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121.
The band positions of three partially overlapping Fe2+ spin-allowed transitions located between 4000 and 9000 cm–1 in almandine-pyrope and almandinespessartine garnets solid solutions were measured using near-infrared (NIR) spectroscopy. The crystal field stabilization energies (CFSE) along both binaries were calculated assuming a splitting of 1100 cm–1 for the lower orbitals. The CFSE show a slight increase along the almandine-spessartine binary from 3730 to 3810 cm–1 and a larger increase from 3730 to 3970 cm–1 for the almandine-pyrope binary. Dodecahedral Fe2+-site distortion increases with an increase in spessartine component and decreases with increasing pyrope component, in agreement with average dodecahedral site distortions determined from diffraction experiments. The excess CFSE's along both joins are negative. For the almandinespessartine binary they are small, but are about 3.5 times larger in magnitude along the join almandine-pyrope, where an interaction parameter of W= -2.9 KJ/mole has been derived from a symmetric mixing model. The excess CFSE are relatively small compared to the magnitudes of the excess enthalpies of mixing that have been assigned to garnet solid solutions. Moreover, they give no indication which could support the positive and asymmetric excess enthalpies of mixing that have been proposed for almandine-pyrope solid solutions. 相似文献
122.
A synoptic climatology of warm season heavy rainfall is developed from patterns of 850 mb thermal advection over the Appalachian region. Heavy rain events are categorized according to the position and orientation of a warm air advection (WAA) ridge, a feature found in nearly two-thirds of the events. Numerous study events occur within the conditionally unstable region of the WAA ridge. In fact, numerous occurrences of heavy rainfall are tied to a superpositioning of a WAA and air mass instability ridge in the vicinity or upstream of the heavy rain area. 相似文献
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124.
A precipitate of cobalt oxyhydroxides formed by bubbling oxygen through a dilute solution of Co(NO3)2 held at pH 9.0 and 25°C was aged for 23 months in contact with the original solution, with access to atmospheric oxygen. Co3O4 and CoOOH were identified in the precipitate by X-ray diffraction. Chemical equilibria involving these solids were evaluated by measurements of solution pH and Co2+ activities and by redox potential measurements and gave a of . This value and other thermodynamic data show relative feasibility of hypothetical reaction steps and changes in reaction paths during automated coprecipitation titrations and subsequent aging of a precipitate that finally contained βMnOOH, MnO2 (birnessite) and CoOOH. 相似文献
125.
Vindell Hsu Charles E. Helsley Eduard Berg David A. Novelo-Casanova 《Pure and Applied Geophysics》1984,122(6):878-893
A close correlation in spatial distribution of local seismic activity and energy release patterns before and after the 1979 Petatlan, Mexico earthquake suggests heterogeneity within the fault plane of this major low-angle thrust event associated with subduction along the Middle America Trench. A simple two-asperity model is proposed to account for the complexity. Foreshocks and aftershocks of the neighboring 1981 Playa Azul earthquake showed a similar pattern. As both events occurred at the junction of the Orozco Fracture Zone and the Middle America Trench, we speculate that the observed complex fault plane is caused by subduction of the rugged ocean floor of the Orozco Fracture Zone. Short-term precursory seismicity prior to the Petatlan earthquake can be explained by using the asperity model and migration of a slip front from the south-east to the north-west across the main shock source region. 相似文献
126.
Charles A. Lin 《Meteorology and Atmospheric Physics》1984,34(4):309-317
Summary The zonally averaged meridional energy transport is parameterized in terms of the zonally averaged temperature gradient and its radiative equilibrium value. Two climate regimes are identified: radiative equilibrium and isothermal climates. The transport and temperature gradient are intermediate between corresponding quantities of these two climates. The parameterization assumes a linear increase of transport as temperature gradient departs from its radiative equilibrium value. The parameterization is formulated using a one-dimensional climate model. Ice-albedo feedback provides the mechanism for climate changes. The parameterization works well for climates associated with seasonal changes.
With 4 Figures 相似文献
Parameterisierung des meridionalen Energiestromes in einem eindimensionalen Klimamodell
Zusammenfassung Der zonal gemittelte, meridionale Energietransport wird in Abhängigkeit vom zonal gemittelten Temperaturgradienten und seinem Strahlungsgleichgewicht parameterisiert. Zwei Klimaregime können identifiziert werden: Strahlungsgleichgewicht und isothermes Klima. Der Transport und der Temperaturgradient befinden sich zwischen den korrespondierenden Werten dieser zwei Klimate. Die Parameterisierung nimmt eine lineare Zunahme des Transportes mit der Abweichung des Temperaturgradienten vom seinem Strahlungsgleichgewichtswert an. Die Parameterisierung wird unter Verwendung eines eindimensionalen Klimamodelles formuliert. Die Eis-Albedo-Rückkopplung liefert den Mechanismus für Klimadnderungen. Die Parameterisierung funktioniert gut fur Klimate, welche jahreszeitliche Anderungen beinhalten.
With 4 Figures 相似文献
127.
Charles M. Onasch 《Tectonophysics》1984,110(1-2)
Compression and extension axes are deduced from quartz deformation lamellae in a quartzite and a graywacke folded into an asymetrical syncline. Deformation lamellae fabrics in the two sandstones are distinctly different. In the graywacke, regardless of bedding orientation or position on the fold, compression axes are normal or nearly normal to the axial planar rough cleavage. Extension axes generally lie in the cleavage plane, parallel to dip. In most quartzite samples, compression axes are parallel or subparallel to bedding, at high angles to the fold axis and extension axes are normal to bedding. Two samples from the very base of the formation indicate compression parallel to the fold axis with extension parallel to bedding, at high angles to the fold axis. One of these two shows both patterns. The lamellae fabric geometry in these two samples suggests the presence of a neutral surface in the quartzite. The lamellae-derived compression and extension axes are in good agreement with the buckling behavior of a viscous layer (quartzite) embedded in a less viscous medium (graywacke and shale below and shale and carbonate above). 相似文献
128.
Estuaries and Coasts - A coring system using a compressed air supply and a sediment shaking procedure using a soil dispersant are described which greatly simplify and shorten the task of... 相似文献
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130.