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31.
Trace elements contamination of agricultural soils affected by sulphide exploitation (Iberian Pyrite Belt,Sw Spain) 总被引:1,自引:0,他引:1
Agricultural soils of the Riotinto mining area (Iberian Pyrite Belt) have been studied to assess the degree of pollution by
trace elements as a consequence of the extraction and treatment of sulphides. Fifteen soil samples were collected and analysed
by ICP-OES and INAA for 51 elements. Chemical analyses showed an As–Cu–Pb–Zn association related with the mineralisation of
the Iberian Pyrite Belt. Concentrations were 19–994 mg kg−1 for As, 41–4,890 mg kg−1 for Pb, 95–897 mg kg−1 for Zn and of 27–1,160 mg kg−1 for Cu. Most of the samples displayed concentrations of these elements higher than the 90th percentile of the corresponding
geological dominium, which suggests an anthropogenic input besides the bedrock influence. Samples collected from sediments
were more contaminated than leptosols because they were polluted by leachates or by mining spills coming from the waste rock
piles. The weathering of the bedrock is responsible for high concentrations in Co, Cr and Ni, but an anthropogenic input,
such as wind-blown dust, seems to be indicative of the high content of As, Cu, Pb and Zn in leptosols. The metal partitioning
patterns show that most trace elements are associated with Fe amorphous oxy-hydroxides, or take part of the residual fraction.
According to the results obtained, the following mobility sequence is proposed for major and minor elements: Mn, Pb, Cd, > Zn,
Cu > Ni > As > Fe > Cr. The high mobility of Pb, Cu and Zn involve an environmental risk in this area, even in soils where
the concentrations are not so high. 相似文献
32.
Heavy metals in sediments of the Tecate River, Mexico 总被引:1,自引:0,他引:1
F. T. Wakida D. Lara-Ruiz J. Temores-Peña J. G. Rodriguez-Ventura C. Diaz E. Garcia-Flores 《Environmental Geology》2008,54(3):637-642
Ten sites along the Tecate River, Mexico were sampled to evaluate the cadmium, lead, nickel and chromium concentrations in
sediments. The result shows contamination for cadmium in most of the sites, where two sites were class 4 (polluted to strongly
polluted) according to geoaccumulation index proposed by Muller. Two sites were found polluted for all the heavy metals analyzed
(Cr, Cd, Pb and Ni), indicating the effect of anthropogenic activities. A correlation between Ni and Cd concentration had
been found indicating a common source. These metals are usually used in electroplating industry. The results of this study
can be used for decision makers to prioritize measures to control the pollution for these metals. 相似文献
33.
Quick-look assessments to identify optimal CO2 EOR storage sites 总被引:1,自引:0,他引:1
Vanessa Núñez-López Mark H. Holtz Derek J. Wood William A. Ambrose Susan D. Hovorka 《Environmental Geology》2008,54(8):1695-1706
A newly developed, multistage quick-look methodology allows for the efficient screening of an unmanageably large number of
reservoirs to generate a workable set of sites that closely match the requirements for optimal CO2 enhanced oil recovery (EOR) storage. The objective of the study is to quickly identify miscible CO2 EOR candidates in areas that contain thousands of reservoirs and to estimate additional oil recovery and sequestration capacities
of selected top options through dimensionless modeling and reservoir characterization. Quick-look assessments indicate that
the CO2 EOR resource potential along the US Gulf Coast is 4.7 billion barrels, and CO2 sequestration capacity is 2.6 billion metric tons. In the first stage, oil reservoirs are screened and ranked in terms of
technical and practical feasibility for miscible CO2 EOR. The second stage provides quick estimates of CO2 EOR potential and sequestration capacities. In the third stage, a dimensionless group model is applied to a selected set
of sites to improve the estimates of oil recovery and storage potential using appropriate inputs for rock and fluid properties,
disregarding reservoir architecture and sweep design. The fourth stage validates and refines the results by simulating flow
in a model that describes the internal architecture and fluid distribution in the reservoir. The stated approach both saves
time and allows more resources to be applied to the best candidate sites. 相似文献
34.
The Cu–Co–Ni Texeo mine has been the most important source of Cu in NW Spain since Roman times and now, approximately 40,000 m3 of wastes from mine and metallurgical operations, containing average concentrations of 9,263 mg kg−1 Cu, 1,100 mg kg−1 As, 549 mg kg−1 Co, and 840 mg kg−1 Ni, remain on-site. Since the cessation of the activity, the abandoned works, facilities and waste piles have been posing
a threat to the environment, derived from the release of toxic elements. In order to assess the potential environmental pollution
caused by the mining operations, a sequential sampling strategy was undertaken in wastes, soil, surface and groundwater, and
sediments. First, screening field tools were used to identify hotspots, before defining formal sampling strategies; so, in
the areas where anomalies were detected in a first sampling stage, a second detailed sampling campaign was undertaken. Metal
concentrations in the soils are highly above the local background, reaching up to 9,921 mg kg−1 Cu, 1,373 mg kg−1 As, 685 mg kg−1 Co, and 1,040 mg kg−1 Ni, among others. Copper concentrations downstream of the mine works reach values up to 1,869 μg l−1 and 240 mg kg−1 in surface water and stream sediments, respectively. Computer-based risk assessment for the site gives a carcinogenic risk
associated with the presence of As in surface waters and soils, and a health risk for long exposures; so, trigger levels of
these elements are high enough to warrant further investigation. 相似文献
35.
M. M. Jordán S. Pina F. García-Orenes M. B. Almendro-Candel E. García-Sánchez 《Environmental Geology》2008,55(2):453-462
The ecologic restoration criteria in areas degraded from extraction activities require making use of their mine spoils. These
materials do not meet fertility conditions to guarantee restoration success and therefore, need the incorporation of organic
amendments to obtain efficient substratum. Reducing the deficiencies in the organic material and restoration material nutrients
with the contribution of treated sewage sludge is proposed in this work. This experiment was based on a controlled study using
columns. The work was conducted with two mine spoils, both very rich in calcium carbonate. The first mineral, of poor quality,
came from the formation of aggregates of crushed limestone (Z). The other residual material examined originated in limestone extraction, formed by the levels of interspersed non-limestone
materials and the remains of stripped soils (D). Two treatments were undertaken (30,000 and 90,000 kg/ha of sewage sludge), in addition to a control treatment. The water
contribution was carried out with a device that simulated either short-duration rain or a flooding irrigation system in order
to cover the surface and then percolate through the soil. The collection of leached water took place 24 h after the applications.
Different parameters of the leached water were determined, including pH, electrical conductivity, nitrate anions, ammonium,
phosphates, sulphates and chlorides. The values obtained for each irrigation application are discussed, and the nitrate values
obtained were very elevated. 相似文献
36.
Flood hazard delineation combining geomorphological and hydrological methods: an example in the Northern Iberian Peninsula 总被引:2,自引:1,他引:1
Flood mapping requires the combination and integration of geomorphological and hydrological-hydraulic methods; however, despite
this, there is very little scientific literature that compares and validates both methods. Two types of analysis are addressed
in the present article. On the one hand, maps of flood plains have been elaborated using geomorphological evidence and historical
flood data in the mountainous area of northwestern Spain, covering an area of more then 232 km2 of floodplains. On the other hand, a hydrometeorological model has been developed (Clark semidistributed unit hydrograph)
in the Sarria River basin (155 km2, NW Spain). This basin is not gauged, hence the model was subjected to a goodness-of-fit test of its parameter (curve number)
by means of Monte Carlo simulation. The peak flows obtained by means of the hydrological model were used for hydraulic modeling
(one-phase, one-dimensional and steady flow) in a 4 km2 urban stretch of the river bed. The delineation of surface areas affected by floods since 1918, as well as those analyzed
subsequent to the geomorphological study, reveals a high degree of reliability in the delineation of the flooded areas with
frequent recurrence intervals (<50 years). If we compare these flooded surface areas with the estimate obtained by the hydrological-hydraulic
method we can see that the latter method overestimates the extent of the surface water by 144% for very frequent recurrence
intervals (>10 years) and underestimates it as the recurrence interval increases, by up to 80% less floodplain for exceptional
events (>500 years). Finally, a management map is put forth combining the most reliable results available by integrating both
methods.
Originally presented at the Sixth International Conference on Geomorphology. 相似文献
37.
Gravitational spreading of mountain ridges displays primary disequilibrium of flysch mountain areas of the Czech Carpathians.
The progression of various types of mass movements is a product of long-term ridge disintegration and is predisposed by the
geological structure of the area and the upper Tertiary-Quaternary morphogenesis of the mountain area. Deep-seated slope deformations
are spatially interconnected by the occurrence of some other types of slope deformations (e.g. debris flows, debris slides,
slumps, rock avalanches, etc.), which pose a considerable risk for the existence of human society. An important causative
factor in these dynamically developing hazardous processes is, among other factors, the way in which land has been used in
the last three centuries. Therefore, the occurrence of various types of slope deformations is studied in terms of their relation
to deep-seated gravitational deformations and in terms of other limiting factors (structural geological, morphological and
climatic factors, manmade impacts, etc.). The paper presents several case studies of slope deformations (Velká Čantoryje Mt,
Lysá hora Mt, Ropice Mt and Smrk Mt) in the area of the Outer Carpathians within the territory of the Czech Republic and also
adverts to some consequences in terms of the socioeconomic structure of the landscape. 相似文献
38.
Vittorio Zanon Fátima Viveiros Catarina Silva Ana Rita Hipólito Teresa Ferreira 《Natural Hazards》2008,45(1):19-31
A detailed study was carried out on a piece of land that had been struck by lightning during the violent rainstorm that raged
over the Island of S?o Miguel (Azores Archipelago) in late October 2006. Temperature and gas measurements (CO2, CO, H2S and CH4) were performed in four study trenches, dug in an area of ∼3 m2, where an underground fire had been initiated by the impact with a lightning stroke, followed by the emission of a column
of gases and smoke. The soil under study was originally a well-pedogenized about 80 cm thick bed, made of volcanic clayey
to silty tephra fallouts and contained 5.5–9.7% of organic matter. The underground fire was monitored for one week and revealed a peak release of
404 ppm CO and 3.4% CO2 originating from a horizon located about 45 cm under the soil surface. Measurements of temperature, performed one week after
the impact, indicated a maximum value of 326°C inside the soil, while 516.5°C were measured on the surface of a lava block
interred about 20 cm under the surface. Subsequently, a stratigraphic and sedimentologic study proved the role of the grain-size
of the soil and of the organic matter content of the different horizons of the impact area, in determining the ratio between
anoxic/oxidised combustion conditions and in the progress of the process itself. It was also noticed that combustion was not
total all over in the soil bed and that the process had slightly migrated toward SW during the observation period. The combustion
process went on for about ten days, in spite of several other violent rainstorms, until it was artificially extinguished through
the excavations made to obtain study trenches. This particular circumstance evidenced the potential natural hazard represented
by this kind of atmospheric event, especially in a land where the volcanic nature of the soil may easily mislead inexperienced
observers and, consequently, delay proper action. 相似文献
39.
Biaxial test simulations using a packing of polygonal particles 总被引:1,自引:0,他引:1
The mechanical response of cohesionless granular materials under monotonic loading is studied by performing molecular dynamic simulations. The diversity of shapes of soil grains is modelled by using randomly generated convex polygons as granular particles. Results of the biaxial test obtained for dense and loose media show that samples achieve the same void ratio at large strains independent of their initial density state. This limit state resembles the so‐called critical state of soil mechanics, except for some stress fluctuations, which remain for large deformations. These fluctuations are studied at the micro‐mechanical level, by following the evolution of the co‐ordination number, force chains and the fraction of the sliding contacts of the sample. Copyright © 2007 John Wiley & Sons, Ltd. 相似文献
40.
Summary The Aguablanca Ni-Cu-(PGE) magmatic sulphide deposit is associated with a magmatic breccia located in the northern part of
the Aguablanca gabbro (SW, Iberia). Three types of ores are present: semi-massive, disseminated, and chalcopyrite-rich veined
ore. The principal ore minerals are pyrrhotite, pentlandite and chalcopyrite. A relatively abundant platinum-group mineral
(PGM) assemblage is present and includes merenskyite, melonite, michenerite, moncheite and sperrylite. Moreover, concentrations
of base and precious metals and micro-PIXE analyses were obtained for the three ore-types. The mineralogy and the mantle-normalised
chalcophile element profiles strongly suggest that semi-massive ore represents mss crystallisation, whereas the disseminated ore represents an unfractionated sulphide liquid and the chalcopyrite-rich veined
ore a Cu-rich sulphide liquid. Palladium-bearing minerals occur commonly enclosed within sulphides, indicating a magmatic
origin rather than hydrothermal. The occurrences and the composition of these minerals suggest that Pd was initially dissolved
in the sulphides and subsequently exsolved at low temperatures to form bismutotellurides. Negative Pt and Au anomalies in
the mantle-normalised chalcophile element profiles, a lack of Cu-S correlation and textural observations (such as sperrylite
losing its euhedral shape when in contact with altered minerals) suggest partial remobilisation of Pt, Au and Cu by postmagmatic
hydrothermal fluids after the sulphide crystallisation.
Authors’ addresses: R. Pi?a, L. Ortega, R. Lunar, Departamento de Cristalografía y Mineralogía, Facultad de Geología, Universidad Complutense de Madrid, ES-28040 Madrid,
Spain; F. Gervilla, Facultad de Ciencias, Instituto Andaluz de Ciencias de la Tierra, Universidad de Granada-CSIC, Avda. Fuentenueva, s/n, ES-18002
Granada, Spain 相似文献