Kinetic study of the kaolinite-mullite reaction sequence. Part I: Kaolinite dehydroxylation     

M. Bellotto  A. Gualtieri  G. Artioli  S. M. Clark 《Physics and Chemistry of Minerals》1995,22(4):207-217

The decomposition reaction of kaolinite has been investigated as a function of the defectivity of the starting material and the temperature of reaction. Time resolved energy-dispersive powder diffraction patterns have been measured using synchrotron radiation, both under a constant heating rate (heating rates from 10 to 100° C/min) and in isothermal conditions (in the temperature range 500 to 700° C). The apparent activation energy of the dehydroxylation process is different for kaolinites exhibiting a different degree of stacking fault density. The results of the analysis of the kinetic data indicate that the starting reaction mechanism is controlled by diffusion in the kaolinite particle. The diffusion process is dependent on the defective nature of both kaolinite and metakaolinite. At high temperatures, and at higher heating rates, the reaction mechanism changes and the resistance in the boundary layer outside the crystallites becomes the rate-limiting factor, and nucleation begins within the reacting particle. During the final stage of the dehydroxylation process the reaction is limited by heat or mass transfer, and this might be interpreted by the limited diffusion between the unreacted kaolinite domains and the metakaolinite matrix.  相似文献   

Paraffin hydrocarbon patterns in petroleum-polluted mussels     

Robert C Clark  John S Finley 《Marine pollution bulletin》1973,4(11):172-176

This paper explains how modern analytical techniques can be used to detect hydrocarbons in marine organisms at extremely low concentrations, below those detectable by taste or smell.  相似文献   

High-temperature condensates in chondrites and the environment in which they formed     

L Grossman  S.P Clark 《Geochimica et cosmochimica acta》1973,37(3):635-649

Chemical compositions of melilitee and titaniferous pyroxenes in calcium- and aluminum-rich inclusions in carbonaceous chondrites are consistent with their origin as hightemperature condensates from a gas of solar composition. Thermodynamic calculations indicate that the highest temperature minerals equilibrated with the gas at temperatures in excess of 1400°K. The lack of evidence for direct condensation of gas to liquid enables us to set an upper limit to the pressure when the inclusions formed which may be as low as 2.2 × 10^?3atm. Glasses, which are commonly found in chondrules, are interpreted as quench products of liquids formed by secondary reheating of primary solid condensates. The high-temperature inclusions constitute evidence that accretion of grains to cm-sized objects occurred at a very early stage in the evolution of the solar nebula.  相似文献   

Oil on Puget Sound: Supervised by Juris Vagners,coordinated by Paul Mar. Published by Washington Sea Grant. Distributed by University of Washington Press,Seattle, Washington,USA 98195 (1972). 648 pp. Price $10.00     

Robert C. Clark 《Marine pollution bulletin》1973,4(2):31

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V473 Lyrae: a Blazhko-effect Cepheid?     

Chris Koen 《Monthly notices of the Royal Astronomical Society》2001,322(1):97-99

The amplitude spectra of the light curves of RR Lyrae Blazhko stars can often be typified by symmetrical triplets. It is shown that the same applies to V473 Lyr. Furthermore, the star is probably a radial pulsator – as is thought to be the case for the RR Lyrae stars – thus ruling out rotational splitting of a purely non-radial mode.  相似文献   

Studies of the solar chromosphere from millimetre and sub-millimetre observations     

J. E. Beckman  C. D. Clark 《Solar physics》1973,29(1):25-39

Spectroheliograms were obtained in bands centred at 1.2 mm, 0.8 mm and 0.4 mm wavelength during 1969 and 1971. In order to obtain photometrically valid data, a specialized set of reduction techniques was employed, obviating the effects of severe differential attenuation across the disc by atmospheric water vapour and of emission noise from the atmosphere, before taking out the instrumental spread functions of the telescope and detector.Comparison of our maps with those of other observers at 3 mm and 8.6 mm wavelength suggests that the chromospheric brightness temperature increments above active regions show a monotonic increase with increasing height above the photosphere over the normal increase in brightness temperature in the quiet chromosphere. Within the limit of angular resolution of 3 available, no evidence was recorded of normal limb brightening in our three passbands but the presence of isophotes at 50% of the central disc temperature consistently circumscribing the optical limb implies a narrow spike of sub-millimetre brightening close to the limb.  相似文献   

Saturn's satellites: Nuar-infrared spectrophotometry (0.6–2.5 μm) of the leading and trailing sides and compositional implications     

Roger N. Clark  Robert H. Brown  Pamela D. Owensby  Alex Steele 《Icarus》1984,58(2):265-281

Near-infrared spectra, 0.65–2.5 μm, are presented for Tethys, Dione, Rhea, Iapetus, and Hyperion. Water ice absorptions at 2.0, 1.5, and 1.25 μm are seen in the spectra of all five objects (except the 1.25-μm band was not detected in spectra of Hyperion) and the weak 1.04-μm ice absorption is detected on the leading and trailing sides of Rhea, and the trailing side of Dione. Upper limits to the 1.04-μm ice band depth are <0.3% for the leading side of Dione; <0.7% for the leading side of Iapetus, and the trailing side of Tethys; <1% on the trailing side of Iapetus; and <5% on the leading side of Tethys. The leading-trailing side ice band depth differences on Saturn's satellites are similar to those for the Galilean satellites, indicating possible surface modification by magnetospheric charged particle bombardment. Limits are determined for the amount of particulates, trapped gases, and amonium hydroxide on the surface. The surfaces of Saturn's satellites (except the dark side of Iapetus) are nearly pure water ice, with probably less than about 1 wt% particulate minerals. The ice could be clathrates with as much as a few weight percent trapped gases. The upper limit of amonium hydroxide depends on the spectral data precision and varies from ～ 1 wt% NH₃ for the leading side of Rhea to ～ 10 wt% NH₃ for Dione.  相似文献   

Chromospheric magnetic fields associated with supergranulation     

Alfred Clark Jr. 《Solar physics》1968,4(4):386-400

Some theoretical models are given which illustrate the structure of chromospheric magnetic fields associated with supergranulation. It is found that the chromospheric fields depend critically on whether or not there are large-scale vertical motions at the level where the horizontal supergranule motions are observed. In the absence of such motions, the concentration of field produced in the photosphere does not persist more than a few scale heights into the chromosphere; however, the chromospheric mass density is increased above the supergranule boundaries in this case. Completely different results-such as a chromospheric potential field-may be obtained by the inclusion of vertical motions. It is concluded that a rather wide range of chromospheric-field structures is consistent with present observational knowledge of the supergranulation.  相似文献   

J, H, K photometry of 433 Eros and other asteroids     

Clark R. Chapman  David Morrison 《Icarus》1976,28(1):91-94

We report photometry for nine asteroids at wavelengths of 1.25, 1.65, and 2.22 μm. Three C-type objects (88, 129, and 511) seem slightly redder in H?K and J?H color indices than four S-type objects (5, 6, 7, and 116) and an E-type object (64). Eros has an unusually red J?H color index; its infrared spectral reflectance is consistent with an appreciable quantity of metallic iron plus some pyroxene and olivine on its surface. JHK photometry is less diagnostic of composition than either higher resolution spectrophotometry in the infrared or spectrophotometry at shorter wavelengths.  相似文献   

Preface     

Simon M. Cargill  Allen L. Clark 《Mathematical Geology》1978,10(5):405-406

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