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21.
Fractional crystallization of peraluminous F- and H2O-rich granite magmas progressively enriches the remaining melt with volatiles. We show that, at saturation, the melt may separate into two immiscible conjugate melt fractions, one of the fractions shows increasing peraluminosity and the other increasing peralkalinity. These melt fractions also fractionate the incompatible elements to significantly different degrees. Coexisting melt fractions have differing chemical and physical properties and, due to their high density and viscosity contrasts, they will tend to separate readily from each other. Once separated, each melt fraction evolves independently in response to changing T/P/X conditions and further immiscibility events may occur, each generating its own conjugate pair of melt fractions. The strongly peralkaline melt fractions in particular are very reactive and commonly react until equilibrium is attained. Consequently, the peralkaline melt fraction is commonly preserved only in the isolated melt and mineral inclusions.

We demonstrate that the differences between melt fractions that can be seen most clearly in differing melt inclusion compositions are also visible in the composition of the resulting ore-forming and accessory minerals, and are visible on scales from a few micrometers to hundreds of meters.  相似文献   

22.
Evolution of the late Cenozoic Chaco foreland basin, Southern Bolivia   总被引:3,自引:1,他引:3  
Eastward Andean orogenic growth since the late Oligocene led to variable crustal loading, flexural subsidence and foreland basin sedimentation in the Chaco basin. To understand the interaction between Andean tectonics and contemporaneous foreland development, we analyse stratigraphic, sedimentologic and seismic data from the Subandean Belt and the Chaco Basin. The structural features provide a mechanism for transferring zones of deposition, subsidence and uplift. These can be reconstructed based on regional distribution of clastic sequences. Isopach maps, combined with sedimentary architecture analysis, establish systematic thickness variations, facies changes and depositional styles. The foreland basin consists of five stratigraphic successions controlled by Andean orogenic episodes and climate: (1) the foreland basin sequence commences between ~27 and 14 Ma with the regionally unconformable, thin, easterly sourced fluvial Petaca strata. It represents a significant time interval of low sediment accumulation in a forebulge‐backbulge depocentre. (2) The overlying ~14–7 Ma‐old Yecua Formation, deposited in marine, fluvial and lacustrine settings, represents increased subsidence rates from thrust‐belt loading outpacing sedimentation rates. It marks the onset of active deformation and the underfilled stage of the foreland basin in a distal foredeep. (3) The overlying ~7–6 Ma‐old, westerly sourced Tariquia Formation indicates a relatively high accommodation and sediment supply concomitant with the onset of deposition of Andean‐derived sediment in the medial‐foredeep depocentre on a distal fluvial megafan. Progradation of syntectonic, wedge‐shaped, westerly sourced, thickening‐ and coarsening‐upward clastics of the (4) ~6–2.1 Ma‐old Guandacay and (5) ~2.1 Ma‐to‐Recent Emborozú Formations represent the propagation of the deformation front in the present Subandean Zone, thereby indicating selective trapping of coarse sediments in the proximal foredeep and wedge‐top depocentres, respectively. Overall, the late Cenozoic stratigraphic intervals record the easterly propagation of the deformation front and foreland depocentre in response to loading and flexure by the growing Intra‐ and Subandean fold‐and‐thrust belt.  相似文献   
23.
The nature and origin of the sediments and crust of the Murray Ridge System and northern Indus Fan are discussed. The uppermost unit consists of Middle Miocene to recent channel–levee complexes typical of submarine fans. This unit is underlain by a second unit composed of hemipelagic to pelagic sediments deposited during the drift phase after the break-up of India–Seychelles–Africa. A predrift sequence of assumed Mesozoic age occurring only as observed above basement ridges is composed of highly consolidated rocks. Different types of the acoustic basement were detected, which reflection seismic pattern, magnetic anomalies and gravity field modeling indicate to be of continental character. The continental crust is extremely thinned in the northern Indus Fan, lacking a typical block-faulted structure. The Indian continent–ocean transition is marked on single MCS profiles by sequences of seaward-dipping reflectors (SDR). In the northwestern Arabian Sea, the Indian plate margin is characterized by several phases of volcanism and deformation revealed from interpretation of multichannel seismic profiles and magnetic anomalies. From this study, thinned continental crust spreads between the northern Murray Ridge System and India underneath the northern Indus Fan.  相似文献   
24.
Syntectonic antitaxial and ataxial fibrous veins were investigated using SEM, microprobe, cathodoluminescence (CL) and optical microscopy. In antitaxial calcite veins, fibres and surrounding selvage grew simultaneously, with similar growth rates of crystallographically differently oriented grains. New material precipitated at the vein margin in antitaxial and bi-mineralic ataxial microstructures. Bridges of country rock material formed during vein growth in an initial en-echelon vein system. In our antitaxial and bi-mineralic ataxial samples, the spacing of solid inclusions does not reflect individual crack-seal openings.  相似文献   
25.
We present a new procedure, the pdf method (pdf=probability density function), for reconstructing Quaternary climate utilizing botanical data. The procedure includes the advantages of the indicator species method by considering the fossil and modern presence and absence of taxa rather than their frequencies, thus avoiding the need for modern analog plant communities. Overcoming the problematic use of absolute limits to describe climate response ranges is the main progress of the pdf method in comparison to the indicator species method. This advantage results from estimating probability density functions (pdfs) for monthly mean January and July temperature conditional on the present day occurrence of single taxa. Gaussian distributions sufficiently approximate pdfs of many, although not all, studied taxa. On the assumption of statistical independence, the procedure calculates a joint pdf as the product of the pdfs of the individual taxa. This algorithm weights each taxon according to the extent of its climate response range expressed by its covariance structure. We interpret the maximum of the resulting pdf as the most likely climate and its confidence interval as the uncertainty range. To avoid an artificial reduction of uncertainty arising from the use of numerous similar pdfs, a preselection method is proposed based on the Mahalanobis distance between pdfs. The pdf method was applied to the Carpinus phase of a profile from Gröbern, Germany, that spans the last interglaciation (Eemian). The reconstructed most probable January and July temperatures of about 0.0°C and 18.4°C barely differ from the modern values of −0.5°C and 18.3°C.  相似文献   
26.
Sedimentological, granulometric and petrographic data are presented from a detailed study on a crystal-rich mass flow deposit, which is presumably related to the eruption of a sublacustrine cryptodome. The deposit forms a prominent intercalation in the Lower Permian Collio Formation in the Italian Alps north of Brescia. Outcrops of the 10–20-m-thick volcaniclastic deposit (Dasdana I Beds, DB) can be traced over 12 km from east to west. The DB consists of a thick, crystal-rich, sandy–gravelly lower subunit representing a sequence of amalgamated Bouma-a(b) divisions overlain by a thin, well-bedded, sandy–muddy subunit that is rich in outsize porphyritic silicic fragments. Modal and computer-aided image analyses reveal that the crystal-rich lower subunit contains up to 80% of volcanogenic crystals. Some samples contain up to 60% of porphyritic fragments, which have a phenocryst content of about 20%. The wide textural range from cryptocrystalline, poikilomosaic, to rarer medium-grained granophyric groundmass, the irregular to lensoid shapes of the porphyritic fragments, and the presence of basement and sedimentary clasts suggest that the DB originated from a sublacustrine eruption of a partially extrusive cryptodome (ca. 1.6 km3). Two other porphyritic felsic cryptodomes (Dosso dei Lupi, Dosso del Bue), described briefly here, emplaced into the Collio Formation sometime after the DB event, and expose flat bases and tilted sediments at their sides. Textures observed in these domes are comparable to those found in the DB porphyritic fragments.  相似文献   
27.
Provenance studies on Early to Middle Ordovician clastic formations of the southern Puna basin in north-western Argentina indicate that the sedimentary detritus is generally composed of reworked crustal material. Tremadoc quartz-rich turbidites (Tolar Chico Formation, mean composition Qt89 F7 L4) are followed by volcaniclastic rocks and greywackes (Tolillar Formation, mean Qt33 F42 L25). These are in turn overlain by volcaniclastic deposits (mean Qt24 F30 L46) of the Diablo Formation (late Arenig–early Llanvirn) that are intercalated by lava flows. All units were deformed in the Oclóyic Orogeny during the Middle and Late Ordovician. Sandstones of the Tolar Chico Formation are characterized by Th/Sc ratios > 1, La/Sc ratios ≈ 10, whereas associated fine-grained wackes show slightly lower values for both ratios. LREE (light rare earth elements) enrichment of the arenites is ≈ 50× chondrite, Eu/Eu* values are between 0·72 and 0·92, and flat HREE (heavy rare earth elements) patterns indicate a derivation from mostly felsic rocks of typical upper crustal composition. The εNd(t = sed) values scatter around −11 to −9. The calculated Nd-TDM residence ages vary between 1·8 and 2·0 Ga indicating contribution by a Palaeoproterozoic crustal component. The Th/Sc and La/Sc ratios of the Tolillar Formation are lower than those of the Tolar Chico Formation. Normalized REE (rare earth elements) patterns display a similar shape to PAAS (post-Archaean average Australian shale) but with higher abundances of HREEs. Eu/Eu* values range between 0·44 and 1·17, where the higher values reflect the abundance of plagioclase and feldspar-bearing volcanic lithoclasts. Average εNd(t = sed) values are less negative at −5·1, and Nd-TDM are lower at 1·6 Ga. This is consistent with characteristics of regional rocks of upper continental crust composition, which most probably represent the sources of the studied detritus. The rocks of the Diablo Formation have the lowest Th/Sc and La/Sc ratios, lower LREE abundances than the average continental crust and are slightly enriched in HREEs. Eu/Eu* values are between 0·63 and 1·17. The Nd isotopes (εNd(t = sed) = −3 to −1; TDM = 1·2 Ga) indicate that one source component was less fractionated than both the underlying Early Ordovician and the overlying Middle Ordovician units. Synsedimentary vulcanites in the Diablo Formation show the same isotopic composition. Our data indicate that the sedimentary detritus is generally composed of reworked crustal material, but that the Diablo Formation appears to contain ≈ 80% of a less fractionated component, derived from a contemporaneous continental volcanic arc. There are no data indicating an exotic detrital source or the accretion of an exotic block at this part of the Gondwana margin during the Ordovician.  相似文献   
28.
Strontium isotope evolution of Late Permian and Triassic seawater   总被引:7,自引:0,他引:7  
The 87Sr/86Sr values based on brachiopods and conodonts define a nearly continuous record for the Late Permian and Triassic intervals. Minor gaps in measurements exist only for the uppermost Brahmanian, lower part of the Upper Olenekian, and Middle Norian, and only sparse data are available for the Late Permian. These 219 measurements include 67 brachiopods and 114 conodont samples from the Tethyan realm as well as 37 brachiopods and one conodont sample from the mid-European Middle Triassic Muschelkalk Sea. The Late Permian/Lower Triassic interval is characterized by a steep 1.3 × 10−3 rise, from 0.7070 at the base of the Dzhulfian to 0.7082 in the late Olenekian, a rate of change comparable to that in the Cenozoic. In the mid-Triassic (Anisian and Ladinian), the isotope values fall to 0.7075, followed again by a rise to 0.7081 in the Middle/Late Norian. The 87Sr/86Sr values decline again in the Late Norian (Sevatian) and Rhaetian to 0.7076.The sharp rise in the 87Sr/86Sr values during the Late Permian/Early Triassic was coincident with widespread clastic sedimentation. Because of the paucity of tectonic uplifts, the enhanced erosion may have been due to intermittent humid phases, during mainly an arid interval, coupled with the absence of a dense protective land plant cover following the mass extinction during the latest Permian. The apex of the 87Sr/86Sr curve at the Olenekian/Anisian boundary coincides with cessation of the large-scale clastic sedimentation and also marks the final recovery of land vegetation, as indicated by the renewed onset of coal formation in the Middle Triassic. The rising 87Sr/86Sr values from the Middle Carnian to the Late Norian coincide with the uplift and erosion of the Cimmeride-Indosinian orogens marking the closure of the Palaeotethys. The subsequent Rhaetian decline that continues into Jurassic (Pliensbachian/Toarcian boundary), on the other hand, coincides with the opening of the Vardar Ocean and its eastern continuation in the Izmir-Ankara Ophiolitic Belt.Samples from the Upper Muschelkalk are more radiogenic than the global trend. This may reflect separation of the basin from the open ocean. Due to strong meteoric influx from a large land mass in the north, the Germanic Basin became increasing brackish up section in the north and east, but because of the high evaporation rates, the salt content was not much reduced in the southern and central basin where a rich, but increasingly endemic, marine fauna survived.  相似文献   
29.
The development of the boundary layer during a cold air outbreak in the FramStrait is documented by aircraft measurements. The convection was organisedinto roll vortices with aspect ratios increasing from 2.9 near the ice edgeto more than 6 at 100 km further downstream. This increase coincides with anincrease of the latent heat release in the cloud layer. The stability parameter-zi/L varies from about zero at the ice edge to 30 at a distance of 200 kmdownstream over open water where the satellite picture still shows cloudstreets. The increase is mainly due to the deepening of the boundary layer.The turbulent vertical sensible and latent heat fluxes near the surface amountto 400 W m-2 within a 300 km off-ice zone. 25% of the upward heat fluxin the subcloud layer is carried out by organised roll motions. Experimentswith a 2-dimensional non-hydrostatic model show a similar roll aspect ratio inthe first 50 km, but further downstream where condensational heating is moreimportant the modelled roll wavelengths are distinctly smaller than the observedones.  相似文献   
30.
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