Volume thermal expansion along the jadeite–diopside join     

Francesco Pandolfo  Fernando Cámara  M. Chiara Domeneghetti  Matteo Alvaro  Fabrizio Nestola  Shun-Ichiro Karato  George Amulele 《Physics and Chemistry of Minerals》2015,42(1):1-14

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Effects of ocean acidification and high temperatures on the bryozoan Myriapora truncata at natural CO2 vents     

Riccardo Rodolfo‐Metalpa  Chiara Lombardi  Silvia Cocito  Jason M. Hall‐Spencer  Maria Cristina Gambi 《Marine Ecology》2010,31(3):447-456

There are serious concerns that ocean acidification will combine with the effects of global warming to cause major shifts in marine ecosystems, but there is a lack of field data on the combined ecological effects of these changes due to the difficulty of creating large‐scale, long‐term exposures to elevated CO₂ and temperature. Here we report the first coastal transplant experiment designed to investigate the effects of naturally acidified seawater on the rates of net calcification and dissolution of the branched calcitic bryozoan Myriapora truncata (Pallas, 1766). Colonies were transplanted to normal (pH 8.1), high (mean pH 7.66, minimum value 7.33) and extremely high CO₂ conditions (mean pH 7.43, minimum value 6.83) at gas vents off Ischia Island (Tyrrhenian Sea, Italy). The net calcification rates of live colonies and the dissolution rates of dead colonies were estimated by weighing after 45 days (May–June 2008) and after 128 days (July–October) to examine the hypothesis that high CO₂ levels affect bryozoan growth and survival differently during moderate and warm water conditions. In the first observation period, seawater temperatures ranged from 19 to 24 °C; dead M. truncata colonies dissolved at high CO₂ levels (pH 7.66), whereas live specimens maintained the same net calcification rate as those growing at normal pH. In extremely high CO₂ conditions (mean pH 7.43), the live bryozoans calcified significantly less than those at normal pH. Therefore, established colonies of M. truncata seem well able to withstand the levels of ocean acidification predicted in the next 200 years, possibly because the soft tissues protect the skeleton from an external decrease in pH. However, during the second period of observation a prolonged period of high seawater temperatures (25–28 °C) halted calcification both in controls and at high CO₂, and all transplants died when high temperatures were combined with extremely high CO₂ levels. Clearly, attempts to predict the future response of organisms to ocean acidification need to consider the effects of concurrent changes such as the Mediterranean trend for increased summer temperatures in surface waters. Although M. truncata was resilient to short‐term exposure to high levels of ocean acidification at normal temperatures, our field transplants showed that its ability to calcify at higher temperatures was compromised, adding it to the growing list of species now potentially threatened by global warming.  相似文献   

An adaptive capacity spectrum method for assessment of bridges subjected to earthquake action     

Chiara Casarotti  Rui Pinho 《Bulletin of Earthquake Engineering》2007,5(3):377-390

Estimating seismic demands on structures, to predict their performance level with confidence, requires explicit consideration of the structural inelastic behaviour: to this end, the use of nonlinear static procedures is inevitably going to be favoured over complex nonlinear time-history methods. The currently available assessment procedures have been tested predominantly against building frames. A newly derived assessment procedure is proposed within the scope of bridge applications, based on an innovative displacement-based adaptive pushover technique. The procedure, which can be incorporated into a performance-based engineering philosophy, is applicable to MDOF continuous span bridges with flexible or rigid superstructures, and for varying degrees of abutment restraint. As a first application to determine the viability of the proposed procedure, a parametric study is conducted on a ensemble of bridges subjected to earthquake motion. It is shown that, compared to the seismic demand estimated by means of the more accurate nonlinear dynamic analysis tool, the novel static assessment method can lead to the attainment of satisfactory predictions, both in terms of displacement as well as moment demand on members.  相似文献   

M1, M2 site populations and distortion parameters in synthetic Mg-Fe orthopyroxenes from Mössbauer spectra and X-ray structure refinements     

M. Chiara Domeneghetti  Gabriele Steffen 《Physics and Chemistry of Minerals》1992,19(5):298-306

Synthetic orthopyroxenes free of trivalent cations Mg _x Fe _2-x Si₂O₆ (x=0; 1; 1.6) were investigated using both Mössbauer spectroscopy (MS) and single-crystal X-ray diffraction (XRD) in order to compare the results obtained on the same samples by the two techniques. The Mg-Fe distribution over M1 and M2 octahedral sites was determined on compounds with x = 1 and x=1.6, unheated and annealed at 650, 850 and 1040° C for 29 to 42 hours to obtain different degrees of order. The data obtained by the two techniques are in very good agreement, thus suggesting, for these compositions, the absence of systematic errors. The investigation of a synthetic compound with x=0 (ferrosilite) confirmed that the accuracy of both methods is very good. The observed small discrepancies between the results are not significant if compared with the relevant standard deviations which, for both methods, were derived by leastsquares calculations. The best fit is obtained for Fe(M1)/ Fe(tot) parameters that, in both methods, are directly calculated without using data from chemical analysis. For the unheated samples the values by MS and XRD are respectively: 0.185(9) and 0.180(4) for x = 1.6; 0.282(8) and 0.285(2) for x=1; 0.503(7) and 0.502(1) for x=0. For all the investigated samples the correlation between the geometrical distortion parameters, calculated by X-ray refinement, and the quadrupole splitting values, measured by Mössbauer spectroscopy, agrees with the theoretical model of Ingalls (1964).  相似文献   

Representation of Uncertainty and Integration of PGIS-based Grazing Intensity Maps Using Evidential Belief Functions     

Jane Bemigisha  John Carranza  rew K. Skidmore  Mike McCall  Chiara Polce  Herbert H.T. Prins 《Transactions in GIS》2009,13(3):273-293

In a project to classify livestock grazing intensity using participatory geographic information systems (PGIS), we encountered the problem of how to synthesize PGIS-based maps of livestock grazing intensity that were prepared separately by local experts. We investigated the utility of evidential belief functions (EBFs) and Dempster's rule of combination to represent classification uncertainty and integrate the PGIS-based grazing intensity maps. These maps were used as individual sets of evidence in the application of EBFs to evaluate the proposition that " This area or pixel belongs to the high, medium, or low grazing intensity class because the local expert(s) says (say) so ". The class-area-weighted averages of EBFs based on each of the PGIS-based maps show that the lowest degree of classification uncertainty is associated with maps in which "vegetation species" was used as the mapping criterion. This criterion, together with local landscape attributes of livestock use may be considered as an appropriate standard measure for grazing intensity. The maps of integrated EBFs of grazing intensity show that classification uncertainty is high when the local experts apply at least two mapping criteria together. This study demonstrates the usefulness of EBFs to represent classification uncertainty and the possibility to use the EBF values in identifying and using criteria for PGIS-based mapping of livestock grazing intensity.  相似文献   

Reply to discussion by Elter and Padovano of ‘Deformation during exhumation of medium‐ and high‐grade metamorphic rocks in the Variscan chain in northern Sardinia (Italy)’     

Rodolfo Carosi  Chiara Frassi  Chiara Montomoli 《Geological Journal》2010,45(4):483-486

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Assessment of the role of facies heterogeneity at the fine scale by numerical transport experiments and connectivity indicators   总被引：2，自引：1，他引：1  

Chiara Vassena  Laura Cattaneo  Mauro Giudici 《Hydrogeology Journal》2010,18(3):651-668

The heterogeneity of facies at the scale of individual lithological levels controls, at a macroscopic scale, water flow and contaminant transport in porous sediments. In particular the presence of organized features such as permeable connected levels, has a significant effect on travel times and dispersion. Here, the effects of facies heterogeneity on flow and transport are studied for three blocks, whose volume is of the order of a cubic meter, dug from alluvial sediments from the Ticino valley (Italy). Using the results of numerical tracer experiments on these domains, the longitudinal dispersion coefficient is computed with an Eulerian approach based on the fit of the breakthrough curves with the analytical solution of the convective-dispersive transport equation. Moreover, the dispersion tensor is computed with a Lagrangian approach from the second order moments of particle distributions. Three types of connectivity indicators are tested: (1) connectivity function; (2) flow, transport and statistical connectivity; (3) original (intrinsic, normal and total) indicators of facies connectivity. The connectivity function provides the most complete information. Some of the transport and statistical connectivity indicators are correlated with dispersivity. The simultaneous analysis of the three indicators of facies connectivity emphasizes the fundamental geometrical features that control transport.  相似文献   

Construction of three-phase data to model multiphase flow in porous media: Comparing an optimization approach to the finite element approach     

Raphaël di Chiara Roupert  Gerhard Schäfer  Philippe Ackerer  Michel Quintard  Guy Chavent 《Comptes Rendus Geoscience》2010,342(11):855-863

Multiphase flow modelling is a major issue in the assessment of groundwater pollution. Three-phase flows are commonly governed by mathematical models that associate a pressure equation with two saturation equations. These equations involve a number of secondary variables that reflect the fluid behaviour in a porous medium. To improve the computational efficiency of multiphase flow simulators, several simplified reformulations of three-phase flow equations have been proposed. However, they require the construction of new secondary variables adapted to the reformulated flow equations. In this article, two different approaches are compared to quantify these variables. A numerical example is given for a typical fine sand.  相似文献   

A distributed thermodynamic model for energy and mass balance computation: FEST–EWB     

Chiara Corbari  Giovanni Ravazzani  Marco Mancini 《水文研究》2011,25(9):1443-1452

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Highly gravity-driven flow of a NAPL in water-saturated porous media using the discontinuous Galerkin finite-element method with a generalised Godunov scheme     

Lauriane Schneider  Raphaël di Chiara Roupert  Gerhard Schäfer  Philippe Helluy 《Computational Geosciences》2015,19(4):855-876

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