Si,Al ordering in leucite by high-resolution 27Al MAS NMR spectroscopy     

Brian L. Phillips  R. James Kirkpatrick  Andrew Putnis 《Physics and Chemistry of Minerals》1989,16(6):591-598

High-resolution ²⁷Al MAS NMR spectra of natural leucite recorded at H ₀=11.7T contain three resolvable resonances at ²⁷Al δ _i = 69.2, 64.7, and 61.0±0.5 ppm. These three resonances are assigned to the three inequivalent framework positions of leucite: T3, T2, and T1, respectively. Fitting the observed spectra yields a Si,Al distribution for leucite in which approximately one-half of the Al is in T1 and one-quarter in each of T2 and T3. This Si,Al distribution differs substantially from those obtained by previous workers using ²⁹Si NMR spectroscopy and X-ray diffraction. New ²⁹Si NMR spectra and revision of previously reported ²⁹Si NMR peak assignments, however, make the ²⁷Al and ²⁹Si NMR results consistent. The ²⁷Al δ _i correlate linearly with the mean T-O-T′ bond angles of the average structure, which allows the peak assignments to be made. However, this correlation lies distinctly toward higher frequency and larger bond angles than correlations for Si,Al ordered aluminosilicates, suggesting that the mean T(Al)-O-T′(Si) bond angle for each site in leucite is smaller than the mean bond angle of the average structure, which is averaged over T(Al)-O-T′(Si) and T(Si)-OT′(Si,Al) angles.  相似文献   

Structure and subduction processes along the Oregon-Washington margin     

Guy R. Cochrane  Brian T. R. Lewis  Kevin J. McClain 《Pure and Applied Geophysics》1988,128(3-4):767-800

Seismic reflection and refraction data off Washington and Oregon are used to determine the style of sediment deformation and to infer the physical properties of accreted sediments on the lower slope. Onshore-offshore seismic refraction data off Washington are used to determine the location of the trench, or where the plate bending starts.We find that off Washington the subduction zone is characterized by a trench whose physiographic expression is buried under several kilometers of sediments and is tens of kilometers landward of the lower slope, which is accreting seaward as the result of the offscraping of sediments.Seismic reflection data support previous observations that offscraping occurs along seaward and landward dipping thrust faults. Refraction data indicate that a sediment package thrust up along a seaward dipping fault (off Washington) was not measurably changed in velocity with respect to a Cascadia basin section. However a package uplifted by thrusting along a landward dipping fault (off Oregon) did have increased velocity. It is suggested that the increased velocities off Oregon could be the result of erosion and exposure of more deeply buried and compacted sediments, rather than the result of dewatering due to tectonic stress. Off Washington the sensitivity of velocity to porosity and resolution of the seismic method does not preclude dewatering due to tectonic stress, but it does limit the degree of dewatering.In the deeper parts of the lower slope section off Washington and Oregon velocities as high as 3 to 4 km/sec are found. Heat flow data indicate that the temperatures in this high velocity regime are greater than 100°C. It is hypothesized that lithification related to clay diagenesis may be partly responsible for the high velocities, rather than simply compaction. It also appears that the high velocity sediments are subducted while the unlithified low velocity sediments are offscraped.  相似文献   

Book reviews     

F. Alejandro Nava  Manfred Koch  Andrzej Hanyga  Jacek Leliwa-Kopystyński  Frazer Tabeart  Sueo Veno  Andrzej W. Wernik  Yu. N. Korenkov  Kenji Satake  Carlos Lozano  Aysel Karafistan  Ian N. James  Anthony Dore  Jacek Wałczewski  Krzysztof Haman  Brian F. Farrell 《Pure and Applied Geophysics》1994,143(4):753-780

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A study of the geoelectrical properties of peatlands and their influence on ground-penetrating radar surveying1     

Brian D. Theimer  David C. Nobes  Barry G. Warner 《Geophysical Prospecting》1994,42(3):179-209

Geophysical surveys and chemical analyses on cores were carried out in three Ontario peatlands, from which we have gained a better understanding of the peat properties that control the geophysical responses. The electrical conductivity depends linearly on the concentration of total dissolved solids in the peat pore waters and the pore waters in turn bear the ionic signatures of the underlying mineral sediments. The ionic concentration, and thus the electrical conductivity, increase linearly from the surface to basement. The average bulk electrical conductivity of peatlands at Ellice Marsh, near Stratford, and at Wally Creek Area Forest Drainage Project, near Cochrane, are of the order of 25 mS/m. The Mer Bleue peatland, near Ottawa, has extremely high electrical conductivity, reaching levels of up to 380 mS/m near the base of the peat. The Mer Bleue peatland water has correspondingly high values of total dissolved solids, which originate from the underlying Champlain Sea glaciomarine clays. The dielectric permittivity in peats is largely controlled by the bulk water content. Ground penetrating radar can detect changes in water content greater than 3%, occurring within a depth interval less than 15 cm. The principal peatland interfaces detected are the near-surface aerobic to anaerobic transition and the peat to mineral basement contact. The potential for the successful detection of the basement contact using the radar can be predicted using the radar instrument specifications, estimates of the peatland depth, and either the bulk peat or the peat pore water electrical conductivities. Predicted depths of penetration of up to 10 m for Ellice Marsh and Wally Creek exceed the observed depths of 1 to 2 m. At Mer Bleue, on the other hand, we observe that, as predicted, a 100 MHz signal will penetrate to the base of a 2 m thick peat but a 200 MHz signal will not.  相似文献   

Seasonal variation of the stable isotopic compositions of coastal marine plankton from Woods Hole,Massachusetts and Georges Bank     

Sam C. Wainright  Brian Fry 《Estuaries and Coasts》1994,17(3):552-560

A study of the isotopic composition of plankton from Woods Hole Harbor was conducted to investigate seasonal variation in carbon and nitrogen stable isotopes in a shallow coastal environment. Stable isotopic ratios of carbon and nitrogen both showed temporal variation on the scale of weeks to months, with heaviest (most positive) values in summer to fall for both isotopes. Particulate organic matter (POM) δ¹³C values were highest (?19‰ to ?21‰) in August to November and lower (?21‰ to ?25‰) at other times of the year, while δ¹³N-POM values were highest (9.5‰ to 12‰) in March to September and lower (7.5‰ to 9.5‰) at other times of the year. Stable isotopic values were significantly correlated with temperature, DI¹³C, and C∶N ratios, but not with [DIC], [POC], [PN], [chlorophyll], or the taxonomic composition of the phytoplankton. There was no direct evidence of allochthonous inputs of carbon and nitrogen to the system. Woods Hole δ¹³C values were virtually identical to Georges Bank plankton values; similar POC: Chlorophyll and C∶N ratios in the two systems further suggest that Woods Hole Harbor is principally a marine system. The high δ¹³C values of net plankton (>20 μm) during summer and early fall are consistent with a smaller degree of photosynthetic isotopic fractionation at that time, related to temperature and/or [CO_2(aq)]. This pattern was not seen, however, in total POM. Plankton δ¹³N values were higher in Woods Hole Harbor than on Georges Bank, especially during warmer periods, possibly due to high rates of nitrification and organic matter recycling in Woods Hole waters. Relatively wide ranges of stable isotopic values from both Woods Hole Harbor and Georges Bank suggest that seasonality should be considered when attempting to establish endmember C and N isotopic values for temperate marine plankton. Preliminary results from size-fractionated samples suggest that cyanobacteria may fractionate carbon isotopes to a greater degree than net phytoplankton.  相似文献   

Diver-operated piston corer for nearshore use     

Francis J. Sansone  James T. Hollibaugh  Sue M. Vink  Randoph M. Chambers  Samantha B. Joye  Brian N. Popp 《Estuaries and Coasts》1994,17(3):716-720

A diver-operated piston corer suitable for collecting cores of >3 m length from fine-grained nearshore sediment has been developed. The corer uses a platform that rests on the sediment surface supporting both the operators and a derrick that maintains the piston at the sediment-water interface. The core is insected into and recovered from the sediment manually. The technique offers several advantages; low cost, minimal disruption of the sediment-water interface, little compaction of the sediment, the ability to collect longer length cores than is possible with gravity corers, and the ability to be deployed from relatively small boats. Dissolved ammonium and inorganic carbon data are presented from a 3.3-m core collected by this technique from Tomales Bay, California.  相似文献   

Book reviews     

Kacper R. Rybicki  Brian J. Mitchell  Louise H. Kellogg  Andrea Borgia  Allan M. Rubin  Douglas R. Schmitt  Douglas R. Schmitt  Edo Nyland  Zbigniew Fajklewicz  David Stevenson  Janusz L. Borkowski 《Pure and Applied Geophysics》1990,133(1):179-180

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Anisotropy beneath Hawaii from surface wave particle motion observations     

Pradeep K. Vig  Brian J. Mitchell 《Pure and Applied Geophysics》1990,133(1):1-22

Observed polarization ellipses for fundamental-mode surface waves observed at a digital station in Hawaii deviate from those expected for isotropic models of crust and mantle structure for that region. The anomalous motion occurs as rotations of the ellipse about all three axes in a cartesian corrdinate system. The largest and most consistent deviations occur as anomalous slopes of the ellipse about the horizontal axis transverse to the direction of propagation.The observed orientations and magnitudes of these angles can be explained by models of the upper mantle which contain olivine for which thea-axis dips significantly from the horizontal and which includes a sufficiently thick sedimentary layer (1 km) and a thicker than normal oceanic crust (15 km). The ellipses are also generally inclined from great circle paths about the vertical axis and are tilted about the axis aligned with the propagation direction. Both angles are small and difficult to measure, but the inclination angles are consistent with a model of the upper mantle in which thea-axis of olivine is preferentially oriented in an east-west direction.  相似文献   

A review of methods used to determine the fractal dimension of linear features   总被引：7，自引：0，他引：7  

Brian Klinkenberg 《Mathematical Geology》1994,26(1):23-46

An in-depth review of the more commonly applied methods used in the determination of the fractal dimension of one-dimensional curves is presented. Many often conflicting opinions about the different methods have been collected and are contrasted with each other. In addition, several little known but potentially useful techniques are also reviewed. General recommendations which should be considered whenever applying any method are made.  相似文献   

Book review     

Charles Fairhurst  Renata Dmowska  Gregory L. Duckworth  Brian J. Mitchell  David V. Wiltschko  Charles G. Sammis 《Pure and Applied Geophysics》1985,123(5):791-803

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