Phyllocladane in brown coal from Handlová, Slovakia: Isolation and structural characterization     

Anton Zubrik  David Šaman  Soňa Vašíčková  Bernd R.T. Simoneit  L’udmila Turčániová  Michal Lovás  Josef Cvačka 《Organic Geochemistry》2009,40(1):126-134

Aliphatic diterpenes were isolated from brown coal from Handlová, Slovakia, using microwave assisted extraction of mechanically activated coal powder. The parameters of the extraction procedure were optimized to get the target compounds in high yield. The total extract was separated using adsorption chromatography. GC–MS revealed tetracyclic and tricyclic diterpanes in the aliphatic fraction; they were identified as 16α(H)-phyllocladane (83%), isopimarane (11%), 18-norisopimarane (4%), abietane (2%) and fichtelite (<0.1%). It was found that more than 2 g of the most abundant diterpane, 16α(H)-phyllocladane could be extracted from 1 kg of Handlová coal. Because of the scarcity of relevant analytical data, 16α(H)-phyllocladane was thoroughly characterized by spectroscopic and chromatographic methods. A complete set of ¹H and ¹³C NMR data is given including their comparison with published values and ab initio calculations. EI mass and IR spectra of 16α(H)-phyllocladane are shown and discussed. Kováts retention indices measured on two common GC stationary phases are also given.  相似文献   

Preliminary health risk assessment for polybrominated diphenyl ethers and polybrominated dibenzo-p-dioxins/furans in seafood from Guangzhou and Zhoushan, China   总被引：1，自引：0，他引：1  

Miyake Y  Jiang Q  Yuan W  Hanari N  Okazawa T  Wyrzykowska B  So MK  Lam PK  Yamashita N 《Marine pollution bulletin》2008,57(6-12):357-364

Dietary intake is one of the important routes of human exposure to brominated flame retardants (BFRs) such as polybrominated diphenyl ethers (PBDEs). The use of PBDEs may also result in exposure to polybrominated dibenzo-p-dioxins and dibenzofurans (PBDDs/DFs), as these compounds are impurities in technical mixtures of BFRs and can also be formed unintentionally by the same processes that generate chlorinated dioxins. This study determined the concentrations of polybrominated compounds in common seafood in Guangzhou and Zhoushan, and assessed the health risks of these chemicals via consumption of contaminated seafood. Seafood samples (fish, bivalves, shrimp, crab, and cephalopods) purchased from local markets in 2003 and 2004 were analyzed for PBDEs and PBDDs/DFs. The highest concentration of total PBDEs (46.3 ng g(-1) lipid wt.) was detected in fish from Guangzhou, in which BDEs 47 and 209 were the two predominant congeners. The total daily intakes of PBDEs, PBDDs, and PBDFs were, 946, 6.39, and 6.54 pg kg(-1) body weight (bw) in Guangzhou, and 489, 4.99, and 7.65 pg kg(-1) bw in Zhoushan, respectively. The hazard ratios for PBDDs and PBDFs were both greater than unity, indicating that these compounds may pose some health risks to the local population.  相似文献   

Integration of the nuclease protection assay with sandwich hybridization (NPA-SH) for sensitive detection of Heterocapsa triquetra     

PARK Mirye  PARK So Yun  HWANG Jinik  JUNG Seung Won  LEE Juyun  CHANG Man  LEE Taek-Kyun 《海洋学报(英文版)》2018,(5)

Microalgae are photosynthetic microorganisms that function as primary producers in aquatic ecosystems. Some species of microalgae undergo rapid growth and cause harmful blooms in marine ecosystems. Heterocapsa triquetra is one of the most common bloom-forming species in estuarine and coastal waters worldwide. Although this species does not produce toxins, unlike some other Heterocapsa species, the high density of its blooms can cause significant ecological damage. We developed a H. triquetra species-specific nuclease protection assay sandwich hybridization(NPA-SH) probe that targets the large subunit of ribosomal RNA(LSU r RNA). We tested probe specificity and sensitivity with five other dinoflagellates that also cause red tides. Our assay detected H.triquetra at a concentration of 1.5×104 cells/m L, more sensitive than required for a red-tide guidance warning by the Korea Ministry of Oceans and Fisheries in 2015(3.0×104 cells/m L). We also used the NPA-SH assay to monitor H. triquetra in the Tongyeong region of the southern sea area of Korea during 2014. This method could detect H.triquetra cells within 3 h. Our assay is useful for monitoring H. triquetra under field conditions.  相似文献   

Reply to Comment on “Underwater Explosion (UWE) Analysis of the ROKS Cheonan Incident” by K. S. Kim     

So Gu Kim  Yefim Gitterman 《Pure and Applied Geophysics》2013,170(3):479-484

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Estimating snow distribution over a large area and its application for water resources     

So Kazama  Hirokazu Izumi  Priyantha Ranjan Sarukkalige  Takayuki Nasu  Masaki Sawamoto 《水文研究》2008,22(13):2315-2324

The spatial and temporal distribution of the snow water equivalent (SWE), snow density and snow depth were estimated by a method combining remote sensing technology and degree‐day techniques over a study area of 370 000 km². The advantages of this simulation model are its simplicity and the availability of degree‐day parameters, which can be successively evaluated by referring to snow area maps created from satellite images. This simulation worked very well for estimating SWE and helped to separate the areas of thin snow cover from heavier snowfall. However, shallow snow in warm regions led to some misjudgments in the snow area maps because of the time lag between when the satellite image was acquired and the simulation itself. Vulnerable areas, where a large variation in the amount of snow affects people's life, could be identified from the differences between heavy and light snow years. This vulnerability stems from a predicted lack of irrigation water for rice production caused by future climate change. The model developed in this study has the potential to contribute to water management activities and decision‐making processes when considering necessary adaptations to future climate change. Copyright © 2007 John Wiley & Sons, Ltd.  相似文献   

Relationships between tissue concentrations of paralytic shellfish toxins and antioxidative responses of clams, Ruditapes philippinarum     

Choi NM  Yeung LW  Siu WH  So IM  Jack RW  Hsieh DP  Wu RS  Lam PK 《Marine pollution bulletin》2006,52(5):572-578

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Distribution of perfluorinated compounds in surface seawaters between Asia and Antarctica   总被引：3，自引：0，他引：3  

Wei S  Chen LQ  Taniyasu S  So MK  Murphy MB  Yamashita N  Yeung LW  Lam PK 《Marine pollution bulletin》2007,54(11):1813-1818

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Influences of catchment characteristics on nitrogen concentration in largely forested streams during the base flow period     

Baolin Su  So Kazama  Seiichiro Katayama  Masaki Sawamoto 《水文研究》2006,20(20):4391-4403

Based on measured stream nitrogen concentrations at outlets of 12 small sub‐areas (1·3–54·7 km²) in a largely forested catchment during the base flow period, we investigated the influences of discharges and different catchment characteristics on stream nitrogen concentration. Our field surveys were carried out during the 11‐month's period from April 2001 to February 2002 and the correlations between nitrogen concentrations and catchment characteristics were studied. The results showed that the vegetation cover was strongly correlated to total nitrogen (TN) and nitrate + nitrite ? nitrogen (NO_x‐N) concentrations. That is, the TN and NO_x‐N concentrations had positive correlations with mean normalized difference vegetation cover index (NDVI) of each sub‐area during dormant seasons (mean NDVI < 0 · 70) and had negative correlations during the growing season (mean NDVI ≥ 0 . 70). The significance of catchment characteristics to TN and NO_x‐N concentrations was ranked as vegetation cover > soil > topography > land use, and the best models can account for 55–64% of the variance of TN and NO_x‐N concentrations. Copyright © 2006 John Wiley & Sons, Ltd.  相似文献   

HI shells in the Leiden-Dwingeloo HI survey     

Soňa Ehlerová  Jan Palouš  Richard Wünsch 《Astrophysics and Space Science》2004,289(3-4):279-282

An algorithm of an automatic search for HI shells is presentedand results of identifications in the Leiden-DwingelooHI survey are shown. An identification algorithm searches forlocal minima in channel maps, then creates 3-dimensional objects,HI holes. There is no a priori constraint on the shape of an HI hole, only the dimension criterion: dimensions of the structuremust lie in a preselected interval.When this algorithm is applied to the Leiden-Dwingeloo HI survey,it finds about 1000 structures, which are seen in 4 or more consecutivevelocity channels (Δ v ≥ 4 kms^-1. A total energy contained in all structures in the Milky Way is of theorder of 10⁵⁵ erg, which is less than the energy correspondingto the observed SNR. 80% of the energy contained in holes resides at low galactic z-coordinates, |z|<2 kpc.  相似文献   

Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea     

Gi-Tak Chae  Sung-Moon Yun  Kyoung-Ho Kim  Chil-Sup So 《水文科学杂志》2013,58(8):1672-1683

Abstract

In order to evaluate groundwater quality and geochemical reactions arising from mixing between seawater and dilute groundwater, we performed a hydrochemical investigation of alluvial groundwater in a limestone-rich coastal area of eastern South Korea. Two sites were chosen for comparison: an upstream site and a downstream site. Data of major ion chemistry and ratios of oxygen–hydrogen isotopes (δ¹⁸O, δD) revealed different major sources of groundwater salinity: recharge by sea-spray-affected precipitation in the upstream site, and seawater intrusion and diffusion zone fluctuation in the downstream site. The results of geochemical modelling showed that Ca²⁺ enrichment in the downstream area is caused by calcite dissolution enhanced by the ionic strength increase, as a result of seawater–groundwater mixing under open system conditions with a constant P_CO2 value (about 10^?1.5 atm). The results show that, for coastal alluvial groundwater residing on limestone, significant hydrochemical change (especially increased hardness) due to calcite dissolution enhanced by seawater mixing should be taken into account for better groundwater management. This process can be effectively evaluated using geochemical modelling.

Editor D. Koutsoyiannis; Associate editor Y. Guttman

Citation Chae, G.-T., Yun, S.-T., Yun, S.-M., Kim, K.-H., and So, C.-S., 2012. Seawater–freshwater mixing and resulting calcite dissolution: an example from a coastal alluvial aquifer in eastern South Korea. Hydrological Sciences Journal, 57 (8),1–12.  相似文献