Oxygen isotope fractionation between apatite-bound carbonate and water determined from controlled experiments with synthetic apatites precipitated at 10-37 °C     

Christophe Lécuyer  Vincent Balter  François Fourel  Romain Amiot  Olga Otero  Gérard Panczer  Rossana Martini 《Geochimica et cosmochimica acta》2010,74(7):2072-584

The oxygen isotope fractionation between the structural carbonate of inorganically precipitated hydroxyapatite (HAP) and water was determined in the range 10-37 °C. Values of 1000 ln α() are linearly correlated with inverse temperature (K) according to the following equation: 1000 ln α() = 25.19 (±0.53)·T⁻¹ − 56.47 (±1.81) (R² = 0.998). This fractionation equation has a slightly steeper slope than those already established between calcite and water ( [O’Neil et al., 1969] and [Kim and O’Neil, 1997]) even though measured fractionations are of comparable amplitude in the temperature range of these experimental studies. It is consequently observed that the oxygen isotope fractionation between apatite carbonate and phosphate increases from about 7.5‰ up to 9.1‰ with decreasing temperature from 37 °C to 10 °C. A compilation of δ¹⁸O values of both phosphate and carbonate from modern mammal teeth and bones confirms that both variables are linearly correlated, despite a significant scattering up to 3.5‰, with a slope close to 1 and an intercept corresponding to a 1000 ln α() value of 8.1‰. This apparent fractionation factor is slightly higher or close to the fractionation factor expected to be in the range 7-8‰ at the body temperature of mammals.  相似文献   

Springtime changes in snow chemistry lead to new insights into mercury methylation in the Arctic     

Catherine Larose  Aurélien Dommergue  Martine De Angelis  Bernard Averty  Nicolas Soumis  Christophe Ferrari 《Geochimica et cosmochimica acta》2010,74(22):6263-6275

Seasonal snow is an active media and an important climate factor that governs nutrient transfer in Arctic ecosystems. Since the snow stores and transforms nutrients and contaminants, it is of crucial importance to gain a better understanding of the dynamics of contaminant cycling within the snowpack and its subsequent release to catchments via meltwater. Over the course of a two-month field study in the spring of 2008, we collected snow and meltwater samples from a seasonal snowpack in Ny-Ålesund, Norway (78°56′N, 11°52′E), which were analyzed for major inorganic ions and some organic acids, as well as total, dissolved, bioavailable mercury (THg, DHg, BioHg, respectively) and monomethylmercury (MMHg) species. We observe a seasonal gradient for ion concentrations, with surface samples becoming less concentrated as the season progressed. A significant negative correlation between BioHg and MMHg was observed in the snowpack. MMHg was positively and significantly correlated to methanesulfonate concentrations. Based on these results, we propose a new model for aerobic methylation of mercury involving species in the dimethylsulfoniopropionate cycle.  相似文献   

Stable isotopes (2H, 18O and 13C) in groundwaters from the northwestern portion of the Guarani Aquifer System (Brazil)     

Didier Gastmans  Hung Kiang Chang  Ian Hutcheon 《Hydrogeology Journal》2010,18(6):1497-1513

The groundwater flow pattern of the western part of the Guarani Aquifer System (GAS), Brazil, is characterized by three regional recharge areas in the north, and a potentiometric divide in the south, which trends north–south approximately. Groundwater flow is radial from these regional recharge areas toward the center of Paraná Sedimentary Basin and toward the western outcrop areas at the border of the Pantanal Matogrossense, because of the potentiometric divide. The isotopic composition of GAS groundwater leads to understanding the paleoclimatic conditions in the regional recharge areas. The δ¹⁸O and δ²H isotopic ratios of GAS groundwaters vary, respectively, from –9.1 to –4.8‰ V-SMOW and –58.4 to –21.7‰ V-SMOW. In the recharge zones, enriched δ¹⁸O values are observed, while in the confined zone lighter δ¹⁸O values are observed. These suggest that climatic conditions were 10°C cooler than the present during the recharge of these waters. The δ¹³C ratios in groundwater of GAS, in the study area, vary from –19.5 to –6.5‰ VPDB, increasing along the regional flow lines toward the confined zone. This variation is related to dissolution of carbonate cement in the sandstones.  相似文献   

History Matching Geostatistical Model Realizations Using a Geometrical Domain Based Parameterization Technique     

Didier Yu Ding  Frédéric Roggero 《Mathematical Geosciences》2010,42(4):413-432

Reservoir characterization needs the integration of various data through history matching, especially dynamic information such as production or 4D seismic data. Although reservoir heterogeneities are commonly generated using geostatistical models, random realizations cannot generally match observed dynamic data. To constrain model realizations to reproduce measured dynamic data, an optimization procedure may be applied in an attempt to minimize an objective function, which quantifies the mismatch between real and simulated data. Such assisted history matching methods require a parameterization of the geostatistical model to allow the updating of an initial model realization. However, there are only a few parameterization methods available to update geostatistical models in a way consistent with the underlying geostatistical properties. This paper presents a local domain parameterization technique that updates geostatistical realizations using assisted history matching. This technique allows us to locally change model realizations through the variation of geometrical domains whose geometry and size can be easily controlled and parameterized. This approach provides a new way to parameterize geostatistical realizations in order to improve history matching efficiency.  相似文献   

The coherence of kilohertz quasi-periodic oscillations in the X-rays from accreting neutron stars   总被引：1，自引：0，他引：1  

Didier Barret  Jean-Francois Olive  M. Coleman Miller 《Monthly notices of the Royal Astronomical Society》2006,370(3):1140-1146

We study in a systematic way the quality factor of the lower and upper kilohertz quasi-periodic oscillations (kHz QPOs) in a sample of low-luminosity neutron star X-ray binaries, showing both QPOs varying over a wide frequency range. The sample includes 4U 1636−536, 4U 1608−522, 4U 1735−44, 4U 1728−34, 4U 1820−303 and 4U 0614+09. We find that all sources except 4U 0614+09 show evidence of a drop in the quality factor of their lower kHz QPOs at high frequency. For 4U 0614+09 only the rising part of the quality factor versus frequency curve has been sampled so far. At the same time, in all sources but 4U 1728−34, the quality factor of the upper kHz QPO increases all the way to the highest detectable frequencies. We show that the high-frequency behaviours of both the lower and the upper kHz QPO quality factors are consistent with what is expected if the drop is produced by the approach of an active oscillating region to the innermost stable circular orbit: the existence of which is a key feature of general relativity in the strong field regime. Within this interpretation, our results imply gravitational masses around 2 M_⊙ for the neutron stars in those systems.  相似文献   

Estimating water fluxes in the critical zone using water stable isotope approaches in the Groundnut and Ferlo basins of Senegal     

Djim M. L. Diongue  Christine Stumpp  Olivier Roupsard  Didier Orange  Frederic C. Do  Serigne Faye 《水文研究》2023,37(1):e14787

Sustainable water management in semi-arid agriculture practices requires quantitative knowledge of water fluxes within the soil-vegetation-atmosphere system. Therefore, we used stable-isotope approaches to evaluate evaporation (E_a), transpiration (T_a), and groundwater recharge (R) at sites in Senegal's Groundnut basin and Ferlo Valley pasture region during the pre-monsoon, monsoon, and post-monsoon seasons of 2021. The approaches were based upon (i) the isothermal evaporation model (for quantifying E_a); (ii) water and isotope mass balances (to partition E_a and T_a for groundnut and pasture); and (iii) the piston displacement method (for estimating R). E_a losses derived from the isothermal evaporation model corresponded primarily to Stage II evaporation, and ranged from 0.02 to 0.09 mm d⁻¹ in the Groundnut basin, versus 0.02–0.11 mm d⁻¹ in Ferlo. At the groundnut site, E_a rates ranged from 0.01 to 0.69 mm d⁻¹; T_a was in the range 0.55–2.29 mm d⁻¹; and the T_a/ET_a ratio was 74%–90%. At the pasture site, the ranges were 0.02–0.39 mm d⁻¹ for E_a; 0.9–1.69 mm d⁻¹ for T_a; and 62–90% for T_a/ET_a. The ET_a value derived for the groundnut site via the isotope approach was similar to those from eddy covariance measurements, and also to the results from the previous validated HYDRUS-1D model. However, the HYDRUS-1D model gave a lower T_a/ET_a ratio (23.2%). The computed groundwater recharge for the groundnut site amounted to less than 2% of the local annual precipitation. Recommendations are made regarding protocols for preventing changes to isotopic compositions of water in samples that are collected in remote arid regions, but must be analysed days later. The article ends with suggestions for studies to follow up on evidence that local aquifers are being recharged via preferential pathways.  相似文献   

Scientific detector workshop 2022 on-sky performance verification of near-infrared e−APD technology for wavefront sensing and demonstration of e−APD pixel performance to improve the sensitivity of large science focal planes     

Gert Finger  Frank Eisenhauer  Reinhard Genzel  Christopher Mandla  Ian Baker  Domingo Alvarez  Antonio Amorim  Wolfgang Brandner  Christophe Dupuy  Casey Deen  Derek Ives  Leander Mehrgan  Manfred Meyer  Karin Perraut  Guy Perrin  Jörg Stegmeier  Christian Straubmeier  Harald J. Weller  Vincent Isgar 《Astronomische Nachrichten》2023,344(8-9):e20230069

Near-infrared adaptive optics as well as fringe tracking for coherent beam combination in optical interferometry require the development of high-speed sensors. Because of the high speed, a large analog bandwidth is required. The short exposure times result in small signal levels which require noiseless detection. Both requirements cannot be met by state-of-the-art conventional CMOS technology of near-infrared arrays as has been attempted previously. A total of five near-infrared SAPHIRA 320 × 256 pixel HgCdTe e⁻APD arrays have been deployed in the wavefront sensors and in the fringe tracker of the VLTI instrument GRAVITY. The current limiting magnitude for coherent exposures with GRAVITY is m_k = 19, which is made possible with ADP technology. New avalanche photo-diode array (APD) developments since GRAVITY include the extension of the spectral sensitivity to the wavelength range from 0.8 to 2.5 μm. After GRAVITY a larger format array with 512 × 512 pixels has been developed for both AO applications at the ELT and for long integration times. Since dark currents of <10⁻³ e⁻/s have been demonstrated with 1Kx1K e⁻APD arrays and 2Kx2K e⁻APD arrays have already been developed, the possibilities and adaptations of e⁻APD technology to provide noiseless large-format science-grade arrays for long integration times are also discussed.  相似文献