Mineralogy,geochemistry and petrogenesis of the Khopoli mafic intrusion,Deccan Traps,India     

Ciro Cucciniello  Ashwini Kumar Choudhary  Alberto Zanetti  Hetu C. Sheth  Shreyas Vichare  Rohan Pereira 《Mineralogy and Petrology》2014,108(3):333-351

The Khopoli intrusion, exposed at the base of the Thakurvadi Formation of the Deccan Traps in the Western Ghats, India, is composed of olivine gabbro with 50–55 % modal olivine, 20–25 % plagioclase, 10–15 % clinopyroxene, 5–10 % low-Ca pyroxene, and <5 % Fe-Ti oxides. It represents a cumulate rock from which trapped interstitial liquid was almost completely expelled. The Khopoli olivine gabbros have high MgO (23.5–26.9 wt.%), Ni (733–883 ppm) and Cr (1,432–1,048 ppm), and low concentrations of incompatible elements including the rare earth elements (REE). The compositions of the most primitive cumulus olivine and clinopyroxene indicate that the parental magma of the Khopoli intrusion was an evolved basaltic melt (Mg# 49–58). Calculated parental melt compositions in equilibrium with clinopyroxene are moderately enriched in the light REE and show many similarities with Deccan tholeiitic basalts of the Bushe, Khandala and Thakurvadi Formations. Nd-Sr isotopic compositions of Khopoli olivine gabbros (εNd_t?=??9.0 to ?12.7; ⁸⁷Sr/⁸⁶Sr?=?0.7088–0.7285) indicate crustal contamination. AFC modelling suggests that the Khopoli olivine gabbros were derived from a Thakurvadi or Khandala-like basaltic melt with variable degrees of crustal contamination. Unlike the commonly alkalic, pre- and post-volcanic intrusions known in the Deccan Traps, the Khopoli intrusion provides a window to the shallow subvolcanic architecture and magmatic processes associated with the main tholeiitic flood basalt sequence. Measured true density values of the Khopoli olivine gabbros are as high as 3.06 g/cm³, and such high-level olivine-rich intrusions in flood basalt provinces can also explain geophysical observations such as high gravity anomalies and high seismic velocity crustal horizons.  相似文献   

Early Cambrian granitoids of North Gondwana margin in the transition from a convergent setting to intra-continental rifting (Ossa-Morena Zone,SW Iberia)     

T. Sánchez-García  M. F. Pereira  F. Bellido  M. Chichorro  J. B. Silva  P. Valverde-Vaquero  Ch. Pin  A. R. Solá 《International Journal of Earth Sciences》2014,103(5):1203-1218

Two distinct Cambrian magmatic pulses are recognized in the Ossa-Morena Zone (SW Iberia): an early rift-(ER) and a main rift-related event. This Cambrian magmatism is related to intra-continental rifting of North Gondwana that is thought to have culminated in the opening of the Rheic Ocean in Lower Ordovician times. New data of whole-rock geochemistry (19 samples), Sm–Nd–Sr isotopes (4 samples) and ID–TIMS U–Pb zircon geochronology (1 sample) of the Early Cambrian ER plutonic rocks of the Ossa-Morena Zone are presented in this contribution. The ER granitoids (Barreiros, Barquete, Calera, Salvatierra de los Barros and Tablada granitoid Massifs) are mostly peraluminous granites. The Sm–Nd isotopic data show moderate negative εNdt values ranging from ?3.5 to +0.1 and TDM ages greatly in excess of emplacement ages. Most ER granitoids are crustal melts. However, a subset of samples shows a transitional anorogenic alkaline tendency, together with more primitive isotopic signatures, documenting the participation of lower crust or mantle-derived sources and suggesting a local transient advanced stage of rifting. The Barreiros granitoid is intrusive into the Ediacaran basement of the Ossa-Morena Zone (Série Negra succession) and has yielded a crystallization age of 524.7 ± 0.8 Ma consistent with other ages of ER magmatic pulse. This age: (1) constrains the age of the metamorphism developed in the Ediacaran back-arc basins before the intrusion of granites and (2) defines the time of the transition from the Ediacaran convergent setting to the Lower Cambrian intra-continental rifting in North Gondwana.  相似文献   

Nematode diversity in different microhabitats in a mangrove region     

Taciana K. Pinto  Melanie C. V. Austen  Richard M. Warwick  Paul J. Somerfield  André M. Esteves  Francisco J. V. Castro  Verônica G. Fonseca‐Genevois  Paulo J. P. Santos 《Marine Ecology》2013,34(3):257-268

Mangroves are highly productive environments that play important ecological and socioeconomic roles; however, they have been impacted to different degrees in most countries worldwide. The knowledge of which organisms inhabit this environment and their ecological interactions is the first step towards its conservation. The natural variability of environmental factors in mangroves provides numerous niches available to different species. Meiofauna have patchy patterns of distribution that are related to the availability of resources. Hence, meiofauna are expected to present a high diversity of different taxa occupying the different microhabitats offered by mangroves. This work aims to test the hypothesis that the assemblage structure of Nematoda varies significantly among mangrove microhabitats and to contribute knowledge on the meiofauna diversity in mangrove environments. This work was carried out in a mangrove region at Pernambuco state, Northeastern Brazil. Qualitative samples were collected in nine microhabitats which show different characteristics mainly in terms of presence of vegetation or another organism and sediment grain size. Univariate and multivariate analysis were applied to Nematoda genera abundance data. Our results demonstrate the existence of significant differences among microhabitats regarding nematode assemblage structure corroborating the hypothesis. Different Nematoda assemblages are present in at least seven microhabitats. These assemblages are composed of nematode genera with different trophic and morphological features, demonstrating a strong relationship between morphological diversity and ecological plasticity. Furthermore, this study also demonstrates the importance of the conservation of this ecosystem and its attributes.  相似文献   

Dark energy as space-time curvature induced by quantum vacuum fluctuations     

Emilio Santos 《Astrophysics and Space Science》2011,332(2):423-435

It is shown that quantum vacuum fluctuations give rise to a curvature of space-time equivalent to a cosmological constant, that is a homogeneous energy density ρ and pressure p fulfilling −p=ρ>0. The fact that the fluctuations produce curvature, even if the vacuum expectation of the energy vanishes, is a consequence of the non-linear character of the Einstein equation. A calculation is made, involving plausible hypotheses within quantized gravity, which establishes a relation between the two-point correlation of the vacuum fluctuations and the space-time curvature. Arguments are given which suggest that the density ρ might be of order the “dark energy” density currently assumed to explain the observed accelerated expansion of the universe.  相似文献   

Heavy metal mobility assessment in sediments from the Odiel River (Iberian Pyritic Belt) using sequential extraction   总被引：1，自引：1，他引：0  

Rafael Beltrán  J. D. de la Rosa  J. C. Santos  M. Beltrán  J. L. Gómez-Ariza 《Environmental Earth Sciences》2010,61(7):1493-1503

The Tessier sequential extraction scheme (SES) was applied to sediments from the Odiel river catchment (Iberian Pyritic Belt, SW of Spain), one of the most acid rivers on Earth, to assess the chemical association (exchangeable, carbonatic, bound to manganese and iron oxides, bound to organic matter and residual mineral) of heavy metals (Zn, Cd, Pb, Cu, Cr, Mn, Ni, Fe, and Hg). Sediments are very heterogeneous in their textural characteristics, showing different grain size. Twenty-seven samples were studied from from areas along the Odiel River, from the source to the mouth, with special interest in the Odiel Marshes Natural Park due to its ecological significance. Samples were classified as sandy (especially at the river mouth with low iron oxide and organic matter content) and clay-silty (in the middle of the river catchment with high iron oxide content). The numerous sandy samples with low pH values explain the low levels of metals upstream, although potential metals contributions arise from mining and ore. However, the presence of sulfate in the mining area and carbonate at the mouth may explain the high presence of lead and iron in these sandy zones. Some percentage of mobile Ni, Cu, and Zn were detected in the mining area, but the elevated relative percentage of exchangeable Cd in the estuary is even more remarkable. The percentage of Zn bound to carbonate is considerable in the catchment but especially in the estuary. However, Cu is only detected in the carbonate phase downstream, in spite of the low concentration of carbonate, which represents a drawback in the application of the Tessier SES to these types of samples. Finally, relatively high percentages of residual, non-mobile, Hg and Pb were observed, in the estuarine and mining areas, respectively. Sand, lime, and clay fractions of representative samples from Areas I, II, and III were used in a metal speciation study. Mainly, the elements analyzed had accumulated in the non-residual fractions. In the mining area of the Pyrite Belt, the elements analyzed are mainly bound to Fe–Mn oxides (Fe + Mn + Cu + Cr + Pb + Mn ± Zn) and the organic matter/sulfide fraction (Ni + Zn + Hg ± Cd), independent of sediment grain size. In conclusion, we show that the results of the study of chemical speciation in sediments from acid rivers are independent of the sediment grain size considered.  相似文献   

Geology of the southern Zambales Ophiolite Complex, Luzon, Philippines     

Graciano P. Yumul JR    Carla B. Dimalanta and  Ferdinand T. Jumawan 《Island Arc》2000,9(4):542-555

Abstract Field, geochemical and geophysical evidence show that the southern Zambales Ophiolite Complex attained its present-day configuration through the juxtapositioning of an arc terrane (San Antonio massif) to a back-arc crust (Cabangan massif). The San Antonio massif manifests island arc-related characteristics (i.e. spinel XCr [Cr/(Cr + Al)] >0.60; mostly plagioclase An92–95; pyroxene crystallizing ahead of plagioclase; orthopyroxene as an early, major crystallizing phase) which cannot be directly parental to the Cabangan massif transitional mid-ocean ridge basalt to island arc tholeiitic volcanic carapace. The two massifs are believed to be separated by a left-lateral strike–slip fault, the Subic Bay Fault Zone. Apart from the presence of highly sheared, allochthonous outcrops, the Subic Bay Fault Zone is generally defined by northwest–southeast trending magnetic and bouguer anomalies. The San Antonio massif was translated southward from the northern part of the Zambales Ophiolite Complex through the Subic Bay Fault Zone. This resulted into its suturing with the Cabangan massif and could have led to the formation of the present-day Subic Bay.  相似文献   

Sewage Sludge Activated Carbon as an Adsorbent and Catalytic Support: Evaluation of Nitrate Removal and Suzuki-Miyaura Cross-Coupling     

Clarissa H. Rosa  Cristiane R. Schmitt  Cecilia S. Fonseca  João Henrique Z. dos Santos  Toni J. Lopes  Gilber R. Rosa 《洁净——土壤、空气、水》2023,51(1):2100399

  相似文献   

Observations of near-inertial oscillations along the Brazilian continental shelf break     

de Freitas  Pedro Paulo  Amorim  Felipe de Luca Lopes  Mill  Guilherme Nogueira  da Costa  Vladimir Santos  Gabioux  Mariela  Cirano  Mauro  Paiva  Afonso de Moraes 《Ocean Dynamics》2019,69(10):1203-1215

Ocean Dynamics - Near-inertial oscillations (NIO) are intermittent motions with a frequency close to the inertial frequency and represent an important fraction of the energy to the currents in the...  相似文献   

Possibilities of discriminating tropical secondary succession in Amazônia using hyperspectral and multiangular CHRIS/PROBA data     

Lênio Soares Galvão  Flávio Jorge PonzoniVeraldo Liesenberg  João Roberto dos Santos 《International Journal of Applied Earth Observation and Geoinformation》2009

CHRIS/PROBA data collected in the Brazilian Amazônia in 4 view angles (−36°, nadir, +36°, +55°) and 62 bands (410–1000 nm range) were evaluated for the discrimination between primary forest and 3 stages of secondary succession after deforestation: initial (SS1; <5 years), intermediate (SS2; 5–15 years) and advanced (SS3; >15 years). Single view angle and multiangular approaches (nadir plus anisotropic information derived from reflectance ratios between view angles) were tested for discrimination. Both approaches used principal components analysis (PCA) applied to pixel spectra representative of each class in order to reduce data dimensionality at each dataset, to enhance separability between the classes, and to provide input variables for multiple discriminant analysis (MDA). The results showed that the off-nadir viewing improved discrimination between the successional stages. Discrimination between SS2 and SS3 was enhanced with PCA at +36° view angle. Primary forest and SS3 presented a more anisotropic behavior than SS2 and SS1, especially in the backward scattering direction (positive view angles) in which great amounts of sunlit canopy components were viewed by the sensor. MDA classification results showed that the multiangular approach produced an overall improvement in the discrimination. From the single (nadir) to the multiangular approach, classification accuracy using a separate set of pixels increased from 83.3% to 98.3% for SS1, 53.3% to 70.0% for SS2, and 58.3% to 76.7% for SS3. The nadir and multiangular classifications were statistically different at a 0.05% level of significance. Kappa statistics increased from 0.63 to 0.82. The results showed that multiangular data can improve the differentiation between primary forest and old stages of natural vegetation regrowth, which have been reported in the literature as the most difficult classes to be mapped in the Amazonian environment.  相似文献   

Spatio-temporal structure of diatom assemblages in a temperate estuary. A STATICO analysis     

Susana Mendes  Ma Jos Fernndez-Gmez  Paula Resende  Mrio Jorge Pereira  Ma Purificacin Galindo-Villardn  Ulisses Miranda Azeiteiro 《Estuarine, Coastal and Shelf Science》2009,84(4):637-644

This study examines the spatio-temporal structure of diatom assemblages in a temperate estuary (Ria de Aveiro, Western Portugal). Eighteen monthly surveys were conducted, from January 2002 to June 2003, at three sampling sites (at both high and low tide) along the estuarine salinity gradient. The relationship of diatom assemblages and environmental variables was analysed using the STATICO method, which has been designed for the simultaneous analysis of paired ecological tables. This method allowed examination of the stable part of the environment-diatom relationship, and also the variations of this relationship through time. The interstructure factor map showed that the relationship between the 11 environmental variables and the abundance of the 231 diatom species considered was strongest in the months May and September 2002 and January, February and May 2003. The stable part of the species–environment relationships mainly consisted of a combined phosphate, chlorophyll a and salinity gradient linked to a freshwater-marine species gradient. A more pronounced gradient was observed in January, February and May 2003. Diatom assemblages showed clear longitudinal patterns due to the presence of both marine and freshwater components. May and September 2002 had the least structured gradients with marine-estuarine species appearing in the freshwater side of the gradient. The most complete gradient in February 2003 could be considered, in terms of bio-ecological categories, as the most structured period of the year, with a combination of strong marine influence in the lower zone and freshwater influence in the upper. The best-structured gradients were during periods of a diatom bloom. Stable diatom assemblages (with a strong structure and a good fit between the diatoms and environment) are described and characterized. This study shows the efficiency of the STATICO analysis. The inclusion of space-time data analysis tools in ecological studies may therefore improve the knowledge of the dynamics of species–environmental assemblages.  相似文献