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This paper introduces four kinds of novel bivariate maximum entropy distributions based on bivariate normal copula, Gumbel–Hougaard copula, Clayton copula and Frank copula. These joint distributions consist of two marginal univariate maximum entropy distributions. Four types of Poisson bivariate compound maximum entropy distributions are developed, based on the occurrence frequency of typhoons, on these novel bivariate maximum entropy distributions and on bivariate compound extreme value theory. Groups of disaster-induced typhoon processes since 1949–2001 in Qingdao area are selected, and the joint distribution of extreme water level and corresponding significant wave height in the same typhoon processes are established using the above Poisson bivariate compound maximum entropy distributions. The results show that all these four distributions are good enough to fit the original data. A novel grade of disaster-induced typhoon surges intensity is established based on the joint return period of extreme water level and corresponding significant wave height, and the disaster-induced typhoons in Qingdao verify this grade criterion. 相似文献
74.
Salt marshes are important ecological areas and play a significant role in coastal flood defence schemes. In many areas of the UK they are adjacent to agricultural areas utilised for the growth of cereal crops, for which mecoprop is used as a selective herbicide in the control of broad-leaf weeds. This study measured concentrations of mecoprop in soils, drainage ditch waters and sediments and salt marsh sediments over a period of 138 days following spring application. Soil concentrations of up to 1827 microg/g were recorded after application, which demonstrated a half life for mecoprop of from 9 to 12 days, with first order kinetics. However, a major rainfall event 9 days after application resulted in significant transport of herbicide to the salt marsh via subsurface field drains, drainage ditches and discharge sluice. Mecoprop concentrations of up to 386 microg/l observed in water samples were above UK guidelines. 相似文献
75.
Wagner José Barreto Dilson Norio Ishikawa Ieda Spacino Scarminio João de Souza Costa Paulo dos Santos Nora Miriam de Fatima Soares Romilaine Mansano Nicolau Adriana Celeste Esteves Gonçalves Sonia Regina Giancoli Barreto 《洁净——土壤、空气、水》2008,36(4):353-359
The conservation of large water resources is essential for the preservation of human life. The quantification and, more importantly, the speciation of chemical substances that indicate the presence of anthropogenic contamination in water resources are of great importance. This paper presents the results of analysis for the determination of organic, inorganic and total phosphorus, pseudo‐sulfur, and iron and manganese, in five fractions, in water sediments collected from the Capivara Hydroelectric Power Plant, Brazil. A study on the seasonal variation of these parameters was conducted, with data having been collected in the winter and in the summer, at two sites along the dam, 5 km apart, close to the city of Primeiro de Maio. Phosphorous was found in sediments and adjacent soil in the organic form (OP), and was used as an indicator of anthropogenic influence on the reservoir banks. Speciation of potentially toxic Mn showed that it is present in the exchangeable fraction of the 0–5 cm depth layer (sediment/water interface), making its transfer to the water column possible. Results from this study showed that domestic and industrial effluent treatment measures are needed for the preservation of the quality of aquatic environments. 相似文献
76.
Caroline Bouvet de Maisonneuve Olivier Bachmann Alain Burgisser 《Bulletin of Volcanology》2009,71(6):643-658
Silicic pumices formed during explosive volcanic eruptions are faithful recorders of the state of the magma in the conduit,
close to or at the fragmentation level. We have characterized four types of pumices from the non-welded rhyolitic Kos Plateau
Tuff, which erupted 161,000 years ago in the East Aegean Arc, Greece. The dominant type of pumice (>90 vol.%) shows highly
elongated tubular vesicles. These tube pumices occur throughout the eruption. Less common pumice types include: (1) “frothy”
pumice (highly porous with large, sub-rounded vesicles), which form 5–10 vol.% of the coarsest pyroclastic flow deposits,
(2) dominantly “microvesicular” and systematically crystal-poor pumices, which are found in early erupted, fine-grained pyroclastic
flow units, and are characterized by many small (<50 μm in diameter) vesicles and few mm-sized, irregular voids, (3) grey
or banded pumices, indicating the interaction between the rhyolite and a more mafic magma, which are found throughout the
eruption sequence and display highly irregular bubble shapes. Except for the grey-banded pumices, all three other types are
compositionally identical and were generated synchronously as they are found in the same pyroclastic units. They, therefore,
record different conditions in the volcanic conduit leading to variable bubble nucleation, growth and coalescence. A total
of 74 pumice samples have been characterized using thin section observation, SEM imagery, porosimetry, and permeametry. We
show that the four pumice types have distinct total and connected porosity, tortuosity and permeability. Grey-banded pumices
show large variations in petrophysical characteristics as a response to mingling of two different magmas. The microvesicular,
crystal-poor, pumices have a bimodal bubble size distribution, interpreted as reflecting an early heterogeneous bubble nucleation
event followed by homogeneous bubble nucleation close to fragmentation. Finally, the significant differences in porosity,
tortuosity and permeability in compositionally identical tube and frothy pumices are the result of variable shear rates in
different parts of the conduit. Differential shear rates may be the result of either: (1) pure shear, inducing a vertical
progression from frothy to tube and implying a relatively thick fragmentation zone to produce both types of pumices at the
same time or (2) localized simple shear, inducing strongly tubular vesicles along the wall and near-spherical bubbles in the
centre of the conduit and not necessarily requiring a thick fragmentation zone. 相似文献
77.
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79.
D. Burdloff M.F. Araújo J.-M. Jouanneau I. Mendes A.M. Monge Soares J.M.A. Dias 《Applied Geochemistry》2008
Organic C (OC) and total N (TN) concentrations, and stable isotope ratios (δ13C) in muddy deposit sediments of the Northern and Southern Portuguese continental shelf were used to identify sources of fine-sized organic matter (<63 μm) during the Holocene period. Sedimentary columns off the Guadiana (core CRIDA 05), Tagus (core MD 992332) and Douro (core KSGX 57) estuaries are characterised by elemental and isotopic values that reflect distinct sources of organic matter (OC/TN and δ13C ranging, respectively, from 8.5 to 21 and from −22.4‰ to −27‰). Intense supplies to the Guadiana continental shelf of fine terrigenous particles during the Younger-Dryas Event are closely linked with higher OC/TN values and lower δ13C ratios. During the postglacial transgression phase, an increasing contribution of marine supplies (up to 80%) occurred. Higher δ13C (up to −22.4‰) values and low OC/TN ratios (down to 8.5) are found as the sea level approaches the current one. The Upper Holocene records emphasize the return to enhanced terrestrial supplies except for the Little Climatic Optimum between the 11th and 15th centuries AD. This climatic event is especially obvious in the three cores as a return to marine production and a decrease in terrestrial sediment supply to the continental shelf. The return to a cooling event, the Little Ice Age, between the 15th and 19th centuries AD, is mirrored by decreased terrigenous supplies in core KSGX 57. Gradually increasing sedimentation in estuaries, as well as formation of coastal dune fields, have been hypothesized on the basis of increasing δ13C and decreasing OC, TN and OC/TN values. 相似文献
80.
Flow and nutrient dynamics in a subterranean estuary (Waquoit Bay, MA, USA): Field data and reactive transport modeling 总被引:3,自引:0,他引:3
A two-dimensional (2D) reactive transport model is used to investigate the controls on nutrient (, , PO4) dynamics in a coastal aquifer. The model couples density-dependent flow to a reaction network which includes oxic degradation of organic matter, denitrification, iron oxide reduction, nitrification, Fe2+ oxidation and sorption of PO4 onto iron oxides. Porewater measurements from a well transect at Waquoit Bay, MA, USA indicate the presence of a reducing plume with high Fe2+, , DOC (dissolved organic carbon) and PO4 concentrations overlying a more oxidizing -rich plume. These two plumes travel nearly conservatively until they start to overlap in the intertidal coastal sediments prior to discharge into the bay. In this zone, the aeration of the surface beach sediments drives nitrification and allows the precipitation of iron oxide, which leads to the removal of PO4 through sorption. Model simulations suggest that removal of through denitrification is inhibited by the limited overlap between the two freshwater plumes, as well as by the refractory nature of terrestrial DOC. Submarine groundwater discharge is a significant source of to the bay. 相似文献