Hydrochemical evolution and arsenic release in shallow aquifer in the Titas Upazila,Eastern Bangladesh     

Wael Kanoua  Broder Merkel 《Arabian Journal of Geosciences》2017,10(13):290

Groundwater arsenic (As) concentrations above 10 μg/L (World Health Organization; WHO standard) are frequently found in the Titas Upazila in Bangladesh. This paper evaluates the groundwater chemistry and the mechanisms of As release acting in an underground aquifer in the middle-northeast part of the Titas Upazila in Bangladesh. Previous measurements and analyses of 43 groundwater samples from the region of interest (ROI) are used. Investigation is based on major ions and important trace elements, including total As and Fe in groundwater samples from shallow (8–36 m below ground level: mbgl) and deep (85–295 mbgl) tube wells in the aforementioned ROI. Principal hydrochemical facies are Ca–HCO₃, with circumneutral pH. The different redox-sensitive constituents (e.g., As, Fe, Mn, NH₄, and SO₄) indicate overlapping redox zones, leading to differences regarding the redox equilibrium. Multivariate statistical analysis (factor analysis) was applied to reduce 20 chemical variables to four factors but still explain 81% of the total variance. The component loadings give hints as to the natural processes in the shallow aquifers, in which organic matter is a key reactant. The observed chemistry of As, Fe, and Mn can be explained by simultaneous equilibrium between Fe-oxide and SO₄ reduction and an equilibrium of rhodochrosite precipitation/dissolution. A correlation test indicates the likeliness of As release by the reductive dissolution of Fe-oxides driven by the degradation of sediments organic matter. Other mechanisms could play a role in As release, albeit to a lesser extent. Reactive transport modeling using PHREEQC reproduced the observed chemistry evolution using simultaneous equilibrium between Fe-oxide and SO₄ reduction and the equilibrium of rhodochrosite dissolution/precipitation alongside organic matter oxidation.  相似文献   

Light-induced bird strikes on vessels in Southwest Greenland     

Merkel FR  Johansen KL 《Marine pollution bulletin》2011,62(11):2330-2336

Light-induced bird strikes are known to occur when vessels navigate during darkness in icy waters using powerful searchlight. In Southwest Greenland, which is important internationally for wintering seabirds, we collected reports of incidents of bird strikes over 2-3 winters (2006-2009) from navy vessels, cargo vessels and trawlers (total n = 19). Forty-one incidents were reported: mainly close to land (<4 km, 78%), but one as far offshore as 205 km. Up to 88 birds were reported killed in a single incident. All occurred between 5 p.m. and 6 a.m. and significantly more birds were involved when visibility was poor (snow) rather than moderate or good. Among five seabird species reported, the common eider (Somateria mollissima) accounted for 95% of the bird casualties. Based on spatial analyses of data on vessel traffic intensity and common eider density we are able to predict areas with high risk of bird strikes in Southwest Greenland.  相似文献   

Sorption of uranium(VI) at the clay mineral–water interface     

Samer Bachmaf  Broder J. Merkel 《Environmental Earth Sciences》2011,63(5):925-934

Batch experiments were conducted to study the sorption of uranium on selected clay minerals (KGa-1b and KGa-2 reference kaolinite, SWy-2 and STx-1b reference montmorillonite, and IBECO natural bentonite) as a function of pH (4–9) and 0.001, 0.01, and 0.025 M NaCl in equilibrium with the CO₂ partial pressure of the atmosphere. Uranium concentrations were kept below 100 μg L⁻¹ to avoid precipitation of amorphous Uranium-hydroxides. Solely PTFE containers and materials were used, because experiments showed significant sorption at higher pH on glass ware. All batch experiments were performed over a period of 24 h, since kinetic experiments proved that the common 10 or 15 min are in many cases by far not sufficient to reach equilibrium. Kaolinite showed much greater uranium sorption than the other clay minerals due to the more aluminol sites available. Sorption on the poorly crystallized KGa-2 was higher than on the well-crystallized KGa-1b. Uranium sorption on STx-1b and IBECO exhibited parabolic behavior with a sorption maximum around pH 6.5. Sorption of uranium on montmorillonites showed a distinct dependency on sodium concentrations because of the effective competition between uranyl and sodium ions, whereas less significant differences in sorption were found for kaolinite. The presence of anatase as impurity in kaolinite enhanced the binding of uranyl-carbonate complexes with surface sites. The kinetic of uranium sorption behavior was primarily dependent on the clay minerals and pH. A multisite surface complexation model without assuming exchange is based on the binding of the most dominant uranium species to aluminol and silanol edge sites of montmorillonite, respectively to aluminol and titanol surface sites of kaolinite. For eight surface species, the log_k was determined from the experimental data using the parameter estimation code PEST together with PHREEQC.  相似文献   

Comparison of polar mesospheric cloud measurements from the Cloud Imaging and Particle Size experiment and the solar backscatter ultraviolet instrument in 2007     

Susanne Benze  Cora E. Randall  Matthew T. DeLand  Gary E. Thomas  David W. Rusch  Scott M. Bailey  James M. Russell  William McClintock  Aimee W. Merkel  Chris Jeppesen 《Journal of Atmospheric and Solar》2009,71(3-4):365-372

We compare measurements from the Aeronomy of Ice in the Mesosphere (AIM) Cloud Imaging and Particle Size (CIPS) experiment to the NOAA-17 solar backscatter ultraviolet (SBUV/2) instrument during the 2007 Northern Hemisphere polar mesospheric cloud (PMC) season. Daily average Rayleigh scattering albedos determined from identical footprints from the CIPS nadir camera and SBUV/2 agree to better than ～5% throughout the season. Average PMC brightness values derived from the two instruments agree to within ±10%. PMC occurrence frequencies are on average ～5% to nearly a factor of two higher in CIPS, depending on latitude. Agreement is best at high latitudes where clouds are brighter and more frequent. The comparisons indicate that AIM CIPS data are valid for scientific analyses. They also show that CIPS measurements can be linked to the long time series of SBUV/2 data to investigate long-term variability in PMCs.  相似文献   

The RIZA-Symposium,Oct. 1–5, 1984 in Munich,FRGermany     

B. Merkel Dr. 《GeoJournal》1985,10(4):418-418

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Evaluation of the recharge processes and impacts of irrigation on groundwater using CFCs and radiogenic isotopes in the Silao-Romita basin, Mexico     

Axel Horst  Jürgen Mahlknecht  Broder J. Merkel  Ramon Aravena  Yann R. Ramos-Arroyo 《Hydrogeology Journal》2008,16(8):1601-1614

The recharge processes in the overexploited aquifer of the Silao Romita basin, central Mexico, were investigated by means of gaseous tracers (chlorofluorocarbons, CFCs) and radioactive isotopes (C-14, tritium). CFC concentrations varied between 0.06 and 12 pmol/l (CFC-11), 0.03 and 1.7 pmol/l (CFC-12), and <0.01 and 0.23 pmol/l (CFC-113). CFC concentrations are controlled by irrigation return flow which became apparent by the comparison with tritium. Tritium activities ranged from 0 to 3.5 TU. The calculated mean residence times of 70 to more than 300 years are considerably lower than the ages estimated based on the CFCs data. These data showed that CFCs were not appropriate for groundwater dating in this particular area but the CFCs were suitable as a qualitative measure of the magnitude of irrigation return flow which proved to be a significant source of recharge in the irrigated areas. Radiocarbon activities were in the range of 6–109 pmC. Carbon-13 values varied between –11.9 and –7.2‰ VPDB. Modelling of carbon isotopes with NETPATH along a plausible flow path reveals considerable influences of exchange with soil CO₂ and carbonate dissolution. Radiocarbon data indicate, at least in one case, the existence of groundwaters with residence times of more than 10,000 years.  相似文献   

Origin of arsenic in the groundwater of the Rioverde basin, Mexico     

B. Planer-Friedrich  M. Armienta  B. Merkel 《Environmental Geology》2001,40(10):1290-1298

Groundwater in the semiarid Rioverde basin in the northern part of Mexico was investigated with respect to major and minor elements including arsenic, as well as As(III) and As(V). The total arsenic concentrations varied from less than 5 to 50 g/L. The in situ arsenic determination method produced reliable results with deviations from -5.6 to 2.2 g/L compared to laboratory HGAAS. Since arsenic and barium were found to be inversely correlated, it was suspected that precipitation of barium arsenate controlled arsenic solubility. Thermodynamically modeling by means of PHREEQC indicated that BaHAsO₄·H₂O (not BaAsO₄) might be a limiting phase, however only at higher concentrations than those determined in this study. Increased arsenic groundwater concentrations were found with lacustrine sediments and decreased concentrations with fluvial Quaternary sediments. Increased total arsenic concentrations correlate with increased As(III) concentrations in the groundwater of the lacustrine sediments.  相似文献   

Groundwater recharge in a sedimentary basin in semi-arid Mexico   总被引：9，自引：1，他引：8  

Jürgen?MahlknechtEmail author  Jean?F.?Schneider  Broder?J.?Merkel  Ignacio?Navarro de León  Stefano?M.?Bernasconi 《Hydrogeology Journal》2004,12(5):511-530

Recharge mechanisms and the hydrochemical evolution of groundwater in a semi-arid, 6,840-km², intermountain basin in central Mexico were investigated using stable isotopes and major chemical constituents. Ionic ratio analysis helped to conceptualize and quantify in part the subsequent geochemical evolution in the aquifer system. Mass balance models (PHREEQC) were used to interpret and rectify the geochemical properties of the aquifer. The recharge conditions have not changed noticeably during the last several thousands of years. The recharge mechanisms are accompanied by leaching of meteoric salts on and near the ground surface during major rain events, which previously accumulated after minor rain events. Rapid and diffuse infiltration can be excluded. Indirect infiltration from wadis (arroyos) and depressions (playas) with little mixing in shallow groundwater contrasts with a high degree of mixing for water with deep circulation. The prevailing source of major cations (Ca²⁺, Mg²⁺, Na⁺, K⁺) is weathering of carbonates and albite, followed by exchange reactions on clays and hydroxides. Ca²⁺/Na⁺ exchange may interchange along the flow path with reverse (Na⁺/Ca²⁺) exchange, although the Ca²⁺/Na⁺ option is prevalent. Meteoric Ca and Mg inputs are relatively small; however, meteoric Na is insignificant. Irrigation return flow plays an important role in the western part of the study area, giving rise to elevated sulfate and chloride concentrations.

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Resumen Se han investigado los mecanismos de recarga y la evolución hidroquímica de las aguas subterráneas en una cuenca semiárida e intermontanosa de México central, de 6.840 km². Para ello, se han utilizado isótopos estables y los constituyentes químicos mayores. El análisis de las relaciones iónicas ha servido para conceptuar y cuantificar en parte su evolución geoquímica posterior dentro del sistema acuífero. Se ha recurrido a modelos de balance de masas (PHREEQC) para interpretar y rectificar las propiedades geoquímicas del acuífero. Las condiciones de recarga no han cambiado de forma apreciable durante los últimos miles de años. Los mecanismos de recarga se ven acompañados por el lixiviado de las sales meteóricas sobre y cerca de la superficie del terreno durante los episodios principales de lluvia, las cuales son acumuladas en episodios menores de lluvia. Se puede excluir la infiltración rápida y difusa. La infiltración indirecta desde arroyos ( wadis) y depresiones ( playas), que apenas se mezcla con las aguas subterráneas someras, contrasta con un elevado nivel de mezcla con el agua de circulación profunda. La fuente dominante de cationes mayores (calcio, magnesio, sodio, potasio) es la meteorización de los carbonatos y albita, mientras que las reacciones de intercambio en las arcillas e hidróxidos son menos importantes. El intercambio ión calcio-ión sodio puede ser reemplazado a lo largo de una línea de flujo por el intercambio opuesto (ión sodio-ión calcio), aunque la primera es prioritaria. Las aportaciones meteóricas de calcio y magnesio son relativamente pequeñas, mientras que la de sodio es insignificante. Los retornos de riego desempeñan un papel importante en la parte occidental del área de estudio, dando lugar a concentraciones elevadas de sulfato y cloruro.

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Résumé Les mécanismes de recharge et lévolution hydrochimique de leau souterraine dans un bassin de montagne de 6 840 km² en zone semi-aride, dans le centre du Mexique, ont été étudiés au moyen des isotopes stables et des composés chimiques majeurs. Lanalyse des rapports ioniques a aidé à conceptualiser et à quantifier en partie lévolution géochimique qui en résulte, dans le système aquifère. Des modèles de bilan de masse (PHREEQC) ont été utilisés pour interpréter et corriger les propriétés de laquifère. Les conditions de recharge nont pas changé notablement au cours des derniers millénaires. Les mécanismes de recharge sont accompagnés, durant les épisodes majeurs de précipitation, dun lessivage, à la surface du sol et à son voisinage, de sels météoriques accumulés auparavant pendant les petits épisodes de pluie. Linfiltration rapide et diffuse peut être exclue. Linfiltration indirecte à partir des oueds (arroyos) et des dépressions (playas) avec un faible mélange dans la nappe superficielle contraste avec le degré élevé de mélange de leau avec les circulations profondes. La source prépondérante des cations majeurs (Ca²⁺, Mg²⁺, Na⁺, K⁺) est laltération des carbonates et des feldspaths ; léchange de cations avec les argiles et les hydroxydes est moins important. Léchange de Ca²⁺ avec Na⁺ peut sinverser le long des axes découlements pour donner un échange de Na⁺ avec Ca²⁺, bien que le cas Ca²⁺/Na⁺ soit prépondérant. Les apports météoriques de Ca et de Mg sont relativement faibles, cependant que celui de Na météorique est insignifiant. Lécoulement par retour dirrigation joue un rôle important dans la partie occidentale de la région étudiée, produisant un accroissement des concentrations élevées en sulfate et en chlorure.

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地下水中铀的反应运移模拟   总被引：7，自引：0，他引：7       下载免费PDF全文

Merkel  B 《地球科学》2000,25(5):451-455

地下水中铀的反应运移模拟对地下水保护和铀矿区的恢复都很重要, 因为铀是一种化学毒害性很高的放射性元素.在地下水及水与固体之间都应考虑对流、弥散、稀释、吸附等化学相互作用.介绍了德国德累斯顿市附近的Koenigstein矿区淋滤条件的可行性研究结果.由于反应运移模拟需占用大量的CPU时间, 所有的运行在一天内完成, 但用简单的混合法进行了稀释.对于这种研究, PHREEQC 2.2证明是一个功能很强的工具.与PHREEQC相对应的数据库WATEQ4F涉及到48种元素、400多种物质、300多种矿物.根据铀和镭的特性, 对其作了一定的修改, 以使它更具相容性和可靠性.   相似文献   

Surface complexation modeling of Uranium(VI) sorption on quartz in the presence and absence of alkaline earth metals     

Sreejesh Nair  Lotfollah Karimzadeh  Broder J. Merkel 《Environmental Earth Sciences》2014,71(4):1737-1745

Surface complexation models (SCMs) are widely utilized as a tool to study the mobility of radionuclide to the environment. In this study, two SCMs, electrostatic (ES) and non-electrostatic (NES) models are employed in order to simulate the sorption behavior of U(VI) on quartz in the absence of Mg, Ca, and Sr and ES model in the presence of alkaline earth metals. The surface reaction constants (log K) for ES and NES models were fitted to experimental data by coupling PEST with PHREEQC. The SCM prediction of U(VI) sorption on quartz in the absence of alkaline earth metals is in good agreement with the experimental data in the pH range 6.5–9. The estimated log K values are sensitive to both ES and NES model calculations. In U(VI)-Mg-quartz, U(VI)-Ca-quartz, and U(VI)-Sr-quartz systems, only the ES model shows the general trend of the experimental data. The estimated log K values are sensitive with respect to the surface reactions. Hence, the ES model is more suitable for model calculations of the U(VI)-Mg-quartz, U(VI)-Ca-quartz, and U(VI)-Sr-quartz systems.  相似文献