Element partitioning between magnesium silicate perovskite and ferropericlase: New insights into bulk lower-mantle geochemistry     

Anne-Line Auzende  James Badro  Frederick J. Ryerson  Peter K. Weber  Stewart J. Fallon  Ahmed Addad  Julien Siebert  Guillaume Fiquet   《Earth and Planetary Science Letters》2008,269(1-2):164-174

In this study, we investigated iron–magnesium exchange and transition-metal trace-element partitioning between magnesium silicate perovskite (Mg,Fe)SiO₃ and ferropericlase (Mg,Fe)O synthetised under lower-mantle conditions (up to 115 GPa and 2200 K) in a laser-heated diamond anvil cell. Recovered samples were thinned to electron transparency by focused ion beam and characterized by analytical transmission electron microscopy (ATEM) and nanometer-scale secondary ion mass spectroscopy (nanoSIMS). Iron concentrations in both phases were obtained from X-ray energy dispersive spectroscopy measurements and nanoSIMS. Our results are the first to show that recently reported spin-state and phase transitions in the lower mantle directly affect the evolution of Fe–Mg exchange between both phases. Mg-perovskite becomes increasingly iron-depleted above 70–80 GPa possibly due to the high spin–low spin transition of iron in ferropericlase. Conversely, the perovskite to post-perovskite transition is accompanied by a strong iron enrichment of the silicate phase, ferropericlase remaining in the Fe-rich phase though. Nanoparticles of metallic iron were observed in the perovskite-bearing runs, suggesting the disproportionation of ferrous iron oxide, but were not observed when the post-perovskite phase was present. Implications on the oxidation state of the Earth and core segregation will be discussed. Transition trace-element (Ni, Mn) concentrations (determined with the nanoSIMS) show similar trends and could thus be used to trace the origin of diamonds generated at depth. This study provides new results likely to improve the geochemical and geophysical models of the Earth's deep interiors.  相似文献   

Diet of winter flounder in a New Jersey estuary: Ontogenetic change and spatial variation     

Linda L. Stehlik  Carol J. Meise 《Estuaries and Coasts》2000,23(3):381-391

Juvenile and adult winter flounder,Pseudopleuronectes americanus Walbaum (Pleuronectidae), from the Navesink River and Sandy Hook Bay, New Jersey, U.S., were examined for ontogenetic, seasonal, and spatial variation in dietary content. Fish (n=1291 non-empty) were placed by cluster analysis of dietary content into three size groups: 15–49, 50–299, and ≥300 mm total length. Clear ontogenetic patterns were revealed, in particular the disappearance of calanoid copepods from the diet as fish grew >50 mm and an increase in number of taxa in the diet with growth. Fish in size group 1 fed upon spionid polychaetes, the calanoid copepodEurytemora affinis, and ampeliscid amphipods. Fish in size group 2 added various species of polychaetes, amphipods, and siphons of the bivalveMya aremaria to their diets. Size group 2 was present during all months of the survey, but only minor seasonal differences in their diet were apparent. One obvious change was the increase in consumption of the shrimpCrangon septemspinosa in summer and fall. Size group 3 fish, collected mainly in fall, ate large volumes ofM. arenaria and glycerid polychaetes. Cluster analysis showed a largescale spatial pattern in diet among fish of size group 1, related to the presence ofE. affinis in winter flounder diets in the river and a marsh cove in the bay. Small-scale spatial differences in diets of fish in size group 2 were possibly related to prey distribution.  相似文献   

32P-postlabelling analysis of DNA adducts and EROD induction as biomarkers of genotoxin exposure in dab (Limanda limanda) from British coastal waters.     

B P Lyons  C Stewart  M F Kirby 《Marine environmental research》2000,50(1-5):575-579

Dab (Limanda limanda) were sampled from a number of polluted and unpolluted areas in British coastal waters. The 32P-postlabelling assay was used to analyse the level of aromatic/hydrophobic DNA adducts in pooled samples of liver tissue. The mean levels of DNA adducts detected from areas known to receive anthropogenic pollutants ranged from 4.0 to 26.8 adducts per 10(8) nucleotides, with all sites containing samples displaying DNA adduct profiles consisting of diagonal radioactive zones. In contrast no DNA adducts were detectable in samples from an unpolluted reference site. The ranking of polluted sites based on DNA adduct levels did not correspond with the ranking of sites based on sediment associated polycyclic aromatic hydrocarbon levels, highlighting the problem of linking the presence of contamination with detectable biological responses. No correlation could be found in this study between EROD activity and the level of DNA adducts.  相似文献   

Potential impacts from tephra fall to electric power systems: a review and mitigation strategies     

J. B. Wardman  T. M. Wilson  P. S. Bodger  J. W. Cole  C. Stewart 《Bulletin of Volcanology》2012,74(10):2221-2241

Modern society is highly dependent on a reliable electricity supply. During explosive volcanic eruptions, tephra contamination of power networks (systems) can compromise the reliability of supply. Outages can have significant cascading impacts for other critical infrastructure sectors and for society as a whole. This paper summarises known impacts to power systems following tephra falls since 1980. The main impacts are (1) supply outages from insulator flashover caused by tephra contamination, (2) disruption of generation facilities, (3) controlled outages during tephra cleaning, (4) abrasion and corrosion of exposed equipment and (5) line (conductor) breakage due to tephra loading. Of these impacts, insulator flashover is the most common disruption. The review highlights multiple instances of electric power systems exhibiting tolerance to tephra falls, suggesting that failure thresholds exist and should be identified to avoid future unplanned interruptions. To address this need, we have produced a fragility function that quantifies the likelihood of insulator flashover at different thicknesses of tephra. Finally, based on our review of case studies, potential mitigation strategies are summarised. Specifically, avoiding tephra-induced insulator flashover by cleaning key facilities such as generation sites and transmission and distribution substations is of critical importance in maintaining the integrity of an electric power system.  相似文献   

Seasonal and interannual variation of the phytoplankton and copepod dynamics in Liverpool Bay     

Naomi Greenwood  Rodney M. Forster  Veronique Créach  Suzanne J. Painting  Anna Dennis  Stewart J. Cutchey  Tiago Silva  David B. Sivyer  Tim Jickells 《Ocean Dynamics》2012,62(2):307-320

The seasonal and interannual variability in the phytoplankton community in Liverpool Bay between 2003 and 2009 has been examined using results from high frequency, in situ measurements combined with discrete samples collected at one location in the bay. The spring phytoplankton bloom (up to 29.4 mg chlorophyll m⁻³) is an annual feature at the study site and its timing may vary by up to 50 days between years. The variability in the underwater light climate and turbulent mixing are identified as key factors controlling the timing of phytoplankton blooms. Modelled average annual gross and net production are estimated to be 223 and 56 g C m⁻² year⁻¹, respectively. Light microscope counts showed that the phytoplankton community is dominated by diatoms, with dinoflagellates appearing annually for short periods of time between July and October. The zooplankton community at the study site is dominated by copepods and use of a fine mesh (80 μm) resulted in higher abundances of copepods determined (up to 2.5 × 10⁶ ind. m⁻²) than has previously reported for this location. There is a strong seasonal cycle in copepod biomass and copepods greater than 270 μm contribute less than 10% of the total biomass. Seasonal trends in copepod biomass lag those in the phytoplankton community with a delay of 3 to 4 months between the maximum phytoplankton biomass and the maximum copepod biomass. Grazing by copepods exceeds net primary production at the site and indicates that an additional advective supply of carbon is required to support the copepod community.  相似文献   

Seeing coal‐seam top ahead of the drill bit through seismic‐while‐drilling          下载免费PDF全文

Iain Mason  Stewart Greenhalgh  Shankar Subramaniyan 《Geophysical Prospecting》2015,63(1):166-182

Blast damage to the tops of coal seams due to incorrect blast standoff distances is a serious issue, costing the industry in Australia about one open‐cut mine for every ten operating mines. The current approach for mapping coal‐seam tops is through drilling and pierce‐point logging. To provide appropriate depth control with accuracy of ±0.2 m for blast hole drilling, it is typically necessary to drill deep reconnaissance boreholes on a 50 m x 50 m grid well in advance of overburden removal. Pierce‐point mapping is expensive and can be inaccurate, particularly when the seam is disturbed by rolls, faults, and other obstacles.Numerical modelling and prototype‐field testing are used in this paper to demonstrate the feasibility of two seismic‐while‐drilling‐based approaches for predicting the approach to the top of coal during blast hole drilling: (i) reverse “walk‐away” vertical seismic profiling recording, in which the drill bit vibration provides the source signal and the geophones are planted on the surface near the drill rig, and (ii) in‐seam seismic recording, in which channel waves, driven by the coupling to the coal of the seismic signal emitted by the approaching drill bit, are guided by the seam to geophones located within the seam in nearby or remote boreholes.  相似文献   

Crew variability in topographic surveys for monitoring wadeable streams: a case study from the Columbia River Basin          下载免费PDF全文

Sara Bangen  Joe Wheaton  Nicolaas Bouwes  Chris Jordan  Carol Volk  Michael B. Ward 《地球表面变化过程与地形》2014,39(15):2070-2086

Digital elevation models (DEMs) derived from ground‐based topographic surveys have become ubiquitous in the field of fluvial geomorphology. Their wide application in spatially explicit analysis includes hydraulic modeling, habitat modeling, and morphological sediment budgeting. However, there is a lack of understanding regarding the repeatability and precision of DEMs derived from ground‐based surveys conducted by different, and inherently subjective, observers. This is of particular concern when we consider the proportion of studies and monitoring programs that are implemented across multiple sites and over time by different observers. We used a case study from the Columbia Habitat Monitoring Program (CHaMP), where seven field crews sampled the same six sites, to quantify the magnitude and effect of observer variability on DEMs interpolated from total station surveys. We quantified the degree to which DEM‐derived metrics and measured geomorphic change were repeatable. Across all six sites, we found an average elevation standard deviation of 0.05 m among surveys, and a mean total range of 0.16 m. A variance partition between site, crew, and unexplained errors for several topographically derived metrics showed that crew variability never accounted for > 1.5% of the total variability. We calculated minor geomorphic changes at one site following a relatively dry flow year between 2012 and 2011. Calculated changes were minimal (unthresholded net changes ±1–3 cm) with six crews detecting an indeterminate sediment budget and one crew detecting a minor net erosional sediment budget. While crew variability does influence the quality of topographic surveys, this study highlights that when consistent surveying methods are employed, the data sets are still sufficient to support derivation of topographic metrics and conduct basic geomorphic change detection. Copyright © 2014 John Wiley & Sons, Ltd.  相似文献   

‘The global warming clock is ticking so see these places while you can’: Voyeuristic tourism and model environmental citizens on Tuvalu's disappearing islands     

Carol Farbotko 《Singapore journal of tropical geography》2010,31(2):224-238

At a time when climate change is being defined and grappled with around the world as a looming large‐scale environmental crisis, low‐lying Pacific islands are being publicized in a range of practices as ‘disappearing islands’, and their inhabitants as future ‘climate refugees’. This paper is concerned with the disappearing island as a space in which new intersections between environmentalism and tourism can be explored. It analyzes specifically western representational practices associated with climate change imperatives on Tuvalu, an atoll state in the central Pacific. New phenomena are emerging there such as climate change tourism and the transformation of the islands into showcases of renewable energy. These phenomena are analyzed in order to understand how climate change meanings are being shaped by various participants in the debate. I argue that Pacific islanders are heroized as climate change saviours when environmentalists attempt to locate ethnocentric notions of environmentally harmonious, ‘traditional’ culture on disappearing islands. Further, islanders are objectified in the rhetoric of climate change tourism. Imagined destinies for atoll dwellers as climate saviours are sited uncomfortably alongside voyeuristic gazes turned towards inundated islands. Competing forces of compassion and voyeurism produced in the name of the Tuvaluan indigene are entrenching an iconic role for the Tuvaluan atoll dweller as climate change hero/victim.  相似文献   

The Cassini Campaign observations of the Jupiter aurora by the Ultraviolet Imaging Spectrograph and the Space Telescope Imaging Spectrograph     

Joseph M. Ajello  Wayne Pryor  Ian Stewart  Jacques Gustin  J.-C. Gérard 《Icarus》2005,178(2):327-345

We have analyzed the Cassini Ultraviolet Imaging Spectrometer (UVIS) observations of the Jupiter aurora with an auroral atmosphere two-stream electron transport code. The observations of Jupiter by UVIS took place during the Cassini Campaign. The Cassini Campaign included support spectral and imaging observations by the Hubble Space Telescope (HST) Space Telescope Imaging Spectrograph (STIS). A major result for the UVIS observations was the identification of a large color variation between the far ultraviolet (FUV: 1100-1700 Å) and extreme ultraviolet (EUV: 800-1100 Å) spectral regions. This change probably occurs because of a large variation in the ratio of the soft electron flux (10-3000 eV) responsible for the EUV aurora to the hard electron flux (∼15-22 keV) responsible for the FUV aurora. On the basis of this result a new color ratio for integrated intensities for EUV and FUV was defined (4πI1550-1620 Å/4πI1030-1150 Å) which varied by approximately a factor of 6. The FUV color ratio (4πI1550-1620 Å/4πI1230-1300 Å) was more stable with a variation of less than 50% for the observations studied. The medium resolution (0.9 Å FWHM, G140M grating) FUV observations (1295-1345 Å and 1495-1540 Å) by STIS on 13 January 2001, on the other hand, were analyzed by a spectral modeling technique using a recently developed high-spectral resolution model for the electron-excited H₂ rotational lines. The STIS FUV data were analyzed with a model that considered the Lyman band spectrum (B ) as composed of an allowed direct excitation component (X ) and an optically forbidden component (X followed by the cascade transition ). The medium-resolution spectral regions for the Jupiter aurora were carefully chosen to emphasize the cascade component. The ratio of the two components is a direct measurement of the mean secondary electron energy of the aurora. The mean secondary electron energy of the aurora varies between 50 and 200 eV for the polar cap, limb and auroral oval observations. We examine a long time base of Galileo Ultraviolet Spectrometer color ratios from the standard mission (1996-1998) and compare them to Cassini UVIS, HST, and International Ultraviolet Explorer (IUE) observations.  相似文献   

The influence of flushing rates, terrestrial input and low salmon escapement densities on paleolimnological reconstructions of sockeye salmon (Oncorhynchus nerka) nutrient dynamics in Alaska and British Columbia   总被引：3，自引：2，他引：1  

Anita J. Holtham  Irene Gregory-Eaves  Marlow G. Pellatt  Daniel T. Selbie  Laura Stewart  Bruce P. Finney  John P. Smol 《Journal of Paleolimnology》2004,32(3):255-271

Recent advances in paleolimnology have enabled reconstructions of past sockeye salmon (Oncorhynchus nerka) dynamics using a number of proxy-indicators, including diatoms and stable isotopes. Thus far, studies have focused on nursery lakes with high escapement densities and low flushing rates, ensuring that levels of salmon-derived nutrients (SDN) are high and are incorporated into the food chain. This study examines three oligotrophic sockeye salmon nursery lakes in Alaska (Afognak and Saltery lakes) and British Columbia (Hobiton Lake) to determine if sockeye salmon populations can be tracked in nursery systems with lower salmon escapement densities, higher flushing rates and/or higher terrestrial input. We adopted a multi-proxy approach using diatoms, stable isotopes (¹⁵N), organic carbon to nitrogen (C/N) ratios and pollen to draw inferences from ²¹⁰Pb-dated sediment cores. ¹⁵N showed little response to historic variation in sockeye salmon populations, even in Saltery Lake, which has a very high escapement density, and in Afognak Lake, in which average escapement is known to have increased. Dilution effects due to high flushing rates were likely partly responsible for the low ¹⁵N and minimal variation throughout the cores, although very high terrestrial input in Hobiton Lake also dampened the salmon signal. Small changes in diatom species assemblages, however, were evident in all three lakes and may be in response to fluctuating loads of salmon-derived nutrients. Most notably, increases of mesotrophic diatom taxa, such as Asterionella formosa and Aulacoseira subarctica, corresponded to increased salmon production in Alaskan lakes as a result of enhancement (fertilization) activities and climatic changes. Changes in the relative abundance of Cyclotella pseudostelligera in Hobiton Lake may also be in response to a significant decline in sockeye salmon populations off the west coast of Vancouver Island in the 1970s. Other factors, however, such as logging and lake fertilization may also have influenced diatom species composition. These results confirm that, while salmon-derived nutrients may be of key importance in juvenile salmonid development in some lakes, this may not be the case in all systems, especially those in which flushing rates are high. Further, in these systems, diatom communities appear to respond more sensitively to fluctuations in salmon populations (and therefore nutrients) than stable isotope methods, provided that other changes in trophic status are minor.  相似文献