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11.
Summary Anandite has an approximate formula of Ba(Fe3+, Fe2+)3[Si2(Fe3+, Fe2+, Si)2O10–x(OH)x] (S, Cl) (OH), withx=0–1, and belongs to the 2 O brittle mica group. It is orthorhombic; space groupPnmn;a=5.468(9) Å,b=9.489(18)Å,c=19.963(11) Å;Z=4.The structure was determined from 3dim. Weissenberg-data, starting with an approximate structure in the pseudo space groupCcmm. Least squares refinement resulted inR=0.061 for 409 photometric intensities, andR=0.131 for all 853 observedhkl-reflexions.The iron of the tetrahedral layer is concentrated in one of the two crystallographically different kinds of tetrahedra. The basal oxygen rings of the tetrahedral layer form approximate hexagons and have not the ditrigonal configuration of the common micas. This peculiarity is considered to be a consequence of the size and charge of the barium ion. The role of OH in the common micas is played partly by S2– and Cl– in anandite.
With 4 Figures 相似文献
Die Kristallstruktur des 2 O Sprödglimmers Anandit
Zusammenfassung Anandit hat die ungefähre Formel Ba(Fe3+, Fe2+)3[Si2(Fe3+, Fe2+, Si)2O10–x(OH)x] (S, Cl) (OH) mitx=0–1 und gehört zur 2O Sprödglimmergruppe. Er ist rhombisch; RaumgruppePnmn; a=5,468(9) Å,b=9,489(18) Å,c=19,963(11) Å;Z=4.Die Struktur wurde aus Weissenberg-Daten bestimmt, wobei mit einer approximativen Struktur in der PseudoraumpruppeCcmm begonnen wurde. Die Verfeinerung nach der Methode der kleinsten Quadrate führte für 409 photometrierte Reflexe aufR=0,061 und für alle 853 beobachtetenhkl-Reflexe aufR=0,131.Der Eisengehalt der Tetraederschicht ist in einer der beiden kristallographisch verschiedenen Tetraederarten konzentriert. Die basalen Sauerstoffringe der Tetraederschicht bilden annäherungsweise Sechsecke und haben nicht die ditrigonale Konfiguration der gewöhnlichen Glimmer. In Anandit spielen S2– und Cl– teilweise die Rolle der Hydroxylgruppen in den gewöhnlichen Glimmern.
With 4 Figures 相似文献
12.
Summary The refined lattice parameters of beryllonite are:a=8.178 (3) Å,b=7.818 (2) Å,c=14.114 (6) Å, =90.00° (2); space groupP21/n,Z=12. Integrated Weissenberg photographs were taken by using CuK radiation and multiple film packs. The anisotropic refinement of the crystal structure by means of least-square methods gave a finalR value of 0.063 for the 1388 observed reflections. In the crystal structure PO4 and BeO4 tetrahedra, linked by shared oxygen atoms in a three-dimensional network, form pseudo-ditrigonal rings perpendicular to theb axis. The independent Na atoms lying in the channels formed by the rings are coordinated as an irregular nine-cornered polyhedron and as distorted octahedra.
With 2 Figures 相似文献
Verfeinerung der Kristallstruktur des Beryllonits,NaBePO 4
Zusammenfassung Verfeinerte Gitterkonstanten des Beryllonits lauten:a=8,178 (3) Å,b=7,818 (2) Å,c=14,114 (6) Å, =90,00 (2)°; Raumgruppe:P21/n,Z=12. Integrierte Weissenbergaufnahmen wurden mit CuK-Strahlung und multiplen Filmpaketen aufgenommen. Die anisotrope Verfeinerung der Kristallstruktur nach der Methode der kleinsten Quadrate ergab für 1388 beob. Reflexe einen abschließendenR-Wert von 0,063. In der Kristallstruktur bilden PO4-und BeO4-Tetraeder, die über gemeinsame Sauerstoffe zu einem dreidimensionalen Gerüst verknüpft sind, pseudo-ditrigonale Ringe senkrecht zurb-Achse. Die kristallographisch unabhängigen Arten von Na-Atomen, welche in den aus Ringen gebildeten Kanälen liegen, sind in der Form eines unregelmäßigen neuneckigen Polyeders bzw. in der Form verzerrter Oktaeder koordiniert.
With 2 Figures 相似文献
13.
ABSTRACTWater indicators and indices are useful tools to assess river basin performance, that is, to measure whether the basin operates satisfactorily under a wide range of possible future demands and hydrological conditions. Spanish regulations assess the performance of water demands by using reliability indicators (RIs), established by law in 2008. This article raises the possibility of updating RIs by comparing them with sustainability indicators (SIs). SIs are widely used for the assessment of river basin performance and several policy scenarios. We applied a water allocation model to the Guadiana River basin in Spain to compare indicators under three scenarios. The study was framed within the science of socio-hydrology, combining the physical environment of a water system with its influence on social aspects. SIs gave better results than RIs when comparing future scenarios. We also propose the introduction of a vulnerability indicator into Spanish regulations. 相似文献
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Graciano P. Yumul Jr. Nathaniel A. Cruz Nathaniel T. Servando Carla B. Dimalanta 《《幕》》2008,31(4):378-383
In the early part of 2006 the Philippines was hit by a La Nina event which brought floods, flashfloods and landslides. The most significant event was the February 2006 landslide that covered the whole community of Guinsaugon, in Southern Leyte, resulting in 154 deaths with 973 people still missing. Another rare event was the simultaneous presence of two tropical cyclones inside the Philippine Area of Responsibility (PAR) in August-- Tropical Depression Bopha and Tropical Storm Saomai--that enhanced the southwest monsoon. With the strong winds and high waves associated with the southwest mon- soon, an oil tanker, the M/T Solar 1, sank, resulting in the worst oil spill the country has ever suffered. Lastly, with a weak El Nino phenomenon forming in the Pacific Ocean and affecting the Philippines, a destructive typhoon, Xangsane, made a multi-landfall before hitting Metropolitan Manila. This was followed by the landfall of three superty- phoons--Cimaron, Chebi and Durian--during the last quarter of the year, bringing tremendous destruction of life and property. The occurrence of these weather events are attributed to climate variability the effects of which were exacerbated by a range of factors that include inappropriate land use. 相似文献
18.
Guanabara Bay (GB) is considered to be one of the most polluted environments of the southern Brazilian coastline. This typical estuarine system is impacted by the heavy discharge of both industrial and domestic waste from the Rio de Janeiro metropolitan area. The mollusc community structure and distribution was investigated between 2000 and 2001, using a three month sampling design of 38 stations, according to austral seasons. Species abundance was aggregated into progressively higher taxa matrices (genus, family, order) and were analysed using multivariate techniques. Mollusc distribution in GB varied significantly in space and time and was probably ruled by the organic enrichment effects of hypoxia and altered redox conditions coupled with prevailing patterns of circulation. Within the sectors of GB an increasing gradient in mollusc diversity and occurrence was observed, ranging from the azoic and impoverished stations in the inner sector to a well-structured community in terms of species composition and abundance inhabiting the outer sector. The non-metric multidimensional scaling (nMDS) and cluster analysis showed similar results when species were aggregated into genera and families, while greater difference occurred at coarser taxonomic identification (order). The literature about taxonomic sufficiency has demonstrated that faunal patterns at different taxonomic levels tend to become similar with increased pollution. In Guanabara Bay, an analysis carried out solely at family level is perfectly adequate to describe the ecophysiological stress. Further aggregation to order level changed the perceived patterns of differences. However, a different taxonomic resolution can be chosen depending on the type of ecological patterns investigated. 相似文献
19.
Landslides constitute one of the most important natural hazards in Italy as they are widespread and result in considerable damage and fatalities every year. The Italian Landslide Inventory (IFFI) Project was launched in 1999 with the aim of identifying and mapping landslides over the entire Italian territory. The inventory currently holds over 480,000 landslides and has been available by means of Web services since 2005. The aim of this study is to define quality indices for evaluation of the homogeneity and completeness of the IFFI database. In order to estimate the completeness of the landslide attribute information, a heuristic approach has been used to assign weighting values to significant parameters selected from the landslide data sheet. The completeness and homogeneity of the landslide mapping has been evaluated by means of three different methods: an area-frequency distribution analysis; the proximity of the landslides surveyed to urban areas; variation of the landslide index within the same lithology. The quality indices have allowed identification of areas with a high level of completeness and critical areas in which the data collected have been underestimated or are not very accurate. The quality assessment of collected and stored data is essential in order to use the IFFI database for definition and implementation of landslide susceptibility models and for land use planning and management. 相似文献
20.
Carla Meurk 《The Australian geographer》2014,45(1):37-52
This paper examines invasive animal management institutions, using theories at the interstices of anthropology and geography, to question current approaches to management based on neoclassical and neoliberal economic rationales. I present an analysis of two feral pig management regimes in Far North Queensland, Australia: (i) bounty systems of payment for feral pig control; and (ii) a community-based feral pig trapping program. I show how these management methods reshape important social and cultural processes through their overlapping technological and economic elements. On the basis of this analysis, I propose a conceptual framework for invasive animal management planning that incorporates a beneficiary–benefactor analysis alongside cost–benefit analyses. I argue that ecological-economic theories of pest management may be usefully enhanced by addressing the links between economic and social behaviours. 相似文献