Anisidine adsorption on Co-supported pumice     

Belgin Bardakçı  Neslihan Kaya  Taner Kalaycı 《Environmental Earth Sciences》2013,70(2):849-856

In this study, the adsorption of 2-, 3-, 4-anisidines on metal (Co)-supported pumice has been performed. The amount of cobalt on pumice was measured by ICP-OES analysis. Scanning electron microscopy indicated the formation of metal modification on the pumice surface. The samples were examined by Fourier transform infrared spectroscopic analysis of the adsorption process. The data show that after cobalt cation was supported on pumice, the adsorption of 2-, 3-, 4-anisidines was characterized by the bands at 2,958, 1,633, 1,450, 760, and 734 cm^?1. Adsorption of anisidines was observed only on Co-supported pumice, not on bulk pumice. The results show that the main adsorption process can only occur on the metal cation and metal oxide surface of pumice. Geometrical effects of isomers were monitored after adsorption.  相似文献   

Fuzzy process capability indices for quality control of irrigation water   总被引：1，自引：0，他引：1  

Cengiz Kahraman  İhsan Kaya 《Stochastic Environmental Research and Risk Assessment (SERRA)》2009,23(4):451-462

Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of $ \hat C_p Water covers over 70% of the Earth surface and is a very important resource to people and the environment. Water pollution affects drinking water, rivers, lakes and oceans all over the world. This consequently harms human health and the natural environment. Water pollution can also affect the crops. So, water pollution is an important issue for humanity. Therefore, the control of irrigation water is a necessity. In this paper, a methodology based on process capability indices (PCIs) has been presented to control the levels of pH, dissolved oxygen (DO) and temperature (T) in dam’s water for irrigation. Fuzzy PCIs have been proposed for this aim. The fuzzy estimates of and are obtained for pH, DO, and T based on Buckley’s interval estimation approach and based on fuzzy specification limits. An application has been made for Kesikk?prü Dam in Ankara, Turkey. In this paper, Buckley’s approach is re-arranged to obtain a triangular fuzzy membership function because it cannot be obtained from Buckley’s approach in some situation.  相似文献   

Paleogene evolution and demise of the proto‐Paratethys Sea in Central Asia (Tarim and Tajik basins): Role of intensified tectonic activity at ca. 41 Ma     

Mustafa Y. Kaya  Guillaume Dupont‐Nivet  Jean‐Noël Proust  Pierrick Roperch  Laurie Bougeois  Niels Meijer  Joost Frieling  Chiara Fioroni  Sevin zkan Alt&#x;ner  Ezgi Vardar  Natasha Barbolini  Marius Stoica  Jovid Aminov  Mehmut Mamtimin  Guo Zhaojie 《Basin Research》2019,31(3):461-486

The proto‐Paratethys Sea covered a vast area extending from the Mediterranean Tethys to the Tarim Basin in western China during Cretaceous and early Paleogene. Climate modelling and proxy studies suggest that Asian aridification has been governed by westerly moisture modulated by fluctuations of the proto‐Paratethys Sea. Transgressive and regressive episodes of the proto‐Paratethys Sea have been previously recognized but their timing, extent and depositional environments remain poorly constrained. This hampers understanding of their driving mechanisms (tectonic and/or eustatic) and their contribution to Asian aridification. Here, we present a new chronostratigraphic framework based on biostratigraphy and magnetostratigraphy as well as a detailed palaeoenvironmental analysis for the Paleogene proto‐Paratethys Sea incursions in the Tajik and Tarim basins. This enables us to identify the major drivers of marine fluctuations and their potential consequences on Asian aridification. A major regional restriction event, marked by the exceptionally thick (≤ 400 m) shelf evaporites is assigned a Danian‐Selandian age (ca. 63–59 Ma) in the Aertashi Formation. This is followed by the largest recorded proto‐Paratethys Sea incursion with a transgression estimated as early Thanetian (ca. 59–57 Ma) and a regression within the Ypresian (ca. 53–52 Ma), both within the Qimugen Formation. The transgression of the next incursion in the Kalatar and Wulagen formations is now constrained as early Lutetian (ca. 47–46 Ma), whereas its regression in the Bashibulake Formation is constrained as late Lutetian (ca. 41 Ma) and is associated with a drastic increase in both tectonic subsidence and basin infilling. The age of the final and least pronounced sea incursion restricted to the westernmost margin of the Tarim Basin is assigned as Bartonian–Priabonian (ca. 39.7–36.7 Ma). We interpret the long‐term westward retreat of the proto‐Paratethys Sea starting at ca. 41 Ma to be associated with far‐field tectonic effects of the Indo‐Asia collision and Pamir/Tibetan plateau uplift. Short‐term eustatic sea level transgressions are superimposed on this long‐term regression and seem coeval with the transgression events in the other northern Peri‐Tethyan sedimentary provinces for the 1st and 2nd sea incursions. However, the 3rd sea incursion is interpreted as related to tectonism. The transgressive and regressive intervals of the proto‐Paratethys Sea correlate well with the reported humid and arid phases, respectively in the Qaidam and Xining basins, thus demonstrating the role of the proto‐Paratethys Sea as an important moisture source for the Asian interior and its regression as a contributor to Asian aridification.  相似文献   

Solution of the propagation of the waves in open channels by the transfer matrix method     

R. Daneshfaraz  B. Kaya   《Ocean Engineering》2008,35(11-12):1075-1079

Many problems in mechanics can be solved by the use of the transfer matrix method. The use of this method in hydraulics engineering is not widespread and only limited studies are available. In this study, linearized St. Venant equations were used and the use of transfer matrix in ocean engineering was investigated for long waves in open channels, and numerical application was carried out. The results obtained through the transfer matrix method, which is quite easy to use, program and comprehend, showed similar results obtained from the characteristics method and finite differences method.  相似文献   

Geotechnical land suitability assessment using spatial multi-criteria decision analysis     

E.?AkyolEmail author  A.?Kaya  M.?Alkan 《Arabian Journal of Geosciences》2016,9(7):498

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Tributyltin and triphenyltin induce spermatogenesis in ovary of female abalone,Haliotis gigantea   总被引：1，自引：0，他引：1  

Horiguchi T  Kojima M  Kaya M  Matsuo T  Shiraishi H  Morita M  Adachi Y 《Marine environmental research》2002,54(3-5):679-684

Two-month flow-through exposure experiments of tributyltin (TBT) and triphenyltin (TPhT) were conducted with abalone, Haliotis gigantea. Nominal concentrations of 100 ng TBT/l and 100 ng TPhT/l caused significant spermatogenesis in ovaries of exposed females. There were also significantly more contracted primary oocytes observed in females exposed to either TBT or TPhT than controls. The incidence of two types of unknown cells was also significant in females exposed to TPhT. No significant histological changes were observed in testis of exposed males. This ovarian spermatogenesis caused by TBT and/or TPhT resembles gastropod imposex. Remarkably high concentrations of TBT and TPhT were observed in the head (including central nervous system ganglia), compared to muscles concentrations. Accumulation of TBT and TPhT in the head may disturb reproductive hormonal regulators through neuropeptides released from ganglia. This, as well as possible aromatase inhibition, may be one of the inducers for spermatogenesis in the abalone ovaries.  相似文献   

Modelling mid-Z element atmospheres for strongly magnetized neutron stars     

Kaya Mori  Wynn C. G. Ho 《Monthly notices of the Royal Astronomical Society》2007,377(2):905-919

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Artificial neural network study of observed pattern of scour depth around bridge piers     

Abidin Kaya 《Computers and Geotechnics》2010

An artificial neural networks (ANN) model is developed to study the observed pattern of local scour at bridge piers using an FHWA (Federal Highway Administration) data set composed of 380 measurements at 56 bridges in 13 states. Various ANN estimates of observed pier scour depth on different choices of input variables are examined. Reducing the number of variables from 14 to 9 has negligible effect on the coefficient of determination, R², (0.73 vs. 0.72). Further sensitivity analysis indicates that pier scour depth can be estimated using only four variables: pier shape and skew, flow depth and velocity with a coefficient of determination of 0.81, suggesting that inclusion of some variables actually diminishes the quality of ANN predictions of short term observed pattern of scour. The ANN estimates indicate that flow depth and flow velocity make up 66% of the coefficient of determination.  相似文献   

Monitoring urban growth on the European side of the Istanbul metropolitan area: A case study     

S. Kaya  P.J. Curran 《International Journal of Applied Earth Observation and Geoinformation》2006

Istanbul is the largest city in Turkey with an area of around 5750 km² and a population of around 10.8 M (2000). In 1980, the population was only around 4.7 M and so has more than doubled in only 2 decades. In 2000, around 65% of the population were living on the European side of the city with its large industrial/commercial and trade centres. The population is increasing as a result of both births exceeding deaths and mass immigration. Consequently, planned and unplanned housing are increasing while green areas are decreasing in area. Monitoring urban growth will enable the Municipality of Istanbul to better manage this complex urban area.  相似文献   

Continuing observation of disturbed reproductive cycle and ovarian spermatogenesis in the giant abalone, Haliotis madaka from an organotin-contaminated site of Japan   总被引：1，自引：0，他引：1  

Horiguchi T  Kojima M  Takiguchi N  Kaya M  Shiraishi H  Morita M 《Marine pollution bulletin》2005,51(8-12):817-822

Histological examination of gonads as well as chemical analysis of organotin compounds in tissues of the giant abalone, Haliotis madaka, was conducted to evaluate continuing endocrine disruption in abalone populations in Japan. Abalone specimens were collected from two different areas, Tsushima as a reference site and Jogashima as a site representative of declining abalone populations where serious organotin contamination had been observed, each month from January 1998 to March 1999. Scores were given to the development stages of reproductive cells in the ovary and testis. The degree of sexual maturation was evaluated by calculating the mean value of a histogram of these scores for the reproductive cells of each abalone. The temporal variations in degree of sexual maturation showed that female and male abalone from Tsushima matured synchronously, while those from Jogashima did not, which were similar to results of the previous study during September 1995–November 1996. Approximately 19% of the female abalone from Jogashima were masculinized with an ovo-testis, which was also similar to the result of the previous study. The masculinization of female abalone is reported to be induced by tributyltin (TBT) and triphenyltin (TPhT) from antifouling paints. Concentrations of the sum of butyltins (TBT, dibutyltin (DBT) and monobutyltin (MBT): ΣBTs) and the sum of phenyltins (TPhT, diphenyltin (DPhT) and monophenyltin (MPhT): ΣPhTs) in the muscle of abalone from Jogashima (n = 73) of 7.8 ± 9.0 ng/g wet wt. and 4.5 ± 6.8 ng/g wet wt., respectively, were significantly higher than those from Tsushima (n = 87) of 4.7 ± 4.9 ng/g wet wt. and 0.8 ± 1.7 ng/g wet wt., respectively (p < 0.05 for ΣBTs; p < 0.001 for ΣPhTs), although concentrations of TBT and TPhT in the muscle of abalone from Jogashima (n = 73) of 2.2 ± 2.5 ng/g wet wt. and 5.8 ± 5.1 ng/g wet wt., respectively, were insignificantly and significantly higher than those from Tsushima (n = 87) of 0.4 ± 0.6 ng/g wet wt. and 0.5 ± 0.9 ng/g wet wt., respectively, (p > 0.05 for TBT; p < 0.001 for TPhT). Thus, endocrine disruption as well as contamination by organotins in the giant abalone from Jogashima is still persisting.  相似文献