Retention of arsenic and phosphorus in iron-rich concretions of Tagus salt marshes   总被引：1，自引：0，他引：1  

Miguel Caetano  Carlos Vale 《Marine Chemistry》2002,79(3-4)

Iron-rich concretions are frequently found around plant roots in Tagus estuary (Portugal) where radial delivery of O₂ takes place. Salt marsh sediments exhibit cracks that are an additional feature to introduce O₂ and other solutes in the upper sediments. Metal concentrations in salt marsh sediments are clearly above the background levels reflecting the anthropogenic sources from a large city with 2.5 million inhabitants, and several industrial centres. In order to evaluate how both oxidised structures influences the redistribution of redox sensitive elements in salt marsh sediments, concretions were collected from roots of Halimione portucaloides below the oxygenated zone. These tubular cylindrical structures were analysed for Fe, Al, Mn, As, and P along 1-cm radial transect in a millimetre scale from the inner part to the adjacent anoxic sediment. In addition, oxidised cracks were analysed for the same spatial resolution, from the sediment–water interface to anoxic layers (2-cm transept). The parallelism between Fe, As, and P concentrations at this microscale is the most noticeable aspect. Iron and As presented very high concentrations in the 4-mm concretions (3.4 mmol g⁻¹ and 3.1 μmol g⁻¹, respectively) and decreased sharply to the host sediment. Oxygen released from roots oxidise the solid sulphides, and the reduced Fe and As are transported towards the root by both diffusion and pore water flow associated with the root water uptake. Subsequently, Fe(III) precipitates and As is retained by sorption and/or coprecipitation. These elements are also enriched in the first 2-mm of oxidised cracks, but in lower concentrations (50% and 30%, respectively). Manganese concentrations in concretions were low (11.8 μmol g⁻¹), indicating that Fe dominates the sediment chemistry. Phosphorus and iron concentrations in the ascorbate fraction were higher in the oxidising surfaces of concretions (10.7 μmol g⁻¹ and 1.6 mmol g⁻¹, respectively) and of cracks (5.1 μmol g⁻¹ and 0.47 mmol g⁻¹). The parallelism of Fe and As distributions includes not only their similar redox chemistries, but also that to phosphate, including control by coprecipitation of the host iron phases. The mechanisms involved in the mobilisation of As and P are however different, whereas As comes from the oxidation of iron sulphides; dissolved P derives from reduction of ferri-hydroxide phases.  相似文献   

Contribution of artificial reefs to the diet of the white sea bream (Diplodus sargus)   总被引：1，自引：0，他引：1  

Leitao  Francisco; Santos  Miguel N.; Monteiro  Carlos C. 《ICES Journal of Marine Science》2007,64(3):473-478

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The Effect of Human Exclusion on the Population Structure of Key-Hole Limpets Fissurella crassa and F. limbata on the Coast of Central Chile     

Doris  Oliva Juan Carlos  Castilla 《Marine Ecology》1986,7(3):201-217

Abstract. We describe the basic ecology of two key-hole limpets, Fissurella crassa and Fissurella limbata , which are heavily harvested by coastal shellfishermen (mariscadores) at the rocky intertidal of central Chile. The ecological role of human predation on these species was assessed. Anthropic exclusion from a stretch of the rocky intertidal at Las Cruces (non-harvested area) for about two and a half years resulted in changes of the densities and size distributions of these fissurelid species as compared to populations in control zones (harvested area). Differential human predation generates, on key-hole limpets, responses of different intensities related to the accessibility of man to the mesohabitats (sheltered platforms, exposed platforms and vertical walls) and fringes of the intertidal (mid-low intertidal and Lessonia nigrescens fringe). Thus, size distributions and mean densities of both fissurelids differ widely between the harvested and non-harvested areas on both platform habitats but not on vertical walls. In the mid-low intertidal fringe, differences are greater than in the less accessible L. nigrescens intertidal fringe. Moreover, we discuss the way in which other species, directly harvested by mariscadores (i. e., the mollusc Concholepas concholepas) can affect the keyhole limpet populations of central Chile rocky shores. Finally, we highlight the ecological role of these limpets on the dynamics of intertidal ecosystems and how they can modify community landscape.  相似文献   

Presence of Hippidion at two sites of western Argentina: Diet composition and contribution to the study of the extinction of Pleistocene megafauna     

Alejandro García  Eduardo Martínez Carretero  María A. Dacar   《Quaternary International》2008,180(1):22

The composition of Hippidion diet, and possible changes that could relate to its extinction, were evaluated in the Argentinean-Chilean Central Andes, a Neotropical environment characterized by arid to semiarid conditions (Andean hot and cold deserts). Microhistological analyses were made on feces of Hippidion found at Los Morrillos (31°43′S–68°42′W, 3000 m a.s.l.) and Gruta del Indio (34°35′S, 68°22′W, 660 m a.s.l.). At Gruta del Indio the diet of Hippidion was based mainly on woody species. At Los Morrillos, it was based on herbaceous species.This flexibility in diet composition could be a relative adaptive advantage allowing a longer permanence of this species in comparison to others recorded in the region (such as Megatheriumand Mylodon). Nevertheless, this advantage was not enough to guarantee its survival during the Holocene. Extinction could have been affected by diverse agents, such as growing aridification of the area, increasing competition with other species (mainly Lama guanicoe), and human presence, along with a relatively low population density (as expected from the limited presence of Hippidion at the archaeological and palaeontological sites of South America. At Gruta del Indio significant changes in the diet of Hippidion corresponding to different intervals of the period 31,000–9000 ¹⁴C BP are not evident. Given this evidence for similar diets for Hippidion throughout the late Quaternary, other factors need to be considered to explain the extinction of this horse.  相似文献   

Zoogeographical affinities and the use of vertebrates in Xochicalco (Morelos, Mexico)     

Eduardo Corona-M.   《Quaternary International》2008,180(1):145

Xochicalco is a Mesoamerican locality that developed after the fall of Teotihuacan, and became one of the most important urban, ceremonial and military communities of its time. Chronologically, it is situated in the Epiclassic period (700–900 A.D.) and its buildings show a marked hierarchical distribution. The site is located in the current State of Morelos (Mexico), embedded in the Mexican Transition Zone between the two major American zoogeographic regions: Nearctic and Neotropic. The animal remains identified show a mixed assemblage from both regions. With the aim of exploring the relationship between the zoogeographical affinities of identified fauna and differential uses due to the hierarchical distribution of the site, the data were processed using two multivariate analyses in order to find the animals that characterize each social level. This comparison shows that some animals are common to all the social levels, suggesting easy availability, while a few others, mainly from the Neotropic area, were associated only with the elite places suggesting their quality as social markers. This approach offers an initial hypothesis about the different cultural attitudes toward the animals in a Mesoamerican locality, little studied, showing a positive relationship between the zoogeographic affinity and the social hierarchy.  相似文献   

Estimates of heat flow and heat production and a thermal model of the São Francisco craton     

Carlos H. Alexandrino  Valiya M. Hamza 《International Journal of Earth Sciences》2008,97(2):289-306

An updated analysis of geothermal data from the highland area of eastern Brazil has been carried out and the characteristics of regional variations in geothermal gradients and heat flow examined. The database employed includes results of geothermal measurements at 45 localities. The results indicate that the Salvador craton and the adjacent metamorphic fold belts northeastern parts of the study area are characterized by geothermal gradients in the range of 6–17°C/km. The estimated heat flow values fall in the range of 28–53 mW/m², with low values in the cratonic area relative to the fold belts. On the other hand, the São Francisco craton and the intracratonic São Francisco sedimentary basin in the southwestern parts are characterized by relatively higher gradient values, in the range of 14–42°C/km, with the corresponding heat flow values falling in the range of 36–89 mW/m². Maps of regional variations indicate that high heat flow anomaly in the São Francisco craton is limited to areas of sedimentary cover, to the west of the Espinhaço mountain belt. Crustal thermal models have been developed to examine the implications of the observed intracratonic variations in heat flow. The thermal models take into consideration variation of thermal conductivity with temperature as well as change of radiogenic heat generation with depth. Vertical distributions of seismic velocities were used in obtaining estimates of radiogenic heat production in crustal layers. Crustal temperatures are calculated based on a procedure that makes simultaneous use of the Kirchoff and Generalized Integral Transforms, providing thereby analytical solutions in 2D and 3D geometry. The results point to temperature variations of up to 300°C at the Moho depth, between the northern Salvador and southern São Francisco cratons. There are indications that differences in rheological properties, related to thermal field, are responsible for the contrasting styles of deformation patterns in the adjacent metamorphic fold belts.  相似文献   

Periodic orbits of an electric charge in a magnetic dipole field     

Lidia Jiménez-Lara  Eduardo Piña 《Celestial Mechanics and Dynamical Astronomy》1990,49(4):327-345

Periodic orbits in the Stormer problem are studied using the symmetry lines of the Poincaré map introduced by De Vogelaere. Many known facts are explained by mean of these lines. The dynamics of four special symmetry lines when the Stormer parameter ₁ changes is presented, and we obtain a clear global view of the structure of the simple periodic orbits and their bifurcations, including the asymmetrical ones. New asymmetrical multiple periodic orbits are obtained.  相似文献   

Eta carinae nebulosities in 1963     

Carlos Donzelli  J. L. Sérsic  Adela Abraham 《Astrophysics and Space Science》1990,174(2):285-289

The purpose of this note is to give further information regarding the positions of some condensations around Carinae in 1963, an epoch not yet considered in the literature. The new information is unable to confirm the deceleration hypothesis of theeir motion.  相似文献   

The behavior of trace elements during schwertmannite precipitation and subsequent transformation into goethite and jarosite   总被引：5，自引：0，他引：5  

Patricia Acero  Carlos Ayora  José-Miguel Nieto 《Geochimica et cosmochimica acta》2006,70(16):4130-4139

Schwertmannite is a ubiquitous mineral formed from acid rock drainage (ARD), and plays a major role in controlling the water chemistry of many acid streams. The formation of schwertmannite was investigated in the acid discharge of the Monte Romero abandoned mine (Iberian Pyrite Belt, SW, Spain). Schwertmannite precipitated from supersaturated solutions mainly owing to the oxidation of Fe(II) to Fe(III) and transformed with time into goethite and jarosite. In a few hours, schwertmannite precipitation removed more than half of the arsenic load from solution, whereas the concentration of divalent trace metals (Zn, Cu, Pb, Cd, Ni, and Co) remained almost unchanged. In the laboratory, natural schwertmannite was kept in contact with its coexisting acid water in a flask with a solid-liquid mass ratio of 1:5 for 353 days. During this time, the pH of the solution dropped from 3.07 to 1.74 and the concentrations of sulfate and Fe increased. During the first 164 days, schwertmannite transformed into goethite plus H₃O-jarosite but, subsequently, goethite was the only mineral to form. Some of the trace elements, such as Al, Cu, Pb, and As were depleted in solution during the first stage as schwertmannite transformed into goethite plus H₃O-jarosite. On the contrary, the transformation of schwertmannite to goethite (with no jarosite) during the second stage released Al, Cu, and As to the solution. Despite the variation in their concentrations in solution, approximately 80% of the total Al and Cu inventories and more than 99% As and Pb remained in the solid phase throughout the entire aging process.  相似文献   

The “El Pilote” fluorite skarn: A crucial deposit in the understanding and interpretation of the origin and mobilization of F from northern Mexico deposits     

Gilles Levresse  Jordi Tritlla  Janet Villareal  Eduardo Gonzalez-Partida 《Journal of Geochemical Exploration》2006,89(1-3):205

Fluorite deposits are widespread in northern Mexico and those deposits have traditionally been categorized as exclusively hydrothermal–magmatic in origin. Recently, two different fluorite-bearing type models have been proposed for the Northern Mexican deposits: (1) MVT-like deposits formed from basinal brines mobilized during the Laramide Orogeny (La Encantada deposit, Gonzalez-Partida et al., [Gonzalez-Partida, E., Carrillo-Chavez, A., Grimmer, J.O.W., Pironon, J., 2002. Petroleum-rich fluid inclusions in fluorite, Purisima mine, Coahuila, Mexico. International Geological Review 44 (8), 751–763.]; Tritlla et al., [Tritlla, J., Gonzalez-Partida, E., Levresse, G., Banks, D., Pironon, J., 2004. Fluorite deposits at Encantada-Buenavista, Mexico: products of Mississippi Valley type processes — a reply. Ore Geology Reviews 25, 329–332.]); and (2) fluorite-bearing skarns in close contact with rhyolite intrusives (Levinson, [Levinson, A.A., 1962. Beryllium–fluorine mineralization at Aguachile Mountain, Coahuila, Mexico. American Mineralogist 47, 67–75.]). The El Pilote fluorite deposit falls into the second category, and is the only known example of a magmatic-related fluorite deposit in the area. The fluorite trace-element patterns from both the El Pilote skarn and La Encantada MVT deposits display comparable and very low relative abundances as well as comparable chondrite-normalized REE patterns; this would suggest that the skarn F-source comes from the remobilization of a MVT fluorite manto.  相似文献