Levels of persistent organic pollutants and residual pattern of DDTs in small cetaceans from the coast of São Paulo, Brazil     

G.T. Yogui  M.C.O. Santos  R.C. Montone 《Marine pollution bulletin》2010,60(10):1862-1867

The State of São Paulo is the most developed area in Brazil and was impacted by persistent organic pollutants for several decades. This study investigated organochlorines in five species of small cetaceans (Pontoporia blainvillei, Stenella frontalis, Sotalia guianensis, Tursiops truncatus and Steno bredanensis) found dead along the coast of São Paulo between 1997 and 2003. DDTs (15.9 μg g⁻¹ lipid; mean for all pooled individuals) and PCBs (8.08 μg g⁻¹) exhibited the highest concentrations in the animals, reflecting large amounts formerly used in Brazil. Lower levels of mirex (0.149 μg g⁻¹), HCB (0.051 μg g⁻¹), CHLs (0.008 μg g⁻¹) and HCHs (0.007 μg g⁻¹) were detected in all species. Residual pattern of DDTs in dolphins suggests that o,p′-DDT is more recalcitrant than p,p′-DDT in the body of the animals and/or the environment. In contrast to p,p′-DDT, residues of o,p′-DDT seem to be preferentially converted into o,p′-DDD rather than o,p′-DDE.  相似文献   

Geophysical analysis of Catalão I alkaline–carbonatite complex in Goiás,Brazil          下载免费PDF全文

M.S.M. Mantovani  V.H.A. Louro  V.B. Ribeiro  H.S. Requejo  R.P.Z. dos Santos 《Geophysical Prospecting》2016,64(1):216-227

The Catalão I alkaline–carbonatite complex, which is located in Central Brazil, is one of the main producers of niobium and phosphates in the world. It has been intensely studied geologically and geochemically for its economic potential. This work presents a geophysical analysis over this complex, identifying its behaviour in the subsurface and in portions that have not been explored yet. Different geophysical methods and techniques were applied to achieve the most reliable results possible: at the surface, through radiometric, geological, and topographic data, and at depth, by geological, magnetic, and gravimetric data. The analysis was successfully completed with inversions of gravity and magnetic data that resulted in quite similar models, both in volume and shape. Their density and magnetic susceptibility contrasts were consistent with the expected dunite–pyroxenite lithology from the original mafic intrusion and indicated (by exclusion) the volume of the carbonatite body, which along with the known contents of phosphates and niobium allowed an indirect estimate of the reserves and resources of the complex.  相似文献   

Shaking table testing for masonry infill walls: unreinforced versus reinforced solutions          下载免费PDF全文

Paulo B. Lourenço  João M. Leite  Manuel F. Paulo‐Pereira  A. Campos‐Costa  P. X. Candeias  Nuno Mendes 《地震工程与结构动力学》2016,45(14):2241-2260

Several factors influence the behaviour of infilled frames, which have been a subject of research in the past with moderate success. The new generation of European design standards imposes the need to prevent brittle collapse of the infills and makes the structural engineer accountable for this requirement, yet it fails to provide sufficient information for masonry infills design. Therefore, the present work aims at understanding the seismic behaviour of masonry infill walls within reinforced concrete frames, using both unreinforced and reinforced solutions (bed joint reinforcement and reinforced plaster). For this purpose, three reinforced concrete buildings with different infill solutions were constructed at a scale of 1:1.5, all with the same geometry, and were tested on the shaking table of the National Laboratory for Civil Engineering, Portugal. All solutions performed adequately for the design earthquake, with no visible damage. Still, the experimental tests show that the double‐leaf‐unreinforced infill walls underperformed during a large earthquake, collapsing out of plane by rotating as rigid bodies with multiple configurations. Also the reinforced concrete buildings collapsed, because of the adverse interaction with the infill walls. The infill walls with bed joint reinforcement and reinforced plaster did not collapse out of plane, because of their connection to the concrete frame, which is an essential requirement. Copyright © 2016 John Wiley & Sons, Ltd.  相似文献   

Study on the Historical Distribution of Metals in Aquatic Sediments     

Wagner José Barreto  Dílson Norio Ishikawa  Andressa Clara Nicolau  Evandro Domingues Magalhães  Fabiana Inoue  Paulo dos Santos Nora  Rodolfo Funfas  Sônia Regina Giancoli Barreto 《洁净——土壤、空气、水》2010,38(7):608-613

In this study, the historical distribution of metals, phosphorous, and sulfur at four different depths in the sediments of different lakes formed in the course of an urban river (in Londrina, Parana State, Brazil) were determined. The transport of metals along the course of the river was observed mainly for Mn, Cr, and Zn. High concentrations of Pb in the Capivara Bay and Cr in the river were attributed to contamination from a battery plant and a tannery, respectively. The concentrations of heavy metals in the deepest layers of the sediments remain high several years after deposition.  相似文献   

Consequences of linseed oil spills in salt marsh sediments     

Pereira MG  Mudge SM  Latchford J 《Marine pollution bulletin》2002,44(6):520-533

In a simulated spill in a salt marsh, linseed oil penetrated rapidly into the sediments at a rate of 10(-7) cm2 s(-1). The oil concentration remained unchanged for the first month after the spill, but 60% of the oil disappeared from the top 30 cm after a further month. The oil adsorbed to and accumulated in the muddy sediments (top 15 cm) leading to decreased sediment permeability, pH, Eh, abundance of plant roots and infauna and to the establishment of anoxic conditions. These changes accompanied transformations in the original fatty acid composition of the linseed oil, mainly associated with a decrease in 18 : 3omega3, an increase in the other fatty acids and the presence of 'new' fatty acids. A rapid increase in the abundance of heterotrophic aerobic and anaerobic bacteria and aerobic oil degrading bacteria, suggested that these micro-organisms degraded the oil. The role of the bacteria in oil degradation was confirmed in laboratory experiments where the fatty acids composition of the linseed oil underwent identical transformations to those obtained in the field. The degradation of linseed oil appears to be a sequential process initiated by aerobic and/or anaerobic bacteria and continued by sulphate reducing bacteria, which were unable to degrade the raw oil.  相似文献   

The contribution of the first stars to the cosmic infrared background     

Michael R. Santos  Volker Bromm  Marc Kamionkowski 《Monthly notices of the Royal Astronomical Society》2002,336(4):1082-1092

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Effects of climate, invasive species and anthropogenic impacts on the growth of the seagrass Posidonia oceanica (L.) Delile in Liguria (NW Mediterranean Sea)     

Peirano A  Damasso V  Montefalcone M  Morri C  Bianchi CN 《Marine pollution bulletin》2005,50(8):817-822

Eight shallow water Posidonia oceanica meadows were sampled in June 1999 along 300 km of the Ligurian coast and were compared through shoot density and lepidochronology. The growth of the seagrass was examined in the light of climate fluctuations and local stresses, colonisation by alien, invasive alga Caulerpa taxifolia, and effects of the oil spill from the tanker "Haven", and other anthropogenic impacts. Both shoot density and lepidochronology pointed to a generalised state of regression of all the meadows. The analysis of long-term growth curves of the rhizomes showed a positive trend parallel to the increase of air temperature. Two main groups of meadows were individuated on the basis of growth curve similarity. The first included four meadows, namely Ventimiglia, Imperia, Noli and Prelo, that were characterised by average values of rhizome growth of 8-9.1 mmyear(-1) and shoot density greater than 200 shootsm(-2). Although the Imperia meadow was the only one where the alien invasive alga C. taxifolia was found, it did not show differences for rhizome growth in comparison to the other meadows. The second group was formed by meadows that had suffered past anthropogenic impacts: Arenzano and Monterosso al Mare. They showed higher rhizome growth rates (9.4-10.6 mmyear(-1)) and shoot densities between 200 and 100 shootsm(-2). At Arenzano, where "Haven" oil was stranded in April 1991, no rhizome older than 8 years was found, thus confirming the shoot mortality induced by the oil spill event. The two last meadows exhibited growth curves very different from all the others: Portovenere, is a shallow meadow where P. oceanica merely survives in an extremely degraded situation with highest rhizome growth rate (12 mmyear(-1)), the other, Riva Trigoso, is the only meadow implanted on rock and had the lowest growth rates (7.1 mm year(-1)).  相似文献   

Stochastic Modeling of Variably Saturated Transient Flow in Fractal Porous Media     

Luis Guarracino  Juan E. Santos 《Mathematical Geology》2004,36(2):217-238

This work presents the application of a Monte Carlo simulation method to perform an statistical analysis of transient variably saturated flow in an hypothetical random porous media. For each realization of the stochastic soil parameters entering as coefficients in Richards' flow equation, the pressure head and the flow field are computed using a mixed finite element procedure for the spatial discretization combined with a backward Euler and a modified Picard iteration in time. The hybridization of the mixed method provides a novel way for evaluating hydraulic conductivity on interelement boundaries. The proposed methodology can handle both large variability and fractal structure in the hydraulic parameters. The saturated conductivity K _s and the shape parameter _vg in the van Genuchten model are treated as stochastic fractal functions known as fractional Brownian motion (fBm) or fractional Gaussian noise (fGn). The statistical moments of the pressure head, water content, and flow components are obtained by averaging realizations of the fractal parameters in Monte Carlo fashion. A numerical example showing the application of the proposed methodology to characterize groundwater flow in highly heterogeneous soils is presented.  相似文献   

Acid mine drainage and acid rock drainage processes in the environment of Herrerías Mine (Iberian Pyrite Belt, Huelva-Spain) and impact on the Andevalo Dam   总被引：1，自引：0，他引：1  

J. A. Grande  R. Beltrán  A. Sáinz  J.C. Santos  M. L. de la Torre  J. Borrego 《Environmental Geology》2005,47(2):185-196

The present work describes the process of acid water discharge into the Andévalo Dam (Iberian Pyrite Belt, Huelva-Spain) starting from the interpretation of rainfall data and chemical analyses regarding pH, conductivity, metal and sulphate content in water, from a time series corresponding to the sampling of two confluent channels that discharge water into the referred dam. Statistical data treatment allows us to conclude the existence of acid mine drainage processes in the Chorrito Stream, which are translated into very low pH values and high sulphate and metal concentrations in the water coming from Herrerías Mine. On the other hand, the Higuereta Stream shows, for the same parameters, much lower values that can be interpreted as the channel response to acid rock drainage processes in its drainage basin induced by the rocky outcrops of the Iberian Pyrite Belt.  相似文献   

Along strike changes in the structural evolution over a brittle detachment fault: Example of the Pleistocene Corinth–Patras rift (Greece)     

Nicolas Flott  Denis Sorel  Carla Müller  Julien Tensi 《Tectonophysics》2005,403(1-4):77-94

The Patras, Corinth, and northern Saronic gulfs occupy a 200-km-long, N120° trending Pleistocene rift zone, where Peloponnese drifts away from mainland Greece. The axes of Patras and Corinth basins are 25 km apart and linked by two transfer-fault zones trending N040°. The older one defines the western slope of Panachaïkon mountain, and the younger one limits the narrow Rion–Patras littoral plain. Between these two faults, the ca. 4-km-thick Rion–Patras series dips 20–30° SSW. It is part of the Patras gulf synrift deposits, which pile in an asymmetric basin governed by a fault dipping ca. 25–35° NNE, located in the southern Gulf of Patras. Mapping of this fault to the east in northern Peloponnese shows that it is an inactive north-dipping low-angle normal fault (0° to 30°N), called the northern Peloponnese major fault (NPMF). The structural evolution of the NPMF was different in the gulfs of Patras and Corinth. In the Gulf of Patras, it is still active. In northern Peloponnese, footwall uplift and coeval southward tilting flattened the fault and locked its southern part. Steeper normal faults formed north of the locked area, connecting the still active northern part of the NPMF to the surface. After several locks, the presently active normal faults (Psathopyrgos, Aigion, Helike) trend along the southern shore of the Gulf of Corinth. This migration of faults caused the relative 25 km northward shift of the Corinth basin, and the formation of NE–SW trending transfer-faults between the Corinth and Patras gulfs.  相似文献