A Practical Approach to the Design, Monitoring, and Optimization of In Situ MTBE Aerobic Biobarriers     

Paul C. Johnson  Cristin L. Bruce  Karen D. Miller 《Ground Water Monitoring & Remediation》2010,30(1):58-66

A paradigm for the design, monitoring, and optimization of in situ methyl tert -butyl ether (MTBE) aerobic biobarriers is presented. In this technology, an oxygen-rich biologically reactive treatment zone (the "biobarrier") is established in situ and downgradient of the source of dissolved MTBE contamination in groundwater, typically gasoline-impacted soils resulting from leaks and spills at service station sites or other fuel storage and distribution facilities. The system is designed so that groundwater containing dissolved MTBE flows to, and through, the biobarrier treatment zone, ideally under natural gradient conditions so that no pumping is necessary. As the groundwater passes through the biobarrier, the MTBE is converted by microorganisms to innocuous by-products. The system also reduces concentrations of other aerobically degradable chemicals dissolved in the groundwater, such as benzene, toluene, xylenes, and tert -butyl alcohol. This design paradigm is based on experience gained while designing, monitoring, and optimizing pilot-scale and full-scale MTBE biobarrier systems. It is largely empirically based, although the design approach does rely on simple engineering calculations. The paradigm emphasizes gas injection–based oxygen delivery schemes, although many of the steps would be common to other methods of delivering oxygen to aquifers.  相似文献   

Seasonal and annual variations in abundance and species composition of two nearshore fish communities in Maine     

Mark A. Lazzari  Sally Sherman  Clarisse S. Brown  Jeremy King  Bruce J. Joule  Stanley B. Chenoweth  Richard W. Langton 《Estuaries and Coasts》1999,22(3):636-647

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How processing digital elevation models can affect simulated water budgets   总被引：1，自引：0，他引：1  

Kuniansky EL  Lowery MA  Campbell BG 《Ground water》2009,47(1):97-107

For regional models, the shallow water table surface is often used as a source/sink boundary condition, as model grid scale precludes simulation of the water table aquifer. This approach is appropriate when the water table surface is relatively stationary. Since water table surface maps are not readily available, the elevation of the water table used in model cells is estimated via a two-step process. First, a regression equation is developed using existing land and water table elevations from wells in the area. This equation is then used to predict the water table surface for each model cell using land surface elevation available from digital elevation models (DEM). Two methods of processing DEM for estimating the land surface for each cell are commonly used (value nearest the cell centroid or mean value in the cell). This article demonstrates how these two methods of DEM processing can affect the simulated water budget. For the example presented, approximately 20% more total flow through the aquifer system is simulated if the centroid value rather than the mean value is used. This is due to the one-third greater average ground water gradients associated with the centroid value than the mean value. The results will vary depending on the particular model area topography and cell size. The use of the mean DEM value in each model cell will result in a more conservative water budget and is more appropriate because the model cell water table value should be representative of the entire cell area, not the centroid of the model cell.  相似文献   

Measuring and monitoring persistent organic pollutants in the context of risk assessment   总被引：3，自引：0，他引：3  

Wu RS  Chan AK  Richardson BJ  Au DW  Fang JK  Lam PK  Giesy JP 《Marine pollution bulletin》2008,57(6-12):236-244

Due to growing concerns regarding persistent organic pollutants (POPs) in the environment, extensive studies and monitoring programs have been carried out in the last two decades to determine their concentrations in water, sediment, and more recently, in biota. An extensive review and analysis of the existing literature shows that whilst the vast majority of these efforts either attempt to compare (a) spatial changes (to identify "hot spots"), or (b) temporal changes to detect deterioration/improvement occurring in the environment, most studies could not provide sufficient statistical power to estimate concentrations of POPs in the environment and detect spatial and temporal changes. Despite various national POPs standards having been established, there has been a surprising paucity of emphasis in establishing accurate threshold concentrations that indicate potential significant threats to ecosystems and public health. Although most monitoring programs attempt to check compliance through reference to certain "environmental quality objectives", it should be pointed out that many of these established standards are typically associated with a large degree of uncertainty and rely on a large number of assumptions, some of which may be arbitrary. Non-compliance should trigger concern, so that the problem can be tracked down and rectified, but non-compliance must not be interpreted in a simplistic and mechanical way. Contaminants occurring in the physical environment may not necessarily be biologically available, and even when they are bioavailable, they may not necessarily elicit adverse biological effects at the individual or population levels. As such, we here argue that routine monitoring and reporting of abiotic and biotic POPs concentrations could be of limited use, unless such data can be related directly to the assessment of public health and ecological risks. Risk can be inferred from the ratio of predicted environmental concentration (PEC) and the predicted no effect concentration (PNEC). Currently, the paucity of data does not allow accurate estimation of PNEC, and future endeavors should therefore, be devoted to determine the threshold concentrations of POPs that can cause undesirable biological effects on sensitive receivers and important biological components in the receiving environment (e.g. keystone species, populations with high energy flow values, etc.), to enable derivation of PNECs based on solid scientific evidence and reduce uncertainty. Using the threshold body burden of POPs required to elicit damages of lysosomal integrity in the green mussel (Perna virvidis) as an example, we illustrate how measurement of POPs in body tissue could be used in predicting environmental risk in a meaningful way.  相似文献   

Generalized dual porosity: A numerical method for representing spatially variable sub-grid scale processes     

George A. Zyvoloski  Bruce A. Robinson  Hari S. Viswanathan 《Advances in water resources》2008

A generalized dual porosity method (GDPM) has been developed to incorporate sub-grid scale heterogeneity into large-scale flow and transport simulations. The method is spatially variable in the sense that the method can be applied with different levels of resolution for different spatial nodes in the simulation. The method utilizes the nodal connectivity structure and linear equation solvers of unstructured grids like those used in the finite element method, and can be applied to any problem without externally modifying the numerical grid. The algorithm scales linearly in CPU time and storage with the number of GDPM nodes. We demonstrate the utility and computational efficiency of the technique with two verification problems and an example problem of a field site.  相似文献   

Antioxidant responses to polycyclic aromatic hydrocarbons and organochlorine pesticides in green-lipped mussels (Perna viridis): do mussels "integrate" biomarker responses?   总被引：1，自引：0，他引：1  

Richardson BJ  Mak E  De Luca-Abbott SB  Martin M  McClellan K  Lam PK 《Marine pollution bulletin》2008,57(6-12):503-514

Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCs) are generally present in the marine environment in complex mixtures. The ecotoxicological nature of contaminant interactions, however, is poorly understood, with most scientific observations derived from single contaminant exposure experiments. The objective of this experiment was to examine dose-response relationships between antioxidant parameters and body contaminant levels in mussels exposed to different exposure regimes under laboratory conditions. Accordingly, the green-lipped mussel, Perna viridis, was challenged with a mixture of PAHs (anthracene, fluoranthene, pyrene, benzo[a]pyrene) and OC pesticides (alpha-HCH, aldrin, dieldrin, p,p'-DDT) over a 4 week period. Contaminants were delivered under four different dosing regimes, with all treatments receiving the same total contaminant load by the end of the exposure period. Antioxidant biomarkers were measured after 1, 2, 3 and 4 weeks, including glutathione (GSH), gluathione-S-transferase (GST), superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx), glutathione reductase (GR) and lipid peroxidase (LPO). GST and CAT were induced in hepatic tissues in most of the exposure regimes, with the majority of significant induction occurring in a constant exposure regime and a two-step alternate exposure regime. Significant differences among exposure regimes were detected in the body burden of contaminants after 28 days. Hepatic CAT and GSH are proposed as potentially useful biomarkers as they showed good correlation with target contaminants and were not readily affected by different dosing patterns.  相似文献   

Organochlorine contaminants in the muscle of striped bass illegally harvested from shad gill nets in the Hudson River Estuary     

Deshpande AD  Doyle SA  Dockum BW  Tesolin-Gee A 《Marine pollution bulletin》2008,56(12):2088-2093

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Antioxidant responses to polycyclic aromatic hydrocarbons and organochlorine pesticides in green-lipped mussels (Perna viridis): Do mussels “integrate” biomarker responses?     

Bruce J. Richardson  Eva Mak  Sharon B. De Luca-Abbott  Michael Martin  Katherine McClellan  Paul K.S. Lam 《Marine pollution bulletin》2008,57(6-12):503

Polycyclic aromatic hydrocarbons (PAHs) and organochlorine pesticides (OCs) are generally present in the marine environment in complex mixtures. The ecotoxicological nature of contaminant interactions, however, is poorly understood, with most scientific observations derived from single contaminant exposure experiments. The objective of this experiment was to examine dose-response relationships between antioxidant parameters and body contaminant levels in mussels exposed to different exposure regimes under laboratory conditions. Accordingly, the green-lipped mussel, Perna viridis, was challenged with a mixture of PAHs (anthracene, fluoranthene, pyrene, benzo[a]pyrene) and OC pesticides (α-HCH, aldrin, dieldrin, p,p′-DDT) over a 4 week period. Contaminants were delivered under four different dosing regimes, with all treatments receiving the same total contaminant load by the end of the exposure period. Antioxidant biomarkers were measured after 1, 2, 3 and 4 weeks, including glutathione (GSH), gluathione-S-transferase (GST), superoxide dismutase (SOD), catalase (CAT), glutathione peroxidase (GPx), glutathione reductase (GR) and lipid peroxidase (LPO). GST and CAT were induced in hepatic tissues in most of the exposure regimes, with the majority of significant induction occurring in a constant exposure regime and a two-step alternate exposure regime. Significant differences among exposure regimes were detected in the body burden of contaminants after 28 days. Hepatic CAT and GSH are proposed as potentially useful biomarkers as they showed good correlation with target contaminants and were not readily affected by different dosing patterns.  相似文献   

Cross-equatorial flow of grounded abyssal ocean currents     

Alexander Kim  Bruce R. Sutherland 《地球物理与天体物理流体动力学》2014,108(4):363-386

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Detection ranges and uncertainty of passive Radio Frequency Identification (RFID) transponders for sediment tracking in gravel rivers and coastal environments          下载免费PDF全文

Margot Chapuis  Christina J. Bright  John Hufnagel  Bruce MacVicar 《地球表面变化过程与地形》2014,39(15):2109-2120

Since the earliest use of this technology, a growing number of researchers have employed passive Radio Frequency Identification (RFID) transponders to track sediment transport in gravel rivers and coastal environments. RFID transponders are advantageous because they are inexpensive, durable and use unique codes that allow sediment particle mobility and displacement to be assessed on a clast‐by‐clast basis. Despite these advantages, this technology is in need of a rigorous error and detection analysis. Many studies work with a precision of ~1 m, which is insufficient for some applications, and signal shadowing can occur due to clustering of tagged particles. Information on in‐field performance is also incomplete with respect to burial and submergence, especially for different transponders and antennae combinations. The objectives of this study are to qualify and quantify the factors that influence the detection zone of RFID tracers including antenna type, transponder size, transponder orientation, burial depth, submergence and clustering. Results of this study show that the detection zone is complex in shape due to a set of lobes in the detection field and provide a better understanding of transponder detection shape for different RFID transponder/antenna combinations. This study highlights a strong influence of clustering and submergence, but no significant effect of burial. Finally we propose standard operating procedures for tagging and tracking in rivers and coastal environments. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献