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31.
This study evaluated the toxicity of dispersant application which is, in nearshore area, a controversial response technique to oil spill. Through an experimental approach with juveniles of Liza aurata, the toxicity of five exposure conditions was evaluated: (i) a chemically dispersed oil simulating dispersant application; (ii) a single dispersant as an internal control of chemically dispersed oil; (iii) a mechanically dispersed oil simulating natural dispersion of oil; (iv) a water soluble fraction of oil simulating an undispersed and untreated oil slick and (v) uncontaminated seawater as a control exposure condition. The relative concentration of PAHs (polycyclic aromatic hydrocarbons) biliary metabolites showed that the incorporation of these toxic compounds was increased if the oil was dispersed, whether mechanically or chemically. However, toxicity was not observed at the organism level since the aerobic metabolic scope and the critical swimming speed of exposed fish were not impaired.  相似文献   
32.
Hydrological classification systems seek to provide information about the dominant processes in the catchment to enable information to be transferred between catchments. Currently, there is no widely agreed‐upon system for classifying river catchments. This paper develops a novel approach to classifying catchments based on the temporal dependence structure of daily mean river flow time series, applied to 116 near‐natural ‘benchmark’ catchments in the UK. The classification system is validated using 49 independent catchments. Temporal dependence in river flow data is driven by the flow pathways, connectivity and storage within the catchment and can thus be used to assess the influence catchment characteristics have on moderating the precipitation‐to‐flow relationship. Semi‐variograms were computed for the 116 benchmark catchments to provide a robust and efficient way of characterising temporal dependence. Cluster analysis was performed on the semi‐variograms, resulting in four distinct clusters. The influence of a wide range of catchment characteristics on the semi‐variogram shape was investigated, including: elevation, land cover, physiographic characteristics, soil type and geology. Geology, depth to gleyed layer in soils, slope of the catchment and the percentage of arable land were significantly different between the clusters. These characteristics drive the temporal dependence structure by influencing the rate at which water moves through the catchment and/or the storage in the catchment. Quadratic discriminant analysis was used to show that a model with five catchment characteristics is able to predict the temporal dependence structure for un‐gauged catchments. This method could form the basis for future regionalisation strategies, as a way of transferring information on the precipitation‐to‐flow relationship between gauged and un‐gauged catchments. © 2014 The Authors. Hydrological Processes by published by John Wiley & Sons, Ltd.  相似文献   
33.
Effective national and regional policy guidance on climate change adaptation relies on robust scientific evidence. This two-part series of papers develops and implements a novel scenario-neutral framework enabling an assessment of the vulnerability of flood flows in British catchments to climatic change, to underpin the development of guidance for the flood management community. In this first part, the sensitivity of the 20-year return period flood peak (RP20) to changes in precipitation (P), temperature (T) and potential evapotranspiration (PE) is systematically assessed for 154 catchments. A sensitivity domain of 4,200 scenarios is applied combining 525 and 8 sets of P and T/PE mean monthly changes, respectively, with seasonality incorporated using a single-phase harmonic function. Using the change factor method, the percentage change in RP20 associated with each scenario of the sensitivity domain is calculated, giving flood response surfaces for each catchment. Using a clustering procedure on the response surfaces, the 154 catchments are divided into nine groups: flood sensitivity types. These sensitivity types show that some catchments are (very) sensitive to changes in P but others buffer the response, while the location of catchments of the same type does not show any strong geographical pattern. These results reflect the range of hydrological processes found in Britain, and demonstrate the potential importance of catchment properties (physical and climatic) in the propagation of change in climate to change in floods, and so in characterising the sensitivity types (covered in the companion paper).  相似文献   
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