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101.
Tropical mobile mud belts represent a major class of biogeochemical and diagenetic systems characterized by extensive and frequent physical reworking of fine-grained, organic-rich deposits underlying oxygenated waters. Large regions of the Gulf of Papua, Papua New Guinea deltaic complex are dominated by such conditions. A reworked mud belt lies within the inner shelf between 10 and 20 m depth on a sedimentary clinoform derived from coalescing deltas. Deposits across the topset are typically suboxic, nonsulfidic over the upper 0.5–1 m, and have low to moderate maximum pore water concentrations of dissolved Fe(II) and Mn(II) (100–200, but up to 800 μM). Sediments are reactive, with surficial ΣCO2 production 0.1–0.3 mM d−1 and benthic O2 fluxes 23±15 mmol m−2 d−1 (upper 20 cm). The highest rates occur within inner topset deposits (10–20 m) and near the high accumulation rollover region of the topset–foreset beds (40–50 m). Lower rates are found inshore along intertidal channels—mangrove fringe and within scoured or exposed consolidated deposits of the middle topset region. Remineralization rate patterns are independent of relative dominance by terrestrial or marine carbon in sediments. Dissolved O2 usually penetrates 2–5 mm into surface sediments when macrofaunal burrows are absent. More than 75% of the highly reactive sedimentary Fe(III) pool (350–400 μmol g−1) is typically diagenetically reduced in the upper 0.5 m. Pore water can be measureably depleted at depths >0.5 m, but dissolved H2S generally remains below detection over the upper 1–2 m. As in other deltaic topset regions, concentration gradients often indicate that compared to many marine deposits of similar sediment accumulation rates, relatively refractory Corg is supplied to the SO4 reducing zone. Sedimentary C/S ratios are 4–6 within the suboxic topset regions but decrease to <3 in offshore foreset beds where sulfidic diagenesis dominates. Only 15–20% of the diagenetically reduced Fe(II) is pyritic and a maximum of 10–25% is carbonate, implying that most Fe(II) is associated with authigenic or lithogenic silicates or oxides. The dominance of suboxic, nonsulfidic diagenetic processes reflect coupling between delivery of oxide-rich terrestrial debris, remobilization and reoxidation of deposits, and repetitive entrainment/remineralization of both labile and refractory organics. Distinct sedimentary indicators of reactive, suboxic mobile mud belts within tropical climatic zones are: abundant total highly reactive Fe (ΣFeR )>300 μmol g−1; most reactive Fe is diagenetically reduced (ΣFe(II)/ΣFeR0.7–0.8); the proportion of diagenetically reduced Fe present as pyrite is low (Py–Fe(II)<0.2); C/S 4–8; and Corg/particle surface area <0.4 (mg C m−2). These depositional environments must be most common in tropical climates during high sea stand.  相似文献   
102.
Environmental models constructed with a spatial domain require choices about the representation of space. Decisions in the adaptation of a spatial data model can have significant consequences on the ability to predict environmental function as a result of changes to levels of aggregation of input parameters and scaling issues in the processes being modelled. In some cases, it is possible to construct a systematic framework to evaluate the uncertainty in predictions using different spatial models; in other cases, the realm of possibilities plus the complexity of the environmental model in question may inhibit numeric uncertainty estimates. We demonstrate a range of potential spatial data models to parameterize a landscape‐level hydroecological model (RHESSys). The effects of data model choice are illustrated, both in terms of input parameter distributions and resulting ecophysiological predictions. Predicted productivity varied widely, as a function of both the number of modelling units, and of arbitrary decisions such as the origin of a raster grid. It is therefore important to use as much information about the modelled environment as possible. Combinations of adaptive methods to evaluate distributions of input data, plus knowledge of dominant controls of ecosystem processes, can help evaluate potential representations. In this case, variance‐based delineation of vegetation patches is shown to improve the ability to intelligently choose a patch distribution that minimizes the number of patches, while maintaining a degree of aggregation that does not overly bias the predictions.  相似文献   
103.
The Vaikijaur Cu–Au–(Mo) deposit is located in the ca. 1.88 Ga calc-alkaline Jokkmokk granitoid near the Archaean–Proterozoic palaeoboundary within the Fennoscandian shield of northern Sweden. The Skellefte VMS district lies immediately to the south and the northern Norrbotten Fe-oxide–Cu–Au deposits to the north. The Vaikijaur deposit occupies an area of 2×3 km within the Jokkmokk granitoid and includes stockwork quartz-sulphide veinlets and disseminated chalcopyrite, pyrite, gold, molybdenite, magnetite, and pyrrhotite. Porphyritic mafic dykes were emplaced along fractures in a ring dyke pattern. The Jokkmokk granitoid, dykes, and the mineralized area are foliated, indicating that mineralization predated the main regional deformation. The mineralized area is characterized by strong potassic alteration. Phyllic and propylitic alteration zones are also present. A pyrite-rich inner core is surrounded by a concentric zone with pyrite, chalcopyrite, and gold. Molybdenite is distributed irregularly throughout the chalcopyrite zone. Geophysical data indicate a strongly conductive central zone in the mineralized area bordered by conductive and high magnetic zones. Five high precision Re–Os age determinations for three molybdenite occurrences from outcrop and drill core samples constrain the age of porphyry-style Cu–Au–(Mo) mineralization to between 1889±10 and 1868±6 Ma. A younger molybdenite is associated with a much later metamorphic event at about 1750 Ma. These data suggest that primary porphyry-style mineralization was associated with calc-alkaline magmatism within the Archaean–Proterozoic boundary zone at ca. 1.89–1.87 Ga.  相似文献   
104.
In 1963, Gandin published a monograph on “optimum interpolation for the objective analysis of meteorological fields, ? a method that is similar mathematically to geodetical least-squares prediction and collocation, simple kriging, and spectral interpolation. The common problem is the interpolation or extrapolation or estimation of a continuous spatial property from finitely many observations. Gandin 's method is presented in an inverse-theoretical context with focus on a methodological comparison with related methods. Underlying mathematical assumptions as well as geological implications are discussed. An introductory overview of inverse methods in the earth sciences is given, with emphasis on methods with a structure analysis step.  相似文献   
105.
The Aitik Cu–Au–Ag deposit is located in northern Sweden and is hosted by strongly deformed 1.9 Ga Svecofennian volcano-sedimentary rocks. The main copper mineralization, which occurs as disseminations and veinlets, is hosted by garnet–biotite schist. Subeconomic mineralization in the footwall to the ore is hosted by feldspar–biotite–amphibole gneiss and porphyritic quartz monzodiorite. The deposit has been affected by post-mineralization metamorphic and igneous activity. Fluid inclusions in six samples of copper-mineralized quartz veins record the presence of three different fluid populations. The main ore was deposited from an aqueous, highly saline (31–37 eq. wt% NaCl + CaCl2) fluid. This fluid was trapped in inclusions intimately associated with the main chalcopyrite mineralization. Later bornite deposition took place from a less saline (18–27 eq. wt% NaCl + CaCl2), aqueous fluid. A third fluid composed of almost pure CO2, interacted with the copper-rich system during a post-ore event. The Aitik Cu–Au–Ag deposit shares some features with both porphyry-type and Fe-oxide–Cu–Au deposits. A high calcium content of the ore fluids, similar to other Cu–Au deposits in northern Scandinavia, suggests a contribution to the salinity of the mainly magmatic-hydrothermal fluids from evaporitic rocks in stratigraphically lower units.  相似文献   
106.
This paper explores the changing relationship of a region (Hawkes Bay, New Zealand), its industries and enterprises to Asia-Pacific industrial complexes. Land-based industries in Hawkes Bay provide examples of new connections and local adaptations of production to emerging agro-food and forestry complexes, centred upon East Asia. Integration into these complexes, which has only been possible in the context of the gradual relaxation of regulatory regimes that has occurred over the past two decades, has facilitated access to new markets. In some cases, integration is an outcome of East Asian ownership of New Zealand-based nodes along the commodity chain. In others, it is an outcome of New Zealand actors producing to meet 'site of consumption' demand. The paper concludes that new dynamics in the spheres of trade, production and investment are instituted by and feed into new geographic links and interactions, referred to in the paper as a rescaling of the region.  相似文献   
107.
It is well known that the majority of buoy measurements are located around the US coast and along some Europeans countries. The lack of long-term and densely spaced in situ measurements in the Southern Hemisphere in general, and the South Atlantic in particular, hinders several investigations due to the lack of detailed metocean information. Here, we present an effort to overcome this limitation, with a dense network of buoys along the Brazilian coast, equipped with several meteorological and oceanographic sensors. Out of ten currently operational buoys, three are employed to present the main characteristics of waves in the Southern part of the network. For the first time, sensor characteristics and settings are described, as well as the methods applied to the raw wave data. Statistics and distributions of wave parameters, swell propagating events, comparison with a numerical model and altimeters and a discussion about the occurrence of freak waves are presented.  相似文献   
108.
Land use and marine spatial planning processes are increasingly supported by systematic assessment techniques, particularly by multi‐criteria spatial analysis methods. This has been facilitated by the growing release and uptake of web‐mapping tools, which contribute to transparent, consistent, and informed planning processes and decisions. This article reviews the usability, functionality, and applicability of contemporary planning web‐mapping tools to identify the state‐of‐the‐art and future prospects. The review reveals that interfaces are increasingly available and intuitively applicable by non‐specialized users. Basic map navigation and data querying functionality is being expanded to incorporate advanced map‐making and online data geoprocessing capabilities that enable deriving new data and insights. However, the majority of published planning web tools are one‐off solutions, and a disconnect between research and practice is rendering many of these inaccessible or obsolete. Despite the significant progress made in advancing their provision in the last decade, there is a need for developing transferable interfaces that are maintained beyond project end dates, for them to effectively and consistently support planning processes.  相似文献   
109.
Global, high-quality, satellite-based observation of oceanic currents over the past 13 years has revealed ubiquitous quasi-horizontal eddies in the mesoscale (tens to hundreds of kilometers), confirming the view of a highly turbulent ocean suggested by observational programs in the 1970s. Idealized quasigeostrophic turbulence models suggest mesoscale turbulent flow can vary between isotropic, and highly anisotropic zonal jets. Here we compare the zonal and meridional velocity variance from satellite altimetry. We find that, for an unexplained reason and despite the chaotic nature of turbulence, the surface flow is organized into mesoscale patches where either zonal or meridional velocity variance dominates. The patches persist over 13 years, much longer than the turbulent timescale of a few months. Implications include potentially highly anisotropic redistribution of tracers by the mesoscale flow. Zonally averaged velocity variances reveal a slight preference for meridional over zonal velocity variance. Realistic primitive equation models succeed in reproducing both the patchy structure in local preference for either zonal or meridional velocity variance, and the zonally averaged preference for meridional variance. Idealized models of fully developed, quasigeostrophic turbulence fail in both regards.  相似文献   
110.
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