The Paleoenvironment and Lithic Taphonomy of Shi’Bat Dihya 1, a Middle Paleolithic Site in Wadi Surdud,Yemen     

Luca Sitzia  Pascal Bertran  Stphane Boulogne  Michel Brenet  Rmy Crassard  Anne Delagnes  Marine Frouin  Christine Hatt  Jacques Jaubert  Lamya Khalidi  Erwan Messager  Norbert Mercier  Alain Meunier  Stphane Peign  Alain Queffelec  Chantal Tribolo  Roberto Macchiarelli 《Geoarchaeology》2012,27(6):471-491

The Shi'bat Dihya 1 site in western Yemen, dated by optically stimulated luminescence to 55 ka, provides insight into the Middle Paleolithic peopling of the Arabian Peninsula. The archaeological layer is interstratified within thick, sandy silt floodplain deposits filling a piedmont basin. Luminescence dates, lack of soil development, and gypsum precipitation indicate a high accretion rate of the floodplain during Marine Isotope Stage 3, in connection with a (semi)‐arid environment. Rapid overbank sedimentation was likely a result of the remobilization of loess material deposited on the Yemeni Great Escarpment at the periphery of the adjacent Tihama coastal sand desert or of other sources. Fabric and size analyses of the lithic artifacts, together with spatial projections, indicate site modifications by floods. Primary modifications include (1) selective accumulation of medium‐sized lithic pieces as a result of hydraulic sorting, (2) bimodal orientation of artifacts, and (3) ripple‐like arrangement of lithics and bone/tooth fragments. The overrepresentation of teeth may also be a consequence of sorting. Although floods have distorted the original site patterning, long‐distance transport of artifacts by water can be excluded, as indicated by relatively high refitting rate, close proximity of artifacts derived from the same block of raw material, and lack of abrasion of the pieces. Therefore, the site is considered “geologically” in situ because its remobilization by water occurred shortly after human abandonment. This study also stresses that the effective preservation of a site cannot be assessed without careful taphonomic study, even in a potentially favorable depositional context such as silty alluvium.  相似文献   

Armouring of well cement in H₂S–CO₂ saturated brine by calcite coating – Experiments and numerical modelling     

Nicolas Jacquemet  Jacques Pironon  Vincent Lagneau  Jérémie Saint-Marc 《Applied Geochemistry》2012

The active acid gas (H₂S–CO₂ mixture) injection operations in North America provide practical experience for the operators in charge of industrial scale CO₂ geological storage sites. Potential leakage via wells and their environmental impacts make well construction durability an issue for efficiency/safety of gas geological storage. In such operations, the well cement is in contact with reservoir brines and the injected gas, meaning that gas–water–solid chemical reactions may change the physical properties of the cement and its ability to confine the gas downhole. The cement-forming Calcium silicate hydrates carbonation (by CO₂) and ferrite sulfidation (by H₂S) reactions are expected. The main objective of this study is to determine their consequences on cement mineralogy and transfer ability. Fifteen and 60 days duration batch experiments were performed in which well cement bars were immersed in brine itself caped by a H₂S–CO₂ phase at 500 bar–120 °C. Scanning electron microscopy including observations/analyses and elemental mapping, mineralogical mapping by micro-Raman spectroscopy, X-ray diffraction and water porosimetry were used to characterize the aged cement. Speciation by micro-Raman spectroscopy of brine trapped within synthetic fluid inclusions were also performed. The expected calcium silicate hydrates carbonation and ferrite sulfidation reactions were evidenced. Furthermore, armouring of the cement through the fast creation of a non-porous calcite coating, global porosity decrease of the cement (clogging) and mineral assemblage conservation were demonstrated. The low W/R ratio of the experimental system (allowing the cement to buffer the interstitial and external solution pH at basic values) and mixed species diffusion and chemical reactions are proposed to explain these features. This interpretation is confirmed by reactive transport modelling performed with the HYTEC code. The observed cement armouring, clogging and mineral assemblage conservation suggest that the tested cement has improved transfer properties in the experimental conditions. This work suggests that in both acid gas and CO₂ geological storage, clogging of cement or at least mineral assemblage conservation and slowing of carbonation progress could occur in near-well zones where slight water flow occurs e.g. in the vicinity of caprock shales.  相似文献   

Thermodynamic properties of chlorite and berthierine derived from calorimetric measurements     

Philippe Blanc  Hélène Gailhanou  Jacques Rogez  Georges Mikaelian  Hitoshi Kawaji  Fabienne Warmont  Stéphane Gaboreau  Sylvain Grangeon  Jean-Marc Grenèche  Philippe Vieillard  Claire I. Fialips  Eric Giffaut  Eric C. Gaucher  F. Claret 《Physics and Chemistry of Minerals》2014,41(8):603-615

In the context of the deep waste disposal, we have investigated the respective stabilities of two iron-bearing clay minerals: berthierine ISGS from Illinois [USA; (Al_0.975FeIII_0.182FeII_1.422Mg_0.157Li_0.035Mn_0.002)(Si_1.332Al_0.668)O₅(OH)₄] and chlorite CCa-2 from Flagstaff Hill, California [USA; (Si_2.633Al_1.367)(Al_1.116FeIII_0.215Mg_2.952FeII_1.712Mn_0.012Ca_0.011)O₁₀(OH)₈]. For berthierine, the complete thermodynamic dataset was determined at 1 bar and from 2 to 310 K, using calorimetric methods. The standard enthalpies of formation were obtained by solution-reaction calorimetry at 298.15 K, and the heat capacities were measured by heat-pulse calorimetry. For chlorite, the standard enthalpy of formation is measured by solution-reaction calorimetry at 298.15 K. This is completing the entropy and heat capacity obtained previously by Gailhanou et al. (Geochim Cosmochim Acta 73:4738–4749, 2009) between 2 and 520 K, by using low-temperature adiabatic calorimetry and differential scanning calorimetry. For both minerals, the standard entropies and the Gibbs free energies of formation at 298.15 K were then calculated. An assessment of the measured properties could be carried out with respect to literature data. Eventually, the thermodynamic dataset allowed realizing theoretical calculations concerning the berthierine to chlorite transition. The latter showed that, from a thermodynamic viewpoint, the main factor controlling this transition is probably the composition of the berthierine and chlorite minerals and the nature of the secondary minerals rather than temperature.  相似文献   

Insights from trace element geochemistry as to the roles of subduction zone geometry and subduction input on the chemistry of arc magmas   总被引：2，自引：0，他引：2  

Heidi Wehrmann  Kaj Hoernle  Dieter Garbe-Schönberg  Guillaume Jacques  Julia Mahlke  Kai Schumann 《International Journal of Earth Sciences》2014,103(7):1929-1944

Subduction zones of continental, transitional, and oceanic settings, relative to the nature of the overriding plate, are compared in terms of trace element compositions of mafic to intermediate arc rocks, in order to evaluate the relationship between subduction parameters and the presence of subduction fluids. The continental Chilean Southern Volcanic Zone (SVZ) and the transitional to oceanic Central American Volcanic Arc (CAVA) show increasing degrees of melting with increasing involvement of slab fluids, as is typical for hydrous flux melting beneath arc volcanoes. At the SVZ, the central segment with the thinnest continental crust/lithosphere erupted the highest-degree melts from the most depleted sources, similar to the oceanic-like Nicaraguan segment of the CAVA. The northern part of the SVZ, located on the thickest continental crust/lithosphere, exhibits features more similar to Costa Rica situated on the Caribbean Large Igneous Province, with lower degrees of melting from more enriched source materials. The composition of the slab fluids is characteristic for each arc system, with a particularly pronounced enrichment in Pb at the SVZ and in Ba at the CAVA. A direct compositional relationship between the arc rocks and the corresponding marine sediments that are subducted at the trenches clearly shows that the compositional signature of the lavas erupted in the different arcs carries an inherited signal from the subducted sediments.  相似文献   

Fission track thermochronology of the Beni Bousera peridotite massif (Internal Rif,Morocco) and the exhumation of ultramafic rocks in the Gibraltar Arc     

Ali Azdimousa  Jacques Bourgois  Gérard Poupeau  Mercedes Vázquez  Lahcen Asebriy  Erika Labrin 《Arabian Journal of Geosciences》2014,7(5):1993-2005

The Beni Bousera peridotite massif and its metamorphic surrounding rocks have been analyzed by the fission track (FT) method. The aim was to determine the cooling and uplift history of these mantle and associated crustal rocks after the last major metamorphic event that dates back to the Lower Miocene–Upper Oligocene time (～22–24 Ma). The zircon FT analyses give an average cooling—i.e., below 320 °C—age of ～19.5 Ma. In addition, the apatite FT data give an average cooling—i.e., below 110 °C—age of ～15.5 Ma. Taking into account the thermal properties of the different thermochronological systems used in this work, we have estimated a rate of cooling close to 50 °C/Ma. This cooling rate constrains a denudation rate of about ～2 mm year^?1 from 20 to 15 Ma. These results are similar to those determined in the Ronda peridotite massif of the Betic Cordilleras documenting that some ultrabasic massifs of the internal zones of the two segments of the Gibraltar Arc have a similar evolution. However, Burdigalian sediments occur along the Betic segment (Alozaina area, western Betic segment) unconformably overlying peridotite. At this site, ultramafic rock was exposed to weathering at ages ranging from 20.43 to 15.97 Ma. Since the Beni Bousera peridotite was still at depth until 15.5 Ma, we infer that no simple age projection from massif to massif is possible along the Gibraltar Arc. Moreover, the confined fission track lengths data reveal that a light warming (～100 °C) has reheated the massif during the Late Miocene before the Pliocene–Quaternary tectonic uplift.  相似文献   

The Corossol structure: A possible impact crater on the seafloor of the northwestern Gulf of St. Lawrence,Eastern Canada     

Patrick Lajeunesse  Guillaume St‐Onge  Jacques Locat  Mathieu J. Duchesne  Michael D. Higgins  Richard Sanfaçon  Joseph Ortiz 《Meteoritics & planetary science》2013,48(12):2542-2558

We report on a 4.1 (±0.2) km diameter and 185 m deep circular submarine structure exposed on the seabed in >40 m water depths in the northwestern Gulf of St. Lawrence (Eastern Canada) from the analysis of high‐resolution multibeam bathymetric and seismic data. The presence of a circular form characterized by a central uplift and concentric rings resembles the morphology and geometry of complex meteorite impact structures. Also, other origins, such as kimberlites, intrusions, karsts, or diapirs, can be eliminated on geological criteria. A single 4 cm long breccia fragment recovered from the central uplift has numerous glassy droplets of fluorapatite composition, assumed to be impact melts, and a single quartz grain with planar intersection features thought to be shock‐induced planar deformation features (PDFs). The absolute age of this possible impact structure is unknown, but its geological setting indicates that it was formed long after the Mid‐Ordovician and before regional pre‐Quaternary sea‐level lowstands. Present results outline the need for further examination to confirm an impact origin and to precisely date the formation of the structure.  相似文献   

Shear Strength Development with Burial in Eel River Margin Slope Sediments     

Jacques Locat  Homa Lee  Robert Kayen  Ken Israel  Marie-Claude Savoie  Éric Boulanger 《Marine Georesources & Geotechnology》2013,31(2):111-135

As part of the STRATAFORM project, a series of cores were obtained from the Eel River Margin area of Eureka, California. The geotechnical analysis of intact specimens and of reconstituted samples provides some insight on the development of shear strength with burial. The results show the effect of bioturbation in the early part of the lifetime of a sediment. SEDCON tests were used to proposed various relationships which help predict the changes in density, liquidity index, and strength as a function of depth. These relationships are found useful from near the water sediment-interface down to a depth of at least 400 m in the sediment column.  相似文献   

Was the lethal eruption of Lake Nyos related to a double CO₂/H₂O density inversion?     

Jacques Touret  Michel Grégoire  Merlin Teitchou 《Comptes Rendus Geoscience》2010,342(1):19-26

The 1986 lethal eruption of Lake Nyos (Cameroon) was caused by a sudden inversion between deep, CO₂-loaded bottom lake waters and denser, gas-free surface waters. A deep CO₂ source has been found in fluid inclusions which occur predominantly in clinopyroxenes from lherzolitic mantle xenoliths, brought to the surface by the last erupted alkali basalts. P–T conditions of CO₂ trapping correspond to a gas density equal (or higher) than that of liquid water. It is suggested that this dense CO₂, found in many ultrabasic mantle xenoliths worldwide, has accumulated at km depth, below a column of descending lake water. It may remain in a stable state for a long period, as long as the temperature is above the density inversion temperature for pure H₂O/CO₂ systems. At an estimated depth of about 3 km, cooling by descending waters (to about 30 °C) induces a density inversion for the upper part of the CO₂ reservoir. This causes a constant, regular upstream of low-density CO₂ which, in its turn, feeds the shallower lake density inversion.  相似文献   

Crystal chemistry of suspended matter in a tropical hydrosystem, Nyong basin (Cameroon, Africa)     

Gwenaelle Olivi  -Lauquet  Thierry Allard  Jacques Bertaux  Jean-Pierre Muller 《Chemical Geology》2000,170(1-4):113-131

Suspended matter (SM) from the Nyong basin (Cameroon, Africa), a tropical watershed, was collected by tangential flow ultrafiltration to separate particulate (>0.45 μm) and colloidal (<0.45 μm; >20 kDa) fractions. In this basin, two distinctive systems in a selected small catchment (Nsimi–Zoétélé) of the Nyong river basin have been considered: (i) colourless water (groundwater and spring) with a low suspended load (<3 mg/l) and a low total organic carbon content (TOC<1 mg/l) and (ii) coloured water (Mengong brook and Nyong river), which is organic rich (TOC>10 mg/l) and contains higher amounts of SM (10–20 mg/l) than the colourless water. Freeze-dried samples of SM have been analysed by X-ray diffraction (XRD), transmission electron microscopy (TEM), Fourier-transform infrared spectroscopy (FTIR), electron paramagnetic resonance spectroscopy (EPR), and visible diffuse reflectance spectroscopy (DRS).

Colourless water mainly contains mineral phases, such as poorly ordered kaolinite, plus quartz and goethite in the particulate fraction, and euhedral kaolinite plus amorphous iron oxyhydroxides in the colloidal fraction. In contrast, the SM in coloured water is mainly organic in nature. The mineral phases in the particulate fraction are similar to those from clear water, but with additional phytoliths and diatom frustules composed of biogenic opal. In the colloidal fraction, complexation of Fe³⁺ and Mn²⁺ with organic matter is evidenced by EPR, together with significant occurrence of Fe oxyhydroxides associated with organic matter.

The sites of Al, Si, Fe, Mn in colloidal fractions derived from spectroscopic analyses are discussed with reference to chemical analyses performed by inductively coupled plasma mass spectrometry. Most of the observed solid phases or species correspond to those expected from published thermodynamic calculations for the same hydrosystem, except the colloidal iron oxyhydroxides in the coloured water. The presence of such iron phases is emphasised since they are expected to have large sorption capacities for numerous trace elements.

The crystal chemistry of SM is used to discuss the origin of the mineral particles transported from the soil to the main rivers in terms of mechanical and chemical erosion processes.  相似文献   

Magmatic source enrichment by slab-derived melts in a young post-collision setting, central Mindanao (Philippines)   总被引：28，自引：0，他引：28  

Fernando G. Sajona  Ren  C. Maury  Manuel Pubellier  Jacques Leterrier  Herv  Bellon  Joseph Cotten 《Lithos》2000,54(3-4):173-206

Central Mindanao was the locus of a Pliocene (4–5 Ma old) arc–arc collision event followed by basaltic to dacitic magmatism starting at 2.3 Ma, representing the most voluminous volcanic field in the Philippines. Lava compositions range from calc-alkaline to shoshonitic. Adakites and Nb-enriched basalts are among the magmatic products. All the lavas are Na-rich (up to 4.88%), with Na₂O/K₂O ratios from 2.5 to 6.5. Sr, Nd and Pb isotopic compositions are similar to MORB, except for some shoshonitic lavas that have slightly less radiogenic Nd ratios. K-enrichment in basalts can be related to both fractional crystallization (FC) at moderate pressures and to partial melting of an enriched source. Trace element systematics indicate that the sub-central Mindanao mantle is characterized by the presence of garnet, phlogopite, amphibole, and perhaps some titanate phase. The enrichment of this source is attributed to the interaction of slab-derived melts, i.e., adakites, with the arc mantle. This would explain the presence of Nb-enriched basalts, transitional adakites and high-magnesium andesites, as well as the bulk Na-enrichment and relatively unradiogenic character of the central Mindanao lavas. We envision an ion-exchange type of enrichment, in which the HFSE, LILE and LREE, mobilized during slab melting, are preferentially enriched in the metasomatized mantle, resulting in a diversity of post-collision magma compositions. The MORB-like isotopic signatures of the central Mindanao lavas preclude important contributions of slab-derived hydrous fluids, sediments, continental crust or an OIB-type contaminant. Slab melting after cessation of subduction is deemed possible by thermal rebound of previously depressed geotherms. Initial contributions to mantle enrichment in post-collision sites may thus come from slab melts. In most other cases of post-collision magmatism, however, this signature can be easily masked by enrichments coming from other sources, e.g., the continental lithosphere.  相似文献