Aqueous Surfactant Washing of Residual Oil Contamination from Sandy Soil   总被引：2，自引：0，他引：2  

Carolina C. Ang  Abdul S. Abdul 《Ground Water Monitoring & Remediation》1991,11(2):121-127

A laboratory study was conducted to determine the efficiency of different aqueous concentrations of an alcohol ethoxylate surfactant in washing residual levels of an oil [automatic transmission fluid (ATF)] from sandy soil. Five glass columns packed with the soil were prepared in a manner that simulated conditions leading to residual saturation in an actual oil leak. Each of four columns was washed continuously with 28 pore volumes of solution by pumping either 0.0 percent (water), 0.5 percent, 1.0 percent, or 2.0 percent aqueous surfactant solutions through the columns. The fifth column was washed intermittently with 28 pore volumes of a 1.0 percent surfactant solution. Water washed only 25.5 percent of the ATF from the column soil, while the 0.5 percent, 1 percent, and 2 percent surfactant solutions washed 55 percent, 60 percent, and 72.8 percent of the ATF, respectively. The distribution of the ATF remaining in the column after washing showed that the ATF removed by water was mainly from the outlet side of the column, while the ATF removed by the 2.0 percent surfactant solution was mainly from the inlet side of the column. This observation indicated that different mechanisms were involved; namely, the displacement of oil through the soil-pore space, the dispersion of oil due to reduced surface tension, and the solubilization of oil by surfactant micelles. In the case of water, the displacement of oil was the main washing mechanism, while all three mechanisms were operative during surfactant washing. ATF dispersion and solubilization were improved at higher surfactant concentrations. The column that was washed intermittently to pulse ATF from dead end pores did not show a significant improvement over the column that was continuously washed with the same 1.0 percent surfactant solution. The results show promising potential for application in the field and will be further investigated in a two-dimensional model aquifer.  相似文献   

Abundance and distribution of fluoride concentrations in groundwater: La Ballenera catchment,southeast of Buenos Aires Province,Argentina     

Carolina Calvi  Daniel Martinez  Cristina Dapeña  Florencia Gutheim 《Environmental Earth Sciences》2016,75(6):534

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The Na i D resonance lines in main-sequence late-type stars     

Rodrigo F. Díaz  Carolina Cincunegui  Pablo J. D. Mauas 《Monthly notices of the Royal Astronomical Society》2007,378(3):1007-1018

We study the sodium D lines (D1: 5895.92 Å; D2: 5889.95 Å) in late-type dwarf stars. The stars have spectral types between F6 and M5.5 ( B − V between 0.457 and 1.807) and metallicity between  [Fe/H]=−0.82  and 0.6. We obtained medium-resolution echelle spectra using the 2.15-m telescope at the Argentinian observatory Complejo Astronómico El Leoncito (CASLEO). The observations have been performed periodically since 1999. The spectra were calibrated in wavelength and in flux. A definition of the pseudo-continuum level is found for all our observations. We also define a continuum level for calibration purposes. The equivalent width of the D lines is computed in detail for all our spectra and related to the colour index ( B − V ) of the stars. When possible, we perform a careful comparison with previous studies. Finally, we construct a spectral index  ( R '_D)  as the ratio between the flux in the D lines and the bolometric flux. We find that, once corrected for the photospheric contribution, this index can be used as a chromospheric activity indicator in stars with a high level of activity. Additionally, we find that combining some of our results, we obtain a method to calibrate in flux stars of unknown colour.  相似文献   

Using historical source data to understand urban flood risk: a socio-hydrological modelling application at Gregório Creek,Brazil     

Ana Carolina Sarmento Buarque  Namrata Bhattacharya-Mis  Maria Clara Fava  Felipe Augusto Arguello de Souza  Eduardo Mario Mendiondo 《水文科学杂志》2020,65(7):1075-1083

ABSTRACT

The city of São Carlos, state of São Paulo, Brazil, has a historical coexistence between society and floods. Unplanned urbanization in this area is a representative feature of how Brazilian cities have developed, undermining the impact of natural hazards. The Gregório Creek catchment is an enigma of complex dynamics concerning the relationship between humans and water in Brazilian cities. Our hypothesis is that social memory of floods can improve future resilience. In this paper we analyse flood risk dynamics in a small urban catchment, identify the impacts of social memory on building resilience and propose measures to reduce the risk of floods. We applied a socio-hydrological model using data collected from newspapers from 1940 to 2018. The model was able to elucidate human–water processes in the catchment and the historical source data proved to be a useful tool to fill gaps in the data in small urban basins.  相似文献   

Out of Africa in the Pleistocene     

Carolina Mallol 《Geoarchaeology》2002,17(6):627-629

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Adjustments in channel morphology due to land‐use changes and check dam installation in mountain torrents of Calabria (southern Italy)          下载免费PDF全文

Diego Fortugno  Carolina Boix‐Fayos  Giuseppe Bombino  Pietro Denisi  Juan Manuel Quiñonero Rubio  Vincenzo Tamburino  Demetrio Antonio Zema 《地球表面变化过程与地形》2017,42(14):2469-2483

In Mediterranean semi‐arid conditions, the availability of studies monitoring channel adjustments as a response to reforestation and check dams over representative observation periods, could help develop new management strategies. This investigation is an integrated approach assessing the adjustments of channel morphology in a typical torrent of southern Italy after land‐use changes and check dam construction across a period of about 60 years. A statistical analysis of historical rainfall records, an analysis of land‐use changes in the catchment area and a geomorphological mapping of channel adjustments were carried out and combined with field surveys of bed surface grain‐size over a 5‐km reach including 14 check dams. The analysis of the historical rainfall records showed a slight decrease in the amount and erosivity of precipitation. Mapping of land‐use changes highlighted a general increase of vegetal coverage on the slopes adjacent to the monitored reaches. Together with the check dam network installation, this increase could have induced a reduction in water and sediment supply. The different erosional and depositional forms and adjustments showed a general narrowing between consecutive check dams together with local modifications detected upstream (bed aggradation and cross‐section expansion together with low‐flow realignments) and downstream (local incision) of the installed check dams. Changes in the torrent bends were also detected as a response to erosional and depositional processes with different intensities. The study highlighted: the efficiency of check dams against the disrupting power of intense floods by stabilizing the active channel and the influence of reforestation in increasing hillslope protection from erosion and disconnectivity of water and sediment flows towards the active channel. Only slight management interventions (for instance, the conversion of the existing check dams into open structures) are suggested, in order to mobilize the residual sediment avoiding further generalized incision of the active channel and coast line erosion. Copyright © 2017 John Wiley & Sons, Ltd.  相似文献   

Atacama Field Campaign: laboratory and in-situ measurements for remote sensing applications     

Cristian Mattar  Andrés Santamaría-Artigas  Flavio Ponzoni  Cibele T. Pinto  Carolina Barrientos  Glynn Hulley 《International Journal of Digital Earth》2019,12(1):43-61

This work presents the preliminary results of the first field calibration campaign performed in the Atacama Desert, Chile, between the 18 and 22 August 2014, called the Atacama Field Campaign (ATAFIC 2014). In situ measurements were performed in order to spectrally characterize the surface reflectance spectra between 0.3 and 2.5?µm, radiometric temperature (8.0–14.0?µm) and atmospheric measurements. A soil sample was collected and analyzed using Fourier Transform Infrared Spectroscopy and X-Ray Diffraction techniques to characterize the surface reflectance spectra and mineralogical composition, respectively. ASTER land surface emissivity in addition to GOES, MODIS and Landsat-8 land surface temperature (LST) were also used. Results showed that the spectral features of the Atacama soil and the characteristics of this geographical zone, which is featured as the most hyper-arid and cloudless place in the world, make this area a potential target for surface reflectance characterization. Day and night LST comparison between field and remote sensing data are lower than 2?K and the Root Mean Square Error for land surface emissivity is close to 2%. This work opens the possibilities to consider the Atacama Desert as a reference target for calibration and validation activities for earth observation missions’ purposes.  相似文献   

Long term variation in rainfall erosivity in Uruguay: a preliminary Fournier approach     

Carolina Munka  Gabriela Cruz  Ruben Mario Caffera 《GeoJournal》2007,70(4):257-262

In order to explore the consequences of precipitation increase on soil erosion in Uruguay, the monthly Fournier Index (FI) and the annual Modified Fournier Index (MFI) were developed as a preliminary approach, covering consecutive decadal periods from 1931 to 2000. Rainfall data were used from 13 stations distributed all over the country. MFI shows a decrease in the 1940s, an increase during the 1950s, then a little decrease during the 1960s and 1970s and an increase in the 1980s, remaining near these last values during the 1990s. FI behavior in July and October in the last two decades shows a decrease in the Northeast region of the country—the region with highest annual precipitation—and a slight increase over the Southeast—the region with the lowest annual precipitation and the only region with a winter rainfall maximum. For the core months of winter and early spring there is a decline in erosivity in the Northeast, but an increase in the Southeast. January shows erosivity decreasing in the South during the last two decades. In April there is a peak in precipitation variability all across the country. FI shows an early increase during the 1940s in the Northwest, and generally very low values during the 1970s, with the return of high values in the 1990s, especially in the Northern corner. Results pose a challenge in order to improve research on the erosion problem, since the main source of freshwater nationwide remains surface river flow, which is prone to higher turbidity problems in areas of high soil erosion.  相似文献   

Joint effects of climate warming and exotic litter (Eucalyptus globulus Labill.) on stream detritivore fitness and litter breakdown     

Francisco Correa-Araneda  Luz Boyero  Ricardo Figueroa  Carolina Sánchez  Roberto Abdala  Antonio Ruiz-García  Manuel A. S. Graça 《Aquatic Sciences - Research Across Boundaries》2015,77(2):197-205

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Transgressive dunefield landforms and vegetation associations,Doña Juana,Veracruz, Mexico     

Patrick Hesp  Marisa Martinez  Graziela Miot da Silva  Natalia Rodríguez‐Revelo  Erika Gutierrez  Adriana Humanes  Daniela Laínez  Irene Montaño  Verónica Palacios  Agustín Quesada  Lorena Storero  Gabriela González Trilla  Carolina Trochine 《地球表面变化过程与地形》2011,36(3):285-295

Transgressive dune fields often comprise a multiplicity of landforms where vegetation processes largely affect landform dynamics, which in turn, also affect vegetation processes. These associations have seldom been studied in detail. This paper examines four separate landform types in a complex coastal transgressive dunefield located in the central Gulf of Mexico, in order to assess the relationships between dunefield habitat, local environmental factors, vegetation associations and landform evolution. Topographic surveys using tape and clinometer were conducted in conjunction with vegetation survey transects at four locations across the Doña Juana dunefield. Vegetation surveys allowed the estimation of relative plant cover of each plant species found along the transects. A large variety of landforms were found at the Doña Juana Dunefield: deflation plains, gegenwalle (counter) ridges, transverse dune trailing ridges, blowouts and parabolic dunes, aklé (fish‐scale shaped) dunefields and precipitation ridges, with plant species associations developing on these different landforms equally variable. Flood tolerant species were located in the lower parts (deflation plain and gegenwalle ridges) whereas the older and dryer parts were covered by coastal matorral shrubs. Burial‐tolerant species were dominant in the most mobile areas (blowouts and aklé dunefield and margin). The dune trailing ridge, with relatively milder conditions, showed the highest richness, with no dominant species. A dual interaction was found such that colonizing species both create and affect topography, and in turn, topography determines vegetation association and succession patterns. In coastal dunes, the vegetation and abiotic environment (namely the different landforms and the inherent micronevironmental variability) interact tightly and generate a complex and highly dynamic biogeomorphic system where substrate mobility and colonization processes reinforce one another in positive feedback. Copyright © 2010 John Wiley & Sons, Ltd.  相似文献