Interactive effects of the type of milling media and CuSO₄ addition on the flotation performance of sulphide minerals from Merensky ore Part II: Froth stability     

Z. Ekmekci  D.J. Bradshaw  P.J. Harris  A.M. Buswell 《International Journal of Mineral Processing》2006

The limitations of pulp chemistry measurements in the flotation of a platinum group mineral (PGM) bearing Merensky ore were demonstrated in Part 1 of this article. In this paper the importance of the contribution of the froth structure due to changing froth stability is analysed using the batch flotation data. The effects of mild steel (MS) and stainless steel (SS) milling media and the addition of copper sulphate on the flotation performance of the sulphide minerals in Merensky ore have been evaluated in relation to the changes in stability of the froth phase. The effects of pulp chemistry and froth stability on the flotation of sulphide minerals were distinguished by using two different rate constants (k_t and k_w). The rate constant (k_w) calculated as a function of cumulative water recovery was used to describe characteristics of froth phase and k_t was calculated as a function of flotation time. The results revealed that the type of grinding media and copper sulphate addition had an interactive effect on the froth stability. While mild steel (MS) milling increased the froth stability due to the presence of hydrophilic iron hydroxides and colloidal metallic iron, the addition of copper sulphate reduced the stability, especially with stainless steel (SS) milling. Copper sulphate addition had a dual role in the flotation of Merensky ore in that it caused destabilisation of the froth zone as well as activation of selected sulphide minerals. The dominant effect was found to depend on the type of milling media and floatability of the mineral in question and this work has demonstrated the importance of using a combination of measurements to evaluate flotation performance holistically.  相似文献   

The Wuchiapingian–Changhsingian boundary (Upper Permian) at Meishan of Changxing County, South China     

Wang Yue  Shen Shuzhong  Cao Changqun  Wang Wei  Charles Henderson  Jin Yugan   《Journal of Asian Earth Sciences》2006,26(6):575-583

Section D at Meishan, Changxing County in the Zhejiang Province, China, has been extensively studied in various aspects of the stratigraphy during the past 20 years. It was ratified by the International Union of Geological Sciences (IUGS) as the Global Standard Stratotype Section and Point (GSSP) for the Permian–Triassic boundary in 2000, and is also a potential stratotype for the Wuchiapingian–Changhsingian boundary. However, the contact relationship between the Longtan (Wuchiapingian) and Changxing (Chainghsingian) formations has been a controversial subject for years. Recent studies on Section C, about 300 m west of Section D, at Meishan confirm a complete depositional succession around the boundary and suggest that the proposed boundary level, the FAD of Clarkina wangi within the lineage from C. longicuspidata to C. wangi, is consistent with the first appearance of the index Changhsingian fusulinid Palaeofusulina sinensis and tapashanitid ammonoids.  相似文献   

The effect of multiple stressors on salt marsh end-of-season biomass     

Jenneke M. Visser  Charles E. Sasser  Brian S. Cade 《Estuaries and Coasts》2006,29(2):328-339

It is becoming more apparent that commonly used statistical methods (e.g. analysis of variance and regression) are not the best methods for estimating limiting relationships or stressor effects. A major challenge of estimating the effects associated with a measured subset of limiting factors is to account for the effects of unmeasured factors in an ecologically realistic matter. We used quantile regression to elucidate multiple stressor effects on end-of-season biomass data from two salt marsh sites in coastal Louisiana collected for 18 yr. Stressor effects evaluated based on available data were flooding, salinity air temperature, cloud cover, precipitation deficit, grazing by muskrat, and surface water nitrogen and phosphorus. Precipitation deficit combined with surface water nitrogen provided the best two-parameter model to explain variation in the peak biomass with different slopes and intercepts for the two study sites. Precipitation deficit, cloud cover, and temperature were significantly correlated with each other. Surface water nitrogen was significantly correlated with surface water phosphorus and muskrat density. The site with the larger duration of flooding showed reduced peak biomass, when cloud cover and surface water nitrogen were optimal. Variation in the relatively low salinity occurring in our study area did not explain any of the variation inSpartina alterniflora biomass.  相似文献   

Asymmetric vegetation responses to mid-Holocene aridity at the prairie-forest ecotone in south-central Minnesota     

Charles E. Umbanhowar Jr.  Philip Camill  Rebecca Teed 《Quaternary Research》2006,66(1):53-66

The mid-Holocene (ca. 8000-4000 cal yr BP) was a time of marked aridity throughout much of Minnesota, and the changes due to mid-Holocene aridity are seen as an analog for future responses to global warming. In this study, we compare the transition into (ca. 9000-7000 yr ago) and out of (ca. 5000-2500 yr ago) the mid-Holocene (MH) period at Kimble Pond and Sharkey Lake, located along the prairie forest ecotone in south-central Minnesota, using high resolution (∼ 5-36 yr) sampling of pollen, charcoal, sediment magnetic and loss-on-ignition properties. Changes in vegetation were asymmetrical with increasing aridity being marked by a pronounced shift from woodland/forest-dominated landscape to a more open mix of grassland and woodland/savanna. In contrast, at the end of the MH, grassland remained an important component of the landscape despite increasing effective moisture, and high charcoal influxes (median 2.7-4.0 vs. 0.6-1.7 mm² cm^− 2 yr^− 1 at start of MH) suggest the role of fire in limiting woodland expansion. Asymmetric vegetation responses, variation among and within proxies, and the near-absence of fire today suggest caution in using changes associated with mid-Holocene aridity at the prairie forest boundary as an analog for future responses to global warming.  相似文献   

Effect of polypropylene fibre and lime admixture on engineering properties of clayey soil   总被引：2，自引：0，他引：2  

Yi Cai  Bin Shi  Charles W.W. Ng  Chao-sheng Tang 《Engineering Geology》2006,87(3-4):230-240

In order to reduce the brittleness of soil stabilized by lime only, a recent study of a newly proposed mixture of polypropylene fibre and lime for ground improvement is described and reported in the paper. To investigate and understand the influence of the mixture of polypropylene fibre and lime on the engineering properties of a clayey soil, nine groups of treated soil specimens were prepared and tested at three different percentages of fibre content (i.e. 0.05%, 0.15%, 0.25% by weight of the parent soil) and three different percentages of lime (i.e. 2%, 5%, 8% by weight of the parent soil). These treated specimens were subjected to unconfined compression, direct shear, swelling and shrinkage tests. Through scanning electron microscopy (SEM) analysis of the specimens after shearing, the improving mechanisms of polypropylene fibre and lime in the soil were discussed and the observed test results were explained. It was found that fibre content, lime content and curing duration had significant influence on the engineering properties of the fibre–lime treated soil. An increase in lime content resulted in an initial increase followed by a slight decrease in unconfined compressive strength, cohesion and angle of internal friction of the clayey soil. On the other hand, an increase in lime content led to a reduction of swelling and shrinkage potential. However, an increase in fibre content caused an increase in strength and shrinkage potential but brought on the reduction of swelling potential. An increase in curing duration improved the unconfined compressive strength and shear strength parameters of the stabilized soil significantly. Based on the SEM analysis, it was found that the presence of fibre contributed to physical interaction between fibre and soil whereas the use of lime produced chemical reaction between lime and soil and changed soil fabric significantly.  相似文献   

A subduction wedge origin for Paleoarchean peridotitic diamonds and harzburgites from the Panda kimberlite, Slave craton: evidence from Re–Os isotope systematics     

K. J. Westerlund  S. B. Shirey  S. H. Richardson  R. W. Carlson  J. J. Gurney  J. W. Harris 《Contributions to Mineralogy and Petrology》2006,152(3):275-294

An extensive study of peridotitic sulfide inclusion bearing diamonds and their prospective harzburgitic host rocks from the 53 Ma Panda kimberlite pipe, Ekati Mine, NWT Canada, has been undertaken with the Re–Os system to establish their age and petrogenesis. Diamonds with peridotitic sulfide inclusions have poorly aggregated nitrogen (<30% N as B centers) at N contents of 200–800 ppm which differs from that of chromite and silicate bearing diamonds and indicates residence in the cooler portion of the Slave craton lithospheric mantle. For most of the sulfide inclusions, relatively low Re contents (average 0.457 ppm) and high Os contents (average 339 ppm) lead to extremely low ¹⁸⁷Re/¹⁸⁸Os, typically << 0.05. An age of 3.52 ± 0.17 Ga (MSWD = 0.46) and a precise initial ¹⁸⁷Os/¹⁸⁸Os of 0.1093 ± 0.0001 are given by a single regression of 11 inclusions from five diamonds that individually provide coincident internal isochrons. This initial Os isotopic composition is 6% enriched in ¹⁸⁷Os over 3.5 Ga chondritic or primitive mantle. Sulfide inclusions with less radiogenic initial Os isotopic compositions reflect isotopic heterogeneity in diamond forming fluids. The harzburgites have even lower initial ¹⁸⁷Os/¹⁸⁸Os than the sulfide inclusions, some approaching the isotopic composition of 3.5 Ga chondritic mantle. In several cases isotopically distinct sulfides occur in different growth zones of the same diamond. This supports a model where C–O–H–S fluids carrying a radiogenic Os signature were introduced into depleted harzburgite and produced diamonds containing sulfides conforming to the 3.5 Ga isochron. Reaction of this fluid with harzburgite led to diamonds with less radiogenic inclusions while elevating the Os isotope ratios of some harzburgites. Subduction is a viable way of introducing such fluids. This implies a role for subduction in creating early continental nuclei at 3.5 Ga and generating peridotitic diamonds.Electronic Supplementary Material Supplementary material is available for this article at and is accessible for authorized users.  相似文献   

Discussion on "Mississippi Valley-type lead–zinc deposits through geological time: implications from recent age-dating research" by D.L. Leach, D. Bradley, M.T. Lewchuk, D.T.A. Symons, G. de Marsily, and J. Brannon (2001) Mineralium Deposita 36:711–740     

Stephen E. Kesler  Charles W. Carrigan 《Mineralium Deposita》2002,37(8):800-802

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Kankan diamonds (Guinea) III: δ13C and nitrogen characteristics of deep diamonds     

T. Stachel  J. Harris  S. Aulbach  P. Deines 《Contributions to Mineralogy and Petrology》2002,142(4):465-475

Diamonds from the Kankan area in Guinea formed over a large depth profile beginning within the cratonic mantle lithosphere and extending through the asthenosphere and transition zone into the lower mantle. The carbon isotopic composition, the concentration of nitrogen impurities and the nitrogen aggregation level of diamonds representing this entire depth range have been determined. Peridotitic and eclogitic diamonds of lithospheric origin from Kankan have carbon isotopic compositions ('¹³C: peridotitic -5.4 to -2.2‰; eclogitic -19.7 to -0.7‰) and nitrogen characteristics (N: peridotitic 17-648 atomic ppm; eclogitic 0-1,313 atomic ppm; aggregation from IaA to IaB) which are generally typical for diamonds of these two suites worldwide. Geothermobarometry of peridotitic and eclogitic inclusion parageneses (worldwide sources) indicates that both suites formed under very similar conditions within the cratonic lithosphere, which is not consistent with a derivation of diamonds with light carbon isotopic composition from subducted organic matter within subducting oceanic slabs. Diamonds containing majorite garnet inclusions fall to the isotopically heavy side ('¹³C: -3.1‰ to +0.9‰) of the worldwide diamond population. Nitrogen contents are low (0-126 atomic ppm) and one of the two nitrogen-bearing diamonds shows such a low level of nitrogen aggregation (30% B-centre) that it cannot have been exposed to ambient temperatures of the transition zone (̿,400 °C) for more than 0.2 Ma. This suggests rapid upward transport and formation of some Kankan diamonds pene-contemporaneous to Cretaceous kimberlite activity. Similar to these diamonds from the asthenosphere and the transition zone, lower mantle diamonds show a small shift towards isotopic heavy compositions (-6.6 to -0.5‰, mode at -3.5‰). As already observed for other mines, the nitrogen contents of lower mantle diamonds were below detection (using FTIRS). The mutual shift of sublithospheric diamonds towards isotopic heavier compositions suggests a common carbon source, which may have inherited an isotopic heavy composition from a component consisting of subducted carbonates.  相似文献   

Water quality variation and clam growth: Is pH really a non-issue in estuaries?     

Amy H. Ringwood  Charles J. Keppler 《Estuaries and Coasts》2002,25(5):901-907

A tandem deployment system was used to critically evaluate relationships between important water chemistry parameters (pH, salinity, dissolved oxygen) and biotic performance based on clam growth. The effects of environmental conditions on growth of juvenile clams,Mercenaria mercenaria, were determined after 7-day field deployments in cages at reference sites from 1998 to 2000. Continuous measurements of the overlying water chemistry parameters were monitored by deploying an in situ water quality instrument (Hydrolab Datasonde) at the same time. While salinity was identified as an important determinant of clam growth over wide salinity ranges (10–35‰), pH was also found to be a very important parameter, especially in low-salinity regimes (<25‰). Average pH measurements ranged from 7.2 to 7.8; minimal pHs ranged from 6.9 to 7.6. The results indicated that when average pH levels fell below 7.5 or minimum pH levels fell below 7.2, growth rates were <50% that of clams deployed under higher pH conditions. Estuarine systems are generally perceived as being well-buffered so pH is frequently assumed to be unimportant, but our results suggest that pH levels can decline in estuarine systems to levels that can adversely affect biological responses. The potential impacts on biological resources of even moderate decreases in pH, particularly in systems that naturally tend to have lower pH conditions, may be more important than previously realized.  相似文献   

Rapp, G.R.: Archaeomineralogy (Natural Science in Archaeology Series)     

Charles R. Stern 《Mineralium Deposita》2002,38(5):649-649

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