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181.
Higher-order moments, minima and maxima of turbulent temperature and water vapour mixing ratio probability density functions measured with an eddy-covariance system near the ground were related to each other and to vertical boundary-layer profiles of the same scalars obtained through airborne soundings. The dependence of kurtosis on squared skewness showed a kurtosis intercept below the Gaussian expectation, suggesting a compression of the probability density function by the presence of natural boundaries. This hypothesis was corroborated by comparing actual minima and maxima of turbulent fluctuations to estimates obtained from the first four sample moments by fitting a four-parameter beta distribution. The most sharply defined boundaries were found for the minima of temperature datasets during the day, indicating that negative temperature fluctuations at the sensor are limited by the availability of lower temperatures in the boundary layer. By comparison to vertical profiles, it could be verified that the turbulent minimum of temperature near the ground is close to the minimum of potential temperature in the boundary layer. The turbulent minimum of water vapour mixing ratio was found to be equal to the mixing ratio at a height above the minimum of the temperature profile. This height roughly agrees with the top of the non-local unstable domain according to bulk Richardson number profiles. We conclude that turbulence statistics measured near the surface cannot be solely explained by local effects, but contain information about the whole boundary layer including the entrainment zone.  相似文献   
182.
An experimental investigation of the three-dimensional flow through an urban-type array (four rows of three cuboid Plexiglas blocks) in a laboratory modelled neutrally stratified atmospheric boundary layer is presented. We concentrate on the effect of the streamwise spacing between adjacent rows defining two different flow regimes (wake interference and skimming flow) as well as the effect of the incident angle of the approaching boundary layer. Stereoscopic particle image velocimetry measurements provide all three components of the velocity field in closely spaced two-dimensional planes in a region located in the middle row downstream of the centre block. It is found that the maximal exchange rate between the fluid within the street and the flow above is for the wake interference regime. Two regions are apparent: one influenced by streamwise velocity fluctuations, the other by spanwise fluctuations. In addition, the incidence angle of the incoming flow has a much more dramatic effect for the wake interference regime that would greatly favour dispersion. Coherent-structure identification tools are applied to obtain information on the shape, extent and localisation of vortical structures.  相似文献   
183.
We report lithium (Li) isotopic measurements in seawater-derived waters that were discharged from geothermal wells, thermal springs, and sub-marine springs located in volcanic island arc areas in Guadeloupe (the Bouillante geothermal field) and Martinique (Lamentin plain and the Diamant areas). While Li isotopic signatures of the geothermal fluids collected from deep reservoirs were found to be homogeneous for a given site, the δ7Li signatures for each of these reservoirs were significantly different. The first low temperature (25-250 °C) experiments of Li isotope exchange during seawater/basalt interaction confirmed that Li isotopic exchange is strongly temperature dependent, as previously inferred from natural studies. Li isotopic fractionation ranged from +19.4‰ (Δsolution-solid) at 25 °C to +6.7‰ at 250 °C. These experiments demonstrated the importance of Li isotopic fractionation during the formation of Li-bearing secondary minerals and allowed us to determine the following empirical relationship between isotopic fractionation and temperature: Δsolution-solid = 7847/T − 8.093. Application of experimental results and literature data to the Bouillante area suggested that geothermal water was in equilibrium at 250-260 °C. It likely has a deep and large reservoir located in the upper sheeted dike complex of the oceanic crust, just below the transition zone between andesite volcanic flows and the basaltic dikes. The upper dike section, from which Li is extracted by hydrothermal fluids, was characterized by light Li isotopic values in the rocks, indicating retention of 6Li by the altered rocks. For the Lamentin and Diamant areas, the geothermal fluids appeared to be in equilibrium with reservoir volcano-sedimentary rocks at 90-120 °C and 180 °C, respectively. Further evidence for this argument is provided by the fact that only the Na/Li thermometric relationship determined for sedimentary basins yielded temperature values in agreement with those measured or estimated for the reservoir fluids. This suggests the importance of a sedimentary signature in these reservoir rocks. Altogether, this study highlights that the use of Li isotopic systematics is a powerful tool for characterizing the origin of geothermal waters as well as the nature of their reservoir rocks.  相似文献   
184.
Syn-orogenic detachments in accretionary wedges make the exhumation of high-pressure and low-temperature metamorphic rocks possible with little erosion. The velocity of exhumation within the subduction channel or the accretionary complex, and thus the shape of PT paths, depend upon the kinematic boundary conditions. A component of slab retreat tends to open the channel and facilitates the exhumation. We document the effect of slab retreat on the shape of PT paths using the example of the Phyllite–Quartzite Nappe that has been exhumed below the Cretan syn-orogenic detachment during the Miocene in Crete and the Peloponnese. Data show a clear tendency toward colder conditions at peak pressure and during exhumation where the intensity of slab retreat is larger. This spatial evolution of PT gradient is accompanied with an evolution from a partly coaxial regime below the Peloponnese section of the detachment toward a clearly non-coaxial regime in Crete.  相似文献   
185.
Limb and nadir spectra acquired by Cassini/CIRS (Composite InfraRed Spectrometer) are analyzed in order to derive, for the first time, the meridional variations of diacetylene (C4H2) and methylacetylene (CH3C2H) mixing ratios in Saturn’s stratosphere, from 5 hPa up to 0.05 hPa and 80°S to 45°N. We find that the C4H2 and CH3C2H meridional distributions mimic that of acetylene (C2H2), exhibiting small-scale variations that are not present in photochemical model predictions. The most striking feature of the meridional distribution of both molecules is an asymmetry between mid-southern and mid-northern latitudes. The mid-southern latitudes are found depleted in hydrocarbons relative to their northern counterparts. In contrast, photochemical models predict similar abundances at north and south mid-latitudes. We favor a dynamical explanation for this asymmetry, with upwelling in the south and downwelling in the north, the latter coinciding with the region undergoing ring shadowing. The depletion in hydrocarbons at mid-southern latitudes could also result from chemical reactions with oxygen-bearing molecules.Poleward of 60°S, at 0.1 and 0.05 hPa, we find that the CH3C2H and C4H2 abundances increase dramatically. This behavior is in sharp contradiction with photochemical model predictions, which exhibit a strong decrease towards the south pole. Several processes could explain our observations, such as subsidence, a large vertical eddy diffusion coefficient at high altitudes, auroral chemistry that enhances CH3C2H and C4H2 production, or shielding from photolysis by aerosols or molecules produced from auroral chemistry. However, problems remain with all these hypotheses, including the lack of similar behavior at lower altitudes.Our derived mean mixing ratios at 0.5 hPa of (2.4 ± 0.3) × 10−10 for C4H2 and of (1.1 ± 0.3) × 10−9 for CH3C2H are compatible with the analysis of global-average ISO observations performed by Moses et al. (Moses, J.I., Bézard, B., Lellouch, E., Gladstone, G.R., Feuchtgruber, H., Allen, M. [2000a]. Icarus 143, 244-298). Finally, we provide values for the ratios [CH3C2H]/[C2H2] and [C4H2]/[C2H2] that can constrain the coupled chemistry of these hydrocarbons.  相似文献   
186.
3D structural modeling is a major instrument in geosciences, e.g. for the assessment of groundwater and energy resources or nuclear waste underground storage. Fault network modeling is a particularly crucial step during this task, for faults compartmentalize rock units and plays a key role in subsurface flow, whether faults are sealing barriers or drains. Whereas most structural uncertainty modeling techniques only allow for geometrical changes and keep the topology fixed, we propose a new method for creating realistic stochastic fault networks with different topologies. The idea is to combine an implicit representation of geological surfaces which provides new perspectives for handling topological changes with a stochastic binary tree to represent the spatial regions. Each node of the tree is a fault, separating the space in two fault blocks. Changes in this binary tree modify the fault relations and therefore the topology of the model.  相似文献   
187.
While corporate adaptation strategies in response to climate change have been characterized, the determinants of adaptation have not been comprehensively analyzed. Knowledge of these determinants is particularly useful for policy makers to provide favorable conditions in support of corporate adaptation measures. Based on unique data from a survey of Swiss ski lift operators, this paper empirically examines such determinants at the business level. Our econometric analysis with linear regression and count data models finds a positive influence of the awareness of possible climate change effects on the scope of corporate adaptation. Surprisingly, no significant influence of the vulnerability to climate change effects on the scope of adaptation could be found. Finally, the dependency on the affected business and the ability to adapt influence the specific strategic directions of corporate adaptation.  相似文献   
188.
Turbulent fluxes of sensible and latent heat and ozone were measured aboard a German Aerospace Research Establishment motorglider over the Swiss Plateau during the first field experiment of the Swiss air pollution experiment POLLUMET. In the lower part of the boundary layer, the ozone fluxes are negative (downward) throughout the day as a result of deposition and photochemical destruction at the surface. In the upper part of the boundary layer, the ozone fluxes tend to be negative until mid-afternoon and then become positive. The change in sign occurs after the ozone concentration in the boundary layer exceeds that in the reservoir above the inversion. Downdrafts bringing air parcels with ozone deficits across the inversion then become major contributors to the flux. The positive fluxes at upper levels result in an increase in flux divergence in mid-afternoon that is balanced by a relatively large source term in the ozone concentration budget.  相似文献   
189.
The correlation of the size and spatial distribution of fragments from the Sikhote Alin' meteoroid, 1947, was examined.With Frost's logarithmic rule of spatial sorting of meteorite fragments, supported by an ad hoc developed averaging procedure, a new approach to the size distribution was made possible.It was found that the meteoroid has been originally broken into several - presumably 5–6 - large fragments unequal in size, which further fragmented with various efficiency and speed.The conclusions are compatible with the reports of the witnesses of the fall of the meteorite.  相似文献   
190.
Raman spectra of Mg2GeO4-olivine were obtained from ambient pressure up to 34 GPa at ambient temperature. Under quasi-hydrostatic pressure conditions, the following modifications in the Raman spectra occur as pressure increases: 1) near 11 GPa, two sharp extra bands appear in the 600–700 cm?1 frequency range, and increase in intensity with respect to the olivine bands; 2) above 22 GPa, these two bands become very intense, and the number, position and relative intensity of the other vibrational bands drastically change; 3) the intensity of sharp bands progressively decreases above 25 GPa. The transformation occurs at lower pressures under non-hydrostatic conditions. During decompression to atmospheric pressure, the high-pressure phase partially reverts to olivine. These observations can be interpreted as the progressive metastable transformation from the olivine structure to a crystalline phase with four-fold coordinated Ge, in which the GeO4 tetrahedra are polymerized. We propose that the metastable high-pressure phase is a structurally disordered spinelloid close to the hypothethical ω- or ?*-phase, and forms by a shear mechanism assisted by the development of a dynamical instability in the olivine structure. Implications for the transformations undergone by olivines under far-from-equilibrium conditions (e.g. in subducting lithospheric slabs and in shocks) are discussed.  相似文献   
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