Weathering processes in waste materials from a mining area in a semiarid zone     

Cortes Navarro-Hervás  Carmen Pérez-Sirvent  María José Martínez-Sánchez  Mari Luz García-Lorenzo  José Molina 《Applied Geochemistry》2012

Chemical and mineralogical characterization of waste materials present in an abandoned Pb, Zn–Ag mining site (SE, Spain) was carried out. In unaltered rocks, the mineralogy is characterized by plagioclase, pyroxene, magnetite, ilmenite, amphibole, biotite and quartz. Trace-element contents of these samples represent unaltered values. In mine-waste materials, pH ranged from acidic to slightly acidic and trace-element content was generally high, especially for Pb and Zn, although there were also substantial As concentrations. X-ray diffraction results suggested that these samples have a complex mineralogy, including alteration products. Surficial materials in the study area were affected by weathering processes, generating supergene assemblages, including Fe and Mn oxides and hydroxides, carbonates, hydrated sulfates and jarosite. Knowledge of the geochemical processes that took place in the past and which are still taking place provide an important tool for assessing associated environmental problems in this area.  相似文献   

Review of the El Soplao Amber Outcrop,Early Cretaceous of Cantabria,Spain     

María NAJARRO  Enrique PE?ALVER  Ricardo PéREZ-DE LA FUENTE  Jaime ORTEGA-BLANCO  Cesar MENOR-SALVáN  Eduardo BARRóN  Carmen SORIANO  Idoia ROSALES  Rafael LóPEZ DEL VALLE  Francisco VELASCO  Fernando TORNOS  Véronique DAVIERO-GOMEZ  Bernard GOMEZ  Xavier DELCLòS 《《地质学报》英文版》2010,84(4):959-976

<正>El Soplao outcrop,an Early Cretaceous amber deposit recently discovered in northern Spain (Cantabria),has been shown to be the largest site of amber with arthropod inclusions that has been found in Spain so far.Relevant data provided herein for biogeochemistry of the amber,palynology,taphonomy and arthropod bioinclusions complement those previously published.This set of data suggests at least two botanical sources for the amber of El Soplao deposit.The first(type A amber)strongly supports a source related to Cheirolepidiaceae,and the second(type B amber)shows non-specific conifer biomarkers.Comparison of molecular composition of type A amber with Frenelopsis leaves(Cheirolepidiaceae)strongly suggests a biochemical affinity and a common botanical origin.A preliminary palynological study indicates a regional high taxonomical diversity,mainly of pteridophyte spores and gymnosperm pollen grains.According to the preliminary palynological data,the region was inhabited by conifer forests adapted to a dry season under a subtropical climate.The abundant charcoalified wood associated with the amber in the same beds is evidence of paleofires that most likely promoted both the resin production and an intensive erosion of the litter,and subsequent great accumulation of amber plus plant cuticles.In addition,for the first time in the fossil record, charcoalified plant fibers as bioinclusions in amber are reported.Other relevant taphonomic data are the exceptional presence of serpulids and bryozoans on the surfaces of some amber pieces indicating both a long exposure on marine or brackish-water and a mixed assemblage of amber.Lastly,new findings of insect bioinclusions,some of them uncommon in the fossil record or showing remarkable adaptations,are reported.In conclusion,a documented scenario for the origin of the El Soplao amber outcrop is provided.  相似文献   

Selenium and iodine anomalies in soils and health     

Jaume Bech  Elena Korobova  Carmen Pérez-Sirvent 《Journal of Geochemical Exploration》2010

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The tropical storm Noel and its effects on the territory of the Dominican Republic     

Michela Izzo  Pietro Patrizio Ciro Aucelli  Yudith Javier  Caridad Pérez  Carmen Maria Rosskopf 《Natural Hazards》2010,53(1):139-158

In the period between the end of October and the beginning of November 2007, the Dominican Republic was hit by the tropical storm Noel, then turned into hurricane in its movement toward the Californian coasts. The passage of Noel was accompanied by huge precipitation especially in the south-western part of the country. In some areas, the rainfall registered in 6 days exceeded 700 mm, i.e., more than two-thirds of the mean annual precipitation. The return periods calculated for this rainfall event vary greatly from region to region: while they locally reach 200 years, such as in San José de Ocoa (50 km west of Santo Domingo), in other areas, as for instance in the territory of the capital Santo Domingo, return periods do not exceed 20 years. The tropical storm caused huge damage both in terms of human victims and economic losses, related to diffused inundations and landslide phenomena, which may be attributed only partially to the exceptionality of the event. As a matter of fact, in many regions, the inadequate answer of the territory—widely characterized by serious problems of land degradation and an almost complete lack of territorial planning—appears to be the major responsible for the occurred negative effects. The impact assessment, based on the calculation of an Impact Index, confirms this statement.  相似文献   

Patterns of Ca/Sr and Sr/Sr variation before and after a whole watershed CaSiO₃ addition at the Hubbard Brook Experimental Forest, USA     

Carmen A. Nezat  Joel D. Blum  Charles T. Driscoll 《Geochimica et cosmochimica acta》2010,74(11):3129-7046

Forty-one metric tons of the mineral wollastonite (CaSiO₃) was applied to an 11.8 hectare watershed at the Hubbard Brook Experimental Forest (HBEF; White Mountains, New Hampshire, USA) with the goal of restoring the Ca estimated to have been depleted from the soil exchange complex by acid deposition. This experiment provided an opportunity to gain qualitative information on whole watershed hydrologic flow paths by studying the response of stream water chemistry to the addition of Ca. Because the Ca/Sr and ⁸⁷Sr/⁸⁶Sr ratios of wollastonite strongly contrast that of other Ca sources in the watershed, the wollastonite-derived Ca can be identified and its amount estimated in various ecosystem components. Stream water chemistry at the HBEF varies seasonally due to shifts in the proportion of base flow and interflow. Prior to the wollastonite application, seasonal variations in ⁸⁷Sr/⁸⁶Sr ratios indicated that ⁸⁷Sr/⁸⁶Sr was higher during base flow than interflow, due largely to greater amounts of biotite weathering along deeper flow paths. After the application, Ca/Sr and ⁸⁷Sr/⁸⁶Sr changed markedly as the high Ca/Sr and low ⁸⁷Sr/⁸⁶Sr wollastonite dissolved and mixed with stream water. The Ca addition provided information on the response times of various flow paths and ion exchange processes to Ca addition in this small upland watershed. During the first year after the addition, wollastonite applied to the near stream zone dissolved and was partially immobilized by cation exchange sites in the hyporheic zone. In the second and third years after the addition we infer that much of this Ca and Sr was subsequently desorbed from the hyporheic zone and was exported from the watershed in stream flow. In the fourth through ninth years after the addition, Ca and Sr from wollastonite that had dissolved in upland soils was transported to the stream by interflow during wet periods when the ground water table was elevated. Between years three and nine the minimum annual Ca/Sr ratio (in late summer base flow) increased, providing evidence that Ca and Sr had increasingly infiltrated to the deepest flow paths. Strong seasonal variations in Ca/Sr and ⁸⁷Sr/⁸⁶Sr ratios of stream water resulted from the wollastonite addition to upland forest soils, and these ratios have become sensitive to changing flow paths during the annual cycle. Most notably, high flow events now produce large excursions in stream geochemistry toward the high Ca/Sr and low ⁸⁷Sr/⁸⁶Sr ratios of wollastonite. Nine years after the application we estimate that ∼360 kg of Ca from wollastonite has been exported from the watershed in stream flow. The rate of export of Ca from wollastonite dissolution has stabilized at about 11 kg of Ca per year, which accounts for ∼30% of the dissolved Ca in the stream water. Given that 19 metric tons of Ca were applied to the watershed, and assuming this current rate of loss, it should take over 1000 years for this added Ca to be transported from the watershed.  相似文献   

Evidence of a partial melt zone beneath Stromboli volcano (Italy) from inversion of teleseismic receiver functions     

Carmen Martinez-Arevalo  Carla Musumeci  Domenico Patanè 《地学学报》2009,21(5):386-392

Teleseismic body waves from broadband seismic stations are used to investigate the crustal and uppermost mantle structure of Stromboli volcano through inversion of the receiver functions (RFs). First, we computed RFs in the frequency domain using a multiple-taper spectral correlation technique. Then, the non-linear neighbourhood algorithm was applied to estimate the seismic shear wave velocity of the crust and uppermost mantle and to define the main seismic velocity discontinuities. The stability of the inversion solution was tested using a range of initial random seeds and model parameterizations. A shallow Moho, present at depth of 14.8 km, is evidence of a thinned crust beneath Stromboli volcano. However, the most intriguing and innovative result is a low S velocity layer in the uppermost mantle, below 32 km. The low S velocity layer suggests a possible partial melt region associated with the volcanism, as also recently supported by tomographic studies and petrological estimations.  相似文献   

Impact of climate variability on summer fires in a Mediterranean environment (northeastern Iberian Peninsula)     

Marco Turco  Maria Carmen Llasat  Jost von Hardenberg  Antonello Provenzale 《Climatic change》2013,116(3-4):665-678

We analyse the impact of climate interannual variability on summer forest fires in Catalonia (northeastern Iberian Peninsula). The study period covers 25 years, from 1983 to 2007. During this period more than 16000 fire events were recorded and the total burned area was more than 240 kha, i.e. around 7.5% of whole Catalonia. We show that the interannual variability of summer fires is significantly correlated with summer precipitation and summer maximum temperature. In addition, fires are significantly related to antecedent climate conditions, showing positive correlation with lagged precipitation and negative correlation with lagged temperatures, both with a time lag of two years, and negative correlation with the minimum temperature in the spring of the same year. The interaction between antecedent climate conditions and fire variability highlights the importance of climate not only in regulating fuel flammability, but also fuel structure. On the basis of these results, we discuss a simple regression model that explains up to 76% of the variance of the Burned Area and up to 91% of the variance of the number of fires. This simple regression model produces reliable out-of-sample predictions of the impact of climate variability on summer forest fires and it could be used to estimate fire response to different climate change scenarios, assuming that climate-vegetation-humans-fire interactions will not change significantly.  相似文献   

The Zoning of Semi-Enclosed Bodies of Water According to the Sediment Pollution: The Bay of Algeciras as a Case Example     

Elisa Rojo-Nieto  Carmen Garrido-Pérez  Giorgio Anfuso-Melfi  Francisco Lopez-Aguayo  Diego Sales-Marquez  Jose Antonio Perales-Vargas-Machuca 《Estuaries and Coasts》2011,34(6):1129-1139

This paper reports a study of the occurrence and levels of polycyclic aromatic hydrocarbons (PAHs) in a bay characterised by a chronic persistent impact. A total of 55 sediment samples were taken at different depths up to 111 m in two sampling campaigns. Chemical analyses were carried out by gas chromatography-mass spectroscopy. The results indicate that: (1) significant spatial variations exist, (2) levels of PAHs are related more strongly to the spatial distribution of sediments than to mineralogy/granulometry, (3) the sediments are slightly-to-moderately contaminated by PAHs, and (4) these PAHs derive from pyrolytic and petrogenic sources. Through use of an innovative data classification system (proposed according to depth and spatial location of sampling points), and using factorial and cluster techniques, five zones have been differentiated depending on the contamination level and source.  相似文献   

Hydrologic characteristics of Appalachian loose‐dumped spoil in the Cumberland Plateau of eastern Kentucky     

Timothy J. Taylor  Carmen T. Agouridis  Richard C. Warner  Christopher D. Barton  Patrick N. Angel 《水文研究》2009,23(23):3372-3381

Heavily compacted lands, typical of traditional surface mine reclamation techniques, have been shown to hinder tree growth, increase levels of flooding, and produce suboptimal water quality. Utilizing loose‐dumped spoil, in accordance with the Forestry Reclamation Approach (FRA), has demonstrated success with regards to promoting tree growth and survival; however, additional information is needed to assess the potential of FRA to ameliorate other environmental concerns related to water quantity. To better understand the hydrologic characteristics of loose‐dumped spoil, key hydrograph parameters (discharge volume, peak discharge, discharge duration, lag time, and response time) were monitored for three common spoil types: (1) predominately brown weathered sandstone, (2) predominately gray weathered sandstone, and (3) a mixture of both sandstones and shale. Although spoil types were found to differ hydrologically, these differences were relatively minor. Measured discharge volumes were low (averaging 12% of rainfall for all events and treatments), peak discharge rates were small (between 2·5 × 10^?5 and 3 × 10^?3 m³/s), and the duration of discharge was long (6 days on average). From a hydrologic perspective, the results of this study indicate that mine spoils need not be segregated for reclamation as long as the spoil is placed in accordance with the loose‐dumped techniques as outlined in the FRA. Copyright © 2009 John Wiley & Sons, Ltd.  相似文献   

Black shales and massive sulfide deposits: causal or casual relationships? Insights from Rammelsberg, Tharsis, and Draa Sfar     

Reinaldo S��ez  Carmen Moreno  Felipe Gonz��lez  Gabriel R. Almod��var 《Mineralium Deposita》2011,46(5-6):585-614

Black shales and massive sulfides represent reduced lithofacies that require isolation from oxic environments to be preserved. This, together with the sedimentary affinity of both lithofacies, can explain their common concurrence in the geologic record. The present study is based on the comparison of Rammelsberg in Germany, Tharsis in Spain, and Draa Sfar in Morocco, three massive sulfide deposits closely associated with black shales that are distributed along the European and North African Variscan orogen. The study entails geochemical, biostratigraphic, and stratigraphic analyses of the black shale sequences hosting the three deposits and mineralogical and textural analyses of the sulfides. All three deposits were formed in immature, tectonically unstable basins within an active continental margin or continental magmatic arc. Their stratigraphic records consist of a sequence of black shales enclosing massive sulfides and variable proportions of bimodal volcanic and subvolcanic rocks. The major differences among the three deposits concern the size, composition, and mineralogy. Regarding age, they are diachronous and younger southward: Rammelsberg is middle Eifelian, Tharsis latest Famennian, and Draa Sfar late Viséan. The study of redox conditions of the paleoenvironment using organic and inorganic proxies highlights similarities and significant differences among the three ore-hosting basins during massive sulfide and black shale deposition. The black shales generally display low C_org and high S_tot contents. At Rammelsberg, the S_tot/C_tot ratios provide values typical for normal Middle Devonian marine environments, which suggests that the original reactive organic C is now fixed in carbonates. At Tharsis, most of the samples have C_org >1 and S_tot/C_org values equivalent to those of Devonian?CCarboniferous normal marine sediments. However, some pyritic hanging-wall samples have C_org <1 and S_tot up to 5?wt.%, suggesting the epigenetic addition of HS^?. The S_tot/C_org ratio for the Draa Sfar samples resembles that of Middle Carboniferous normal marine environments. Geochemical inorganic proxies used to define the environmental conditions include the enrichment factors of U (U_EF) and Mo (Mo_EF) together with V/Cr and V/(V?+?Ni) ratios. Footwall shales at Filón Norte (Tharsis) show positive and eventually elevated U_EF and Mo_EF values, which suggests anoxic conditions, whereas at Rammelsberg and Draa Sfar oxic bottom water is indicated. The relations V/Cr and V/(V + Ni) in all three cases point to a redox boundary near the sediment?Cwater interface, although at Tharsis some samples indicate anoxic/euxinic conditions (i.e., V/(V + Ni) >0.9). Regarding the environmental conditions of the source areas, feldspar illitization and selective depletion in Na and Ca occurred at the three studies sites. Available sulfur isotopic data from the Rammelsberg and Tharsis sulfide ore indicate that biogenic reduction of marine sulfate was a major sulfur source during massive sulfide generation. Nevertheless, a hydrothermal sulfur source has also been detected. At Rammelsberg, this is indicated from the polymetallic sulfides that replace sedimentary and diagenetic pyrite. At Tharsis, the bacteriogenic sulfur signature is also restricted to sulfide with less evolved textures, whereas a hydrothermal source is more evident in sulfides showing evidence of recrystallization. Both geochemical and isotopic data suggest that the bacteriogenic reduction process was inhibited by rapid burial. The sedimentation rates calculated for Rammelsberg, Tharsis, and Draa Sfar were in the range 7?C13, 8?C14, and 19?C27?cm/ka, respectively. Continuous sedimentation of black shale favored the isolation of the massive sulfides and organic material from bottom waters and hence favored their preservation. Accordingly, the relationships between black shales and massive sulfides are considered to be casual. Nevertheless, the tectono-sedimentary evolution of each basin controlled the deposition of both black shales and massive sulfides and the parameters that favored their coeval deposition.  相似文献