Ca_0.15Fe_0.85CO₃) at 22°C. Formation of precursor phases such as amorphous nonmagnetic, noncarbonate Fe(II) solids are important in the pathways to formation of biogenic magnetite or siderite, particularly at high Fe(III) reduction rates, and these solids may have ⁵⁶Fe/⁵⁴Fe ratios that are up to 1‰ lower than Fe(II)_aq. Under low Fe(III) reduction rates, where equilibrium is likely to be attained, it appears that both sorbed Fe(II) and amorphous Fe(II)(s) components have isotopic compositions that are similar to those of Fe(II)_aq.The relative order of δ⁵⁶Fe values for these biogenic minerals and aqueous Fe(II) is: magnetite > siderite ≈ Fe(II)_aq > Ca-bearing Fe carbonate, and this is similar to that observed for minerals from natural samples such as Banded Iron Formations (BIFs). Where magnetite from BIFs has δ⁵⁶Fe >0‰, the calculated δ⁵⁶Fe value for aqueous Fe(II) suggests a source from midocean ridge (MOR) hydrothermal fluids. In contrast, magnetite from BIFs that has δ⁵⁶Fe ≤0‰ apparently requires formation from aqueous Fe(II) that had very low δ⁵⁶Fe values. Based on this experimental study, formation of low-δ⁵⁶Fe Fe(II)_aq in nonsulfidic systems seems most likely to have been produced by dissimilatory reduction of ferric oxides by Fe(III)-reducing bacteria.  相似文献   

Geochemical processes in the Onyx River, Wright Valley, Antarctica: Major ions, nutrients, trace metals   总被引：2，自引：0，他引：2  

William J. Green  Brian R. Stage  Shannon Wagers  Silvia Newell 《Geochimica et cosmochimica acta》2005,69(4):839-850

We present data on major ions, nutrients and trace metals in an Antarctic stream. The Onyx River is located in Wright Valley (77-32 S; 161-34 E), one of a group of ancient river and glacier-carved landforms that comprise the McMurdo Dry Valleys of Antarctica. The river is more than 30 km long and is the largest of the glacial meltwater streams that characterize this relatively ice-free region near the Ross Sea. The complete absence of rainfall in the region and the usually small contributions of glacially derived tributaries to the main channel make this a comparatively simple system for geochemical investigation. Moreover, the lack of human impacts, past or present, provides an increasingly rare window onto a pristine aquatic system.For all major ions and silica, we observe increasing concentrations with distance from Lake Brownworth down to the recording weir near Lake Vanda. Chemical weathering rates are unexpectedly high and may be related to the rapid dissolution of ancient carbonate deposits and to the severe physical weathering associated with the harsh Antarctic winter. Of the nutrients, nitrate and dissolved reactive phosphate appear to have quite different sources. Nitrate is enriched in waters near the Lower Wright Glacier and may ultimately be derived from stratospheric sources; while phosphate is likely to be the product of chemical weathering of valley rocks and soils. We confirm the work of earlier investigations regarding the importance of the Boulder Pavement as a nutrient sink.Dissolved Mn, Fe, Ni, Cu, and Cd are present at nanomolar levels and, in all cases, the concentrations of these metals are lower than in average world river water. We hypothesize that metal uptake and exchange with particulate phases along the course of the river may serve as a buffer for the dissolved load. Concurrent study of these three solute classes points out significant differences in the mechanisms and sites of their removal from the Onyx River.  相似文献   

Reply to letter to the editor from Easterbrook and Kovanen re Quaternary Research 61, 193-203.     

Ian Hutchinson  Thomas S. James  Brian D. Bornhold 《Quaternary Research》2005,63(2):226-227

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Multibeam bathymetric and sediment profiler evidence for ice grounding on the Chukchi Borderland, Arctic Ocean   总被引：1，自引：0，他引：1  

Martin Jakobsson  James V. Gardner  Larry A. Mayer  Jan Backman  Brian Calder  Barbara Kraft 《Quaternary Research》2005,63(2):150-160

Multibeam bathymetry and 3.5-kHz sub-bottom profiler data collected from the US icebreaker Healy in 2003 provide convincing evidence for grounded ice on the Chukchi Borderland off the northern Alaskan margin, Arctic Ocean. The data show parallel, glacially induced seafloor scours, or grooves, and intervening ridges that reach widths of 1000 m (rim to rim) and as much as 40 m relief. Following previous authors, we refer to these features as “megascale glacial lineations (MSGLs).” Additional support for ice grounding is apparent from stratigraphic unconformities, interpreted to have been caused by ice-induced erosion. Most likely, the observed sea-floor features represent evidence for massive ice-shelf grounding. The general ESE/WNW direction of the MSGLs, together with sediment, evidently bulldozed off the Chukchi Plateau, that is mapped on the western (Siberian) side of the plateau, suggests ice flow from the Canada Basin side of Chukchi Borderland. Two separate generations of glacially derived MSGLs are identified on the Chukchi Borderland from the Healy geophysical data. The deepest and oldest extensive MSGLs appear to be draped by sediments less than 5 m thick, whereas no sediment drape can be distinguished within the resolution of the sub-bottom profiles on the younger generation.  相似文献   

Spaces of change: tribal authorities in the former KaNgwane homeland, South Africa     

Brian H King 《Area》2005,37(1):64-72

South Africa's democratic transition has had a significant impact upon localized governance systems in mediating development opportunities within the former apartheid homelands. This paper uses a case study from the former KaNgwane homeland to evaluate the role of the Matsamo Tribal Authority in shaping livelihoods and access to environmental resources. It is argued that although the colonial and apartheid empowerment of the tribal authorities continues to have symbolic and material meaning for rural populations, newly created democratic structures are challenging traditional governance systems in the post-apartheid era. The intersection between these contrasting, and historically situated, systems suggests a dynamic renegotiation is occurring that will continue to impact rural households within the former places of apartheid.  相似文献   

Investigating the Spatiotemporal Links Between Disorder,Crime, and the Fear of Crime   总被引：2，自引：0，他引：2  

Bruce J. Doran  Brian G. Lees 《The Professional geographer》2005,57(1):1-12

While links between social and physical disorder, crime, and the fear of crime have long been areas of research interest, few studies have looked at these links from a spatiotemporal viewpoint. This is somewhat surprising, as many of the factors associated with disorder, crime, and fear are known to vary over time and space. This paper uses GISystems to investigate potential spatiotemporal links between these areas in Wollongong, New South Wales, with specific focus on links between graffiti and the fear of crime. The results reveal that the distribution of fear of crime varies considerably over time and is often spatially coincident with concentrations of disorder. Graffiti was found to be one of the most prevalent types of physical disorder. The results are discussed in the context of the “broken windows” thesis and strategic intervention at the community level.  相似文献   

Compositions of magmatic hydrothermal fluids determined by LA-ICP-MS of fluid inclusions from the porphyry copper–molybdenum deposit at Butte, MT     

Brian G. Rusk  Mark H. Reed  John H. Dilles  Leonhard M. Klemm  Christoph A. Heinrich 《Chemical Geology》2004,210(1-4):173-199

We analyzed 85 fluid inclusions from seven samples from the porphyry Cu–Mo deposit in Butte, MT, using laser ablation-inductively coupled plasma-mass spectrometry (LA-ICP-MS). The Butte deposit formed at unusually great depth relative to most porphyry deposits, and fluid inclusions in deep veins trapped a low-salinity, CO₂-bearing, magmatically derived, supercritical fluid as a single aqueous phase. This fluid is interpreted to be the parent fluid that cooled, decompressed, unmixed, and reacted with wall rock to form the gigantic porphyry Cu deposit at Butte. Few previous analyses of such fluids exist.Low-salinity, aqueous fluids from the earliest veins at Butte are trapped in deep veins with biotite-rich alteration envelopes (EDM veins). These veins, and the Butte quartz monzonite surrounding them, host much of the Butte porphyry Cu mineralization. Twenty fluid inclusions in one EDM quartz vein are dominated by Na, K, Fe (from 0.1 to 1 wt.%) and contain up to 1.3 wt.% Cu. These inclusions contain only small amounts (tens of ppm) of Pb, Zn, and Mn, and typically contain Li, B, Ca, As, Mo, Ag, Sn, Sb, Ba, and W in less than detectable quantities. The abundance of Cu in early fluids indicates that a low-salinity, Cu-rich, aqueous ore fluid can be directly produced by aqueous fluid separation from a granitic magma. Similar inclusions (eight) in an early deep quartz–molybdenite vein with a K-feldspar selvage have similar compositions but contain significantly less Cu than most inclusions in the biotite-altered vein. Analyzed inclusions in both veins contain less than detectable concentrations of Mo even though one is molybdenite-bearing.Low-salinity, CO₂-bearing aqueous fluids are also trapped in pyrite–quartz veins with sericitic selvages. These veins cut both of the above vein types and contain inclusions that were trapped at lower pressure and temperature. Thirty-nine inclusions in two such veins have compositions similar to early fluids, but are enriched by up to a factor of 10 in Mn, Pb, and Zn relative to early fluids, and are slightly depleted in Fe. Many of these inclusions contain as much or more Cu than early fluids, although little chalcopyrite is found in or around pyrite–quartz veins.Eighteen halite-bearing inclusions from three veins from both chalcopyrite-bearing and barren veins with both K-silicate and sericitic selvages were analyzed as well. Halite-saturated inclusions are dominated by Na, K, Fe, and in some inclusions Ca. Whereas these inclusions are significantly enriched in Ca, Mn, Fe, Zn, and Pb, fluids in all three veins contain significantly less Cu than early, high temperature, low-salinity inclusions.Analyses of all inclusion types show that whereas bulk-salinity of the hydrothermal fluid must be largely controlled by the magma, fluid–rock interactions have a significant role in controlling fluid compositions and metal ratios. Cu concentrations range over an order of magnitude, more than any other element, in all four samples containing low-salinity inclusions. We infer that variations are the result of fluid trapping after different amounts of fluid–rock reaction and chalcopyrite precipitation. Enrichment, relative to early fluids, of Mn, Pb, and Zn in fluids related to sericitic alteration is also likely the result of fluid–rock reaction, whereby these elements are released from biotite and feldspars as they alter to sericite. In halite-bearing inclusions, concentrations of Sr, Ca, Pb, and Ba are elevated in inclusions from the pyrite–quartz vein with sericitic alteration relative to halite-bearing inclusions from unaltered and potassically altered samples. Such enrichment is likely caused by the breakdown of plagioclase and K-feldspar in the alteration envelope, releasing Sr, Ca, Pb, and Ba.  相似文献   

BARGEN continuous GPS data across the eastern Basin and Range province, and implications for fault system dynamics   总被引：1，自引：0，他引：1  

Nathan A. Niemi  Brian P. Wernicke  Anke M. Friedrich  Mark Simons  Richard A. Bennett  James L. Davis 《Geophysical Journal International》2004,159(3):842-862

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Cation and sediment concentrations in basal ice from Øksfjordjøkelen, north Norway     

Brice R. Rea  W. Brian Whalley  John Meneely 《Geografiska Annaler: Series A, Physical Geography》2004,86(1):91-105

Abstract Basal ice samples were collected from ice exposures in a natural subglacial cavity beneath an outlet glacier of Øksfjordjøkelen, North Norway. Sediment and cation (Ca²⁺, Mg²⁺, Na⁺, K⁺) concentrations were then determined, and indicate stacking of basal ice units producing a repeat pattern of ‘clean firnification ice’ overlying sediment‐rich ice. All measured cations show correlation with sediment concentration indicating weathering reactions to be the dominant contributor of cations. Regressions of specific sediment surface area per unit volume with cation concentration are performed and used to predict cation concentrations. These predicted values provide an indication of cation relocation within the basal ice sequence. The results suggest limited melting and refreezing resulting in the relocation of predominantly monovalent cations downward through the profile. Exchange of cations into solution during the melting of sediment‐rich ice samples has previously been suggested as a source of error in such investigations. Analyses of sediment‐free regelation ice spicules formed at the bed show cation concentrations above firnification ice levels and comparable, in many instances, to the basal ice samples.  相似文献