Partitioning of manganese between forsterite and silicate liquid   总被引：1，自引：0，他引：1  

E. Bruce Watson 《Geochimica et cosmochimica acta》1977,41(9):1363-1374

Partition coefficients for Mn between forsterite and liquid in the system MgO-CaO-Na₂O-Al₂O₃-SiO₂ (+ about 0.2% Mn) were measured by electron microprobe for a variety of melt compositions over the temperature range 1250–1450°C at one atm pressure. The forsterite-liquid partition coefficient of Mn (mole ratio, MnO in Fo/MnO in liquid, designated D_mn^fo?Liq) depends on liquid composition as well as temperature: at 1350°C, D_Mn^Fo?Liqranges from 0.60 (basic melt, SiO₂ = 47wt%) to 1.24 (acidic melt, SiO₂ = 65wt%). At lower temperatures, the partition coefficient is more strongly dependent on melt composition.The effects of melt composition and temperature on D_Mn^fo?Liq can be separately evaluated by use of the Si:O atomic ratio of the melts. A plot of D_mn^Fo?Liq measured at various temperatures vs melt Si:O for numerous liquid compositions reveals discrete, constant-temperature curves that are not well defined by plotting D_Mn^Fo?Liq against other melt composition parameters such as melt basicity or MgO content. For constant Si:O in the melt, In D_Mn^Fo?Liq vs reciprocal absolute temperature is linear; however, the slope of the plot becomes more positive for higher values of Si:O, indicating a higher energy state for Mn²⁺ ions in acidic melts than in basic melts.Comparison of Mn partitioning data for the iron-free system used in this study with data of other workers on iron-bearing compositions suggests that the effect of iron on Mn partitioning between olivine and melt is small over the range of basalt liquidus temperatures.  相似文献   

Trace-Organics Biodegradation in Aquifer Recharge   总被引：1，自引：0，他引：1  

Bruce E. Rittmann  Perry L. McCarty  Paul V. Roberts 《Ground water》1980,18(3):236-243

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Theoretical grain size limits for single-domain,pseudo-single-domain and multi-domain behavior in titanomagnetite (x = 0.6) as a function of low-temperature oxidation     

Bruce M. Moskowitz 《Earth and Planetary Science Letters》1980,47(2):285-293

A theoretical model of grain size variation of domain transitions in titanomagnetite (x = 0.6) as a function of oxidation (z) is presented. The superparamagnetic (SP) to single-domain (SD) transition d_s, the SD to two-domain (TD) transition d₀, the TD to three-domain (3D) transition and the pseudo-single domain (PSD) to multi-domain (MD) transition are calculated as a function of z. It is shown that all the transition grain sizes increase with z, except for the PSD-MD transition for z > 0.6. The calculations predict that d_s increases from 0.044 to 0.197 μm, d₀ increases from 0.54 to 13 μm, the TD-3D transition increases from 1.6 to 49 μm as z varies from 0 to 0.8. The PSD-MD transition increases from 42 μm at z = 0 to 150 μm at z = 0.6, whereas between z = 0.6 to z = 0.8, the PSD-MD transition decreases to 49 μm. Qualitatively, the model explains some of the trends in magnetic properties of submarine basalts with low-temperature oxidation. Quantitatively, the model does give reasonable estimates of the PSD-MD boundary and d₀, which are close to the experimental values for x = 0.6 and z = 0. Furthermore, the model predicts that psarks or two-domain grains could be the major contributors to the remanence of oxidized submarine pillow basalts.  相似文献   

Cations in olivine,Part 2: Diffusion in olivine xenocrysts,with applications to petrology and mineral physics   总被引：1，自引：0，他引：1  

Amy J. G. Jurewicz  E. Bruce Watson 《Contributions to Mineralogy and Petrology》1988,99(2):186-201

Diffusivities for calcium, iron, magnesium, manganese and aluminum have been measured for St. John's olivine undergoing cation exchange with synthetic basaltic melts. The variety of temperature, pressure and fO₂ conditions under which the diffusivities were measured complement the equilibrium-partitioning study of calcium in olivine-bearing basalts by Jurewicz and Watson, 1988. Olivine was found to be anisotropic with respect to the diffusion of calcium, iron, magnesium and manganese. This anisotropy is a weak function of temperature, but strongly dependent upon oxygen fugacity.Because diffusion is independent of olivine composition over the small range of compositions used in this study, it could be shown that the absolute values of the diffusion coefficients were also functions of temperature and fO₂. At near-atmospheric total pressure and an oxygen fugacity of 10^–8atm, D _Fe>D _Mn>D _Ca and D _MgD _Mn for a range of geologically reasonable temperatures. These relative diffusivities were shown to change with oxygen fugacity. The power-law dependence of diffusion on oxygen partial-pressure was determined for each cation and the results are consistent with the range of values given by Stocker (1978) and by other workers.For Ca and Fe, the effect of hydrostatic pressure on diffusion appears to be weak, at least for transport parallel to the c crystallographic direction. Unfortunately, no true activation volumes (or other pressure-related parameters) could be computed because the oxygen fugacity was not held constant over changes in pressure, and because accurate post-experiment reconstruction of sample orientation was not possible. Al was found to enter high-pressure olivines at concentrations of up to 0.14 weight percent, thus allowing aluminum diffusion to be characterized. The diffusivity of aluminum is, within error, the same as iron at 20 kb at 1430° C at the ambient fO₂ of our piston-cylinder cells. This correspondence suggests that diffusion of Al may depend on transport of either Fe or of Fe ⁺³ defects. While the results of these experiments are generally consistent with results published elsewhere, there are important inconsistencies. Tracer diffusion and interdiffusion in pure, ordered, olivine endmembers (e.g., tephroite and forsterite) showed significantly higher activation energies. This discrepancy could reflect the role of Fe⁺³ defects in diffusion; however, it may also suggest that order-disorder phenomena may be significant factors influencing diffusion in analog systems.The results of this study are applied to four petrologic problems: (1) calculation of rates of equilibration for olivine xenocrysts; (2) calculation of closure temperatures for the CaO/MgO olivine/basalt geothermometer (Jurewicz and Watson 1988); (3) delineation of an intrinsic-/O₂ geobarometer; and (4) investigation of the dependence of olivine dissolution upon crystallographic orientation. In addition, it is demonstrated that diffusion-exchange experiments are useful for studying the dominant point-defect mechanisms for cation diffusion.Currently, a visiting scientist with Air Force Wright Aeronautical Laboratories Materials Laboratory (MLLM), Wright-Patterson AFB, OH 45433  相似文献   

Crystal size distribution (CSD) in rocks and the kinetics and dynamics of crystallization   总被引：2，自引：5，他引：2  

Bruce D. Marsh 《Contributions to Mineralogy and Petrology》1988,99(3):277-291

Crystal-size in crystalline rocks is a fundamental measure of growth rate and age. And if nucleation spawns crystals over a span of time, a broad range of crystal sizes is possible during crystallization. A population balance based on the number density of crystals of each size generally predicts a log-linear distribution with increasing size. The negative slope of such a distribution is a measure of the product of overall population growth rate and mean age and the zero size intercept is nucleation density. Crystal size distributions (CSDs) observed for many lavas are smooth and regular, if not actually linear, when so plotted and can be interpreted using the theory of CSDs developed in chemical engineering by Randolph and Larson (1971). Nucleation density, nucleation and growth rates, and orders of kinetic reactions can be estimated from such data, and physical processes affecting the CSD (e.g. crystal fractionation and accumulation, mixing of populations, annealing in metamorphic and plutonic rocks, and nuclei destruction) can be gauged through analytical modeling. CSD theory provides a formalism for the macroscopic study of kinetic and physical processes affecting crystallization, within which the explicit affect of chemical and physical processes on the CSD can be analytically tested. It is a means by which petrographic information can be quantitatively linked to the kinetics of crystallization, and on these grounds CSDs furnish essential information supplemental to laboratory kinetic studies. In this three part series of papers, Part I provides the general CSD theory in a geological context, while applications to igneous and metamorphic rocks are given, respectively, in Parts II and III.  相似文献   

Introduction     

Bruce C. Heezen 《Tectonophysics》1970,10(5-6):473

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Infrared polarimetry and imaging of ultracompact partially ionized optical sources in the orion nebula     

Bruce McCollum  Michael W. Castelaz 《Astrophysics and Space Science》1995,224(1-2):509-510

Hubble Space Telescope images of the Orion nebula taken with the Wide-Field Camera have revealed subarcsecond structure in several dozen objects which are apparently ionized externally from nearby stars. We have obtained near-IR images and IR polarimetry of the Orion region to search for correlations with the WFC objects. We find that all of the ultracompact WFC objects are associated with IR features of some sort, and that some are associated with strongly polarized IR emission. The object with strongest polarization also shows small IR lobes. In addition, we find some previously unreported sources, showing polarized IR emission, outside the field of the HST images, which we believe may be the same sorts of object. We note that the object with strongest polarization has a double-lobed appearance in the K band image.  相似文献   

Discrimination of a seismic source doublet in the Northridge, California earthquake of 17 January 1994     

Bruce A. Bolt  Nicholas J. Gregor 《Journal of Seismology》1997,1(1):29-37

The January 17, 1994 Northridge earthquake (Mw = 6.7, 34.213° N, 118.537° W, depth = 18.4 km) was recorded extensively in the immediate source region by strong, ground motion accelerometers. The resulting seismograms show complex S wave patterns. Nevertheless, visual correlations of the strong-ground-motion velocity and displacement time-histories clearly identify two significant wave pulses: a secondary S pulse (called S2) arriving 3–5 seconds after the initial S wave pulse (called S1). A plausible assumption is that these phases are generated at areas on the rupturing thrust fault that experienced especially large slip. Conventional travel-time computations, relating the relative arrival times between the onsets of the primary S1 and secondary S2 phases, yield a hypocenter of the initiation point, constrained to a independently etimated fault plane, of the secondary wave source (called H2) at 34.26°N, 118.54° W, with a depth of 14.1 km; the 68% confidence error in depth is 1.3 km. This location is about 6 km up-dip and north from the estimated hypocenter, on the fault plane of the initial principal seismic source (called H1). The seismic moment for both the initial H1 and secondary source H2 was estimated from the SH displacement pulse. Values averaged over eight stations were 8.61 ± 9.56 × 10²⁴ dyne-cm and 2.49 ± 2.31 × 10²⁵ dyne-cm respectively. Reasons why the sum of the two seismic moments is smaller than the total estimated seismic moment of 1.2 × 10²⁶ dyne-cm for the Northridge earthquake are discussed. The location of the initiation point of a second source H2 in the Northridge thrust faulting is consistent with independent computations of the fault slip pattern. The estimated stress drop for the initial and secondary sources are 1 = 150 ± 15 bars and 2 = 110 ± 11 bars, respectively.  相似文献   

OSO-8 observations of the impulsive phase of solar flares in the transition-zone and corona     

Bruce W. Lites  E. C. Bruner Jr.  C. J. Wolfson 《Solar physics》1981,69(2):373-389

Several solar flares have been observed from their onset in C IV 1548.2 and 1–8 Å X-rays using instruments aboard OSO-8. In addition, microwave and H flare patrol data have been obtained for this study. The impulsive brightening in C IV is frequently accompanied by redshifts, interpreted as downflows, of the order of 80 km s^-1. The maximum soft X-ray intensity usually arrives several minutes after the maximum C IV intensity. The most energetic C IV event studied shows a small blueshift just before reaching maximum intensity, and estimates of the mass flux associated with this upflow through the transition-zone are consistent with the increase of mass in the coronal loops as observed in soft X-rays. This event had no observable microwave burst, suggesting that electron beams did not play a major role in the chromospheric and transition-zone excitation. Lastly, our observations suggest that the frequent occurrence of violent dynamical processes at the onset of the flare are associated with the initial energy release mechanism.Currently at High Altitude Observatory, National Center for Atmospheric Research, P.O. Box 3000, Boulder, Colo. 80307, U.S.A.  相似文献   

Possible correlation of Io's posteclipse brightening with major solar flares     

Robert M. Nelson  Bruce W. Hapke 《Icarus》1978,33(1):203-209

In 6 of the 7 instances where posteclipse brightening of Io has been reported by observers using blue filters, a major solar flare occurred within 10° of the sub-Jovian longitude in the 100-day interval prior to observation. In none of the 18 instances where no posteclipse brightening was observed did such a flare occur. It is proposed that a phenomenon associated with a major solar flare causes an increase in the trapped particle flux at Io's orbit by an order of magnitude. The posteclipse brightening may be caused by thermoluminescence of Io's surface material upon emergence. Alternatively, it is possible that the increase in trapped particle flux would warm the surface, creating a temporary atmosphere which would precipitate during eclipse cooling and vaporize in the period of warming after reemergence.  相似文献