Mg tracer diffusion in synthetic forsterite and San Carlos olivine as a function of P,T and fO2   总被引：1，自引：0，他引：1  

Sumit Chakraborty  John R. Farver  Richard A. Yund  David C. Rubie 《Physics and Chemistry of Minerals》1994,21(8):489-500

We present new experimental data on Mg tracer diffusion in oriented single crystals of forsterite (Fo₁₀₀) and San Carlos olivine (Fo₉₂) between 1000–1300° C. The activation energies of diffusion are found to be 400 (±60) kJ/mol (96 kcal/mol) and 275 (±25) kJ/mol (65 kcal/ mol) in forsterite and San Carlos olivine, respectively, along [001] at a fO₂ of 10^–12 bars. There is no change in activation energy of Mg tracer diffusion within this temperature range. Mg tracer diffusion in a nominally pure forsterite is found to be anisotropic (D_c > D_a > D _b) and a function of fO₂. This fO₂ dependence is different from that in olivine containing Fe as a major element, which suggests that the diffusion mechanism of Mg in forsterite is different from that in Fe-bearing olivine at least over some range of fO₂. The diffusion mechanism in nominally pure forsterites may involve impurities present below the limits of detection or alternately, Si or Fe³⁺ interstitial defects, Fe being present as impurity (ppm level) in forsterite. Pressure dependence of Mg tracer diffusivity in forsterite measured to 10 GPa in a multianvil apparatus yields an activation volume of approximately 1–3.5 cm³/ mol. It is found that presence of small amounts of hydrogen bearing species in the atmosphere during diffusion anneal (f_H2 0.2 bars, f_H20 0.24 bars) do not affect Mg tracer diffusion in forsterite within the resolution of our measurement at a total pressure of 1 bar. The observed diffusion process is shown to be extrinsic; hence extrapolation of the diffusion data to lower temperatures should not be plagued by uncertainties related to change of diffusion mechanism from intrinsic to extrinsic.  相似文献   

Depositional Record of Tidal-Flat Sedimentation in the Permian Coal Measures of Central India: Barakar Formation, Mohpani Coalfield, Satpura Gondwana Basin   总被引：1，自引：0，他引：1  

Chandan Chakraborty  Sanjoy Kumar  Ghosh  Tapan Chakraborty 《Gondwana Research》2003,6(4):817-827

The Permian Barakar Formation in the Mohpani coalfield, Satpura Gondwana basin, is composed of three broad lithologies that occur repetitively and are iterdigitated: (1) several metres thick coarse- to medium-grained sandstone bodies with scoured bases, (2) 5-20 m thick medium- to fine-grained sandstone bodies and (3) 5-20 m thick mudstone-dominated packages with variable proportions of centimetre- to decimetre-scale, fine- to medium-grained sandstone, carbonaceous shale and coal. The Barakar strata were previously interpreted as deposits of braided rivers and associated inter-channel flood basin in a continental setting. However, this study recognizes signatures of tidal current from the mudstone-dominated packages implying marine influence during Barakar sedimentation.

The mudstone-dominated sediment bodies are the focus of this paper and comprise of three lithofacies that bear imprints of tidal processes during Barakar sedimentation: (1) heterolith, (2) sandstone, and (3) coal-carbonaceous shale, which alternate with one another within individual bodies. The heterolithic facies show interlayering of sandstone and claystone resembling flaser, wavy and lenticular bedding, as well as pinstripe stratification. Successive sandstone-mudstone couplets indicate periodic waxing and waning of flows. Within individual heterolithic packages, the sandstone:claystone ratio along with the bedding style, varies cyclically upwards giving rise to alternate sandstone-dominated and claystone-dominated intervals suggesting tidal velocity fluctuation reflective of spring-neap lunar cycle. Thickness plots of successive sand-mud couplets also reveal cyclic variation with a conspicuous periodicity of around 12 couplets per cycle, which corroborates the spring-neap-spring (or neap-spring-neap) lunar cycle. Presence of abundant desiccation cracks indicates periodic emergence and points towards an intertidal setting. The sandstone facies is characterized by a variety of wave-generated features such as bundled and chevron upbuilding of lamina, bi-directional foreset orientations, offshooting and draping laminae, scour-and-drape feature, swollen lens-like geometries suggesting their emplacement under storm-induced combined-flow on the tidal-flat. The coal-carbonaceous shale facies represent supratidal marsh environment.  相似文献   

Strain fields and foliation trajectories around pre-, syn-, and post-tectonic plutons in coaxially deformed terranes     

Nibir Mandal  Chandan Chakraborty 《Geological Journal》1990,25(1):19-33

This paper determines, using simple mathematical models, maps of strain fields and foliation trajectories in the neighbourhood of plutonic bodies intruded into a region before, during, and after a lateral compression. The analyses reveal contrasting features for the three cases, which may be useful in distinguishing pre-, syn-, and post-tectonic plutons in coaxially deformed terranes. The theoretically calibrated strain variation curve, along the regional shortening direction, around a pretectonic, rigid plutonic body shows a zone of strain increase (relative to the far-field strain), whereas that around a syntectonic pluton shows a zone of strain decrease along with a zone of strain increase. The foliations deflect outward from a pretectonic pluton, but they bend towards a syntectonic pluton. The analysis also reveals that syntectonic plutons are likely to be elliptical in plan with axial ratio directly dependent on the ratio of the pluton's stress to the tectonic stress. Tectonic foliations deflect away from post-tectonic plutons. However, the foliated area around a post-tectonic pluton is systematically divided into two sets of zones one characterized by foliations showing compressional features, the other showing extensional features.  相似文献   

Using GIS to Assess the Environmental Justice Consequences of Transportation System Changes   总被引：3，自引：0，他引：3  

Jayajit Chakraborty  Lisa A. Schweitzer  & David J. Forkenbrock 《Transactions in GIS》1999,3(3):239-258

Although environmental justice research has typically focused on locations of industrial toxic releases or waste sites, recent developments in GIS and environmental modeling provide a foundation for developing measures designed to evaluate the consequences of transportation system changes. In this paper, we develop and demonstrate a workable GIS-based approach that can be used to assess the impacts of a transportation system change on minorites and low-income residents. We focus specifically on two adverse affects: vehicle-generated air pollution and noise. The buffer analysis capabilities of GIS provide a preliminary assessment of environmental justice. We integrate existing environmental pollution models with GIS software to identify the specific locations where noise and air pollution standards could be violated because of the proposed system change. A comparison of the geographic boundaries of these areas with the racial and economic characteristics of the underlying population obtained from block level census data provides a basis for evaluating disproportionate impacts. An existing urban arterial in Waterloo, Iowa, is used to illustrate the methods developed in this research.  相似文献   

Interannual variability and characteristics of the East India Coastal Current associated with Indian Ocean Dipole events using a high resolution regional ocean model     

Sumit Dandapat  Arun Chakraborty  Jayanarayanan Kuttippurath 《Ocean Dynamics》2018,68(10):1321-1334

The characteristics and variability of the East India Coastal Current (EICC), the western boundary current in the Bay of Bengal (BoB) during the Indian Ocean Dipole (IOD) years between 2006 and 2012 have been investigated using the high-resolution Regional Ocean Modeling System (ROMS). The evolution of temperature, mixed layer depth (MLD), and seasonal basin scale circulation in the upper ocean simulated by the model agrees well with the observations. The EICC in BoB is characterized by a seasonal reversal flow: the poleward EICC during February?May and the equatorward EICC during August?December. A long-term simulation from 2006 to 2012 suggest that the circulation pattern, boundary current structure, and transport in the western BoB are completely different in positive and negative IOD years. As IOD is mainly phase-locked to the seasonal cycle with most significant influence in the Borel autumn, the equatorward EICC is affected during the IOD years. It is found that the strength of this EICC is ~?5 Sv in October 2010 and a weaker EICC dominated by the presence of eddies is observed in October 2006. We also quantified the local and remote forcing effects on the variability of EICC and found that the seasonal coastal Kelvin waves (KWs) play a dominant role in the development of the EICC. During positive IOD year 2006, due the absence of second downwelling KW, the EICC is completely disorganized and dominated by the eddies, whereas in the negative IOD year 2010, the strong second downwelling KW plays a key role in developing organized and stable EICC in the western BoB.  相似文献   

Changes in daily maximum temperature extremes across India over 1951–2014 and their relation with cereal crop productivity     

Debasish?Chakraborty  Vinay?Kumar?SehgalEmail authorView author&#;s OrcID profile  Rajkumar?Dhakar  Eldho?Varghese  Deb?Kumar?Das  Mrinmoy?Ray 《Stochastic Environmental Research and Risk Assessment (SERRA)》2018,32(11):3067-3081

This study used gridded daily maximum temperature data (1°?×?1°) for 1951–2014 period to analyze the trend in monthly extreme warm days (ExWD) and changes in its probability distribution in each grid. It also analyzed the trend in spatial spread of annual ExWD over the study period at four exceedance levels and further related the number of ExWDs with cereal crop productivity of India. Extreme warm days have increased throughout India but were statistically significant in 42% grids. The increase was consistent over all the months in north-eastern region, southern plateau and both the coastal plains. It also increased significantly over north-western and central India during April to June summer period. The probability distribution of ExWD also changed significantly in many grids, especially in southern plateau and both the coastal plains. The changes indicated increased frequency in the existing levels of extremes and new occurrences of higher frequency of extremes. The analysis of land area affected by different levels of extremes indicated significant increase, with the rate being highest for higher extremes. In terms of extreme warm day temperatures, the study identified southern plateau, east and west coast plains, and north-eastern India as highly vulnerable. Using copula probability model, study showed that increase in ExWD from 20 to 60% may increase the probability of 5% or more yield loss from 17 to 53% for Kharif cereals, 11 to 43% for Rabi cereals and 19 to 63% for wheat crop. The results may be used for devising zone specific adaptation strategies.  相似文献   

A Tiered Approach to Evaluating Salinity Sources in Water at Oil and Gas Production Sites          下载免费PDF全文

Shawn M. Paquette  Lisa J. Molofsky  John A. Connor  Kenneth L. Walker  Harley Hopkins  Ayan Chakraborty 《Ground water》2017,55(5):757-769

A suspected increase in the salinity of fresh water resources can trigger a site investigation to identify the source(s) of salinity and the extent of any impacts. These investigations can be complicated by the presence of naturally elevated total dissolved solids or chlorides concentrations, multiple potential sources of salinity, and incomplete data and information on both naturally occurring conditions and the characteristics of potential sources. As a result, data evaluation techniques that are effective at one site may not be effective at another. In order to match the complexity of the evaluation effort to the complexity of the specific site, this paper presents a strategic tiered approach that utilizes established techniques for evaluating and identifying the source(s) of salinity in an efficient step‐by‐step manner. The tiered approach includes: (1) a simple screening process to evaluate whether an impact has occurred and if the source is readily apparent; (2) basic geochemical characterization of the impacted water resource(s) and potential salinity sources coupled with simple visual and statistical data evaluation methods to determine the source(s); and (3) advanced laboratory analyses (e.g., isotopes) and data evaluation methods to identify the source(s) and the extent of salinity impacts where it was not otherwise conclusive. A case study from the U.S. Gulf Coast is presented to illustrate the application of this tiered approach.  相似文献   

Seismic response analysis of a hydraulic fill dam     

Chakraborty  Sayantan  Bheemasetti  Tejo V.  Das  Jasaswee T.  Puppala  Anand J. 《Acta Geotechnica》2020,15(11):3095-3110

Acta Geotechnica - The seismic response of a highly heterogeneous hydraulic fill dam was evaluated by studying the natural frequencies of the first and second modes of vibration and analyzing the...  相似文献   

Preference of echo features for classification of seafloor sediments using neural networks     

Chanchal De  Bishwajit Chakraborty 《Marine Geophysical Researches》2010,31(3):215-221

Selection of a set of dominant echo features to classify seafloor sediments using a multilayer perceptron neural network is investigated at two acoustic frequencies (33 and 210 kHz). Several sets of inputs with different combinations of two, three, four, five, and six echo features are exploited with three-layer neural networks. The performances of the networks are analyzed to assess the most discriminating set of echo features for classification of seafloor sediments. The results of the overall average performances reveal that backscatter strength and time spread are the two most important echo features at 33 kHz, whereas backscatter strength has higher discriminating characteristics at 210 kHz for seafloor sediment classification. In addition, a set of four echo features consisting of backscatter strength, time-spread, statistical skewness, and Hausdroff dimension gives the highest success at both the acoustic frequencies.  相似文献   

Geochemistry of some banded iron-formations of the Archean supracrustals,Jharkhand-Orissa region,India     

H. N. Bhattacharya  Indranil Chakraborty  Kaushik K. Ghosh 《Journal of Earth System Science》2007,116(3):245-259

Banded iron-formations (BIF) form an important part of the Archean supracrustal belts of the Jharkhand-Orissa region, India. Major, trace and REE chemistry of the banded iron-formation of the Gandhamardan, Deo Nala, Gorumahisani and Noamundi sections of the Jharkhand-Orissa region are utilized to explore the source of metals and to address the thermal regime of the basin floor and the redox conditions of the archean sea. Hydrothermal fluids of variable temperatures might have contributed the major part of the Fe and other trace elements to the studied banded iron-formations. Diagenetic fluids from the sea floor sediments and river water might have played a subdued role in supplying the Fe and other elements for the banded iron-formations.  相似文献